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Send EmailLanthanum Chloride, Lanthanum Trichloride, 10099-58-8
| Parameter | Information |
|---|---|
| Product Name | Lanthanum Chloride |
| Chemical Name | Lanthanum Trichloride, Lanthanum(III) Chloride |
| Other Names | LaCl₃ anhydrous, Lanthanum chloride anhydrous, Lanthanum trichloride |
| CAS Number | 10099-58-8 |
| EC Number (EINECS) | 233-237-5 |
| Chemical Formula | LaCl₃ |
| Molecular Weight | 245.26 g/mol |
| Appearance | White crystalline, hygroscopic solid |
| Odor | Odorless |
| Physical State (20°C) | Solid (crystalline) |
Lanthanum chloride (anhydrous) is the chloride salt of lanthanum in its anhydrous form. Lanthanum ions (La³⁺) and chloride ions (Cl⁻) are present in a 1:3 ratio. Unlike the heptahydrate form, this compound contains no water of crystallization. It is highly hygroscopic and readily absorbs moisture from the air to form the hydrated salt.
Structural Features:
LANTHANUM CHLORIDE ANHYDROUS (LaCl₃)
|
La³⁺ - Cl⁻ Ionic Bonds
|
+----------------+----------------+
| | |
Ionic Crystal No Water of High Hygroscopic
Structure Hydration Property
| Parameter | Value |
|---|---|
| Crystal System | Hexagonal (UCl₃ type structure) |
| Molecular Weight | 245.26 g/mol |
| Water Content | None (anhydrous) |
| Density | ~3.84 g/cm³ |
| Appearance | White, hygroscopic crystals |
| Coordination Number | 9 |
| Property | Value | Description |
|---|---|---|
| Appearance | White crystalline, hygroscopic solid | - |
| Odor | Odorless | - |
| Chemical Formula | LaCl₃ | - |
| Molecular Weight | 245.26 g/mol | - |
| Density | ~3.84 g/cm³ | - |
| Melting Point | ~860 °C | - |
| Boiling Point | ~1860 °C | - |
| Water Solubility (25°C) | Completely soluble (>1000 g/L) | - |
| Solubility in Ethanol | Soluble | - |
| Solubility in Acetone | Slightly soluble | - |
| pH (1% solution) | Slightly acidic (~4-5) | - |
| Hygroscopicity | High | Absorbs moisture from air |
| Stability | Stable under normal conditions; moisture sensitive | - |
| Parameter | Industrial Grade | High Purity Grade | Ultra High Purity Grade |
|---|---|---|---|
| Purity | ≥ 99.0% | ≥ 99.9% | ≥ 99.99% |
| LaCl₃ Content | ≥ 99.0% | ≥ 99.9% | ≥ 99.99% |
| Heavy Metals (as Pb) | ≤ 50 ppm | ≤ 10 ppm | ≤ 5 ppm |
| Iron (Fe) | ≤ 50 ppm | ≤ 10 ppm | ≤ 5 ppm |
| Calcium (Ca) | ≤ 100 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Sodium (Na) | ≤ 100 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Sulfate (SO₄²⁻) | ≤ 0.1% | ≤ 0.05% | ≤ 0.02% |
| Nitrate (NO₃⁻) | ≤ 0.1% | ≤ 0.05% | ≤ 0.02% |
| Other Rare Earths | ≤ 1.0% | ≤ 0.1% | ≤ 0.01% |
| Parameter | Information |
|---|---|
| Chemical Stability | Stable under normal conditions; readily absorbs moisture to form LaCl₃·7H₂O |
| Conditions to Avoid | Moisture, high temperature (>860°C), strong oxidizing agents |
| Incompatible Materials | Strong oxidizing agents, strong bases, reactive metals |
| Hazardous Decomposition Products | Lanthanum oxide (La₂O₃), hydrogen chloride (HCl) |
| Hazardous Polymerization | Will not occur |
| Hygroscopicity | High; absorbs moisture from air, forms hydrated salt |
| Photosensitivity | Low |
Hydration:
LaCl₃ + 7H₂O → LaCl₃·7H₂O (in moist air)
Reaction with Alkali:
LaCl₃ + 3NaOH → La(OH)₃↓ + 3NaCl
Reaction with Phosphate:
LaCl₃ + Na₃PO₄ → LaPO₄↓ + 3NaCl
Reaction with Oxalate:
2LaCl₃ + 3Na₂C₂O₄ → La₂(C₂O₄)₃↓ + 6NaCl
| Application | Function | Details |
|---|---|---|
| Phosphate Removal | Phosphate binder | Used in wastewater treatment plants to remove phosphates |
| Aquarium Water Treatment | Phosphate control | Controls phosphate levels in aquariums |
| Industrial Water Treatment | Scale prevention | Prevents scale formation |
| Eutrophication Control | Nutrient removal | Reduces nutrient load in water bodies |
| Application | Function | Details |
|---|---|---|
| Lewis Acid Catalyst | Acid catalyst | Organic synthesis reactions |
| Petrochemicals | Catalyst component | Hydrocarbon conversion |
| Organic Reactions | Catalyst | Various organic syntheses |
| Polymerization | Catalyst additive | Polymer production |
| Intermediate | Chemical intermediate | Various chemical syntheses |
| Application | Function | Details |
