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Send EmailTellurium Chloride, Tellurium Tetrachloride, 10026-07-0
TELLURIUM CHLORIDE (TECL₄)
TELLURIUM CHLORIDE / TELLURIUM TETRACHLORIDE / TELLURIUM(IV) CHLORIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY
| Parameter | Information |
|---|---|
| Product Name | Tellurium Chloride |
| Chemical Name | Tellurium(IV) Chloride, Tellurium Tetrachloride |
| Other Names | TeCl₄ |
| CAS Number | 10026-07-0 |
| EC Number (EINECS) | 233-059-9 |
| Chemical Formula | TeCl₄ |
| Molecular Weight | 269.4 g/mol |
| Appearance | White to pale yellow crystalline solid |
| Odor | Sharp, irritating |
| Physical State (20°C) | Solid (crystalline) |
2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Tellurium chloride is an inorganic compound of tellurium and chlorine. Tellurium ions (Te⁴⁺) and chloride ions (Cl⁻) are present in a 1:4 ratio. It has a molecular structure and appears as a white to pale yellow crystalline solid under ambient conditions. It hydrolyzes in water to form tellurium dioxide (TeO₂) and hydrogen chloride (HCl). It is soluble in organic solvents. It is unstable in humid environments.
Structural Features:
TELLURIUM CHLORIDE [TeCl₄]
|
Te⁴⁺ - Cl⁻ Covalent/Ionic Bonds
|
+----------------+----------------+
| | |
Molecular Hydrolyzes Soluble in
Crystalline in Moisture Organic
Structure (HCl, TeO₂) Solvents
2.2. Structural Properties
| Parameter | Value |
|---|---|
| Crystal Structure | Monoclinic |
| Chemical Formula | TeCl₄ |
| Molecular Weight | 269.4 g/mol |
| Density | ~3.26 g/cm³ (25°C) |
| Appearance | White to pale yellow crystalline solid |
| Melting Point | ~224 °C |
| Boiling Point | ~380 °C (decomposes) |
| Vapor Pressure | Low |
3. PHYSICAL AND CHEMICAL PROPERTIES
| Property | Value | Description |
|---|---|---|
| Appearance | White to pale yellow crystalline solid | - |
| Odor | Sharp, irritating | - |
| Chemical Formula | TeCl₄ | - |
| Molecular Weight | 269.4 g/mol | - |
| Density | ~3.26 g/cm³ | - |
| Melting Point | ~224 °C | - |
| Boiling Point | ~380 °C | Decomposes |
| Solubility in Water (25°C) | Hydrolyzes | Forms TeO₂ + HCl |
| Solubility in Organic Solvents | Soluble | Benzene, chloroform, CCl₄ |
| Vapor Pressure | Low | - |
| Stability | Moisture sensitive | Decomposes to TeO₂ and HCl |
| Hygroscopicity | High | Rapidly absorbs moisture |
4. PURITY GRADES
| Parameter | Technical Grade | High Purity Grade | Analytical Grade |
|---|---|---|---|
| Purity (TeCl₄) | ≥ 97.0% | ≥ 99.0% | ≥ 99.9% |
| Tellurium (Te) Content | ≥ 47.0% | ≥ 47.5% | ≥ 47.8% |
| Chloride (Cl⁻) Content | ≥ 52.5% | ≥ 53.0% | ≥ 53.3% |
| Iron (Fe) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm |
| Lead (Pb) | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Calcium (Ca) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm |
| Sodium (Na) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm |
| Selenium (Se) | ≤ 500 ppm | ≤ 100 ppm | ≤ 50 ppm |
| Sulfate (SO₄²⁻) | ≤ 0.5% | ≤ 0.2% | ≤ 0.1% |
| Moisture / Loss on Drying | ≤ 1.0% | ≤ 0.5% | ≤ 0.2% |
| Particle Size | Variable | Variable | Variable |
5. STABILITY AND REACTIVITY
| Parameter | Information |
|---|---|
| Chemical Stability | Unstable in humid environments; stable under dry conditions. |
| Conditions to Avoid | High humidity, water, high temperatures, exposure to open atmosphere. |
| Incompatible Materials | Water, strong oxidizing agents, strong bases, alkali metals. |
| Hazardous Decomposition Products | Upon hydrolysis: hydrogen chloride (HCl) and tellurium dioxide (TeO₂). |
| Hazardous Polymerization | Will not occur. |
| Hygroscopicity | High; rapidly absorbs moisture and hydrolyzes when exposed to air. |
5.1. Chemical Reactions
Hydrolysis (with Water):
TeCl₄ + 2H₂O → TeO₂↓ + 4HCl↑
Thermal Decomposition:
TeCl₄ → TeCl₂ + Cl₂ (~380°C)
TeCl₄ → Te + 2Cl₂ (higher temperature)
Reaction with Bases:
TeCl₄ + 6NaOH → Na₂TeO₃ + 4NaCl + 3H₂O
Reaction with Alcohols:
TeCl₄ + 4ROH → Te(OR)₄ + 4HCl
6. APPLICATION AREAS
6.1. Chemical Synthesis and Intermediate
| Application | Function | Details |
|---|---|---|
| Intermediate in Tellurium Chemistry | Starting material | Synthesis of tellurium-containing compounds |
| Organic Synthesis | Reagent | Production of organotellurium compounds |
| Precursor for Tellurium Compounds | Precursor | Tellurium organometallic compounds |
6.2. Catalyst Applications
| Application | Function | Details |
