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Dysprosium Chloride Hexahydrate, Dysprosium Chloride Hydrate, Dysprosium Trichloride Hexahydrate, 15059-52-6

Dysprosium Chloride Hexahydrate, Dysprosium Chloride Hydrate, Dysprosium Trichloride Hexahydrate, 15059-52-6

DYSPROSIUM CHLORIDE HEXAHYDRATE (DYCL₃·6H₂O)
DYSPROSIUM CHLORIDE HEXAHYDRATE / DYSPROSIUM TRICHLORIDE HEXAHYDRATE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Dysprosium Chloride Hexahydrate
Chemical Name Dysprosium(III) Chloride Hexahydrate, Dysprosium Trichloride Hexahydrate
Other Names DyCl₃·6H₂O, Dysprosium Chloride Hydrate
CAS Number 15059-52-6
EC Number (EINECS) 239-460-6
Chemical Formula DyCl₃·6H₂O
Molecular Weight 372.99 g/mol
Appearance Yellowish-green crystalline solid
Odor Odorless
Physical State (20°C) Solid (crystalline)

2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Dysprosium chloride hexahydrate is the hydrated form of the chloride salt of the rare earth element dysprosium. Dysprosium ions (Dy³⁺) and chloride ions (Cl⁻) are present in a 1:3 ratio. Each dysprosium chloride unit contains six molecules of water of hydration. The characteristic yellowish-green color originates from the dysprosium ions. Due to its hygroscopic nature, it is sensitive to degradation in humid environments. It exhibits high solubility in water.

Structural Features:

                    DYSPROSIUM CHLORIDE HEXAHYDRATE [DyCl₃·6H₂O]
                          |
                Dy³⁺ - Cl⁻ Ionic Bonds + 6H₂O
                          |
        +----------------+----------------+
        |                |                |
    Yellowish-Green    High Solubility   Highly
    Crystalline        in Water          Hygroscopic

2.2. Structural Properties

Parameter Value
Crystal Structure Monoclinic
Chemical Formula DyCl₃·6H₂O
Molecular Weight 372.99 g/mol
Density ~2.5 g/cm³
Appearance Yellowish-green crystalline solid
Melting Point ~600-700 °C (decomposes)
pH (1M solution) Slightly acidic (~5.0-6.0)

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance Yellowish-green crystalline solid -
Odor Odorless -
Chemical Formula DyCl₃·6H₂O -
Molecular Weight 372.99 g/mol -
Density ~2.5 g/cm³ -
Melting Point ~600-700 °C Decomposes
Solubility in Water (25°C) High solubility -
Solubility in Alcohol Soluble -
Solubility in Acids Soluble -
pH (1M solution) Slightly acidic (~5.0-6.0) -
Stability Hygroscopic Must be stored in moisture-free conditions
Hygroscopicity High Absorbs moisture from air

4. PURITY GRADES

Parameter Technical Grade High Purity Grade Analytical Grade
Purity (DyCl₃·6H₂O) ≥ 99.0% ≥ 99.5% ≥ 99.9%
Dysprosium (Dy) Content ≥ 43.5% ≥ 44.0% ≥ 44.3%
Other Rare Earths ≤ 1.0% ≤ 0.5% ≤ 0.1%
Iron (Fe) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm
Calcium (Ca) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm
Sodium (Na) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm
Lead (Pb) ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Sulfate (SO₄²⁻) ≤ 0.2% ≤ 0.1% ≤ 0.05%
Nitrate (NO₃⁻) ≤ 0.2% ≤ 0.1% ≤ 0.05%
Chloride (Cl⁻) ≥ 28.5% ≥ 29.0% ≥ 29.3%
Loss on Drying Variable Variable Variable
Particle Size (D50) 10-50 µm 5-20 µm 1-10 µm

5. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Hygroscopic; stable under dry, closed conditions.
Conditions to Avoid High humidity, exposure to open atmosphere, prolonged air contact, high temperatures.
Incompatible Materials Strong oxidizing agents, strong acids, alkali metals.
Hazardous Decomposition Products At high temperatures: hydrogen chloride (HCl) and dysprosium oxychloride (DyOCl).
Hazardous Polymerization Will not occur.
Hygroscopicity High; when exposed to air, it absorbs moisture and tends to deliquesce (become liquid).

