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Send EmailIndium Chloride Anhydrous, Indium Monochloride, 13465-10-6
INDIUM CHLORIDE ANHYDROUS (INCL)
INDIUM CHLORIDE ANHYDROUS / INDIUM MONOCHLORIDE / INDIUM(I) CHLORIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY
| Parameter | Information |
|---|---|
| Product Name | Indium Chloride Anhydrous |
| Chemical Name | Indium(I) Chloride, Indium Monochloride |
| Other Names | InCl |
| CAS Number | 13465-10-6 |
| EC Number (EINECS) | 236-658-4 |
| Chemical Formula | InCl |
| Molecular Weight | 150.30 g/mol |
| Appearance | White to yellow crystalline solid |
| Odor | Odorless |
| Physical State (20°C) | Solid (crystalline) |
2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Indium chloride is an inorganic compound of indium and chlorine. Indium ions (In⁺) and chloride ions (Cl⁻) are present in a 1:1 ratio. It is a rare compound of indium in the +1 oxidation state. It appears as a white to yellow crystalline solid. It hydrolyzes in water to form indium oxide (In₂O₃) and hydrogen chloride (HCl). It is soluble in hydrochloric acid. It is unstable in humid environments.
Structural Features:
INDIUM CHLORIDE ANHYDROUS [InCl]
|
In⁺ - Cl⁻ Ionic/Covalent Bonds
|
+----------------+----------------+
| | |
Crystalline Hydrolyzes Soluble in
Structure in Moisture Hydrochloric
(HCl, In₂O₃) Acid
2.2. Structural Properties
| Parameter | Value |
|---|---|
| Crystal Structure | Orthorhombic |
| Chemical Formula | InCl |
| Molecular Weight | 150.30 g/mol |
| Density | ~4.19 g/cm³ (25°C) |
| Appearance | White to yellow crystalline solid |
| Melting Point | ~606 °C |
| Boiling Point | ~800 °C (decomposes) |
| Oxidation State | +1 |
3. PHYSICAL AND CHEMICAL PROPERTIES
| Property | Value | Description |
|---|---|---|
| Appearance | White to yellow crystalline solid | - |
| Odor | Odorless | - |
| Chemical Formula | InCl | - |
| Molecular Weight | 150.30 g/mol | - |
| Density | ~4.19 g/cm³ | - |
| Melting Point | ~606 °C | - |
| Boiling Point | ~800 °C | Decomposes |
| Solubility in Water (25°C) | Hydrolyzes | Forms In₂O₃ + HCl |
| Solubility in Hydrochloric Acid | Soluble | - |
| Oxidation State | +1 | Oxidizes in air |
| Stability | Moisture sensitive | Decomposes to In₂O₃ and HCl |
| Hygroscopicity | High | Rapidly absorbs moisture |
4. PURITY GRADES
| Parameter | Technical Grade | High Purity Grade | Analytical Grade |
|---|---|---|---|
| Purity (InCl) | ≥ 99.0% | ≥ 99.5% | ≥ 99.9% |
| Indium (In) Content | ≥ 77.0% | ≥ 77.5% | ≥ 77.8% |
| Chloride (Cl⁻) Content | ≥ 23.0% | ≥ 23.5% | ≥ 23.8% |
| Indium(III) (In³⁺) | ≤ 1.0% | ≤ 0.5% | ≤ 0.1% |
| Iron (Fe) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm |
| Lead (Pb) | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Zinc (Zn) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm |
| Calcium (Ca) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm |
| Sodium (Na) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm |
| Sulfate (SO₄²⁻) | ≤ 0.5% | ≤ 0.2% | ≤ 0.1% |
| Moisture / Loss on Drying | ≤ 0.5% | ≤ 0.2% | ≤ 0.1% |
| Particle Size | Variable | Variable | Variable |
5. STABILITY AND REACTIVITY
| Parameter | Information |
|---|---|
| Chemical Stability | Unstable in humid environments; stable under dry conditions. Slowly oxidizes in air. |
| Conditions to Avoid | High humidity, water, oxygen, exposure to open atmosphere, high temperatures. |
| Incompatible Materials | Water, strong oxidizing agents, strong bases, alkali metals. |
| Hazardous Decomposition Products | Upon hydrolysis: hydrogen chloride (HCl) and indium oxide (In₂O₃). |
| Hazardous Polymerization | Will not occur. |
| Hygroscopicity | High; rapidly absorbs moisture and hydrolyzes when exposed to air. |
5.1. Chemical Reactions
Hydrolysis (with Water):
2InCl + H₂O → In₂O↓ + 2HCl (intermediate)
4InCl + O₂ → 2In₂O₃ + 2Cl₂ (oxidation)
Oxidation (in Air):
4InCl + O₂ → 2In₂O₃ + 2Cl₂↑
Reaction with Acids:
InCl + HCl → InCl₂ + H₂ (redox reaction)
InCl + 3HCl → InCl₃ + H₂↑ + Cl⁻
Reaction with Bases:
InCl + NaOH → InOH↓ + NaCl
6. APPLICATION AREAS
6.1. Semiconductor and Electronic Materials
| Application | Function | Details |
|---|---|---|
| Indium-Based Semiconductors | Precursor | InP, InAs, InSb production |
| Optoelectronic Materials | Additive | Indium-based optical materials |
