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Dysprosium Nitrate Hexahydrate, Dysprosium Nitrate Hydrate, Dysprosium Trinitrate Hexahydrate, 35725‑30‑5

Dysprosium Nitrate Hexahydrate, Dysprosium Nitrate Hydrate, Dysprosium Trinitrate Hexahydrate, 35725‑30‑5

DYSPROSIUM NITRATE HEXAHYDRATE (DYSPROSIUM(III) NITRATE) 

Chemical Name: Dysprosium(III) Nitrate Hexahydrate
CAS Number: 35725-30-5
EC Number: 609-062-9
UN Number: 1477 (Oxidizing substance)
Customs Tariff Code: 2846.90.00.00.19
HS Code: 283429

1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Description
Chemical Name (IUPAC) Dysprosium(III) nitrate hexahydrate
Other Names Dysprosium Nitrate, Dysprosium Trinitrate Hexahydrate, Dysprosium Nitrate Hydrate
CAS Number 35725-30-5
EC Number (EINECS) 609-062-9
Molecular Formula Dy(NO₃)₃·6H₂O
Molecular Weight 438.52 g/mol
Chemical Class Inorganic nitrate / Rare earth metal nitrate
Appearance Light yellow-green crystalline solid
Odor Odorless
Crystal Structure Monoclinic

CHEMICAL STRUCTURE AND DESCRIPTION:

Dysprosium Nitrate Hexahydrate (Dy(NO₃)₃·6H₂O) is the nitrate salt of dysprosium in the +3 oxidation state, containing six molecules of water of crystallization. The compound features dysprosium ions coordinated by nitrate groups and water molecules. It is highly soluble in water and ethanol. The compound is highly hygroscopic and must be stored in airtight containers. Dysprosium compounds are critical for magnetic alloys (especially Nd-Fe-B magnets with dysprosium addition for temperature stability), optical applications, and advanced ceramic materials.

Structural Features:

  • Hexahydrate form (6 water molecules)

  • Highly water-soluble

  • Light yellow-green appearance

  • Highly hygroscopic

  • Strong oxidizing properties (UN 1477)

  • High magnetic susceptibility (paramagnetic)

2. PHYSICAL AND CHEMICAL PROPERTIES

Property Value
Molecular Formula Dy(NO₃)₃·6H₂O
Molecular Weight 438.52 g/mol
Appearance Light yellow-green crystalline solid
Odor Odorless
Density ~2.6 g/cm³
Melting Point ~60°C (decomposes)
Boiling Point Decomposes before boiling
Solubility in Water Highly soluble
Solubility in Ethanol Soluble
pH (Aqueous Solution) ~4-5 (5% solution)
Hygroscopicity Highly hygroscopic
Crystal Structure Monoclinic
Oxidizing Properties Strong oxidizer (UN 1477)
Magnetic Properties Paramagnetic (high magnetic moment)
Thermal Decomposition Decomposes to Dy₂O₃ at elevated temperatures

Dysprosium Nitrate Hexahydrate is a light yellow-green, highly hygroscopic crystalline solid with a molecular weight of 438.52 g/mol. It is highly soluble in water and ethanol. The compound is a strong oxidizer and must be stored away from combustible materials. Dysprosium compounds exhibit high magnetic susceptibility and are critical for temperature-stable permanent magnets.

3. SOLUBILITY PROFILE

Solvent Solubility Conditions
Water Highly soluble All temperatures
Ethanol Soluble Room temperature
Methanol Soluble -
Acetone Slightly soluble -
Organic Solvents Limited -

Dysprosium Nitrate is highly soluble in water and ethanol. This property makes it an ideal precursor for aqueous solution synthesis, precipitation reactions, and various material processing applications.

4. CHEMICAL PROPERTIES AND REACTIONS

Property Description
Chemical Class Inorganic nitrate / Rare earth metal nitrate
Oxidation State Dy³⁺ (+3)
Oxidizing Properties Strong oxidizer; supports combustion
Hygroscopicity Highly hygroscopic
Thermal Decomposition Decomposes to Dy₂O₃ + NO₂ + O₂
Hydrolysis Slight hydrolysis in aqueous solution
Precursor Reactions Used for oxide, hydroxide, and carbonate precipitation

Dysprosium Nitrate is a strong oxidizer and can support combustion when in contact with combustible materials. Its high solubility makes it an ideal precursor for the preparation of other dysprosium compounds via precipitation reactions. Upon heating, it decomposes to dysprosium oxide (Dy₂O₃) with the release of nitrogen dioxide (NO₂) and oxygen.