|---|---|---|
| Ceramic Additive | Thermal stability | High temperature applications |
| Glass Additive | Optical properties | Improves glass characteristics |
| Refractory Materials | Performance enhancer | High temperature resistance |
| Electronic Ceramics | Dopant | Improves electrical properties |
| Application | Function | Details |
|---|---|---|
| Phosphor Production | Rare earth source | Lanthanum-based phosphors |
| Optical Materials | Optical component | Specialty optical applications |
| Laser Materials | Laser active medium | Laser systems |
| Scintillators | Radiation detection | Nuclear applications |
| Application | Function | Details |
|---|---|---|
| Dielectric Layers | Insulating material | Electronic components |
| Semiconductors | Dopant | Semiconductor manufacturing |
| Capacitors | Dielectric additive | Ceramic capacitors |
| Application | Function | Details |
|---|---|---|
| Laboratory Reagent | Standard solution | Preparation of rare earth solutions |
| Research | Laboratory chemical | Chemical research and development |
| Nanomaterial Precursor | Synthesis precursor | Lanthanum-containing nanomaterials |
| Battery Materials | Electrolyte additive | Lithium-ion batteries |
Lanthanum chloride is derived from lanthanum-containing ores:
| Ore Type | Lanthanum Content | Main Locations |
|---|---|---|
| Monazite | 10-30% of REE content | Australia, Brazil, India, China |
| Bastnäsite | 20-30% of REE content | China, USA (Mountain Pass), Vietnam |
| Xenotime | 5-10% of REE content | China, Malaysia, Australia |
Lanthanum Oxide (La₂O₃)
↓
Dissolution in Hydrochloric Acid (HCl)
↓
LaCl₃ Solution Formation
↓
Filtration → Purification
↓
Evaporation → Crystallization
↓
LaCl₃·7H₂O Crystals
↓
Dehydration (Heating at 200-300°C)
↓
Anhydrous LaCl₃
↓
Classification → Packaging (Air-tight)
| Stage | Description |
|---|---|
| 1. Raw Material | Lanthanum oxide (La₂O₃) is used as starting material |
| 2. Acid Dissolution | Lanthanum oxide is dissolved in hydrochloric acid (HCl) |
| 3. Solution Formation | LaCl₃ solution is formed |
| 4. Filtration | Solution is filtered to remove impurities |
| 5. Evaporation | Water is evaporated to concentrate the solution |
| 6. Crystallization | LaCl₃·7H₂O crystals are formed |
| 7. Dehydration | Heptahydrate is heated at 200-300°C to remove water |
| 8. Packaging | Packaged in air-tight, moisture-proof containers |
| Sector | Suitability | Note |
|---|---|---|
| Water Treatment | ✔ | Phosphate removal |
| Textile | ✖ | Not suitable |
| Ceramics / Glass | ✔ | High temperature applications |
| Electronics | ✔ | Dielectric layers, semiconductors |
| Food | ✖ | Not approved as food additive |
| Catalyst | ✔ | Lewis acid, organic synthesis |
| Pharmaceutical | ✖ | Not for direct pharmaceutical use |
| Application Area | Alternative Materials | Notes |
|---|---|---|
| Water Treatment (Phosphate Removal) | Aluminum Sulfate, Ferric Chloride | Different efficiency and cost |
| Catalyst | Cerium Chloride, Yttrium Chloride | Similar Lewis acid effects |
| Ceramics | Yttrium Oxide, Cerium Oxide | Different thermal properties |
| Parameter | Value |
|---|---|
| Acute Oral Toxicity (LD50, Rat) | > 2,000 mg/kg (low toxicity) |
| Dermal Toxicity | Low |
| Skin Irritation | Mild irritant |
| Eye Irritation | Mild to severe irritant |
| Inhalation | Dust may cause respiratory irritation |
| Carcinogenicity | Not classified as a carcinogen |
| Mutagenicity | Not mutagenic |
| Chronic Effects | May cause liver and lung effects at high doses |
| Environmental Hazards | Low to moderate toxicity to aquatic life |
| Hazard Class | Category | H-Statement |
|---|---|---|
| Skin Irritation | Category 2 | H315: Causes skin irritation |
| Eye Irritation | Category 2 | H319: Causes serious eye irritation |
| Specific Target Organ Toxicity | Category 3 | H335: May cause respiratory irritation |
Signal Word: WARNING
Hazard Pictograms: GHS07 (Exclamation Mark)
| Code | Statement |
|---|---|
| P261 | Avoid breathing dust |
| P264 | Wash hands thoroughly after handling |
| P271 | Use only in well-ventilated areas |
| P280 | Wear protective gloves/eye protection/face protection |