| Thin Film Coatings | Source material | PVD and CVD applications |
6.2. Catalyst Applications
| Application | Function | Details |
|---|---|---|
| Organic Synthesis Catalyst | Catalytic activity | Various organic transformations |
| Polymerization Catalyst | Polymerization initiator | Some polymerization reactions |
6.3. Advanced Materials and Nanotechnology
| Application | Function | Details |
|---|---|---|
| Nanomaterial Synthesis | Starting material | Indium-based nanoparticles |
| Materials Science Research | Source material | New material development |
| Quantum Dots | Precursor | Indium-based quantum dots |
6.4. Sectoral Suitability Table
| Sector | Suitability | Explanation |
|---|---|---|
| Electronics | Suitable | Semiconductor materials, InP, InAs |
| Optoelectronics | Suitable | Optical materials, thin film coatings |
| Catalyst | Suitable | Organic synthesis, polymerization |
| Nanotechnology | Suitable | Nanoparticle synthesis, quantum dots |
| Research | Suitable | Materials science, advanced material development |
| Pharmaceutical | Not Suitable | Toxic, not suitable |
| Agriculture | Not Suitable | Not suitable |
| Food | Not Suitable | Not suitable |
7. PRODUCTION PROCESS
| Stage | Process | Description |
|---|---|---|
| 1. Raw Material Preparation | Indium metal (In) | High purity indium metal |
| 2. Chlorination | Controlled reaction with chlorine gas | 2In + Cl₂ → 2InCl |
| 3. Purification | Sublimation/distillation | Removal of impurities |
| 4. Crystallization | Controlled cooling | Obtaining pure crystalline form |
| 5. Drying | Controlled conditions | Removal of moisture |
| 6. Packaging | Moisture-proof packaging | Packaged under inert atmosphere due to hygroscopic nature |
7.1. Alternative Production Method
| Method | Description |
|---|---|
| Reduction Method | Reduction of indium(III) chloride (InCl₃) with hydrogen or indium metal |
7.2. Major Producing Countries
| Country | Description |
|---|---|
| China | Major producer |
| USA | Indium production (Sigma-Aldrich, American Elements) |
| Germany | High purity production (Alfa Aesar) |
| Japan | High purity production |
8. ALTERNATIVE / SUBSTITUTE PRODUCTS
| Alternative | Description | When to Use |
|---|---|---|
| Indium(III) Chloride (InCl₃) | More stable and common | When stable form is required |
| Gallium Chloride (GaCl₃) | Similar semiconductor applications | When Ga is required |
| Indium Oxide (In₂O₃) | Indium source | When oxide form is required |
| Indium Nitrate (In(NO₃)₃) | Indium source | When different anion is required |
| Indium Bromide (InBr) | Similar chemical properties | When different halogen is required |
9. SAFETY AND TOXICOLOGY
| Parameter | Value |
|---|---|
| Acute Oral Toxicity (LD50, Rat) | > 2,000 mg/kg (low toxicity) |
| Dermal Toxicity | Low |
| Skin Irritation | Mild to moderate irritant |
| Eye Irritation | Serious irritant |
| Inhalation | Dust inhalation may cause respiratory tract irritation. |
| Carcinogenicity | Not classified as carcinogenic. |
| Mutagenicity | Not mutagenic. |
| Chronic Effects | Prolonged exposure may cause lung effects. |
| Environmental Hazards | Moderate aquatic toxicity. |
9.1. GHS Classification
| Hazard Class | Category | H-Statement |
|---|---|---|
| Skin Irritation | Category 2 | H315: Causes skin irritation. |
| Eye Irritation | Category 2A | H319: Causes serious eye irritation. |
| Specific Target Organ Toxicity | Category 3 | H335: May cause respiratory irritation. |
| Hazardous to the Aquatic Environment | Category 2 | H401: Toxic to aquatic life. |
Signal Word: WARNING
Hazard Pictograms: GHS07 (Exclamation Mark)
10. PRECAUTIONARY STATEMENTS (P-CODES)
| Code | Statement |
|---|---|
| P261 | Avoid breathing dust. |
| P264 | Wash thoroughly after handling. |
| P271 | Use only in well-ventilated areas. |
| P280 | Wear protective gloves/eye protection/face protection. |
| P302+P352 | IF ON SKIN: Wash with plenty of soap and water. |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing. |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. |
| P337+P313 | If eye irritation persists: Get medical advice/attention. |
| P501 | Dispose of contents/container in accordance with local regulations. |
11. FIRST AID MEASURES
