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Send EmailCalcium Chloride Anhydrous, Calcium Dichloride, 10043-52-4
CALCIUM CHLORIDE (CACL₂)
CALCIUM CHLORIDE ANHYDROUS / CALCIUM DICHLORIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY
| Parameter | Information |
|---|---|
| Product Name | Calcium Chloride |
| Chemical Name | Calcium Chloride Anhydrous, Calcium Dichloride |
| Other Names | Calcium Salt, Desiccant Salt, CaCl₂ |
| CAS Number | 10043-52-4 |
| EC Number (EINECS) | 233-140-8 |
| Chemical Formula | CaCl₂ |
| Molecular Weight | 110.98 g/mol |
| Appearance | White crystalline solid (powder, granule or prill) |
| Odor | Odorless |
| Physical State (20°C) | Solid |
2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Calcium chloride is an ionic compound of calcium and chlorine. Calcium ions (Ca²⁺) and chloride ions (Cl⁻) are present in a 1:2 ratio. It is known for its highly hygroscopic nature; it strongly absorbs moisture from the air. It exhibits high solubility in water and the dissolution is exothermic (releases heat).
Structural Features:
CALCIUM CHLORIDE [CaCl₂]
|
Ca²⁺ - Cl⁻ Ionic Bonds
|
+----------------+----------------+
| | |
Ionic Crystal Highly Strong
Structure Hygroscopic Desiccant
2.2. Structural Properties
| Parameter | Value |
|---|---|
| Crystal Structure | Orthorhombic (anhydrous) |
| Chemical Formula | CaCl₂ |
| Molecular Weight | 110.98 g/mol |
| Density | ~2.17 g/cm³ (20 °C) |
| Appearance | White crystalline solid |
| Melting Point | ~772 °C |
| Boiling Point | ~1,600 °C |
| pH (1M solution) | ~5.0-8.0 |
3. PHYSICAL AND CHEMICAL PROPERTIES
| Property | Value | Description |
|---|---|---|
| Appearance | White crystalline solid | Powder, granule or prill form |
| Odor | Odorless | - |
| Chemical Formula | CaCl₂ | - |
| Molecular Weight | 110.98 g/mol | - |
| Density | ~2.17 g/cm³ | - |
| Melting Point | ~772 °C | - |
| Solubility in Water (25°C) | High (~74.5 g/100 mL) | - |
| Solubility in Ethanol | Soluble | - |
| Heat of Solution | Exothermic (-82 kJ/mol) | Releases heat |
| Hygroscopicity | Very high | Strong moisture absorber |
| pH (1M solution) | ~5.0-8.0 | - |
| Stability | Stable in air, absorbs moisture | Must be stored in closed containers |
| Vapor Pressure | Low | - |
4. PURITY GRADES
| Parameter | Industrial Grade | Food Grade | Analytical Grade |
|---|---|---|---|
| Purity (CaCl₂) | ≥ 96.0% | ≥ 97.0% | ≥ 99.0% |
| Calcium (Ca) Content | ≥ 34.5% | ≥ 34.9% | ≥ 35.5% |
| Chloride (Cl⁻) Content | ≥ 61.5% | ≥ 62.0% | ≥ 63.0% |
| Magnesium (Mg) | ≤ 1.0% | ≤ 0.5% | ≤ 0.1% |
| Sodium (Na) | ≤ 1.0% | ≤ 0.5% | ≤ 0.1% |
| Iron (Fe) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm |
| Lead (Pb) | ≤ 50 ppm | ≤ 10 ppm | ≤ 5 ppm |
| Arsenic (As) | ≤ 10 ppm | ≤ 3 ppm | ≤ 1 ppm |
| Sulfate (SO₄²⁻) | ≤ 0.5% | ≤ 0.2% | ≤ 0.1% |
| Moisture / Loss on Drying | ≤ 5.0% | ≤ 2.0% | ≤ 1.0% |
| Particle Size | Variable | Variable | Variable |
5. STABILITY AND REACTIVITY
| Parameter | Information |
|---|---|
| Chemical Stability | Stable under normal conditions; decomposes at high temperatures. |
| Conditions to Avoid | High humidity, prolonged air contact, contact with zinc and aluminum. |
| Incompatible Materials | Strong oxidizing agents, zinc, aluminum, magnesium. |
| Hazardous Decomposition Products | At high temperatures: hydrogen chloride (HCl). |
| Hazardous Polymerization | Will not occur. |
| Hygroscopicity | Very high; rapidly absorbs moisture and may liquefy when exposed to air. |
5.1. Chemical Reactions
Behavior in Aqueous Solution:
CaCl₂(aq) → Ca²⁺(aq) + 2Cl⁻(aq)
Heat of Solution:
CaCl₂ + H₂O → CaCl₂·2H₂O + Heat (exothermic)
Reaction with Sulfates:
CaCl₂ + Na₂SO₄ → CaSO₄↓ + 2NaCl
Reaction with Carbonates:
CaCl₂ + Na₂CO₃ → CaCO₃↓ + 2NaCl
6. APPLICATION AREAS
6.1. Desiccant and Moisture Absorber
| Application | Function | Details |
|---|---|---|
| Industrial Desiccant | Moisture absorption | Gas, air and liquid drying |
| Desiccant | Moisture control | Moisture absorber in packaging |
| Laboratory Drying Agent | Drying | Chemical syntheses |
6.2. De-icer and Road Salt
| Application | Function | Details |
|---|---|---|
