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Liquid Paraffin, Paraffin Oil, White Mineral Oil, Light Liquid Paraffin, Polishing Oil, Mineral Oil, Paraffinic Oil, 8012-95-1, 8042-47-5

Liquid Paraffin, Paraffin Oil, White Mineral Oil, Light Liquid Paraffin, Polishing Oil, Mineral Oil, Paraffinic Oil, 8012-95-1, 8042-47-5

LIQUID PARAFFIN (WHITE MINERAL OIL)

SECTION 1: PRODUCT IDENTITY AND CHEMICAL IDENTIFICATION

Parameter Fully Refined Light Liquid Paraffin Semi-Refined Light Liquid Paraffin
Product Name White Mineral Oil (Light Liquid Paraffin) Light Liquid Paraffin (Mineral Oil)
Chemical Name Liquid Paraffin, White Mineral Oil, Paraffin Oil Light Liquid Paraffin, Mineral Oil Technical Grade
CAS Number 8042-47-5 8012-95-1
EC Number (EINECS) 232-455-8 232-384-2
Common Synonyms Liquid Paraffin BP/USP/IP, White Mineral Oil, Paraffin Oil Light Liquid Paraffin, Mineral Oil Technical Grade, Polishing Oil, Paraffinic Oil
Chemical Class Saturated aliphatic hydrocarbon mixture Saturated aliphatic hydrocarbon mixture
Source Petroleum refining (hydrogenation, distillation) Petroleum refining
Appearance Clear, colorless, odorless oily liquid Clear, colorless to slightly yellowish, may have slight technical odor
Purity Grade Pharmaceutical / Cosmetic (BP, USP, IP compliant) Cosmetic / Technical Grade

Note: Liquid paraffin is a highly refined mineral oil derived from petroleum. The main difference between the two grades lies in the degree of refining, purity, and compliance with pharmacopoeia standards. The fully refined grade (8042-47-5) is suitable for the most sensitive applications including pharmaceuticals, food contact, and premium cosmetics. The semi-refined grade (8012-95-1) is a cost-effective alternative for technical applications and general cosmetics where full pharmacopoeia compliance is not mandatory.

SECTION 2: CHEMICAL STRUCTURE

General Structure:

    CH₃—(CH₂)ₙ—CH₃

    n = 16-40 (C16-C40 range)

    Saturated Aliphatic Hydrocarbons
    (Paraffinic and Naphthenic Hydrocarbon Mixture)

Simplified Structure:

    Saturated Hydrocarbon Chains (C16-C40)

    Liquid Paraffin
    (Mineral Oil)
Parameter Description
Chemical Structure Saturated aliphatic hydrocarbons (paraffinic and naphthenic)
Carbon Chain Length C16 – C40 (predominantly)
Functional Groups None (fully saturated)
Odor Odorless (fully refined); slight odor (semi-refined)
Color Colorless (fully refined); slightly yellowish (semi-refined)

SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES

Property Fully Refined (8042-47-5) Semi-Refined (8012-95-1) Test Method / Note
Appearance Clear, colorless liquid Clear, colorless to slightly yellowish Visual
Odor Odorless May have slight technical odor Olfactometric
Density (20°C) 0.83 – 0.87 g/cm³ 0.82 – 0.86 g/cm³ ASTM D4052
Viscosity (40°C) 65 – 230 cSt (grade dependent) Lower viscosity range ASTM D445
Viscosity (100°C) 5 – 15 cSt Variable ASTM D445
Pour Point -15°C to -18°C -6°C to -9°C ASTM D97
Flash Point >170°C >150°C ASTM D93
Water Solubility Insoluble Insoluble General Method
Organic Solvent Solubility Soluble in chloroform and ether Soluble in organic solvents General Method
Aromatic Hydrocarbon Content None; highly refined Trace amounts may be present GC
Sulfur Content <2 ppm <10 ppm ASTM D4294
Color (Saybolt) +30 (minimum) +20 (minimum) ASTM D156
Acid Number ≤0.01 mg KOH/g ≤0.05 mg KOH/g ASTM D974
Saponification Value ≤0.5 mg KOH/g ≤1.0 mg KOH/g ASTM D94
Boiling Range 300-400°C 250-380°C -

SECTION 4: FUNCTIONAL PROPERTIES AND MECHANISM OF ACTION

Property Description
Emollient and Moisturizer Forms a thin, occlusive, lipophilic film on the skin surface. This film reduces transepidermal water loss (TEWL) providing moisturization and softening effects without leaving a greasy feel.
Carrier and Base Oil Acts as an excellent, inert, non-reactive solvent and carrier for active pharmaceutical ingredients, perfumes, and essential oils in ointments, creams, and emulsions.
Lubricant and Polish Provides a durable, high-gloss, water-repellent film on surfaces, making it ideal for furniture polishes, automotive detailing, and metal cleaning products.
Textile Auxiliary Used as a lubricant, softener, and finishing agent in textile and leather processing.
Laxative (Pharmaceutical Grade) When taken in regulated doses, acts as a lubricant laxative by coating stool and intestinal mucosa to facilitate bowel transit. This application is strictly limited to the fully refined, pharmacopoeia-compliant grade.
Mold Release Agent Facilitates easy release of products from molds in plastic, rubber, and food industries.
Rust Preventive Forms a protective film on metal surfaces, preventing corrosion and rusting.

