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Calcium Chloride Anhydrous, Calcium Dichloride, 10043-52-4

Calcium Chloride Anhydrous, Calcium Dichloride, 10043-52-4

CALCIUM CHLORIDE (CACL₂)
CALCIUM CHLORIDE ANHYDROUS / CALCIUM DICHLORIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Calcium Chloride
Chemical Name Calcium Chloride Anhydrous, Calcium Dichloride
Other Names Calcium Salt, Desiccant Salt, CaCl₂
CAS Number 10043-52-4
EC Number (EINECS) 233-140-8
Chemical Formula CaCl₂
Molecular Weight 110.98 g/mol
Appearance White crystalline solid (powder, granule or prill)
Odor Odorless
Physical State (20°C) Solid

2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Calcium chloride is an ionic compound of calcium and chlorine. Calcium ions (Ca²⁺) and chloride ions (Cl⁻) are present in a 1:2 ratio. It is known for its highly hygroscopic nature; it strongly absorbs moisture from the air. It exhibits high solubility in water and the dissolution is exothermic (releases heat).

Structural Features:

                    CALCIUM CHLORIDE [CaCl₂]
                          |
                Ca²⁺ - Cl⁻ Ionic Bonds
                          |
        +----------------+----------------+
        |                |                |
    Ionic Crystal     Highly           Strong
    Structure         Hygroscopic      Desiccant

2.2. Structural Properties

Parameter Value
Crystal Structure Orthorhombic (anhydrous)
Chemical Formula CaCl₂
Molecular Weight 110.98 g/mol
Density ~2.17 g/cm³ (20 °C)
Appearance White crystalline solid
Melting Point ~772 °C
Boiling Point ~1,600 °C
pH (1M solution) ~5.0-8.0

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance White crystalline solid Powder, granule or prill form
Odor Odorless -
Chemical Formula CaCl₂ -
Molecular Weight 110.98 g/mol -
Density ~2.17 g/cm³ -
Melting Point ~772 °C -
Solubility in Water (25°C) High (~74.5 g/100 mL) -
Solubility in Ethanol Soluble -
Heat of Solution Exothermic (-82 kJ/mol) Releases heat
Hygroscopicity Very high Strong moisture absorber
pH (1M solution) ~5.0-8.0 -
Stability Stable in air, absorbs moisture Must be stored in closed containers
Vapor Pressure Low -

4. PURITY GRADES

Parameter Industrial Grade Food Grade Analytical Grade
Purity (CaCl₂) ≥ 96.0% ≥ 97.0% ≥ 99.0%
Calcium (Ca) Content ≥ 34.5% ≥ 34.9% ≥ 35.5%
Chloride (Cl⁻) Content ≥ 61.5% ≥ 62.0% ≥ 63.0%
Magnesium (Mg) ≤ 1.0% ≤ 0.5% ≤ 0.1%
Sodium (Na) ≤ 1.0% ≤ 0.5% ≤ 0.1%
Iron (Fe) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm
Lead (Pb) ≤ 50 ppm ≤ 10 ppm ≤ 5 ppm
Arsenic (As) ≤ 10 ppm ≤ 3 ppm ≤ 1 ppm
Sulfate (SO₄²⁻) ≤ 0.5% ≤ 0.2% ≤ 0.1%
Moisture / Loss on Drying ≤ 5.0% ≤ 2.0% ≤ 1.0%
Particle Size Variable Variable Variable

5. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Stable under normal conditions; decomposes at high temperatures.
Conditions to Avoid High humidity, prolonged air contact, contact with zinc and aluminum.
Incompatible Materials Strong oxidizing agents, zinc, aluminum, magnesium.
Hazardous Decomposition Products At high temperatures: hydrogen chloride (HCl).
Hazardous Polymerization Will not occur.
Hygroscopicity Very high; rapidly absorbs moisture and may liquefy when exposed to air.

5.1. Chemical Reactions

  • Behavior in Aqueous Solution:
    CaCl₂(aq) → Ca²⁺(aq) + 2Cl⁻(aq)

  • Heat of Solution:
    CaCl₂ + H₂O → CaCl₂·2H₂O + Heat (exothermic)

  • Reaction with Sulfates:
    CaCl₂ + Na₂SO₄ → CaSO₄↓ + 2NaCl

  • Reaction with Carbonates:
    CaCl₂ + Na₂CO₃ → CaCO₃↓ + 2NaCl

6. APPLICATION AREAS
6.1. Desiccant and Moisture Absorber

Application Function Details
Industrial Desiccant Moisture absorption Gas, air and liquid drying
Desiccant Moisture control Moisture absorber in packaging
Laboratory Drying Agent Drying Chemical syntheses

6.2. De-icer and Road Salt

Application Function Details
Road Salt De-icing Snow and ice melting in winter
Dust Control Dust suppression Road dust control

6.3. Food Additive (E509)

Application Function Details
Firming Agent Texture preservative Canned foods, cheese production
Food Additive E509 Processed foods

6.4. Construction

Application Function Details
Concrete Accelerator Setting accelerator Accelerates concrete setting in cold weather
Dust Control Dust suppression Construction sites

6.5. Other Applications

Application Function Details
Textile Moisture control Textile processing
Paper Industry Moisture control Paper production
Pharmaceutical Moisture control Pharmaceutical formulations
Cooling Systems Cooling salt Ice and cooling mixtures

6.6. Sectoral Suitability Table

Sector Suitability Explanation
Food Suitable E509 additive
Textile Suitable Moisture control
Construction Suitable Concrete accelerator, dust control
Pharmaceutical Suitable Moisture control, formulation
Agriculture Limited Limited use
Petrochemical Suitable Drying operations
Cooling Suitable Cooling salt

