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Lanthanum Chloride, Lanthanum Trichloride, 10099-58-8

Lanthanum Chloride, Lanthanum Trichloride, 10099-58-8

LANTHANUM CHLORIDE (ANHYDROUS) 

1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Lanthanum Chloride
Chemical Name Lanthanum Trichloride, Lanthanum(III) Chloride
Other Names LaCl₃ anhydrous, Lanthanum chloride anhydrous, Lanthanum trichloride
CAS Number 10099-58-8
EC Number (EINECS) 233-237-5
Chemical Formula LaCl₃
Molecular Weight 245.26 g/mol
Appearance White crystalline, hygroscopic solid
Odor Odorless
Physical State (20°C) Solid (crystalline)

2. CHEMICAL STRUCTURE

2.1. Molecular Structure

Lanthanum chloride (anhydrous) is the chloride salt of lanthanum in its anhydrous form. Lanthanum ions (La³⁺) and chloride ions (Cl⁻) are present in a 1:3 ratio. Unlike the heptahydrate form, this compound contains no water of crystallization. It is highly hygroscopic and readily absorbs moisture from the air to form the hydrated salt.

Structural Features:

                    LANTHANUM CHLORIDE ANHYDROUS (LaCl₃)
                          |
                La³⁺ - Cl⁻ Ionic Bonds
                          |
        +----------------+----------------+
        |                |                |
    Ionic Crystal    No Water of        High Hygroscopic
    Structure        Hydration          Property

2.2. Structural Properties

Parameter Value
Crystal System Hexagonal (UCl₃ type structure)
Molecular Weight 245.26 g/mol
Water Content None (anhydrous)
Density ~3.84 g/cm³
Appearance White, hygroscopic crystals
Coordination Number 9

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance White crystalline, hygroscopic solid -
Odor Odorless -
Chemical Formula LaCl₃ -
Molecular Weight 245.26 g/mol -
Density ~3.84 g/cm³ -
Melting Point ~860 °C -
Boiling Point ~1860 °C -
Water Solubility (25°C) Completely soluble (>1000 g/L) -
Solubility in Ethanol Soluble -
Solubility in Acetone Slightly soluble -
pH (1% solution) Slightly acidic (~4-5) -
Hygroscopicity High Absorbs moisture from air
Stability Stable under normal conditions; moisture sensitive -

4. PURITY GRADES

Parameter Industrial Grade High Purity Grade Ultra High Purity Grade
Purity ≥ 99.0% ≥ 99.9% ≥ 99.99%
LaCl₃ Content ≥ 99.0% ≥ 99.9% ≥ 99.99%
Heavy Metals (as Pb) ≤ 50 ppm ≤ 10 ppm ≤ 5 ppm
Iron (Fe) ≤ 50 ppm ≤ 10 ppm ≤ 5 ppm
Calcium (Ca) ≤ 100 ppm ≤ 20 ppm ≤ 10 ppm
Sodium (Na) ≤ 100 ppm ≤ 20 ppm ≤ 10 ppm
Sulfate (SO₄²⁻) ≤ 0.1% ≤ 0.05% ≤ 0.02%
Nitrate (NO₃⁻) ≤ 0.1% ≤ 0.05% ≤ 0.02%
Other Rare Earths ≤ 1.0% ≤ 0.1% ≤ 0.01%

5. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Stable under normal conditions; readily absorbs moisture to form LaCl₃·7H₂O
Conditions to Avoid Moisture, high temperature (>860°C), strong oxidizing agents
Incompatible Materials Strong oxidizing agents, strong bases, reactive metals
Hazardous Decomposition Products Lanthanum oxide (La₂O₃), hydrogen chloride (HCl)
Hazardous Polymerization Will not occur
Hygroscopicity High; absorbs moisture from air, forms hydrated salt
Photosensitivity Low

5.1. Chemical Reactions

Hydration:

LaCl₃ + 7H₂O → LaCl₃·7H₂O (in moist air)

Reaction with Alkali:

LaCl₃ + 3NaOH → La(OH)₃↓ + 3NaCl

Reaction with Phosphate:

LaCl₃ + Na₃PO₄ → LaPO₄↓ + 3NaCl

Reaction with Oxalate:

2LaCl₃ + 3Na₂C₂O₄ → La₂(C₂O₄)₃↓ + 6NaCl

6. APPLICATION AREAS

6.1. Water Treatment and Phosphate Removal

Application Function Details
Phosphate Removal Phosphate binder Used in wastewater treatment plants to remove phosphates
Aquarium Water Treatment Phosphate control Controls phosphate levels in aquariums
Industrial Water Treatment Scale prevention Prevents scale formation
Eutrophication Control Nutrient removal Reduces nutrient load in water bodies

6.2. Catalyst and Organic Synthesis

Application Function Details
Lewis Acid Catalyst Acid catalyst Organic synthesis reactions
Petrochemicals Catalyst component Hydrocarbon conversion
Organic Reactions Catalyst Various organic syntheses
Polymerization Catalyst additive Polymer production
Intermediate Chemical intermediate Various chemical syntheses

6.3. Ceramics and Glass Production

Application Function Details
Ceramic Additive Thermal stability High temperature applications
Glass Additive Optical properties Improves glass characteristics
Refractory Materials Performance enhancer High temperature resistance
Electronic Ceramics Dopant Improves electrical properties

6.4. Phosphors and Optical Materials

Application Function Details
Phosphor Production Rare earth source Lanthanum-based phosphors
Optical Materials Optical component Specialty optical applications
Laser Materials Laser active medium Laser systems
Scintillators Radiation detection Nuclear applications

6.5. Electronics

Application Function Details
Dielectric Layers Insulating material Electronic components
Semiconductors Dopant Semiconductor manufacturing
Capacitors Dielectric additive Ceramic capacitors

6.6. Other Applications

Application Function Details
Laboratory Reagent Standard solution Preparation of rare earth solutions
Research Laboratory chemical Chemical research and development
Nanomaterial Precursor Synthesis precursor Lanthanum-containing nanomaterials
Battery Materials Electrolyte additive Lithium-ion batteries

7. PRODUCTION PROCESS

7.1. Ore Sources

Lanthanum chloride is derived from lanthanum-containing ores:

Ore Type Lanthanum Content Main Locations
Monazite 10-30% of REE content Australia, Brazil, India, China
Bastnäsite 20-30% of REE content China, USA (Mountain Pass), Vietnam
Xenotime 5-10% of REE content China, Malaysia, Australia

7.2. Production Process Flow

Lanthanum Oxide (La₂O₃)
         ↓
Dissolution in Hydrochloric Acid (HCl)
         ↓
LaCl₃ Solution Formation
         ↓
Filtration → Purification
         ↓
Evaporation → Crystallization
         ↓
LaCl₃·7H₂O Crystals
         ↓
Dehydration (Heating at 200-300°C)
         ↓
Anhydrous LaCl₃
         ↓
Classification → Packaging (Air-tight)

7.3. Process Stages

Stage Description
1. Raw Material Lanthanum oxide (La₂O₃) is used as starting material
2. Acid Dissolution Lanthanum oxide is dissolved in hydrochloric acid (HCl)
3. Solution Formation LaCl₃ solution is formed
4. Filtration Solution is filtered to remove impurities
5. Evaporation Water is evaporated to concentrate the solution
6. Crystallization LaCl₃·7H₂O crystals are formed
7. Dehydration Heptahydrate is heated at 200-300°C to remove water
8. Packaging Packaged in air-tight, moisture-proof containers

8. SECTOR SUITABILITY TABLE

Sector Suitability Note
Water Treatment Phosphate removal
Textile Not suitable
Ceramics / Glass High temperature applications
Electronics Dielectric layers, semiconductors
Food Not approved as food additive
Catalyst Lewis acid, organic synthesis
Pharmaceutical Not for direct pharmaceutical use

9. ALTERNATIVE MATERIALS COMPARISON

Application Area Alternative Materials Notes
Water Treatment (Phosphate Removal) Aluminum Sulfate, Ferric Chloride Different efficiency and cost
Catalyst Cerium Chloride, Yttrium Chloride Similar Lewis acid effects
Ceramics Yttrium Oxide, Cerium Oxide Different thermal properties

10. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 2,000 mg/kg (low toxicity)
Dermal Toxicity Low
Skin Irritation Mild irritant
Eye Irritation Mild to severe irritant
Inhalation Dust may cause respiratory irritation
Carcinogenicity Not classified as a carcinogen
Mutagenicity Not mutagenic
Chronic Effects May cause liver and lung effects at high doses
Environmental Hazards Low to moderate toxicity to aquatic life

11. GHS CLASSIFICATION

Hazard Class Category H-Statement
Skin Irritation Category 2 H315: Causes skin irritation
Eye Irritation Category 2 H319: Causes serious eye irritation
Specific Target Organ Toxicity Category 3 H335: May cause respiratory irritation