Key Chemical Reactions:

Synthesis (Acid Dissolution):
Dy₂O₃ + 6HNO₃ → 2Dy(NO₃)₃ + 3H₂O

Thermal Decomposition:
4Dy(NO₃)₃ → 2Dy₂O₃ + 12NO₂↑ + 3O₂↑

Hydroxide Precipitation:
Dy(NO₃)₃ + 3NaOH → Dy(OH)₃ ↓ + 3NaNO₃

Oxalate Precipitation:
2Dy(NO₃)₃ + 3H₂C₂O₄ → Dy₂(C₂O₄)₃ ↓ + 6HNO₃

5. SPECIFICATIONS (HIGH PURITY)

Parameter Value
Purity (Dy(NO₃)₃·6H₂O) ≥ 99.9% (rare earth purity)
Appearance Light yellow-green crystalline solid
Solubility (5% aq.) Clear solution
Other Rare Earth Elements ≤ 0.1%
Iron (Fe) ≤ 0.001%
Calcium (Ca) ≤ 0.001%
Magnesium (Mg) ≤ 0.001%
Chloride (Cl) ≤ 0.005%
Sulfate (SO₄) ≤ 0.005%
Shelf Life ~2 years (under proper storage)

Dysprosium Nitrate Hexahydrate is available in high purity grades (≥ 99.9% rare earth purity) for research, optical, and electronic applications.

6. APPLICATIONS AND INDUSTRIAL USES

6.1. Magnetic Materials and Alloys (Most Important Application)

Application Description
Nd-Fe-B Magnet Additive Dysprosium addition improves high-temperature stability and coercivity
Heavy Rare Earth Source Precursor for dysprosium metal and alloy production
Magnetic Refrigeration Used in magnetocaloric materials research

Dysprosium compounds are critical for high-performance permanent magnets. Dysprosium is added to Nd-Fe-B magnets to improve temperature stability and coercivity, making them suitable for electric vehicle motors and wind turbine generators operating at elevated temperatures.

6.2. Optical and Glass Applications

Application Description
Special Optical Glasses Used in glass formulations for optical properties
Phosphor Materials Used in phosphor and luminescent material synthesis
Laser Materials Precursor for dysprosium-doped laser crystals

6.3. Advanced Ceramics

Application Description
Ceramic Pigments Used in ceramic pigment formulations
High-Temperature Ceramics Advanced ceramic material production
Refractory Materials High-temperature applications

6.4. Catalyst and Chemical Synthesis

Application Description
Catalyst Precursor Used in catalyst synthesis
Chemical Reagent Laboratory reagent for rare earth chemistry research
Organic Synthesis Used as a Lewis acid catalyst

6.5. Research and Laboratory Applications

Application Description
Analytical Reagent Rare earth element analysis
Coordination Chemistry Model compound for lanthanide coordination studies
Materials Science Precursor for advanced materials and nanomaterials

7. SECTOR SUITABILITY TABLE

Sector / Application Suitability Description
Textile Not Suitable No application area
Food Prohibited Not permitted as food additive or for food contact materials
Cosmetics Prohibited Not permitted in cosmetic formulations under CLP/REACH
Metal / Surface Treatment Suitable Used in rare earth alloys and coatings
Ceramics / Glass Suitable Used in specialty glass and advanced ceramic production
Laboratory / Research Suitable Widely used as reagent in rare earth chemistry
Electronics / Magnetic Suitable Used in magnetic alloys and electronic materials
Construction Chemicals Not Suitable No application area

8. COMMON NAMES

  • Dysprosium nitrate salt

  • Light yellow-green crystalline powder

  • Rare earth nitrate

  • Dysprosium trinitrate

  • Magnetic alloy precursor

9. PRODUCTION PROCESS

Stage Description
Starting Material Dysprosium oxide (Dy₂O₃) or dysprosium carbonate
Acid Dissolution Dissolving dysprosium oxide or carbonate in nitric acid
Reaction Dy₂O₃ + 6HNO₃ → 2Dy(NO₃)₃ + 3H₂O
Concentration Evaporation to concentrate the solution
Crystallization Controlled cooling crystallization
Filtration Separation of crystals from mother liquor
Washing Washing to remove impurities
Drying Controlled drying to obtain hexahydrate form
Packaging Packaging in airtight containers

Reaction Equation:
Dy₂O₃ + 6HNO₃ → 2Dy(NO₃)₃ + 3H₂O

Production Types: High purity grades (hexahydrate form)

Major Producing Countries: China, United States, Japan

Commercial Purity: 99.9% and above (rare earth purity)

10. SAFETY AND TOXICOLOGY

Parameter Value
GHS Classification GHS03 (Oxidizer), GHS07 (Warning)
Hazard Statements H272 (May intensify fire; oxidizer), H302 (Harmful if swallowed)
Precautionary Statements P210, P220, P221, P280
Signal Word Danger
UN Number 1477 (Nitrates, inorganic, n.o.s.)
Hazard Class 5.1 (Oxidizing substances)
Packing Group II
Carcinogenicity Not classified
Reproductive Toxicity Not classified

SPECIAL WARNINGS: Dysprosium Nitrate is classified as a strong oxidizer (UN 1477) . It may intensify fire when in contact with combustible materials. Harmful if swallowed (H302) . The product is for research use only; not for therapeutic or food applications.

