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Tellurium Chloride, Tellurium Tetrachloride, 10026-07-0

Tellurium Chloride, Tellurium Tetrachloride, 10026-07-0

TELLURIUM CHLORIDE (TECL₄)
TELLURIUM CHLORIDE / TELLURIUM TETRACHLORIDE / TELLURIUM(IV) CHLORIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Tellurium Chloride
Chemical Name Tellurium(IV) Chloride, Tellurium Tetrachloride
Other Names TeCl₄
CAS Number 10026-07-0
EC Number (EINECS) 233-059-9
Chemical Formula TeCl₄
Molecular Weight 269.4 g/mol
Appearance White to pale yellow crystalline solid
Odor Sharp, irritating
Physical State (20°C) Solid (crystalline)

2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Tellurium chloride is an inorganic compound of tellurium and chlorine. Tellurium ions (Te⁴⁺) and chloride ions (Cl⁻) are present in a 1:4 ratio. It has a molecular structure and appears as a white to pale yellow crystalline solid under ambient conditions. It hydrolyzes in water to form tellurium dioxide (TeO₂) and hydrogen chloride (HCl). It is soluble in organic solvents. It is unstable in humid environments.

Structural Features:

                    TELLURIUM CHLORIDE [TeCl₄]
                          |
                Te⁴⁺ - Cl⁻ Covalent/Ionic Bonds
                          |
        +----------------+----------------+
        |                |                |
    Molecular          Hydrolyzes       Soluble in
    Crystalline       in Moisture      Organic
    Structure         (HCl, TeO₂)      Solvents

2.2. Structural Properties

Parameter Value
Crystal Structure Monoclinic
Chemical Formula TeCl₄
Molecular Weight 269.4 g/mol
Density ~3.26 g/cm³ (25°C)
Appearance White to pale yellow crystalline solid
Melting Point ~224 °C
Boiling Point ~380 °C (decomposes)
Vapor Pressure Low

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance White to pale yellow crystalline solid -
Odor Sharp, irritating -
Chemical Formula TeCl₄ -
Molecular Weight 269.4 g/mol -
Density ~3.26 g/cm³ -
Melting Point ~224 °C -
Boiling Point ~380 °C Decomposes
Solubility in Water (25°C) Hydrolyzes Forms TeO₂ + HCl
Solubility in Organic Solvents Soluble Benzene, chloroform, CCl₄
Vapor Pressure Low -
Stability Moisture sensitive Decomposes to TeO₂ and HCl
Hygroscopicity High Rapidly absorbs moisture

4. PURITY GRADES

Parameter Technical Grade High Purity Grade Analytical Grade
Purity (TeCl₄) ≥ 97.0% ≥ 99.0% ≥ 99.9%
Tellurium (Te) Content ≥ 47.0% ≥ 47.5% ≥ 47.8%
Chloride (Cl⁻) Content ≥ 52.5% ≥ 53.0% ≥ 53.3%
Iron (Fe) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm
Lead (Pb) ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Calcium (Ca) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm
Sodium (Na) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm
Selenium (Se) ≤ 500 ppm ≤ 100 ppm ≤ 50 ppm
Sulfate (SO₄²⁻) ≤ 0.5% ≤ 0.2% ≤ 0.1%
Moisture / Loss on Drying ≤ 1.0% ≤ 0.5% ≤ 0.2%
Particle Size Variable Variable Variable

5. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Unstable in humid environments; stable under dry conditions.
Conditions to Avoid High humidity, water, high temperatures, exposure to open atmosphere.
Incompatible Materials Water, strong oxidizing agents, strong bases, alkali metals.
Hazardous Decomposition Products Upon hydrolysis: hydrogen chloride (HCl) and tellurium dioxide (TeO₂).
Hazardous Polymerization Will not occur.
Hygroscopicity High; rapidly absorbs moisture and hydrolyzes when exposed to air.