SECTION 5: FULLY REFINED vs SEMI-REFINED COMPARISON

Property Fully Refined (8042-47-5) Semi-Refined (8012-95-1)
CAS Number 8042-47-5 8012-95-1
Purity Grade Pharmaceutical / Cosmetic Cosmetic / Technical
Pharmacopoeia Compliance BP, USP, IP None
FDA Approval (21 CFR 172.878) Yes No
Color Colorless Slightly yellowish
Odor Odorless Slight technical odor
Pour Point -15°C to -18°C -6°C to -9°C
Aromatic Content None Trace amounts
Sulfur Content <2 ppm <10 ppm
Main Applications Pharmaceuticals, food contact, baby oil, premium cosmetics Textile, polishing, industrial lubrication, general cosmetics
Cost High Low-Moderate

SECTION 6: INDUSTRY APPLICATIONS AND SUITABILITY

Industry / Application Fully Refined (8042-47-5) Semi-Refined (8012-95-1)
Cosmetics & Personal Care Full Compatibility (baby oil, moisturizers, cream base) Compatible (general creams, some lotions)
Pharmaceutical Full Compatibility (ointment base, laxative, emulsion carrier) Not Suitable (lack of pharmacopoeia certification)
Food Packaging (Indirect Contact) Full Compatibility (FDA 21 CFR 172.878 approved) Not Recommended
Textile & Leather Full Compatibility (softener, finishing additive) Full Compatibility (lubricant, softener)
Veterinary & Agriculture Full Compatibility (udder cream, topical sprays) Compatible (technical applications)
Cleaning & Polishing Compatible (premium polishes) Full Compatibility (furniture polish, metal cleaner)
Plastics & Rubber Partial Compatibility (mold release) Compatible (plasticizer, processing aid)
Industrial Lubrication Partial Compatibility (light lubrication) Compatible (rust preventive, general lubrication)
Food (Direct Contact) Not Suitable Not Suitable
Oil & Gas Partial Compatibility Compatible

SECTION 7: KEY DIFFERENTIATOR: POUR POINT AND LOW TEMPERATURE PERFORMANCE

The pour point defines the lowest temperature at which the oil remains fluid. This is critical for outdoor or low-temperature applications.

Property Fully Refined (8042-47-5) Semi-Refined (8012-95-1)
Pour Point -15°C to -18°C -6°C to -9°C
Low Temperature Behavior Remains fluid in cold conditions; suitable for outdoor use Higher risk of freezing or becoming excessively viscous in winter
Preferred Applications Veterinary products, outdoor textile applications, pharmaceutical ointments requiring easy spreadability Cosmetics and polishing applications used at room temperature

SECTION 8: ADVANTAGES AND DISADVANTAGES COMPARISON

Property Fully Refined (8042-47-5) Semi-Refined (8012-95-1)
Purity & Safety Very High; pharmacopoeia compliant Moderate to High; technical grade
Regulatory Documentation BP/USP/IP certificates, FDA 21 CFR 172.878 available Standard TDS/MSDS; certificates not guaranteed
Cost Higher (certified, premium) Lower (economical, technical)
Cold Weather Performance Excellent (low pour point) Moderate (freezing risk)
Color and Odor Excellent; colorless and odorless Good; slight color/odor may be present
ERP Alias Management Clear; "Liquid Paraffin BP/USP/IP" Risk of confusion; should be defined as "Mineral Oil Technical Grade"

SECTION 9: QUALITY SPECIFICATIONS

Parameter Fully Refined (Pharmaceutical/Cosmetic) Semi-Refined (Technical) Test Method
Appearance Clear, colorless liquid Clear, slightly yellowish liquid Visual
Odor Odorless Slight characteristic Olfactometric
Density (20°C) 0.83 – 0.87 g/cm³ 0.82 – 0.86 g/cm³ ASTM D4052
Viscosity (40°C) 65 – 230 cSt Variable ASTM D445
Pour Point -15°C to -18°C -6°C to -9°C ASTM D97
Flash Point ≥170°C ≥150°C ASTM D93
Color (Saybolt) ≥+30 ≥+20 ASTM D156
Acid Number ≤0.01 mg KOH/g ≤0.05 mg KOH/g ASTM D974
Saponification Value ≤0.5 mg KOH/g ≤1.0 mg KOH/g ASTM D94
Sulfur Content ≤2 ppm ≤10 ppm ASTM D4294
Aromatic Content ≤0.1% ≤0.5% GC
Heavy Metals (Pb) ≤1 ppm ≤5 ppm ICP-MS
Microbiological Purity TAMC ≤10² CFU/g - USP <61>

