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Erbium Chloride Hydrate, Erbium Trichloride Hexahydrate, 10025-75-9

Erbium Chloride Hydrate, Erbium Trichloride Hexahydrate, 10025-75-9

ERBIUM CHLORIDE HEXAHYDRATE (ERCL₃·6H₂O)
ERBIUM CHLORIDE HYDRATE / ERBIUM TRICHLORIDE HEXAHYDRATE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Erbium Chloride Hexahydrate
Chemical Name Erbium(III) Chloride Hexahydrate, Erbium Trichloride Hexahydrate
Other Names ErCl₃·6H₂O, Erbium Chloride Hydrate
CAS Number 10025-75-9
EC Number (EINECS) 233-385-0
Chemical Formula ErCl₃·6H₂O
Molecular Weight 381.71 g/mol
Appearance Pink crystals or particles
Odor Odorless
Physical State (20°C) Solid (crystalline)

2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Erbium chloride hexahydrate is the hydrated form of the chloride salt of the rare earth element erbium. Erbium ions (Er³⁺) and chloride ions (Cl⁻) are present in a 1:3 ratio. Each erbium chloride unit contains six molecules of water of hydration. The characteristic pink color originates from the erbium ions. Due to its hygroscopic nature, it is sensitive to degradation in humid environments. It is soluble in water and has limited solubility in ethanol.

Structural Features:

                    ERBIUM CHLORIDE HEXAHYDRATE [ErCl₃·6H₂O]
                          |
                Er³⁺ - Cl⁻ Ionic Bonds + 6H₂O
                          |
        +----------------+----------------+
        |                |                |
    Pink Crystalline   Soluble in        Highly
                       Water             Hygroscopic

2.2. Structural Properties

Parameter Value
Crystal Structure Monoclinic
Chemical Formula ErCl₃·6H₂O
Molecular Weight 381.71 g/mol
Density ~2.5 g/cm³
Appearance Pink crystals or particles
Melting Point ~774 °C (anhydrous form)
pH (1M solution) Slightly acidic (~5.0-6.0)

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance Pink crystals or particles -
Odor Odorless -
Chemical Formula ErCl₃·6H₂O -
Molecular Weight 381.71 g/mol -
Density ~2.5 g/cm³ -
Melting Point ~774 °C Anhydrous form
Solubility in Water (25°C) Soluble -
Solubility in Ethanol Limited solubility -
Solubility in Acids Soluble -
pH (1M solution) Slightly acidic (~5.0-6.0) -
Stability Hygroscopic Must be stored in moisture-free conditions
Hygroscopicity High Absorbs moisture from air

4. PURITY GRADES

Parameter Technical Grade High Purity Grade Analytical Grade
Purity (ErCl₃·6H₂O) ≥ 99.0% ≥ 99.5% ≥ 99.9%
Erbium (Er) Content ≥ 43.5% ≥ 44.0% ≥ 44.3%
Other Rare Earths ≤ 1.0% ≤ 0.5% ≤ 0.1%
Iron (Fe) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm
Calcium (Ca) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm
Sodium (Na) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm
Lead (Pb) ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Sulfate (SO₄²⁻) ≤ 0.2% ≤ 0.1% ≤ 0.05%
Nitrate (NO₃⁻) ≤ 0.2% ≤ 0.1% ≤ 0.05%
Chloride (Cl⁻) ≥ 27.5% ≥ 28.0% ≥ 28.3%
Loss on Drying Variable Variable Variable
Particle Size (D50) 10-50 µm 5-20 µm 1-10 µm

5. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Hygroscopic; stable under dry, closed conditions.
Conditions to Avoid High humidity, exposure to open atmosphere, prolonged air contact, high temperatures.
Incompatible Materials Strong oxidizing agents, strong acids, alkali metals.
Hazardous Decomposition Products At high temperatures: hydrogen chloride (HCl) and erbium oxychloride (ErOCl).
Hazardous Polymerization Will not occur.
Hygroscopicity High; when exposed to air, it absorbs moisture and tends to deliquesce (become liquid).