7. PRODUCTION PROCESS

Stage Process Description
1. Raw Material Preparation Calcium carbonate (CaCO₃) or natural brine High purity raw materials
2. Reaction Reaction with HCl CaCO₃ + 2HCl → CaCl₂ + CO₂↑ + H₂O
3. Purification Chemical treatments Removal of impurities
4. Concentration Evaporation Solution is concentrated
5. Drying Thermal treatment Conversion to anhydrous form
6. Formulation Powder, granule or prill Production in desired form
7. Quality Control Analysis and testing ICP-OES, titration, pH

7.1. Major Producing Countries

Country Description
China Major producer
India Major producer
USA Major producer
Europe Major producer

8. ALTERNATIVE / SUBSTITUTE PRODUCTS

Alternative Description When to Use
Magnesium Chloride (MgCl₂) De-icer Lower temperature effectiveness
Sodium Chloride (NaCl) De-icer Lower effectiveness
Potassium Acetate Eco-friendly de-icer When environmental sensitivity is required
Calcium Chloride Dihydrate Less hygroscopic Less hygroscopic form
Sodium Sulfate Desiccant Different drying applications

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) ~1,000 mg/kg (moderate toxicity)
Dermal Toxicity Low
Skin Irritation Mild to moderate irritant
Eye Irritation Serious irritant
Inhalation Dust inhalation may cause respiratory tract irritation.
Carcinogenicity Not classified as carcinogenic.
Mutagenicity Not mutagenic.
Chronic Effects Prolonged exposure may cause skin irritation and gastrointestinal effects.
Environmental Hazards Low to moderate aquatic toxicity.

9.1. GHS Classification

Hazard Class Category H-Statement
Skin Irritation Category 2 H315: Causes skin irritation.
Eye Irritation Category 2A H319: Causes serious eye irritation.
Specific Target Organ Toxicity Category 3 H335: May cause respiratory irritation.

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

10. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust.
P264 Wash thoroughly after handling.
P271 Use only in well-ventilated areas.
P280 Wear protective gloves/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
P337+P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local regulations.

11. FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air. If symptoms persist, seek medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention.
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention.
Ingestion Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention.

12. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, and well-ventilated area. Ensure a moisture-free environment.
Container Requirements Moisture-proof, tightly closed containers.
Temperature Room temperature (15-25°C).
Shelf Life 24-36 months under appropriate conditions.
Stability Note Hygroscopic; rapidly absorbs moisture and may liquefy in humid environments. Must be stored in closed packaging.

13. PACKAGING OPTIONS

Packaging Type Quantity Material
Laboratory Packaging 100 g, 500 g, 1 kg HDPE bottle, aluminum foil bag
Industrial Packaging 25 kg PE-lined kraft bag, moisture-proof
Big-Bag 500 kg, 1000 kg Moisture-proof, palletized
IBC (Intermediate Bulk Container) 1000 kg Moisture-proof

14. TRANSPORT INFORMATION

Parameter Information
UN Number Not classified (no ADR classification)
Hazard Class -
Packing Group -
ADR/RID Not regulated
IMDG Not regulated
IATA Not regulated
HS Code 2827.20.00.00.00 (Calcium chloride)

15. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Registered (01-2119494219-28)
Turkey (KKDIK) Compliance required
TSCA (USA) Registered
FDA/EFSA Approved as food additive E509
ISO 9001:2015 Production compliance

16. OTHER NAMES AND SYNONYMS

Name Description
Calcium Salt Common name
Calcium Dichloride Chemical name
CaCl₂ Chemical abbreviation
Desiccant Salt Trade name
CaCl₂ Flakes Flake form
Calcium Dichloride English name
Calcium Chloride Anhydrous English name

17. QUICK REFERENCE TABLE

Property Value
CAS Number 10043-52-4
EC Number 233-140-8
Chemical Formula CaCl₂
Molecular Weight 110.98 g/mol
Appearance White crystalline solid
Density ~2.17 g/cm³
Melting Point ~772 °C
Solubility in Water High (~74.5 g/100 mL)
HS Code 2827.20.00.00.00
GHS Signal Word WARNING
REACH Registration No 01-2119494219-28

18. CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • Highly Hygroscopic Nature: Calcium chloride has a very high moisture absorption capacity. When exposed to air, it rapidly absorbs moisture, liquefies, and loses its quality. Extreme care must be taken to avoid moisture during storage and handling.

  • Exothermic Dissolution: Releases heat upon contact with water; caution must be taken against splashing and burning when mixing with large amounts of water.

  • Incompatibility: Contact with metals such as zinc, aluminum, and magnesium causes corrosion.

  • Eye and Skin Irritation: Causes irritation to skin and eyes. Protective equipment is mandatory during use.

  • Food Grade: Only food grade (E509) should be used for food applications; industrial grade must not come into contact with food.

BEST PRACTICE RECOMMENDATIONS:

  • Storage:

    • Store in a cool, dry, and well-ventilated area.

    • Use moisture-proof, tightly closed containers.

    • Keep away from metals to prevent corrosion.

    • Store at room temperature (15-25°C).

  • Handling:

    • Immediately close containers tightly when not in use.

    • Use a dust mask (N95 or better), protective goggles, and chemically resistant gloves.

    • Avoid dust formation and inhalation.

    • Wash hands thoroughly after handling.

    • When mixing with water, add slowly and allow for temperature increase of the mixing vessel.

    • For food applications, only use food grade product.

  • Waste Management:

    • Dispose of in accordance with local regulations.

    • Can be disposed of by dilution with water.

    • Do not discharge into water sources in high concentrations.

LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Calcium chloride requires careful handling and storage due to its highly hygroscopic nature and exothermic dissolution; it is a versatile chemical widely used in food, construction, drying, and de-icing applications.

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