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Cadmium Sulfate, Cadmium Sulphate, 10124‑36‑4

Cadmium Sulfate, Cadmium Sulphate, 10124‑36‑4

CADMIUM SULFATE 

1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Cadmium Sulfate
Chemical Name Cadmium(II) Sulfate
Other Names Cadmium Sulphate, Cadmium Sulfate Hydrate
CAS Number 10124-36-4
EC Number (EINECS) 233-331-6
HS Code 283329
Molecular Formula CdSO₄ (anhydrous) or CdSO₄·xH₂O (typically monohydrate or octahydrate)
Molecular Weight ~208.47 g/mol (anhydrous basis)
Purity ≥ 98–99% (industrial or analytical grade)
Appearance White crystalline solid
Odor Odorless
Physical State (20°C) Solid (crystalline)

2. CHEMICAL STRUCTURE

2.1. Molecular Structure

Cadmium sulfate is the sulfate salt of cadmium. Cadmium ions (Cd²⁺) and sulfate ions (SO₄²⁻) are present in a 1:1 ratio. The compound typically exists in anhydrous form or as hydrates (monohydrate, octahydrate). It is hygroscopic and readily absorbs moisture from the air. It is a highly toxic heavy metal salt.

Structural Formula:

                    CADMIUM SULFATE [CdSO₄]
                               |
                     Cd²⁺ - SO₄²⁻ Ionic Bonds
                               |
             +----------------+----------------+
             |                |                |
         Ionic Crystal       Hygroscopic       Toxic
         Structure           Property          Salt

2.2. Structural Properties

Parameter Value
Oxidation State Cd²⁺ (Cadmium +2)
Molecular Weight ~208.47 g/mol (anhydrous)
Hydration States Anhydrous, monohydrate, octahydrate
Appearance White crystalline solid
Density ~4.7 g/cm³ (anhydrous)
pH (aqueous solution) Slightly acidic
Crystal System Monoclinic (anhydrous)

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance White crystalline solid -
Odor Odorless -
Chemical Formula CdSO₄ -
Molecular Weight ~208.47 g/mol -
Density ~4.7 g/cm³ -
Melting Point Decomposes upon heating -
Solubility in Water High solubility -
Solubility in Acids Soluble -
Solubility in Ethanol Insoluble -
Hygroscopicity High Absorbs moisture from air
Stability Stable under normal conditions; sensitive to moisture -
pH (aqueous solution) Slightly acidic -
Thermal Decomposition Decomposes to cadmium oxide (CdO) -
Toxicity Highly toxic -

4. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Stable under normal conditions
Conditions to Avoid Moisture, high temperature, strong oxidizing agents
Incompatible Materials Strong bases, strong oxidizing agents, reducing agents
Hazardous Decomposition Products Cadmium oxide (CdO), sulfur dioxide (SO₂), sulfur trioxide (SO₃)
Hazardous Polymerization Will not occur
Hygroscopicity High; absorbs moisture from air
Photosensitivity Low

4.1. Chemical Reactions

Thermal Decomposition:

CdSO₄ → CdO + SO₃↑

Reaction with Alkali:

CdSO₄ + 2NaOH → Cd(OH)₂↓ + Na₂SO₄

Reaction with Sulfide:

CdSO₄ + Na₂S → CdS↓ + Na₂SO₄

5. APPLICATION AREAS

5.1. Electroplating and Surface Treatment

Application Function Details
Electroplating Corrosion-resistant coatings Cadmium plating for steel and iron components
Metal Surface Treatment Surface finishing Specialty coating applications
Aerospace Industry Corrosion protection Cadmium coatings for aircraft components

5.2. Pigments and Dyes

Application Function Details
Cadmium Pigments Colorant Cadmium yellow, cadmium red pigments
Specialty Paints High-temperature paints Cadmium-based pigments for industrial applications
Glass Coloring Colorant Yellow-orange glass coloring

5.3. Laboratory and Research

Application Function Details
Laboratory Reagent Cadmium chemistry research Used as a reagent in cadmium chemistry
Analytical Chemistry Standard preparation Calibration and analysis
Precursor Compound Starting material Synthesis of other cadmium compounds
Research Material Specialty research Various research applications

5.4. Batteries and Photovoltaics

Application Function Details
Nickel-Cadmium Batteries Electrode material Ni-Cd battery applications (declining due to toxicity)
Photovoltaic Cells Semiconductor material Thin-film solar cells (limited use)
Semiconductor Research Research material Specialty semiconductor studies

6. SECTOR SUITABILITY TABLE

Sector / Application Suitability Description
Textile Not Suitable No application area
Food Not Suitable Prohibited in food additives or food contact materials
Cosmetics Not Suitable Prohibited in cosmetic formulations under CLP/REACH
Metal / Surface Treatment Suitable Used in electroplating and coatings (restricted)
Ceramics / Glass Suitable Limited use in pigments and specialty glass
Laboratory / Research Suitable Used as reagent in cadmium chemistry (under strict control)
Electronics / Optics Suitable Limited use in batteries, photovoltaics, and semiconductors
Construction Chemicals Not Suitable No application area

7. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, well-ventilated area
Container Requirements Sealed, moisture-proof containers
Moisture Protection Store with desiccant; hygroscopic
Temperature Room temperature (15-25°C)
Shelf Life Approximately 2 years under proper conditions
Security Must be stored in secure, locked area due to toxicity
Stability Note Hygroscopic; may absorb moisture if exposed to humid air

8. PACKAGING OPTIONS

Packaging Type Quantity Material
Glass Bottle 10 g, 50 g, 100 g Amber glass with desiccant
Plastic Container 100 g, 500 g, 1 kg HDPE container, moisture-proof
Fiber Drum 5 kg, 10 kg, 25 kg PE-lined, moisture-proof
Steel Drum 25 kg, 50 kg Steel drum with inner liner

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) ~100-200 mg/kg (highly toxic)
Dermal Toxicity Toxic
Skin Irritation Irritant
Eye Irritation Severe irritant
Inhalation Highly toxic; may cause respiratory damage
Carcinogenicity Classified as carcinogenic (H350)
Mutagenicity Mutagenic potential
Reproductive Toxicity Reproductive toxicant
Chronic Effects Kidney damage, lung damage, bone damage (Itai-Itai disease)
Environmental Hazards Very toxic to aquatic life (H410)
Target Organs Kidneys, lungs, bones, liver

10. GHS CLASSIFICATION

Hazard Class Category H-Statement
Acute Toxicity (Oral) Category 3 H301: Toxic if swallowed
Carcinogenicity Category 1B H350: May cause cancer
Germ Cell Mutagenicity Category 2 H341: Suspected of causing genetic defects
Reproductive Toxicity Category 2 H361: Suspected of damaging fertility or the unborn child
Specific Target Organ Toxicity (Repeated Exposure) Category 1 H372: Causes damage to organs through prolonged or repeated exposure
Aquatic Toxicity (Acute) Category 1 H400: Very toxic to aquatic life
Aquatic Toxicity (Chronic) Category 1 H410: Very toxic to aquatic life with long-lasting effects

Signal Word: DANGER

Hazard Pictograms: GHS06 (Skull and Crossbones), GHS08 (Health Hazard), GHS09 (Environment)

11. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P260 Do not breathe dust
P264 Wash hands thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present
P308+P313 IF exposed or concerned: Get medical advice/attention
P391 Collect spillage
P501 Dispose of contents/container in accordance with local regulations

12. FIRST AID MEASURES

Route of Exposure Action to Be Taken
Inhalation Move to fresh air. If breathing difficulty occurs, administer oxygen. Seek immediate medical attention
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. Seek medical attention
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. Seek immediate medical attention
Ingestion Do not induce vomiting. Rinse mouth. Drink water. Seek immediate medical attention. Show this SDS to the attending physician

13. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Restricted; authorization required; SVHC candidate list
Turkey (KKDIK) Strictly regulated; authorization required
TSCA (USA) Registered; restricted
EINECS 233-331-6
Food / Cosmetics Not approved
RoHS Restricted (cadmium in electrical and electronic equipment)
REACH Annex XIV Subject to authorization
EU Directive 2011/65/EU (RoHS) Restricted
OSHA Regulated as highly toxic substance

14. OTHER NAMES AND SYNONYMS

  • Cadmium(II) Sulfate

  • Cadmium Sulphate

  • Cadmium Sulfate Hydrate

  • CdSO₄

15. QUICK REFERENCE TABLE

Property Value
CAS Number 10124-36-4
EC Number 233-331-6
HS Code 283329
Molecular Formula CdSO₄
Molecular Weight ~208.47 g/mol
Appearance White crystalline solid
Density ~4.7 g/cm³
Water Solubility High
Purity ≥ 98-99%
Hygroscopicity High
Toxicity Highly toxic, carcinogenic
GHS Signal Word DANGER

16. CRITICAL NOTICES AND BEST PRACTICES

CRITICAL NOTICES:

  1. Cadmium sulfate is highly toxic and carcinogenic. Must be handled with extreme care in controlled laboratory or industrial environments.

  2. Use in many regions is restricted due to environmental and health risks (REACH, RoHS, etc.).

  3. Must be stored in secure, locked areas with restricted access.

  4. Personal protective equipment (PPE) is mandatory: gloves, goggles, protective clothing, and respiratory protection.

  5. Environmental release is strictly prohibited (H410).

  6. Not approved for food or cosmetic applications.

  7. Disposal must be through licensed hazardous waste facilities.

BEST PRACTICE RECOMMENDATIONS:

Storage:

  • Store in a cool, dry, well-ventilated area

  • Use sealed, moisture-proof containers

  • Store in a locked, secure area with restricted access

  • Keep away from food and feed materials

Handling:

  • Use in well-ventilated areas (fume hood required)

  • Use appropriate PPE (gloves, goggles, protective clothing, respiratory protection)

  • Avoid dust formation

  • Wash hands thoroughly after handling

  • Do not eat, drink or smoke when handling

Waste Management:

  • Dispose in accordance with local, regional, and national regulations

  • Must be disposed of by licensed hazardous waste facilities

  • Do not discharge into water bodies

LEGAL DISCLAIMER

This Technical Data Sheet (TDS) is for informational purposes only and is prepared based on available technical data. Cadmium sulfate is a highly toxic and carcinogenic substance. The user is solely responsible for determining the suitability of the product for their specific application and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, waste, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Appropriate precautions must be taken during handling.

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