|---|---|---|
| Organic Synthesis Catalyst | Catalytic activity | Various organic transformations |
| Polymerization Catalyst | Polymerization initiator | Some polymerization reactions |
6.3. Semiconductor and Materials Research
| Application | Function | Details |
|---|---|---|
| Semiconductor Materials | Additive | Tellurium-based semiconductors |
| Materials Science Research | Starting material | New material development |
| Optical Materials | Precursor | Tellurium oxide and chalcogenide glasses |
6.4. Sectoral Suitability Table
| Sector | Suitability | Explanation |
|---|---|---|
| Electronics | Suitable | Semiconductor materials |
| Catalyst | Suitable | Organic synthesis, polymerization |
| Optical Materials | Suitable | Tellurium-based optical materials |
| Chemical Synthesis | Suitable | Intermediate and precursor |
| Pharmaceutical | Not Suitable | Toxic, not suitable |
| Agriculture | Not Suitable | Not suitable |
| Food | Not Suitable | Not suitable |
7. PRODUCTION PROCESS
| Stage | Process | Description |
|---|---|---|
| 1. Raw Material Preparation | Tellurium metal (Te) | High purity tellurium metal |
| 2. Chlorination | Reaction with chlorine gas | Te + 2Cl₂ → TeCl₄ |
| 3. Purification | Sublimation/distillation | Removal of impurities |
| 4. Crystallization | Controlled cooling | Obtaining pure crystalline form |
| 5. Drying | Controlled conditions | Removal of moisture |
| 6. Packaging | Moisture-proof packaging | Packaged under inert atmosphere due to hygroscopic nature |
7.1. Alternative Production Method
| Method | Description |
|---|---|
| Laboratory Production | Chlorination of tellurium dioxide (TeO₂) with hydrochloric acid |
7.2. Major Producing Countries
| Country | Description |
|---|---|
| China | Major producer |
| USA | Rare element production (Sigma-Aldrich, American Elements) |
| Germany | High purity production (Alfa Aesar) |
| Japan | High purity production |
8. ALTERNATIVE / SUBSTITUTE PRODUCTS
| Alternative | Description | When to Use |
|---|---|---|
| Tellurium Dioxide (TeO₂) | Tellurium source | When oxide form is required |
| Tellurium Tetrabromide (TeBr₄) | Similar chemical properties | When different halogen is required |
| Selenium Chloride (SeCl₄) | Similar chemical properties | When Se is required |
| Sulfur Chloride (SCl₄) | Similar chemical properties | Lower cost alternative |
| Tellurium Tetrabromide | Tellurium source | When different reactivity is required |
9. SAFETY AND TOXICOLOGY
| Parameter | Value |
|---|---|
| Acute Oral Toxicity (LD50, Rat) | ~100 mg/kg (very toxic) |
| Dermal Toxicity | Toxic |
| Skin Irritation | Corrosive / severe irritant |
| Eye Irritation | Severe irritant / corrosive |
| Inhalation | Very toxic if inhaled; may cause pulmonary edema. |
| Carcinogenicity | Not classified as carcinogenic. |
| Mutagenicity | May be mutagenic. |
| Chronic Effects | Prolonged exposure may cause respiratory system, liver, and kidney damage. |
| Environmental Hazards | Very toxic to aquatic life; bioaccumulation potential. |
9.1. GHS Classification
| Hazard Class | Category | H-Statement |
|---|---|---|
| Acute Toxicity (Oral) | Category 2 | H300: Fatal if swallowed. |
| Acute Toxicity (Inhalation) | Category 2 | H330: Fatal if inhaled. |
| Skin Corrosion | Category 1B | H314: Causes severe skin burns and eye damage. |
| Hazardous to the Aquatic Environment | Category 1 | H400: Very toxic to aquatic life. |
| Hazardous to the Aquatic Environment (Long-term) | Category 1 | H410: Very toxic to aquatic life with long lasting effects. |
Signal Word: DANGER
Hazard Pictograms: GHS06 (Toxic), GHS05 (Corrosive), GHS09 (Environment)
10. PRECAUTIONARY STATEMENTS (P-CODES)
| Code | Statement |
|---|---|
| P260 | Do not breathe dust. |
| P261 | Avoid breathing dust. |
| P264 | Wash thoroughly after handling. |
| P270 | Do not eat, drink or smoke when using this product. |
| P271 | Use only in well-ventilated areas. |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection. |
| P301+P310 | IF SWALLOWED: Immediately call a POISON CENTER or doctor. |
| P303+P361+P353 | IF ON SKIN (or hair): Remove all contaminated clothing immediately. Rinse skin with water. |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing. |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. |
| P310 | Immediately call a POISON CENTER or doctor. |
| P391 | Collect spillage. |
| P405 | Store locked up. |