5.1. Chemical Reactions

  • Thermal Decomposition (Hydrated Form):
    ErCl₃·6H₂O → ErCl₃ + 6H₂O (~100-150°C)
    ErCl₃ + H₂O → ErOCl + 2HCl (hydrolysis at high temperature)

  • Behavior in Aqueous Solution:
    ErCl₃(aq) → Er³⁺(aq) + 3Cl⁻(aq)

  • Precipitation with Alkali:
    ErCl₃ + 3NaOH → Er(OH)₃↓ + 3NaCl

6. APPLICATION AREAS
6.1. Optical Materials

Application Function Details
Laser Crystals Additive Erbium-doped laser systems
Fiber Optic Systems Signal amplification Erbium-doped fiber optic amplifiers (EDFA)
Optical Glasses Rare earth additive Special optical applications
Erbium-Doped Glass Optical properties Laser and sensor applications

6.2. Catalyst Applications

Application Function Details
Organic Synthesis Catalyst Catalytic activity Various organic transformations
Polymerization Catalyst Polymerization initiator Some polymerization reactions

6.3. Ceramics and Glass

Application Function Details
Erbium-Doped Ceramics Additive Special ceramic applications
Optical Glass Production Additive Special glass formulations

6.4. Photonics and Quantum Materials

Application Function Details
Photonics Research Material development Quantum and photonic applications
Quantum Materials Starting material Advanced materials research

6.5. Research

Application Function Details
Rare Earth Chemistry Reagent and analysis Rare earth chemistry research
Coordination Complexes Starting material Coordination chemistry studies
Standard Preparation Reference material Calibration and analysis studies

6.6. Sectoral Suitability Table

Sector Suitability Explanation
Optical Materials Suitable Lasers, fiber optic systems
Electronics Suitable Optical and photonic applications
Catalyst Suitable Organic synthesis, polymerization
Ceramics/Glass Suitable Special ceramics and glass production
Research Suitable Photonics, quantum materials
Pharmaceutical Not Suitable Not suitable
Agriculture Not Suitable Not suitable
Food Not Suitable Not suitable

7. PRODUCTION PROCESS

Stage Process Description
1. Raw Material Preparation Erbium oxide (Er₂O₃) High purity erbium oxide obtained
2. Acid Dissolution Dissolution in hydrochloric acid (HCl) Er₂O₃ + 6HCl → 2ErCl₃ + 3H₂O
3. Filtration Removal of impurities Insoluble impurities are filtered out
4. Concentration Evaporation Solution is concentrated
5. Crystallization Hydrated form ErCl₃·6H₂O crystallized
6. Drying Controlled conditions Crystals dried under appropriate conditions
7. Packaging Moisture-proof packaging Packaged in moisture-proof containers due to hygroscopic nature

7.1. Major Producing Countries

Country Description
China Major producer
USA Rare earth production (Sigma-Aldrich, American Elements)
Germany High purity production
Japan High purity production

8. ALTERNATIVE / SUBSTITUTE PRODUCTS

Alternative Description When to Use
Erbium Oxide (Er₂O₃) Erbium source When oxide form is required
Erbium Nitrate (Er(NO₃)₃) Erbium source When different anion is required
Erbium Acetate Organic synthesis When organic solvent compatibility is required
Ytterbium Chloride (YbCl₃) Similar chemical properties When Yb is required
Holmium Chloride (HoCl₃) Similar chemical properties When Ho is required

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 2,000 mg/kg (low toxicity)
Dermal Toxicity Low
Skin Irritation Mild to moderate irritant
Eye Irritation Serious irritant
Inhalation Dust inhalation may cause respiratory tract irritation.
Carcinogenicity Not classified as carcinogenic.
Mutagenicity Not mutagenic.
Chronic Effects Rare earth compounds have low bioavailability; however, high doses may cause liver effects.
Environmental Hazards Moderate aquatic toxicity; caution required due to chloride ion content.

9.1. GHS Classification

Hazard Class Category H-Statement
Skin Irritation Category 2 H315: Causes skin irritation.
Eye Irritation Category 2A H319: Causes serious eye irritation.
Specific Target Organ Toxicity Category 3 H335: May cause respiratory irritation.