SECTION 10: SAFETY AND HEALTH INFORMATION

GHS Classification:

Hazard Class Category
Not classified as hazardous substance

Signal Word: None

Hazard Pictograms: None

Hazard Statements: None

Precautionary Statements:

Code Statement
P264 Wash hands thoroughly after handling
P280 Wear protective gloves
P302+P352 IF ON SKIN: Wash with plenty of soap and water

Toxicological Information:

Parameter Value
Acute Oral Toxicity (LD50, Rat) >5000 mg/kg (very low toxicity)
Acute Dermal Toxicity (LD50, Rabbit) >2000 mg/kg (low toxicity)
Skin Irritation Mild irritant (prolonged contact)
Eye Irritation Mild irritant
Inhalation Low risk (low vapor pressure)
Carcinogenicity Not classified (IARC, NTP)
Mutagenicity Not mutagenic
Aspiration Hazard Yes (liquid form)

SECTION 11: GHS CLASSIFICATION AND LABELING

GHS Classification (in accordance with 1272/2008/EC):

Hazard Class Category H-Statement
Not classified as hazardous substance

Signal Word: None (Not classified as hazardous)

Hazard Pictograms: None

NFPA 704 Hazard Classification:

Health Flammability Reactivity Special
0 1 0 -
(Minimal health hazard) (Combustible) (Stable) (None)

SECTION 12: FIRST AID MEASURES

Route of Exposure Action
Inhalation Vapor not expected. If respiratory discomfort occurs, move to fresh air.
Skin Contact Wash with plenty of soap and water. Avoid prolonged contact.
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Seek medical attention if irritation persists.
Ingestion Do NOT induce vomiting. Seek medical attention. Aspiration risk.
Aspiration Aspiration pneumonitis risk if swallowed. Seek immediate medical attention.

SECTION 13: FIREFIGHTING MEASURES

Parameter Information
Fire Hazard Combustible liquid (Flash Point >150°C)
Flash Point >150°C (Fully Refined); >150°C (Semi-Refined)
Fire-Related Hazards CO, CO₂, unburned hydrocarbons
Suitable Extinguishing Media Water mist, CO₂, dry chemical powder, foam
Unsuitable Extinguishing Media Water jet (may spread burning liquid)
Special Protective Equipment SCBA, full protective clothing

SECTION 14: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Store in a cool (<30°C), dry, well-ventilated area; protect from direct sunlight and heat sources.
Temperature Limits 15-30°C (ideal); do not exceed 30°C
Humidity Low humidity environment
Container Requirements Tightly closed, clean containers (HDPE, stainless steel, lined steel)
Incompatible Materials Strong oxidizing agents, ignition sources
Shelf Life 48-60 months (under proper storage conditions)
Signs of Degradation Darkening color, odor change, cloudiness

SECTION 15: PACKAGING OPTIONS

Packaging Type Quantity / Capacity Material Application Area
HDPE Drum 25 kg, 50 kg, 200 kg HDPE Pharmaceutical, cosmetic, food
Metal Drum (Lined) 200 kg Lined steel Industrial, bulk supply
IBC Container 500 kg, 1000 kg HDPE Large-scale industrial supply
Glass Bottle 1 L, 5 L, 10 L Amber glass Laboratory, high purity
Plastic Bottle 1 L, 5 L, 10 L HDPE Retail, laboratory
Flexibag 1000 kg PE Bulk transport

SECTION 16: TRANSPORTATION INFORMATION

Parameter Information
UN Number Not applicable (not classified as dangerous substance)
Hazard Class Not applicable
Packing Group Not applicable
ADR/RID Not classified as dangerous goods
IMDG Code Not marine pollutant
IATA (Air) Not classified as dangerous goods; can be transported by air
Transport Temperature Ambient temperature; protect from heat
Transport Precautions Protect from leakage; keep away from ignition sources
Marine Pollutant No