| Road Salt | De-icing | Snow and ice melting in winter |
| Dust Control | Dust suppression | Road dust control |
6.3. Food Additive (E509)
| Application | Function | Details |
|---|---|---|
| Firming Agent | Texture preservative | Canned foods, cheese production |
| Food Additive | E509 | Processed foods |
6.4. Construction
| Application | Function | Details |
|---|---|---|
| Concrete Accelerator | Setting accelerator | Accelerates concrete setting in cold weather |
| Dust Control | Dust suppression | Construction sites |
6.5. Other Applications
| Application | Function | Details |
|---|---|---|
| Textile | Moisture control | Textile processing |
| Paper Industry | Moisture control | Paper production |
| Pharmaceutical | Moisture control | Pharmaceutical formulations |
| Cooling Systems | Cooling salt | Ice and cooling mixtures |
6.6. Sectoral Suitability Table
| Sector | Suitability | Explanation |
|---|---|---|
| Food | Suitable | E509 additive |
| Textile | Suitable | Moisture control |
| Construction | Suitable | Concrete accelerator, dust control |
| Pharmaceutical | Suitable | Moisture control, formulation |
| Agriculture | Limited | Limited use |
| Petrochemical | Suitable | Drying operations |
| Cooling | Suitable | Cooling salt |
7. PRODUCTION PROCESS
| Stage | Process | Description |
|---|---|---|
| 1. Raw Material Preparation | Calcium carbonate (CaCO₃) or natural brine | High purity raw materials |
| 2. Reaction | Reaction with HCl | CaCO₃ + 2HCl → CaCl₂ + CO₂↑ + H₂O |
| 3. Purification | Chemical treatments | Removal of impurities |
| 4. Concentration | Evaporation | Solution is concentrated |
| 5. Drying | Thermal treatment | Conversion to anhydrous form |
| 6. Formulation | Powder, granule or prill | Production in desired form |
| 7. Quality Control | Analysis and testing | ICP-OES, titration, pH |
7.1. Major Producing Countries
| Country | Description |
|---|---|
| China | Major producer |
| India | Major producer |
| USA | Major producer |
| Europe | Major producer |
8. ALTERNATIVE / SUBSTITUTE PRODUCTS
| Alternative | Description | When to Use |
|---|---|---|
| Magnesium Chloride (MgCl₂) | De-icer | Lower temperature effectiveness |
| Sodium Chloride (NaCl) | De-icer | Lower effectiveness |
| Potassium Acetate | Eco-friendly de-icer | When environmental sensitivity is required |
| Calcium Chloride Dihydrate | Less hygroscopic | Less hygroscopic form |
| Sodium Sulfate | Desiccant | Different drying applications |
9. SAFETY AND TOXICOLOGY
| Parameter | Value |
|---|---|
| Acute Oral Toxicity (LD50, Rat) | ~1,000 mg/kg (moderate toxicity) |
| Dermal Toxicity | Low |
| Skin Irritation | Mild to moderate irritant |
| Eye Irritation | Serious irritant |
| Inhalation | Dust inhalation may cause respiratory tract irritation. |
| Carcinogenicity | Not classified as carcinogenic. |
| Mutagenicity | Not mutagenic. |
| Chronic Effects | Prolonged exposure may cause skin irritation and gastrointestinal effects. |
| Environmental Hazards | Low to moderate aquatic toxicity. |
9.1. GHS Classification
| Hazard Class | Category | H-Statement |
|---|---|---|
| Skin Irritation | Category 2 | H315: Causes skin irritation. |
| Eye Irritation | Category 2A | H319: Causes serious eye irritation. |
| Specific Target Organ Toxicity | Category 3 | H335: May cause respiratory irritation. |
Signal Word: WARNING
Hazard Pictograms: GHS07 (Exclamation Mark)
10. PRECAUTIONARY STATEMENTS (P-CODES)
| Code | Statement |
|---|---|
| P261 | Avoid breathing dust. |
| P264 | Wash thoroughly after handling. |
| P271 | Use only in well-ventilated areas. |
| P280 | Wear protective gloves/eye protection/face protection. |
| P302+P352 | IF ON SKIN: Wash with plenty of soap and water. |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing. |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. |
| P337+P313 | If eye irritation persists: Get medical advice/attention. |
| P501 | Dispose of contents/container in accordance with local regulations. |
11. FIRST AID MEASURES
| Exposure Route | Action to Take |
|---|---|
| Inhalation | Remove to fresh air. If symptoms persist, seek medical attention. |