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

10. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust.
P264 Wash thoroughly after handling.
P271 Use only in well-ventilated areas.
P280 Wear protective gloves/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
P337+P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local regulations.

11. FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air. If symptoms persist, seek medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention.
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention.
Ingestion Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention.

12. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, and well-ventilated area. Storage under inert atmosphere (Argon or Nitrogen) is recommended.
Container Requirements Moisture-proof, airtight, tightly closed containers. Glass bottle or PTFE-lined containers.
Temperature Room temperature (15-25°C).
Shelf Life 12-18 months under appropriate conditions (due to hygroscopic nature).
Stability Note Highly hygroscopic; rapidly degrades in humid environments. If left open, Er(OH)₃ and Er₂(CO₃)₃ may form.

13. PACKAGING OPTIONS

Packaging Type Quantity Material
Laboratory Packaging 5 g, 10 g, 25 g, 50 g Glass bottle, sealed cap, inert atmosphere
Laboratory Packaging 100 g, 500 g HDPE bottle, inert atmosphere
Industrial Packaging 25 kg PE-lined bag, moisture-proof
Drum 25 kg, 50 kg HDPE drum, moisture-proof

14. TRANSPORT INFORMATION

Parameter Information
UN Number Not classified (specific regulations apply for rare earth compounds)
Hazard Class -
Packing Group -
ADR/RID Not regulated
IMDG Not regulated
IATA Not regulated
HS Code 2846.90.00.00.19 (Other rare earth compounds)

15. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Registered
Turkey (KKDIK) Compliance required
TSCA (USA) Registered
CLP/GHS Compliant
FDA/EFSA Not approved as a food additive
ISO 9001:2015 Production compliance

16. OTHER NAMES AND SYNONYMS

Name Description
Erbium Trichloride Hexahydrate Chemical name
Erbium(III) Chloride Hexahydrate Chemical name
ErCl₃·6H₂O Chemical abbreviation
Erbium Chloride Hydrate English name
Erbium Trichloride Hexahydrate English name

17. QUICK REFERENCE TABLE

Property Value
CAS Number 10025-75-9
EC Number 233-385-0
Chemical Formula ErCl₃·6H₂O
Molecular Weight 381.71 g/mol
Appearance Pink crystals or particles
Density ~2.5 g/cm³
Melting Point ~774 °C (anhydrous form)
Solubility in Water Soluble
HS Code 2846.90.00.00.19
GHS Signal Word WARNING

18. CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • Highly Hygroscopic Nature: Erbium chloride hexahydrate has a very high moisture absorption capacity. When exposed to air, it rapidly absorbs moisture, begins to dissolve, and loses its quality. Extreme care must be taken to avoid moisture during storage and handling.

  • Thermal Decomposition: Above ~100-150°C, water loss begins; at higher temperatures, toxic hydrogen chloride (HCl) gas is released. Ventilation is essential.

  • Incompatibility: Contact with strong oxidizing agents creates a fire and explosion risk.

  • Eye and Skin Irritation: Due to its acidic nature, it causes irritation to skin and eyes. Protective equipment is mandatory during use.

  • Optical Applications: Erbium is a critical element for fiber optic amplifiers (EDFA) and laser systems; high purity requirements are essential.

BEST PRACTICE RECOMMENDATIONS:

  • Storage:

    • Store in a cool, dry, and well-ventilated area.

    • Use moisture-proof, airtight containers.

    • Keep away from oxidizing agents.

    • Store at room temperature (15-25°C).

  • Handling:

    • Immediately close containers tightly when not in use.

    • Ensure a dry working environment during use (humidity control).

    • Use a dust mask (N95 or better), protective goggles, and chemically resistant gloves.

    • Avoid dust formation and inhalation.

    • Wash hands thoroughly after handling.

    • When preparing solutions, add slowly due to acidic character.

  • Waste Management:

    • Dispose of in accordance with local regulations as heavy metal waste.

    • Do not discharge into water sources or sewers.

    • For large quantities, rare earth recovery should be considered.

LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Erbium chloride hexahydrate requires careful handling and storage due to its highly hygroscopic nature and critical role in optical applications; it is an important raw material for laser, fiber optic, and catalyst applications.

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