11. TRANSPORT INFORMATION

Parameter Information
UN Number 1477
Hazard Class 5.1 (Oxidizing substances)
Packing Group II
Proper Shipping Name Nitrates, inorganic, n.o.s. (Dysprosium nitrate)
Marine Pollutant Yes
ADR/RID Label 5.1
IMDG / IATA Oxidizing substance

Dysprosium Nitrate is classified as an oxidizing substance (UN 1477, Class 5.1) . Transport must be conducted away from combustible and flammable materials.

12. REGULATORY INFORMATION

Region Status
EU REACH registered
Turkey (KKDİK) Mandatory compliance; registration required
USA (TSCA) Listed
EINECS 609-062-9
Customs Tariff Code 2846.90.00.00.19
HS Code 283429

Dysprosium Nitrate is registered in all major industrial markets. KKDİK registration is required for use in Turkey.

13. STORAGE AND HANDLING

Parameter Information
Storage Conditions Cool, dry, well-ventilated area; away from heat and direct sunlight
Container Requirements Airtight, moisture-proof containers
Special Storage Store separately from combustible materials, reducing agents, and organic substances
Materials to Avoid Reducing agents, combustible materials, organic substances, moisture
Shelf Life ~2 years (under proper storage)
Hygroscopicity Highly hygroscopic
Packaging Options 100 g, 500 g, 1 kg, 5 kg, 25 kg

Handling Notes:

  • CRITICAL: This compound is a strong oxidizer (UN 1477). Keep away from combustible materials .

  • Avoid dust formation and inhalation

  • Avoid skin and eye contact (use protective gloves and safety goggles)

  • Use in well-ventilated areas

  • Store in airtight containers away from moisture

  • Separate from reducing agents, organic substances, and flammable materials

  • Protect from light

  • Due to highly hygroscopic nature, handle in dry conditions

14. FIRE-FIGHTING MEASURES

Parameter Information
Fire Hazard Not flammable, but supports combustion (oxidizer)
Extinguishing Media Water spray, CO₂, dry chemical powder
Special Hazards May intensify fire; thermal decomposition releases toxic nitrogen oxides
Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing
Decomposition Products Nitrogen oxides (NOx), dysprosium oxides

Dysprosium Nitrate is not flammable but is a strong oxidizer that may intensify fire when in contact with combustible materials . Thermal decomposition may release toxic nitrogen oxides .

15. ACCIDENTAL RELEASE MEASURES

Parameter Information
Personal Protection Wear appropriate PPE (dust mask, safety goggles, protective clothing, gloves)
Ventilation Increase ventilation
Containment Prevent dust dispersion; contain spill
Cleaning Methods Carefully sweep or vacuum; place in appropriate disposal container
Environmental Precautions Prevent entry into drains, sewers, and water bodies
Waste Disposal Dispose according to local regulations

In case of spillage, appropriate personal protective equipment must be worn. Due to its oxidizing nature, avoid contact with combustible materials. Clean up using dry methods.

16. FIRST AID MEASURES

Exposure Route Action
Inhalation Move person to fresh air. If respiratory irritation persists, seek medical attention.
Skin Contact Wash with plenty of water and soap; remove contaminated clothing. If irritation persists, seek medical attention.
Eye Contact Rinse immediately with plenty of water for at least 15 minutes. Remove contact lenses if present. Seek medical attention.
Ingestion Rinse mouth with water. Do NOT induce vomiting. Seek medical attention immediately.

Special Notes:

  • Nitrate salts can cause methemoglobinemia in cases of severe ingestion

  • Medical personnel should be informed about nitrate salt exposure

  • In case of ingestion, do not induce vomiting due to possible aspiration risk

17. RAW MATERIALS AND DOWNSTREAM PRODUCTS

17.1. Raw Materials (Upstream)

Raw Material Description
Monazite Sand Rare earth element ore containing dysprosium
Bastnäsite Rare earth carbonate mineral
Dysprosium Oxide (Dy₂O₃) Starting material for acid dissolution
Nitric Acid (HNO₃) Acid source

17.2. Downstream Products

Product Application
Dysprosium Oxide (Dy₂O₃) Produced by thermal decomposition
Dysprosium Metal Nd-Fe-B magnets, high-temperature alloys
Dysprosium-Doped Materials Phosphors, laser materials
Magnetic Alloys High-temperature stable permanent magnets

