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Gallium Sulfate, Gallium Trisulfate, Gallium Sulfate Hydrate, 13494‑91‑2

Gallium Sulfate, Gallium Trisulfate, Gallium Sulfate Hydrate, 13494‑91‑2

GALLIUM SULFATE 

1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Gallium Sulfate
Chemical Name Gallium(III) Sulfate
Other Names Gallium Trisulfate, Gallium Sulfate Hydrate
CAS Number 13494-91-2
EC Number (EINECS) 236-815-5
HS Code 283429
Molecular Formula Ga₂(SO₄)₃
Molecular Weight ~452.0 g/mol
Purity ≥ 98 – 99.9% (analytical or rare metal purity)
Appearance White crystalline powder
Odor Odorless
Physical State (20°C) Solid (powder)

2. CHEMICAL STRUCTURE

2.1. Molecular Structure

Gallium sulfate is the sulfate salt of gallium. Gallium ions (Ga³⁺) and sulfate ions (SO₄²⁻) are present in a 2:3 ratio. The compound typically exists in anhydrous form, but hydrates are also available. It is hygroscopic and readily absorbs moisture from the air.

Structural Formula:

                    GALLIUM SULFATE [Ga₂(SO₄)₃]
                               |
                     Ga³⁺ - SO₄²⁻ Ionic Bonds
                               |
             +----------------+----------------+
             |                |                |
         Ionic Crystal       Hygroscopic       Acidic
         Structure           Property          Salt

2.2. Structural Properties

Parameter Value
Oxidation State Ga³⁺ (Gallium +3)
Molecular Weight ~452.0 g/mol
Hydration States Anhydrous and hydrate forms exist
Appearance White crystalline powder
Density ~3.0 g/cm³
pH (aqueous solution) Slightly acidic

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance White crystalline powder -
Odor Odorless -
Chemical Formula Ga₂(SO₄)₃ -
Molecular Weight ~452.0 g/mol -
Density ~3.0 g/cm³ -
Melting Point Decomposes upon heating -
Solubility in Water Soluble -
Solubility in Acids Soluble -
Solubility in Ethanol Slightly soluble -
Hygroscopicity High Absorbs moisture from air
Stability Stable under normal conditions; sensitive to moisture and light -
pH (aqueous solution) Slightly acidic -
Thermal Decomposition Decomposes to gallium oxide (Ga₂O₃) -

4. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Stable under normal conditions
Conditions to Avoid Moisture, high temperature, strong oxidizing agents
Incompatible Materials Strong bases, strong oxidizing agents, reducing agents
Hazardous Decomposition Products Gallium oxide (Ga₂O₃), sulfur dioxide (SO₂), sulfur trioxide (SO₃)
Hazardous Polymerization Will not occur
Hygroscopicity High; absorbs moisture from air
Photosensitivity Low

4.1. Chemical Reactions

Thermal Decomposition:

Ga₂(SO₄)₃ → Ga₂O₃ + 3SO₃↑

Reaction with Alkali:

Ga₂(SO₄)₃ + 6NaOH → 2Ga(OH)₃↓ + 3Na₂SO₄

5. APPLICATION AREAS

5.1. Semiconductors and Electronics

Application Function Details
GaAs Production Precursor Gallium arsenide semiconductor production
GaN Production Precursor Gallium nitride semiconductor production
Semiconductor Research Research material Development of new semiconductor materials
Optoelectronics Optical material LED, laser, and photodetector applications

5.2. Production of Gallium Compounds (Precursor)

Application Function Details
Gallium Oxide (Ga₂O₃) Production Precursor High-purity gallium oxide production
Gallium Nitride (GaN) Production Precursor Blue LEDs and high-power electronics
Gallium Arsenide (GaAs) Production Precursor High-frequency and optoelectronic applications
Mixed Metal Oxides Precursor Specialty mixed oxides

5.3. Advanced Ceramics and Specialty Glass

Application Function Details
Advanced Ceramics Performance enhancer Specialty ceramic components
Specialty Glass Optical additive Infrared and optical glasses
Refractory Materials Heat resistance High-temperature applications

5.4. Laboratory and Research

Application Function Details
Laboratory Reagent Gallium research Used as a reagent in gallium chemistry
Precursor Compound Starting material Synthesis of other gallium compounds
Advanced Materials Research Research material Development of new materials
Standard Preparation Reference material Calibration and analysis