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

12. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust
P264 Wash hands thoroughly after handling
P271 Use only in well-ventilated areas
P280 Wear protective gloves/eye protection/face protection
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present
P337+P313 If eye irritation persists: Get medical advice/attention
P501 Dispose of contents/container in accordance with local regulations

13. FIRST AID MEASURES

Route of Exposure Action to Be Taken
Inhalation Move to fresh air. If symptoms persist, seek medical attention
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention
Ingestion Rinse mouth. Drink plenty of water. Do not induce vomiting. Seek medical attention

14. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, well-ventilated area
Container Requirements Air-tight, moisture-proof containers
Moisture Protection Store with desiccant (silica gel)
Temperature Room temperature (15-25°C)
Shelf Life 24 months under proper conditions
Stability Note Highly hygroscopic; readily absorbs moisture to form hydrate

15. PACKAGING OPTIONS

Packaging Type Quantity Material
Kraft Bag 25 kg PE-lined, moisture-proof
Glass Bottle 100 g, 500 g Amber glass with desiccant
Plastic Drum 25 kg, 50 kg HDPE drum, moisture-proof
Fiber Drum 25 kg, 50 kg PE-lined, moisture-proof
IBC Tank 500 kg, 1000 kg Plastic IBC

16. TRANSPORT INFORMATION

Parameter Information
UN Number Not applicable (not dangerous goods)
Hazard Class Not applicable
Packing Group Not applicable
ADR/RID Not regulated
IMDG Not regulated
IATA Not regulated

17. REGULATORY INFORMATION

Region / Authority Status
European Union (REACH) Registered; REACH registration required
Turkey (KKDIK) Compliance required; Ministry of Environment notifications
TSCA (USA) Registered
EINECS 233-237-5
HS Code 2846.90
ISO Manufactured under ISO 9001 quality management
FDA/EFSA Not approved as food additive

18. OTHER NAMES AND SYNONYMS

  • Lanthanum Trichloride

  • Lanthanum(III) Chloride

  • LaCl₃ anhydrous

  • Lanthanum chloride anhydrous

  • Lanthanum trichloride

19. QUICK REFERENCE TABLE

Property Value
CAS Number 10099-58-8
EC Number 233-237-5
Chemical Formula LaCl₃
Molecular Weight 245.26 g/mol
Appearance White crystalline, hygroscopic solid
Density ~3.84 g/cm³
Melting Point ~860 °C
Boiling Point ~1860 °C
Water Solubility Completely soluble
pH (1% solution) ~4-5 (slightly acidic)
Purity 99.9-99.99%
Hygroscopicity High
HS Code 2846.90
GHS Signal Word WARNING
UN Number Not applicable

20. CRITICAL NOTICES AND BEST PRACTICES

CRITICAL NOTICES:

  1. High Hygroscopicity: Anhydrous lanthanum chloride is highly hygroscopic and readily absorbs moisture from the air to form the hydrated salt. Must be stored in air-tight, moisture-proof containers.

  2. Storage Conditions: Must be stored in a dry environment. Exposure to moisture will result in hydration and product degradation.

  3. Handling: Should be handled in low-humidity environments. Containers must be sealed immediately after use.

  4. Incompatibility: Reacts with strong oxidizing agents, strong bases, and reactive metals.

  5. Thermal Stability: Stable up to melting point (~860°C). Decomposes at higher temperatures.

  6. Regulatory Compliance: REACH registration required for EU; KKDIK compliance required for Turkey.

BEST PRACTICE RECOMMENDATIONS:

Storage:

  • Store in a cool, dry, well-ventilated area

  • Use air-tight, moisture-proof containers

  • Store with desiccant (silica gel)

  • Keep away from acids and strong oxidizers

  • Store at room temperature (15-25°C)

Handling:

  • Use in well-ventilated areas

  • Use dust mask, protective goggles, and gloves

  • Avoid dust formation

  • Wash hands after handling

  • Immediately reseal container after use

Waste Management:

  • Dispose in accordance with local regulations

  • Do not discharge into water bodies

  • Consider rare earth recovery for large quantities

LEGAL DISCLAIMER

This Technical Data Sheet (TDS) is for informational purposes only and is prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific application and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, waste, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Lanthanum chloride anhydrous is a highly hygroscopic material; appropriate precautions must be taken during handling.

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