SECTION 17: REGULATORY STATUS

Region / Authority Fully Refined (8042-47-5) Semi-Refined (8012-95-1)
USA (FDA) GRAS (21 CFR 172.878) Not approved
USA (USP/NF) Official monograph None
European Pharmacopoeia Official monograph None
British Pharmacopoeia Official monograph None
Indian Pharmacopoeia Official monograph None
Turkey Approved as pharmaceutical, cosmetic and food ingredient Approved as cosmetic and industrial ingredient
REACH Registered Registered
TSCA (USA) Listed Listed
California (Prop 65) Not listed Not listed
Halal Yes (with certification) Yes
Kosher Yes (with certification) Evaluated
Vegan Yes (mineral-derived) Yes (mineral-derived)

SECTION 18: OTHER NAMES AND SYNONYMS

Type CAS 8042-47-5 CAS 8012-95-1
Turkish Names Likit Parafin, Beyaz Mineral Yağ, Parafin Yağı Hafif Likit Parafin, Mineral Yağ Teknik Sınıf
English Names Liquid Paraffin, White Mineral Oil, Paraffin Oil Light Liquid Paraffin, Mineral Oil Technical Grade
Pharmaceutical Names Liquid Paraffin BP/USP/IP, White Oil -
Trade Marks Marcol, Primol, Blandol Drakeol, Carnation, Krystal
INCI Name Mineral Oil Mineral Oil
CAS Number 8042-47-5 8012-95-1
EC Number 232-455-8 232-384-2
HS Code 2710.19 2710.19

SECTION 19: QUICK REFERENCE AND SELECTION GUIDE

Application Requirement Recommended Product Recommended CAS
BP/USP/IP certification required Fully Refined Light Liquid Paraffin 8042-47-5
Pharmaceutical or food contact use Fully Refined Light Liquid Paraffin 8042-47-5
Premium, odorless baby oil or cosmetics Fully Refined Light Liquid Paraffin 8042-47-5
Outdoor or cold weather application Fully Refined Light Liquid Paraffin 8042-47-5
General cosmetics (room temperature) Semi-Refined Light Liquid Paraffin 8012-95-1
Cost-sensitive polishing or cleaning agent Semi-Refined Light Liquid Paraffin 8012-95-1
Industrial lubrication or textile auxiliary Semi-Refined Light Liquid Paraffin 8012-95-1

SECTION 20: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  1. CAS Selection is Critical: 8042-47-5 (Fully Refined) is for pharmaceutical, food contact, and premium cosmetic applications. 8012-95-1 (Semi-Refined) is for technical and general cosmetic applications. Incorrect CAS selection leads to regulatory non-compliance and product quality issues.

  2. Pour Point Difference: Fully refined (-15°C to -18°C) is superior to semi-refined (-6°C to -9°C) in low-temperature performance. Use fully refined for cold weather or outdoor applications.

  3. Aspiration Risk: Aspiration pneumonitis risk if swallowed. Do not induce vomiting and seek immediate medical attention.

  4. Food Use: Only fully refined (8042-47-5) is approved for indirect food contact under FDA 21 CFR 172.878. Semi-refined (8012-95-1) is not suitable for food applications.

  5. Pharmacopoeia Compliance: Only fully refined (8042-47-5) complies with BP, USP, and IP pharmacopoeias. Pharmaceutical applications must use this grade.

  6. Oxidation: Prolonged air exposure may cause oxidation; antioxidants may be added.

BEST PRACTICE RECOMMENDATIONS:

  1. Correct CAS Selection: Choose the correct CAS based on application requirements. Use 8042-47-5 for pharmaceutical/food; 8012-95-1 for technical/general cosmetic.

  2. Cold Weather Applications: For outdoor or low-temperature applications, use fully refined (8042-47-5) (low pour point).

  3. Storage: Store in a cool (<30°C), dry, well-ventilated area. Keep containers tightly closed to prevent oxidation.

  4. Mixing: Mix at 40-50°C in formulations; avoid high temperatures (oxidation).

  5. Compatibility: Compatible with most oils, esters, and organic ingredients. Does not mix with water; requires emulsifier for emulsion.

  6. Personal Protective Equipment: Nitrile gloves, safety goggles for prolonged contact or large quantities.

  7. Hygiene: Wash hands thoroughly after handling.

  8. Quality Control: Regularly perform pharmacopoeia tests (fully refined), density, viscosity, pour point, color, acid number tests.

LEGAL DISCLAIMER:

The information provided in this document is based on our current knowledge and experience and is presented in good faith. However, as all conditions of use are beyond our control, it does not constitute a binding specification or guarantee. This Technical Data Sheet is for informational purposes only. Users are responsible for testing suitability for their own applications and for complying with all local, regional, and national regulations. For complete safety, storage, use, handling, waste, and regulatory compliance information, please refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier. Liquid paraffin is a widely used ingredient in pharmaceutical, cosmetic, and industrial applications; aspiration risk exists if swallowed. Medical use should be under the supervision of a healthcare professional.

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