| Exposure Route | Action to Take |
|---|---|
| Inhalation | Remove to fresh air. If symptoms persist, seek medical attention. |
| Skin Contact | Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention. |
| Eye Contact | Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention. |
| Ingestion | Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention. |
12. STORAGE AND SHELF LIFE
| Parameter | Condition |
|---|---|
| Storage Conditions | Store in a cool, dry, and well-ventilated area. Store under inert atmosphere (Argon or Nitrogen). |
| Container Requirements | Airtight, moisture-proof containers. Glass bottle or under inert atmosphere. |
| Temperature | Room temperature (15-25°C). |
| Shelf Life | 12-18 months under appropriate conditions (due to oxidation and moisture sensitivity). |
| Stability Note | Hygroscopic; slowly oxidizes in air. Must be stored in closed packaging under inert atmosphere. |
13. PACKAGING OPTIONS
| Packaging Type | Quantity | Material |
|---|---|---|
| Laboratory Packaging | 1 g, 5 g, 10 g, 25 g | Sealed glass ampoule, inert atmosphere |
| Laboratory Packaging | 50 g, 100 g | HDPE bottle, inert atmosphere |
| Industrial Packaging | 500 g, 1 kg | PE-lined drum, moisture-proof |
| Industrial Packaging | 5 kg, 25 kg | HDPE drum, moisture-proof |
14. TRANSPORT INFORMATION
| Parameter | Information |
|---|---|
| UN Number | Not classified (specific regulations apply for metal compounds) |
| Hazard Class | - |
| Packing Group | - |
| ADR/RID | Not regulated |
| IMDG | Not regulated |
| IATA | Not regulated |
| HS Code | 2827.39.00.00.00 (Other chlorides) |
15. REGULATORY STATUS
| Region / Authority | Status |
|---|---|
| European Union (REACH) | Registered |
| Turkey (KKDIK) | Compliance required |
| TSCA (USA) | Registered |
| CLP/GHS | Compliant |
| FDA/EFSA | Not approved as a food additive |
| ISO 9001:2015 | Production compliance |
16. OTHER NAMES AND SYNONYMS
| Name | Description |
|---|---|
| Indium Monochloride | Chemical name |
| Indium(I) Chloride | Chemical name |
| InCl | Chemical abbreviation |
| Indium Chloride Anhydrous | English name |
| Indium Monochloride | English name |
17. QUICK REFERENCE TABLE
| Property | Value |
|---|---|
| CAS Number | 13465-10-6 |
| EC Number | 236-658-4 |
| Chemical Formula | InCl |
| Molecular Weight | 150.30 g/mol |
| Appearance | White to yellow crystalline solid |
| Density | ~4.19 g/cm³ |
| Melting Point | ~606 °C |
| Oxidation State | +1 |
| HS Code | 2827.39.00.00.00 |
| GHS Signal Word | WARNING |
18. CRITICAL WARNINGS AND BEST PRACTICES
CRITICAL WARNINGS:
Oxidation Sensitivity: Indium(I) chloride slowly oxidizes in air to Indium(III) chloride. This affects purity and performance. Must be handled and stored under inert atmosphere.
Highly Hygroscopic Nature: InCl has a very high moisture absorption capacity. When exposed to air, it rapidly absorbs moisture and hydrolyzes. Extreme care must be taken to avoid moisture during storage and handling.
Rare Oxidation State: Indium's +1 oxidation state is less stable than +3 and requires special handling conditions.
Incompatibility: Reacts with water, strong oxidizing agents, and acids.
Eye and Skin Irritation: Causes irritation to skin and eyes. Protective equipment is mandatory during use.
BEST PRACTICE RECOMMENDATIONS:
Storage:
Store under inert atmosphere (Argon or Nitrogen), in a cool, dry, and well-ventilated area.
Use moisture-proof, airtight containers.
Keep away from oxidizing agents, moisture, and air.
Store at room temperature (15-25°C).
Handling:
Work in a glovebox or under inert atmosphere.
Immediately close containers tightly when not in use.
Use a dust mask (N95 or better), protective goggles, and chemically resistant gloves.
Avoid dust formation and inhalation.
Wash hands thoroughly after handling.
Avoid contact with water and moisture.
Waste Management:
Dispose of in accordance with local regulations as heavy metal waste.
Do not discharge into water sources or sewers.
For large quantities, indium recovery should be considered (valuable and critical metal).
LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Indium(I) chloride requires special handling conditions due to its high reactivity, oxidation sensitivity, and moisture sensitivity; it must be used and stored under inert atmosphere.