6. SECTOR SUITABILITY TABLE

Sector / Application Suitability Description
Textile Not Suitable No application area
Food Not Suitable Prohibited in food additives or food contact materials
Cosmetics Not Suitable Prohibited in cosmetic formulations under CLP/REACH
Metal / Surface Treatment Suitable Can be used in specialty alloys and coatings
Ceramics / Glass Suitable Used in advanced ceramics and specialty glass production
Laboratory / Research Suitable Widely used as reagent in gallium chemistry
Electronics / Optics Suitable Critical use in semiconductors, optoelectronics, and photonics
Construction Chemicals Not Suitable No application area

7. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, well-ventilated area
Container Requirements Sealed, moisture-proof containers
Light Protection Protect from light
Moisture Protection Store with desiccant; hygroscopic
Temperature Room temperature (15-25°C)
Shelf Life Approximately 2 years under proper conditions
Stability Note Hygroscopic; may absorb moisture if exposed to humid air

8. PACKAGING OPTIONS

Packaging Type Quantity Material
Glass Bottle 10 g, 50 g, 100 g Amber glass with desiccant
Plastic Container 100 g, 500 g, 1 kg HDPE container, moisture-proof
Fiber Drum 5 kg, 10 kg, 25 kg PE-lined, moisture-proof

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 2,000 mg/kg (low toxicity)
Dermal Toxicity Low
Skin Irritation Mild irritant (H315)
Eye Irritation Mild to severe irritant (H319)
Inhalation Dust may cause respiratory irritation
Carcinogenicity Not classified as a carcinogen
Mutagenicity Not mutagenic
Chronic Effects May cause liver effects at high doses
Environmental Hazards Low to moderate toxicity to aquatic life

10. GHS CLASSIFICATION

Hazard Class Category H-Statement
Skin Irritation Category 2 H315: Causes skin irritation
Eye Irritation Category 2 H319: Causes serious eye irritation

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

11. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust
P264 Wash hands thoroughly after handling
P271 Use only in well-ventilated areas
P280 Wear protective gloves/eye protection/face protection
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present
P337+P313 If eye irritation persists: Get medical advice/attention
P501 Dispose of contents/container in accordance with local regulations

12. FIRST AID MEASURES

Route of Exposure Action to Be Taken
Inhalation Move to fresh air. If symptoms persist, seek medical attention
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention
Ingestion Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention

13. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Registered
Turkey (KKDIK) Compliance required
TSCA (USA) Registered
EINECS 236-815-5
Food / Cosmetics Not approved

14. OTHER NAMES AND SYNONYMS

  • Gallium(III) Sulfate

  • Gallium Trisulfate

  • Gallium Sulfate Hydrate

  • Ga₂(SO₄)₃

15. QUICK REFERENCE TABLE

Property Value
CAS Number 13494-91-2
EC Number 236-815-5
HS Code 283429
Molecular Formula Ga₂(SO₄)₃
Molecular Weight ~452.0 g/mol
Appearance White crystalline powder
Density ~3.0 g/cm³
Water Solubility Soluble
Purity ≥ 98-99.9%
Hygroscopicity High
GHS Signal Word WARNING

16. CRITICAL NOTICES AND BEST PRACTICES

CRITICAL NOTICES:

  1. Gallium sulfate is highly hygroscopic. Must be stored in moisture-proof containers with desiccant.

  2. Protect from light to prevent degradation.

  3. Decomposes at high temperatures to gallium oxide (Ga₂O₃), releasing sulfur oxides.

  4. Causes skin and eye irritation. Use appropriate personal protective equipment.

  5. Dust may cause respiratory irritation. Use in well-ventilated areas.

  6. Primarily used in research, semiconductor, optoelectronics, and photonics applications.

  7. Gallium compounds are important as precursors for critical semiconductor materials such as GaAs and GaN.

BEST PRACTICE RECOMMENDATIONS:

Storage:

  • Store in a cool, dry, well-ventilated area

  • Use sealed, moisture-proof containers with desiccant

  • Protect from light

  • Store at room temperature (15-25°C)

Handling:

  • Use in well-ventilated areas

  • Use dust mask, protective goggles, and gloves

  • Avoid dust formation

  • Wash hands after handling

  • Immediately reseal container after use

Waste Management:

  • Dispose in accordance with local regulations

  • Consider rare metal recovery for large quantities

LEGAL DISCLAIMER

This Technical Data Sheet (TDS) is for informational purposes only and is prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific application and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, waste, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Gallium sulfate is a specialty compound; appropriate precautions must be taken during handling.

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