5.1. Chemical Reactions

  • Thermal Decomposition (Hydrated Form):
    DyCl₃·6H₂O → DyCl₃ + 6H₂O (~100-150°C)
    DyCl₃ + H₂O → DyOCl + 2HCl (hydrolysis at high temperature)

  • Behavior in Aqueous Solution:
    DyCl₃(aq) → Dy³⁺(aq) + 3Cl⁻(aq)

  • Precipitation with Alkali:
    DyCl₃ + 3NaOH → Dy(OH)₃↓ + 3NaCl

6. APPLICATION AREAS
6.1. Magnet Industry

Application Function Details
High Performance Magnets Additive Dy-Fe-B systems, NdFeB magnets
Magnet Alloys Alloying element High temperature resistance enhancer
Dysprosium Metal Production Precursor Raw material for NdFeB magnets

6.2. Optical Materials

Application Function Details
Photonics Materials Additive Light emitting and detecting applications
Luminescent Materials Light conversion Special phosphor formulations
Optical Glasses Rare earth additive Special optical applications

6.3. Catalyst Applications

Application Function Details
Organic Synthesis Catalyst Catalytic activity Various organic transformations
Polymerization Catalyst Polymerization initiator Some polymerization reactions

6.4. Ceramics

Application Function Details
Dysprosium-Doped Ceramics Additive Special ceramic applications
Advanced Ceramics Property enhancement Mechanical and thermal properties

6.5. Research

Application Function Details
Rare Earth Chemistry Reagent and analysis Rare earth chemistry research
Coordination Complexes Starting material Coordination chemistry studies
Standard Preparation Reference material Calibration and analysis studies

6.6. Sectoral Suitability Table

Sector Suitability Explanation
Electronics Suitable Magnetic and optical applications
Magnet Industry Suitable NdFeB magnets, Dy-Fe-B systems
Optical Materials Suitable Photonics, luminescent materials
Catalyst Suitable Organic synthesis, polymerization
Ceramics Suitable Advanced ceramic applications
Research Suitable Chemical and materials science studies
Pharmaceutical Not Suitable Not suitable
Agriculture Not Suitable Not suitable
Food Not Suitable Not suitable

7. PRODUCTION PROCESS

Stage Process Description
1. Raw Material Preparation Dysprosium oxide (Dy₂O₃) High purity dysprosium oxide obtained
2. Acid Dissolution Dissolution in hydrochloric acid (HCl) Dy₂O₃ + 6HCl → 2DyCl₃ + 3H₂O
3. Filtration Removal of impurities Insoluble impurities are filtered out
4. Concentration Evaporation Solution is concentrated
5. Crystallization Hydrated form DyCl₃·6H₂O crystallized
6. Drying Controlled conditions Crystals dried under appropriate conditions
7. Packaging Moisture-proof packaging Packaged in moisture-proof containers due to hygroscopic nature

7.1. Major Producing Countries

Country Description
China Major producer
USA Rare earth production (Sigma-Aldrich, American Elements)
Germany High purity production (Alfa Aesar)
Japan High purity production

8. ALTERNATIVE / SUBSTITUTE PRODUCTS

Alternative Description When to Use
Dysprosium Oxide (Dy₂O₃) Dysprosium source When oxide form is required
Dysprosium Nitrate (Dy(NO₃)₃) Dysprosium source When different anion is required
Dysprosium Acetate Organic synthesis When organic solvent compatibility is required
Terbium Chloride (TbCl₃) Similar chemical properties When Tb is required
Holmium Chloride (HoCl₃) Similar chemical properties When Ho is required

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 2,000 mg/kg (low toxicity)
Dermal Toxicity Low
Skin Irritation Mild to moderate irritant
Eye Irritation Serious irritant
Inhalation Dust inhalation may cause respiratory tract irritation.
Carcinogenicity Not classified as carcinogenic.
Mutagenicity Not mutagenic.
Chronic Effects Rare earth compounds have low bioavailability; however, high doses may cause liver effects.
Environmental Hazards Moderate aquatic toxicity; caution required due to chloride ion content.

9.1. GHS Classification

Hazard Class Category H-Statement
Skin Irritation Category 2 H315: Causes skin irritation.
Eye Irritation Category 2A H319: Causes serious eye irritation.
Specific Target Organ Toxicity Category 3 H335: May cause respiratory irritation.