18. QUALITY CONTROL PARAMETERS

Parameter Analytical Method Description
Purity Titration / ICP Complexometric titration or ICP analysis
Dysprosium Content Gravimetric / ICP Determined as Dy₂O₃
Nitrate Content Ion Chromatography Nitrate ion determination
Rare Earth Impurities ICP-MS / ICP-OES Detection of other lanthanides
Metal Impurities ICP-MS / ICP-OES Fe, Ca, Mg, Na, Zn, Cu, etc.
pH (Aqueous Solution) pH Meter ~4-5 (5% solution)
Moisture Content Karl Fischer Water content determination
Insoluble Matter Gravimetric Filtration and weighing
Appearance Visual Light yellow-green crystalline solid

19. SUMMARY AND CRITICAL WARNINGS

SUMMARY:

Dysprosium Nitrate Hexahydrate (Dy(NO₃)₃·6H₂O, CAS 35725-30-5) is a light yellow-green, highly hygroscopic crystalline solid with a molecular weight of 438.52 g/mol. It is highly soluble in water and ethanol. Thermal decomposition yields dysprosium oxide (Dy₂O₃).

Its most important application is as a precursor for dysprosium compounds used in high-performance magnetic materials. Dysprosium is critical in Nd-Fe-B magnets for improving high-temperature stability and coercivity for electric vehicle motors and wind turbine generators . It is also used in advanced ceramicsspecialty glassesoptical materials, and as a laboratory reagent for rare earth chemistry research.

The compound is classified as a strong oxidizer (UN 1477, Class 5.1) . It may intensify fire when in contact with combustible materials. It is harmful if swallowed (H302) . Due to its highly hygroscopic nature, it must be stored in airtight containers away from moisture and away from combustible and reducing agents. Shelf life is approximately 2 years under proper storage conditions.

Key Properties:

Property Value
Appearance Light yellow-green crystalline solid
Chemical Formula Dy(NO₃)₃·6H₂O
Molecular Weight 438.52 g/mol
CAS Number 35725-30-5
EC Number 609-062-9
Water Solubility Highly soluble
Hygroscopicity Highly hygroscopic
Primary Use Magnetic materials, research

Major Application Areas:

Sector Applications
Electronics / Magnetic Nd-Fe-B magnets, magnetic alloys
Ceramics / Glass Advanced ceramics, optical glasses
Laboratory / Research Reagent, material synthesis
Catalysis Catalyst precursor

Key Safety Points:

  • OXIDIZER: UN 1477, Class 5.1, Packing Group II

  • OXIDIZER: H272 (May intensify fire; oxidizer)

  • HARMFUL: H302 (Harmful if swallowed)

  • HYGROSCOPIC: Must be stored in airtight containers

  • STORAGE: Cool, dry, away from combustibles

  • PROTECTIVE EQUIPMENT: Gloves, safety goggles, dust mask

CRITICAL WARNINGS:

  1. STRONG OXIDIZER (UN 1477): Dysprosium Nitrate is classified as a strong oxidizer (UN 1477, Class 5.1). It may intensify fire when in contact with combustible materials . Store separately from reducing agents, organic substances, and flammable materials.

  2. HIGH SOLUBILITY: With excellent water solubility, Dysprosium Nitrate is ideal for aqueous processing, precipitation reactions, and material synthesis.

  3. HIGHLY HYGROSCOPIC: Dysprosium Nitrate is highly hygroscopic. It must be stored in airtight containers and handled in dry conditions .

  4. MAGNETIC APPLICATIONS: Dysprosium is critical for high-performance permanent magnets, particularly in Nd-Fe-B magnets for electric vehicle motors and wind turbine generators where high-temperature stability is required.

  5. CUSTOMS CLASSIFICATION: The correct customs tariff code is 2846.90.00.00.19 (HS Code: 283429).

  6. REGULATORY COMPLIANCE: REACH, KKDİK, and TSCA registration requirements apply. Not permitted for food, cosmetic, or pharmaceutical applications.

  7. FIRE SAFETY: In case of fire, use water spray, CO₂, or dry chemical powder. Fire may release toxic nitrogen oxide fumes. Firefighters should use SCBA and full protective clothing.

Important Disclaimer: This Technical Data Sheet (TDS) is for informational purposes only. The information provided is based on available data and is believed to be accurate. However, the user is solely responsible for determining the suitability of the product for their specific applications and for complying with all applicable regulations and safety requirements. For complete safety, handling, storage, and regulatory compliance information, always refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier. Users are responsible for testing the product in their own processes and applications. All local, national, and international regulations must be followed when working with Dysprosium Nitrate. Due to its oxidizing nature, hygroscopicity, and environmental classification, a detailed risk assessment and handling procedure must be established prior to use.

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