| P501 | Dispose of contents/container in accordance with local regulations. |
11. FIRST AID MEASURES
| Exposure Route | Action to Take |
|---|---|
| Inhalation | Remove to fresh air. If symptoms persist, seek medical attention. |
| Skin Contact | Remove contaminated clothing. Wash with plenty of soap and water. If irritation persists, seek medical attention. |
| Eye Contact | Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention. |
| Ingestion | Rinse mouth. Do not induce vomiting. Drink plenty of water. If large amount is swallowed, seek medical attention. |
12. STORAGE AND SHELF LIFE
| Parameter | Condition |
|---|---|
| Storage Conditions | Store in a cool, dry, and well-ventilated area. Ensure a moisture-free environment. |
| Container Requirements | Airtight, moisture-proof containers. Glass bottle or under inert atmosphere. |
| Temperature | Room temperature (15-25°C). |
| Shelf Life | 12-24 months under appropriate conditions (due to hygroscopic nature). |
| Stability Note | Highly hygroscopic; rapidly hydrolyzes in humid environments. Must be stored in closed packaging under inert atmosphere. |
13. PACKAGING OPTIONS
| Packaging Type | Quantity | Material |
|---|---|---|
| Laboratory Packaging | 5 g, 10 g, 25 g, 50 g | Sealed glass bottle, ampoule, inert atmosphere |
| Laboratory Packaging | 100 g, 500 g | HDPE bottle, inert atmosphere |
| Industrial Packaging | 1 kg, 5 kg | PE-lined drum, moisture-proof |
| Industrial Packaging | 25 kg | HDPE drum, moisture-proof |
14. TRANSPORT INFORMATION
| Parameter | Information |
|---|---|
| UN Number | 2915 |
| Hazard Class | 8 (Corrosive substances) |
| Packing Group | II |
| ADR/RID | Regulated |
| IMDG | Regulated |
| IATA | Regulated |
| HS Code | 2827.39.00.00.00 (Other chlorides) |
15. REGULATORY STATUS
| Region / Authority | Status |
|---|---|
| European Union (REACH) | Registered |
| Turkey (KKDIK) | Compliance required |
| TSCA (USA) | Registered |
| CLP/GHS | Toxic, Corrosive, Hazardous to the environment |
| FDA/EFSA | Not approved as a food additive |
| ISO 9001:2015 | Production compliance |
16. OTHER NAMES AND SYNONYMS
| Name | Description |
|---|---|
| Tellurium Tetrachloride | Chemical name |
| Tellurium(IV) Chloride | Chemical name |
| TeCl₄ | Chemical abbreviation |
| Tellurium Chloride | English name |
| Tellurium Tetrachloride | English name |
17. QUICK REFERENCE TABLE
| Property | Value |
|---|---|
| CAS Number | 10026-07-0 |
| EC Number | 233-059-9 |
| Chemical Formula | TeCl₄ |
| Molecular Weight | 269.4 g/mol |
| Appearance | White to pale yellow crystalline solid |
| Density | ~3.26 g/cm³ |
| Melting Point | ~224 °C |
| Boiling Point | ~380 °C (decomposes) |
| UN Number | 2915 |
| HS Code | 2827.39.00.00.00 |
| GHS Signal Word | DANGER |
18. CRITICAL WARNINGS AND BEST PRACTICES
CRITICAL WARNINGS:
Highly Toxic: Tellurium chloride is fatal if swallowed or inhaled (H300, H330). Exposure must be strictly minimized.
Corrosive: Causes severe skin burns and eye damage (H314). Protective equipment is mandatory.
Hygroscopic and Moisture Sensitive: Rapidly absorbs moisture and hydrolyzes, releasing toxic hydrogen chloride (HCl) gas. Extreme care must be taken to avoid moisture during storage and handling.
Environmental Hazard: Very toxic to aquatic life (H400/H410). Release into water sources must be strictly prevented.
Thermal Decomposition: Decomposes at ~380°C releasing toxic chlorine gas (Cl₂). Ventilation is essential.
BEST PRACTICE RECOMMENDATIONS:
Storage:
Store in a cool, dry, and well-ventilated area.
Use moisture-proof, airtight containers.
Keep away from water and moisture.
Store at room temperature (15-25°C).
Store locked up.
Handling:
Use in well-ventilated areas with local exhaust ventilation or under a fume hood.
Use a respirator, protective goggles, chemically resistant gloves, and protective clothing.
Avoid dust formation and inhalation.
Avoid contact with water and moisture.
Wash hands thoroughly after handling.
Remove contaminated clothing and wash before reuse.
Waste Management:
Dispose of in accordance with local regulations at licensed disposal facilities.
Do not discharge into water sources.
For large quantities, tellurium recovery should be considered.
LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Tellurium chloride is a highly toxic, corrosive, and environmentally hazardous substance; strict safety measures must be taken during handling, transport, and disposal.