| Skin Contact | Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention. |
| Eye Contact | Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention. |
| Ingestion | Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention. |
12. STORAGE AND SHELF LIFE
| Parameter | Condition |
|---|---|
| Storage Conditions | Store in a cool, dry, and well-ventilated area. Ensure a moisture-free environment. |
| Container Requirements | Moisture-proof, tightly closed containers. |
| Temperature | Room temperature (15-25°C). |
| Shelf Life | 24-36 months under appropriate conditions. |
| Stability Note | Hygroscopic; rapidly absorbs moisture and may liquefy in humid environments. Must be stored in closed packaging. |
13. PACKAGING OPTIONS
| Packaging Type | Quantity | Material |
|---|---|---|
| Laboratory Packaging | 100 g, 500 g, 1 kg | HDPE bottle, aluminum foil bag |
| Industrial Packaging | 25 kg | PE-lined kraft bag, moisture-proof |
| Big-Bag | 500 kg, 1000 kg | Moisture-proof, palletized |
| IBC (Intermediate Bulk Container) | 1000 kg | Moisture-proof |
14. TRANSPORT INFORMATION
| Parameter | Information |
|---|---|
| UN Number | Not classified (no ADR classification) |
| Hazard Class | - |
| Packing Group | - |
| ADR/RID | Not regulated |
| IMDG | Not regulated |
| IATA | Not regulated |
| HS Code | 2827.20.00.00.00 (Calcium chloride) |
15. REGULATORY STATUS
| Region / Authority | Status |
|---|---|
| European Union (REACH) | Registered (01-2119494219-28) |
| Turkey (KKDIK) | Compliance required |
| TSCA (USA) | Registered |
| FDA/EFSA | Approved as food additive E509 |
| ISO 9001:2015 | Production compliance |
16. OTHER NAMES AND SYNONYMS
| Name | Description |
|---|---|
| Calcium Salt | Common name |
| Calcium Dichloride | Chemical name |
| CaCl₂ | Chemical abbreviation |
| Desiccant Salt | Trade name |
| CaCl₂ Flakes | Flake form |
| Calcium Dichloride | English name |
| Calcium Chloride Anhydrous | English name |
17. QUICK REFERENCE TABLE
| Property | Value |
|---|---|
| CAS Number | 10043-52-4 |
| EC Number | 233-140-8 |
| Chemical Formula | CaCl₂ |
| Molecular Weight | 110.98 g/mol |
| Appearance | White crystalline solid |
| Density | ~2.17 g/cm³ |
| Melting Point | ~772 °C |
| Solubility in Water | High (~74.5 g/100 mL) |
| HS Code | 2827.20.00.00.00 |
| GHS Signal Word | WARNING |
| REACH Registration No | 01-2119494219-28 |
18. CRITICAL WARNINGS AND BEST PRACTICES
CRITICAL WARNINGS:
Highly Hygroscopic Nature: Calcium chloride has a very high moisture absorption capacity. When exposed to air, it rapidly absorbs moisture, liquefies, and loses its quality. Extreme care must be taken to avoid moisture during storage and handling.
Exothermic Dissolution: Releases heat upon contact with water; caution must be taken against splashing and burning when mixing with large amounts of water.
Incompatibility: Contact with metals such as zinc, aluminum, and magnesium causes corrosion.
Eye and Skin Irritation: Causes irritation to skin and eyes. Protective equipment is mandatory during use.
Food Grade: Only food grade (E509) should be used for food applications; industrial grade must not come into contact with food.
BEST PRACTICE RECOMMENDATIONS:
Storage:
Store in a cool, dry, and well-ventilated area.
Use moisture-proof, tightly closed containers.
Keep away from metals to prevent corrosion.
Store at room temperature (15-25°C).
Handling:
Immediately close containers tightly when not in use.
Use a dust mask (N95 or better), protective goggles, and chemically resistant gloves.
Avoid dust formation and inhalation.
Wash hands thoroughly after handling.
When mixing with water, add slowly and allow for temperature increase of the mixing vessel.
For food applications, only use food grade product.
Waste Management:
Dispose of in accordance with local regulations.
Can be disposed of by dilution with water.
Do not discharge into water sources in high concentrations.
LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Calcium chloride requires careful handling and storage due to its highly hygroscopic nature and exothermic dissolution; it is a versatile chemical widely used in food, construction, drying, and de-icing applications.