| P302+P352 | IF ON SKIN: Wash with plenty of soap and water |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present |
| P337+P313 | If eye irritation persists: Get medical advice/attention |
| P501 | Dispose of contents/container in accordance with local regulations |
| Route of Exposure | Action to Be Taken |
|---|---|
| Inhalation | Move to fresh air. If symptoms persist, seek medical attention |
| Skin Contact | Wash with plenty of soap and water. Remove contaminated clothing |
| Eye Contact | Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention |
| Ingestion | Rinse mouth. Drink plenty of water. Do not induce vomiting. Seek medical attention |
| Parameter | Condition |
|---|---|
| Storage Conditions | Store in a cool, dry, well-ventilated area |
| Container Requirements | Air-tight, moisture-proof containers |
| Moisture Protection | Store with desiccant (silica gel) |
| Temperature | Room temperature (15-25°C) |
| Shelf Life | 24 months under proper conditions |
| Stability Note | Highly hygroscopic; readily absorbs moisture to form hydrate |
| Packaging Type | Quantity | Material |
|---|---|---|
| Kraft Bag | 25 kg | PE-lined, moisture-proof |
| Glass Bottle | 100 g, 500 g | Amber glass with desiccant |
| Plastic Drum | 25 kg, 50 kg | HDPE drum, moisture-proof |
| Fiber Drum | 25 kg, 50 kg | PE-lined, moisture-proof |
| IBC Tank | 500 kg, 1000 kg | Plastic IBC |
| Parameter | Information |
|---|---|
| UN Number | Not applicable (not dangerous goods) |
| Hazard Class | Not applicable |
| Packing Group | Not applicable |
| ADR/RID | Not regulated |
| IMDG | Not regulated |
| IATA | Not regulated |
| Region / Authority | Status |
|---|---|
| European Union (REACH) | Registered; REACH registration required |
| Turkey (KKDIK) | Compliance required; Ministry of Environment notifications |
| TSCA (USA) | Registered |
| EINECS | 233-237-5 |
| HS Code | 2846.90 |
| ISO | Manufactured under ISO 9001 quality management |
| FDA/EFSA | Not approved as food additive |
Lanthanum Trichloride
Lanthanum(III) Chloride
LaCl₃ anhydrous
Lanthanum chloride anhydrous
Lanthanum trichloride
| Property | Value |
|---|---|
| CAS Number | 10099-58-8 |
| EC Number | 233-237-5 |
| Chemical Formula | LaCl₃ |
| Molecular Weight | 245.26 g/mol |
| Appearance | White crystalline, hygroscopic solid |
| Density | ~3.84 g/cm³ |
| Melting Point | ~860 °C |
| Boiling Point | ~1860 °C |
| Water Solubility | Completely soluble |
| pH (1% solution) | ~4-5 (slightly acidic) |
| Purity | 99.9-99.99% |
| Hygroscopicity | High |
| HS Code | 2846.90 |
| GHS Signal Word | WARNING |
| UN Number | Not applicable |
High Hygroscopicity: Anhydrous lanthanum chloride is highly hygroscopic and readily absorbs moisture from the air to form the hydrated salt. Must be stored in air-tight, moisture-proof containers.
Storage Conditions: Must be stored in a dry environment. Exposure to moisture will result in hydration and product degradation.
Handling: Should be handled in low-humidity environments. Containers must be sealed immediately after use.
Incompatibility: Reacts with strong oxidizing agents, strong bases, and reactive metals.
Thermal Stability: Stable up to melting point (~860°C). Decomposes at higher temperatures.
Regulatory Compliance: REACH registration required for EU; KKDIK compliance required for Turkey.
Storage:
Store in a cool, dry, well-ventilated area
Use air-tight, moisture-proof containers
Store with desiccant (silica gel)
Keep away from acids and strong oxidizers
Store at room temperature (15-25°C)
Handling:
Use in well-ventilated areas
Use dust mask, protective goggles, and gloves
Avoid dust formation
Wash hands after handling
Immediately reseal container after use
Waste Management:
Dispose in accordance with local regulations
Do not discharge into water bodies
Consider rare earth recovery for large quantities
This Technical Data Sheet (TDS) is for informational purposes only and is prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific application and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, waste, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Lanthanum chloride anhydrous is a highly hygroscopic material; appropriate precautions must be taken during handling.