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Yttrium Fluoride, Yttrium Trifluoride, 13709-49-4

Yttrium Fluoride, Yttrium Trifluoride, 13709-49-4

YTTRİUM FLUORIDE (YF₃)
YTTRİUM FLUORIDE / YTTRİUM TRİFLUORIDE / YTTRİUM(III) FLUORIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Yttrium Fluoride
Chemical Name Yttrium(III) Fluoride, Yttrium Trifluoride
Other Names YF₃
CAS Number 13709-49-4
EC Number (EINECS) 237-257-5
Chemical Formula YF₃
Molecular Weight 145.90 g/mol
Appearance White crystalline powder
Odor Odorless
Physical State (20°C) Solid (powder)

2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Yttrium fluoride is the fluoride salt of the rare earth element yttrium. Yttrium ions (Y³⁺) and fluoride ions (F⁻) are present in a 1:3 ratio. It appears as a white crystalline powder. It is insoluble in water but soluble in acids. High purity grades (≥99.99%) are available for optical, electronic, and advanced ceramic applications. It is known for its low refractive index and wide optical transmission range.

Structural Features:

                    YTTRİUM FLUORIDE [YF₃]
                          |
                Y³⁺ - F⁻ Ionic Bonds
                          |
        +----------------+----------------+
        |                |                |
    White Crystalline  Insoluble in      Soluble in
    Powder             Water             Acids

2.2. Structural Properties

Parameter Value
Crystal Structure Orthorhombic
Chemical Formula YF₃
Molecular Weight 145.90 g/mol
Density ~4.01 g/cm³
Appearance White crystalline powder
Melting Point ~1,387 °C
Boiling Point ~2,230 °C
Refractive Index ~1.51
Band Gap ~6.0 eV

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance White crystalline powder Color shade depends on purity
Odor Odorless -
Chemical Formula YF₃ -
Molecular Weight 145.90 g/mol -
Density ~4.01 g/cm³ -
Melting Point ~1,387 °C -
Solubility in Water (25°C) Insoluble -
Solubility in Acids Soluble Forms yttrium salts
Solubility in Alcohol Insoluble -
Crystal Structure Orthorhombic -
Optical Properties Low refractive index Transparent in UV-IR range
Thermal Stability High -
Hygroscopicity Low -

4. PURITY GRADES

Parameter Technical Grade High Purity Grade Analytical Grade Optical Grade
Purity (YF₃) ≥ 99.0% ≥ 99.5% ≥ 99.9% ≥ 99.99%
Yttrium (Y) Content ≥ 61.0% ≥ 61.5% ≥ 61.8% ≥ 62.0%
Fluoride (F⁻) Content ≥ 38.5% ≥ 39.0% ≥ 39.3% ≥ 39.5%
Other Rare Earths ≤ 1.0% ≤ 0.5% ≤ 0.1% ≤ 0.01%
Iron (Fe) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Calcium (Ca) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Silicon (Si) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Heavy Metals (Pb) ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm ≤ 5 ppm
Loss on Drying ≤ 0.5% ≤ 0.3% ≤ 0.2% ≤ 0.1%
Particle Size (D50) 5-20 µm 1-10 µm 0.5-5 µm 0.2-2 µm
BET Surface Area 5-15 m²/g 10-20 m²/g 15-30 m²/g 20-50 m²/g

5. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Stable under normal conditions; stable up to high temperatures.
Conditions to Avoid Strong acids, high humidity (prolonged), strong oxidizing agents.
Incompatible Materials Strong acids, strong oxidizing agents, alkali metals.
Hazardous Decomposition Products Upon oxidation at high temperatures: yttrium oxide (Y₂O₃) and hydrogen fluoride (HF).
Hazardous Polymerization Will not occur.
Hygroscopicity Low.

5.1. Chemical Reactions

  • Reaction with Acids:
    YF₃ + 3HCl → YCl₃ + 3HF
    YF₃ + 3HNO₃ → Y(NO₃)₃ + 3HF

  • Reaction with Bases:
    YF₃ + 3NaOH → Y(OH)₃↓ + 3NaF (at high temperature)

  • Thermal Decomposition:
    2YF₃ → 2YF₂ + F₂ (above ~1,500°C)

6. APPLICATION AREAS
6.1. Optics and Laser Applications

Application Function Details
Optical Ceramics Optical material Transparent ceramics in UV-IR range
Laser Crystals Additive Rare earth-doped laser systems
Optical Coatings Low refractive index Thin film coatings
Infrared Windows IR transparency Defense and industrial applications

6.2. Metallurgy

Application Function Details
Melting Flux Protective agent Melting of rare earth metals
Alloy Additive Alloying element Special metallurgical applications
Yttrium Metal Production Precursor Primary source of yttrium metal

6.3. Electronics and Advanced Materials

Application Function Details
High Purity Ceramics Additive Mechanical and thermal properties
Electronic Components Dielectric material Special electronic applications
Thin Film Coatings Surface engineering Optoelectronic applications

6.4. Sectoral Suitability Table

Sector Suitability Explanation
Optics Suitable Optical ceramics, laser crystals
Metallurgy Suitable Melting flux, alloy additive
Electronics Suitable Thin film coatings, dielectrics
Advanced Materials Suitable High purity ceramics
Food Not Suitable Not suitable
Cosmetics Not Suitable Not suitable