5.1. Chemical Reactions

  • Hydrolysis (with Water):
    TeCl₄ + 2H₂O → TeO₂↓ + 4HCl↑

  • Thermal Decomposition:
    TeCl₄ → TeCl₂ + Cl₂ (~380°C)
    TeCl₄ → Te + 2Cl₂ (higher temperature)

  • Reaction with Bases:
    TeCl₄ + 6NaOH → Na₂TeO₃ + 4NaCl + 3H₂O

  • Reaction with Alcohols:
    TeCl₄ + 4ROH → Te(OR)₄ + 4HCl

6. APPLICATION AREAS
6.1. Chemical Synthesis and Intermediate

Application Function Details
Intermediate in Tellurium Chemistry Starting material Synthesis of tellurium-containing compounds
Organic Synthesis Reagent Production of organotellurium compounds
Precursor for Tellurium Compounds Precursor Tellurium organometallic compounds

6.2. Catalyst Applications

Application Function Details
Organic Synthesis Catalyst Catalytic activity Various organic transformations
Polymerization Catalyst Polymerization initiator Some polymerization reactions

6.3. Semiconductor and Materials Research

Application Function Details
Semiconductor Materials Additive Tellurium-based semiconductors
Materials Science Research Starting material New material development
Optical Materials Precursor Tellurium oxide and chalcogenide glasses

6.4. Sectoral Suitability Table

Sector Suitability Explanation
Electronics Suitable Semiconductor materials
Catalyst Suitable Organic synthesis, polymerization
Optical Materials Suitable Tellurium-based optical materials
Chemical Synthesis Suitable Intermediate and precursor
Pharmaceutical Not Suitable Toxic, not suitable
Agriculture Not Suitable Not suitable
Food Not Suitable Not suitable

7. PRODUCTION PROCESS

Stage Process Description
1. Raw Material Preparation Tellurium metal (Te) High purity tellurium metal
2. Chlorination Reaction with chlorine gas Te + 2Cl₂ → TeCl₄
3. Purification Sublimation/distillation Removal of impurities
4. Crystallization Controlled cooling Obtaining pure crystalline form
5. Drying Controlled conditions Removal of moisture
6. Packaging Moisture-proof packaging Packaged under inert atmosphere due to hygroscopic nature

7.1. Alternative Production Method

Method Description
Laboratory Production Chlorination of tellurium dioxide (TeO₂) with hydrochloric acid

7.2. Major Producing Countries

Country Description
China Major producer
USA Rare element production (Sigma-Aldrich, American Elements)
Germany High purity production (Alfa Aesar)
Japan High purity production

8. ALTERNATIVE / SUBSTITUTE PRODUCTS

Alternative Description When to Use
Tellurium Dioxide (TeO₂) Tellurium source When oxide form is required
Tellurium Tetrabromide (TeBr₄) Similar chemical properties When different halogen is required
Selenium Chloride (SeCl₄) Similar chemical properties When Se is required
Sulfur Chloride (SCl₄) Similar chemical properties Lower cost alternative
Tellurium Tetrabromide Tellurium source When different reactivity is required

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) ~100 mg/kg (very toxic)
Dermal Toxicity Toxic
Skin Irritation Corrosive / severe irritant
Eye Irritation Severe irritant / corrosive
Inhalation Very toxic if inhaled; may cause pulmonary edema.
Carcinogenicity Not classified as carcinogenic.
Mutagenicity May be mutagenic.
Chronic Effects Prolonged exposure may cause respiratory system, liver, and kidney damage.
Environmental Hazards Very toxic to aquatic life; bioaccumulation potential.

9.1. GHS Classification

Hazard Class Category H-Statement
Acute Toxicity (Oral) Category 2 H300: Fatal if swallowed.
Acute Toxicity (Inhalation) Category 2 H330: Fatal if inhaled.
Skin Corrosion Category 1B H314: Causes severe skin burns and eye damage.
Hazardous to the Aquatic Environment Category 1 H400: Very toxic to aquatic life.
Hazardous to the Aquatic Environment (Long-term) Category 1 H410: Very toxic to aquatic life with long lasting effects.

Signal Word: DANGER

Hazard Pictograms: GHS06 (Toxic), GHS05 (Corrosive), GHS09 (Environment)

10. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P260 Do not breathe dust.
P261 Avoid breathing dust.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only in well-ventilated areas.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor.
P303+P361+P353 IF ON SKIN (or hair): Remove all contaminated clothing immediately. Rinse skin with water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
P310 Immediately call a POISON CENTER or doctor.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local regulations.

11. FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air. If symptoms persist, seek medical attention.
Skin Contact Remove contaminated clothing. Wash with plenty of soap and water. If irritation persists, seek medical attention.
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention.
Ingestion Rinse mouth. Do not induce vomiting. Drink plenty of water. If large amount is swallowed, seek medical attention.

12. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, and well-ventilated area. Ensure a moisture-free environment.
Container Requirements Airtight, moisture-proof containers. Glass bottle or under inert atmosphere.
Temperature Room temperature (15-25°C).
Shelf Life 12-24 months under appropriate conditions (due to hygroscopic nature).
Stability Note Highly hygroscopic; rapidly hydrolyzes in humid environments. Must be stored in closed packaging under inert atmosphere.

13. PACKAGING OPTIONS

Packaging Type Quantity Material
Laboratory Packaging 5 g, 10 g, 25 g, 50 g Sealed glass bottle, ampoule, inert atmosphere
Laboratory Packaging 100 g, 500 g HDPE bottle, inert atmosphere
Industrial Packaging 1 kg, 5 kg PE-lined drum, moisture-proof
Industrial Packaging 25 kg HDPE drum, moisture-proof

14. TRANSPORT INFORMATION

Parameter Information
UN Number 2915
Hazard Class 8 (Corrosive substances)
Packing Group II
ADR/RID Regulated
IMDG Regulated
IATA Regulated
HS Code 2827.39.00.00.00 (Other chlorides)

15. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Registered
Turkey (KKDIK) Compliance required
TSCA (USA) Registered
CLP/GHS Toxic, Corrosive, Hazardous to the environment
FDA/EFSA Not approved as a food additive
ISO 9001:2015 Production compliance

16. OTHER NAMES AND SYNONYMS

Name Description
Tellurium Tetrachloride Chemical name
Tellurium(IV) Chloride Chemical name
TeCl₄ Chemical abbreviation
Tellurium Chloride English name
Tellurium Tetrachloride English name

17. QUICK REFERENCE TABLE

Property Value
CAS Number 10026-07-0
EC Number 233-059-9
Chemical Formula TeCl₄
Molecular Weight 269.4 g/mol
Appearance White to pale yellow crystalline solid
Density ~3.26 g/cm³
Melting Point ~224 °C
Boiling Point ~380 °C (decomposes)
UN Number 2915
HS Code 2827.39.00.00.00
GHS Signal Word DANGER

18. CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • Highly Toxic: Tellurium chloride is fatal if swallowed or inhaled (H300, H330). Exposure must be strictly minimized.

  • Corrosive: Causes severe skin burns and eye damage (H314). Protective equipment is mandatory.

  • Hygroscopic and Moisture Sensitive: Rapidly absorbs moisture and hydrolyzes, releasing toxic hydrogen chloride (HCl) gas. Extreme care must be taken to avoid moisture during storage and handling.

  • Environmental Hazard: Very toxic to aquatic life (H400/H410). Release into water sources must be strictly prevented.

  • Thermal Decomposition: Decomposes at ~380°C releasing toxic chlorine gas (Cl₂). Ventilation is essential.

BEST PRACTICE RECOMMENDATIONS:

  • Storage:

    • Store in a cool, dry, and well-ventilated area.

    • Use moisture-proof, airtight containers.

    • Keep away from water and moisture.

    • Store at room temperature (15-25°C).

    • Store locked up.

  • Handling:

    • Use in well-ventilated areas with local exhaust ventilation or under a fume hood.

    • Use a respirator, protective goggles, chemically resistant gloves, and protective clothing.

    • Avoid dust formation and inhalation.

    • Avoid contact with water and moisture.

    • Wash hands thoroughly after handling.

    • Remove contaminated clothing and wash before reuse.

  • Waste Management:

    • Dispose of in accordance with local regulations at licensed disposal facilities.

    • Do not discharge into water sources.

    • For large quantities, tellurium recovery should be considered.

LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Tellurium chloride is a highly toxic, corrosive, and environmentally hazardous substance; strict safety measures must be taken during handling, transport, and disposal.

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