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

10. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust.
P264 Wash thoroughly after handling.
P271 Use only in well-ventilated areas.
P280 Wear protective gloves/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
P337+P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local regulations.

11. FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air. If symptoms persist, seek medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention.
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention.
Ingestion Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention.

12. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, and well-ventilated area. Storage under inert atmosphere (Argon or Nitrogen) is recommended.
Container Requirements Moisture-proof, airtight, tightly closed containers. Glass bottle or PTFE-lined containers.
Temperature Room temperature (15-25°C).
Shelf Life 12-18 months under appropriate conditions (due to hygroscopic nature).
Stability Note Highly hygroscopic; rapidly degrades in humid environments. If left open, Dy(OH)₃ and Dy₂(CO₃)₃ may form.

13. PACKAGING OPTIONS

Packaging Type Quantity Material
Laboratory Packaging 5 g, 10 g, 25 g, 50 g Glass bottle, sealed cap, inert atmosphere
Laboratory Packaging 100 g, 500 g HDPE bottle, inert atmosphere
Industrial Packaging 25 kg PE-lined bag, moisture-proof
Drum 25 kg, 50 kg HDPE drum, moisture-proof

14. TRANSPORT INFORMATION

Parameter Information
UN Number Not classified (specific regulations apply for rare earth compounds)
Hazard Class -
Packing Group -
ADR/RID Not regulated
IMDG Not regulated
IATA Not regulated
HS Code 2846.90.00.00.19 (Other rare earth compounds)

15. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Registered
Turkey (KKDIK) Compliance required
TSCA (USA) Registered
CLP/GHS Compliant
FDA/EFSA Not approved as a food additive
ISO 9001:2015 Production compliance

16. OTHER NAMES AND SYNONYMS

Name Description
Dysprosium Trichloride Hexahydrate Chemical name
Dysprosium(III) Chloride Hexahydrate Chemical name
DyCl₃·6H₂O Chemical abbreviation
Dysprosium Chloride Hydrate English name
Dysprosium Trichloride Hexahydrate English name

17. QUICK REFERENCE TABLE

Property Value
CAS Number 15059-52-6
EC Number 239-460-6
Chemical Formula DyCl₃·6H₂O
Molecular Weight 372.99 g/mol
Appearance Yellowish-green crystalline solid
Density ~2.5 g/cm³
Melting Point ~600-700 °C
Solubility in Water High solubility
HS Code 2846.90.00.00.19
GHS Signal Word WARNING

18. CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • Highly Hygroscopic Nature: Dysprosium chloride hexahydrate has a very high moisture absorption capacity. When exposed to air, it rapidly absorbs moisture, begins to dissolve, and loses its quality. Extreme care must be taken to avoid moisture during storage and handling.

  • Thermal Decomposition: Above ~100-150°C, water loss begins; at higher temperatures, toxic hydrogen chloride (HCl) gas is released. Ventilation is essential.

  • Incompatibility: Contact with strong oxidizing agents creates a fire and explosion risk.

  • Eye and Skin Irritation: Due to its acidic nature, it causes irritation to skin and eyes. Protective equipment is mandatory during use.

  • High Value: Dysprosium is a critical and valuable rare earth element for NdFeB magnets; losses should be minimized and recycling options explored.

BEST PRACTICE RECOMMENDATIONS:

  • Storage:

    • Store in a cool, dry, and well-ventilated area.

    • Use moisture-proof, airtight containers.

    • Keep away from oxidizing agents.

    • Store at room temperature (15-25°C).

  • Handling:

    • Immediately close containers tightly when not in use.

    • Ensure a dry working environment during use (humidity control).

    • Use a dust mask (N95 or better), protective goggles, and chemically resistant gloves.

    • Avoid dust formation and inhalation.

    • Wash hands thoroughly after handling.

    • When preparing solutions, add slowly due to acidic character.

  • Waste Management:

    • Dispose of in accordance with local regulations as heavy metal waste.

    • Do not discharge into water sources or sewers.

    • For large quantities, rare earth recovery should be considered.

LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Dysprosium chloride hexahydrate requires careful handling and storage due to its highly hygroscopic nature and critical role in the magnet industry; it is an important raw material for high-performance magnets, optical materials, and catalyst applications.

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