7. PRODUCTION PROCESS

Stage Process Description
1. Raw Material Preparation Yttrium oxide (Y₂O₃) or yttrium salts High purity yttrium sources
2. Fluorination Reaction with hydrogen fluoride (HF) or ammonium fluoride Y₂O₃ + 6HF → 2YF₃ + 3H₂O
3. Precipitation Chemical precipitation Yttrium fluoride precipitate
4. Filtration Removal of impurities Precipitate separated and washed
5. Drying Controlled conditions Removal of moisture
6. Calcination Thermal treatment Obtaining crystalline form
7. Milling Mechanical processing Achieving desired particle size
8. Packaging Moisture-proof packaging Packaged under inert atmosphere for high purity grades

7.1. Major Producing Countries

Country Description
China Major producer
USA Rare earth production
Germany High purity production
Japan High purity production

8. ALTERNATIVE / SUBSTITUTE PRODUCTS

Alternative Description When to Use
Yttrium Oxide (Y₂O₃) Yttrium source When oxide form is required
Lanthanum Fluoride (LaF₃) Similar optical properties When La is required
Gadolinium Fluoride (GdF₃) Similar optical properties When Gd is required
Yttrium Chloride (YCl₃) Yttrium source When different anion is required
Yttrium Nitrate (Y(NO₃)₃) Yttrium source When soluble form is required

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 2,000 mg/kg (low toxicity)
Dermal Toxicity Low
Skin Irritation Mild irritant
Eye Irritation Mild to moderate irritant
Inhalation Fine dust inhalation may cause respiratory tract irritation.
Carcinogenicity Not classified as carcinogenic.
Mutagenicity Not mutagenic.
Chronic Effects Rare earth compounds have low bioavailability; prolonged exposure may cause lung effects.
Environmental Hazards Low to moderate aquatic toxicity; caution required due to fluoride ion content.

9.1. GHS Classification

Hazard Class Category H-Statement
Skin Irritation Category 2 H315: Causes skin irritation.
Eye Irritation Category 2A H319: Causes serious eye irritation.
Specific Target Organ Toxicity Category 3 H335: May cause respiratory irritation.

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

10. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust.
P264 Wash thoroughly after handling.
P271 Use only in well-ventilated areas.
P280 Wear protective gloves/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
P337+P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local regulations.

11. FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air. If symptoms persist, seek medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention.
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention.
Ingestion Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention.

12. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, and well-ventilated area. Ensure a moisture-free environment.
Container Requirements Moisture-proof, tightly closed containers.
Temperature Room temperature (15-25°C).
Shelf Life 24-36 months under appropriate conditions.
Stability Note Stable under normal conditions; keep away from acids and strong oxidizing agents.

13. PACKAGING OPTIONS

Packaging Type Quantity Material
Laboratory Packaging 10 g, 25 g, 50 g, 100 g, 500 g HDPE bottle, aluminum foil bag
Laboratory Packaging 1 kg HDPE bottle, inert atmosphere
Industrial Packaging 25 kg PE-lined kraft bag, moisture-proof
Drum 25 kg, 50 kg HDPE drum, moisture-proof
IBC (Intermediate Bulk Container) 500 kg, 1000 kg Moisture-proof, palletized

14. TRANSPORT INFORMATION

Parameter Information
UN Number Generally not classified; must be verified via SDS
Hazard Class -
Packing Group -
ADR/RID Not regulated (special precautions may be required for powder form)
IMDG Not regulated
IATA Not regulated
HS Code 2826.90.00.00.00 (Other inorganic fluorides)

15. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Registered; must be confirmed with supplier
Turkey (KKDIK) Compliance required
TSCA (USA) Registered
EINECS 237-257-5
ISO Compliant with optical material standards

16. OTHER NAMES AND SYNONYMS

Name Description
Yttrium Trifluoride Chemical name
Yttrium(III) Fluoride Chemical name
YF₃ Chemical abbreviation
Rare Earth Fluoride Category name
Yttrium Fluoride English name
Yttrium Trifluoride English name

17. QUICK REFERENCE TABLE

Property Value
CAS Number 13709-49-4
EC Number 237-257-5
Chemical Formula YF₃
Molecular Weight 145.90 g/mol
Appearance White crystalline powder
Density ~4.01 g/cm³
Melting Point ~1,387 °C
Crystal Structure Orthorhombic
HS Code 2826.90.00.00.00
GHS Signal Word WARNING

18. CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • Optical Applications: Yttrium fluoride is a critical material for optical ceramics, laser crystals, and infrared windows due to its low refractive index and wide optical transmission range (UV-IR).

  • High Purity Requirement: Optical and electronic applications require high purity (>99.9%); impurities negatively affect optical performance.

  • Fluoride Content: Contact with acids may release toxic hydrogen fluoride (HF) gas. Acid use must be controlled.

  • Incompatibility: Reacts with strong acids and oxidizing agents.

  • Powder Hazard: Fine powder form may cause respiratory tract irritation. Dust control measures must be taken.

BEST PRACTICE RECOMMENDATIONS:

  • Storage:

    • Store in a cool, dry, and well-ventilated area.

    • Use moisture-proof, tightly closed containers.

    • Keep away from acids and oxidizing agents.

    • Store at room temperature (15-25°C).

  • Handling:

    • Use in well-ventilated areas with local exhaust ventilation.

    • Use a dust mask (N95 or better), protective goggles, and gloves.

    • Avoid dust formation and inhalation.

    • Wash hands thoroughly after handling.

    • Ensure controlled conditions when working with acids.

    • Take precautions against HF formation during high-temperature processes.

  • Waste Management:

    • Dispose of in accordance with local regulations.

    • Do not discharge into water sources.

    • For large quantities, rare earth recycling should be considered.

LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Yttrium fluoride is a critical rare earth compound for optical and metallurgical applications; careful handling and storage are required due to high purity requirements and fluoride content.

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