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Germanium Oxide, Germanium Dioxide, 1310-53-8

Didymium Oxide, 11141-21-2

DIDYMIUM OXIDE (CAS 11141-21-2)
DIDYMIUM OXIDE / NEODYMIUM-PRASEODYMIUM OXIDE MIXTURE / MIXED RARE EARTH OXIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Didymium Oxide
Chemical Name Neodymium–Praseodymium Oxide Mixture
Other Names Didymium Oxide, Mixed Rare Earth Oxide, Nd₂O₃ + Pr₆O₁₁ Mixture
CAS Number 11141-21-2
Chemical Formula Nd₂O₃ + Pr₆O₁₁ (mixture)
Molecular Weight ~666 g/mol (depending on mixture ratio)
Appearance Brown powder (reddish tones)
Odor Odorless
Physical State (20°C) Solid (powder)

2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Didymium oxide is not a single element oxide but a mixture of neodymium oxide (Nd₂O₃) and praseodymium oxide (Pr₆O₁₁). Historically, the term "didymium" was used before these two elements were separated. The mixture ratio varies depending on the application. It exhibits strong absorption bands in the visible light spectrum, making it valuable for filter applications. It is insoluble in water but soluble in acids.

Structural Features:

                    DIDYMIUM OXIDE [Nd₂O₃ + Pr₆O₁₁]
                          |
                Nd₂O₃ + Pr₆O₁₁ Mixture
                          |
        +----------------+----------------+
        |                |                |
    Brown             Strong Optical     Soluble in
    Powder Form       Absorption         Acids
    (Reddish Tones)

2.2. Structural Properties

Parameter Value
Crystal Structure Depends on mixture components (cubic + fluorite-like)
Chemical Formula Nd₂O₃ + Pr₆O₁₁ (mixture)
Molecular Weight ~666 g/mol (depending on mixture ratio)
Appearance Brown powder (reddish tones)
Optical Properties Strong absorption bands in visible light

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance Brown powder (reddish tones) Color shade depends on mixture ratio
Odor Odorless -
Chemical Formula Nd₂O₃ + Pr₆O₁₁ -
Molecular Weight ~666 g/mol Depends on mixture ratio
Solubility in Water (25°C) Insoluble -
Solubility in Acids Soluble Forms rare earth salts
Solubility in Alcohol Insoluble -
Optical Properties Strong absorption in visible light Optical filter applications
Thermal Stability High -
Hygroscopicity Low -

4. TYPICAL COMPOSITION (VARIANT DEPENDENT)

Parameter Typical Value Range
Neodymium Oxide (Nd₂O₃) 70 – 80%
Praseodymium Oxide (Pr₆O₁₁) 20 – 30%
Other Rare Earths ≤ 1.0%
Iron (Fe) ≤ 100 ppm
Calcium (Ca) ≤ 100 ppm
Silicon (Si) ≤ 100 ppm
Heavy Metals (Pb) ≤ 50 ppm
Chloride (Cl⁻) ≤ 0.1%
Loss on Drying ≤ 0.5%
Particle Size (D50) 1-10 µm

5. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Stable under normal conditions.
Conditions to Avoid Strong acids, high humidity (prolonged).
Incompatible Materials Strong acids, strong reducing agents, halogens.
Hazardous Decomposition Products With acids: neodymium and praseodymium salts.
Hazardous Polymerization Will not occur.
Hygroscopicity Low.

5.1. Chemical Reactions

  • Reaction with Acids:
    Nd₂O₃ + 6HCl → 2NdCl₃ + 3H₂O
    Pr₆O₁₁ + 18HCl → 6PrCl₃ + Cl₂↑ + 9H₂O

6. APPLICATION AREAS
6.1. Glass Industry

Application Function Details
Glass Coloring Colorant Brown-reddish tones
Glass Decolorizing Color neutralization Neutralizes iron impurities
Welder's Goggles Light-selective filter Absorbs harmful radiation
Optical Filters Spectral control Selective absorption in visible light

6.2. Electronics

Application Function Details
Temperature-Compensating Capacitors Dielectric material Radio, TV, radar circuits
Ceramic Capacitors Electronic component Special electronic applications

6.3. Metallurgy

Application Function Details
Stainless Steel Production Additive Mechanical property improvement
Metallurgical Research Alloy additive Special alloy applications

6.4. Textile

Application Function Details
Special Textile Processes Additive Some special textile processes

6.5. Carbon Arc Lamps

Application Function Details
Carbon Arc Cores Arc stabilizer Especially fluoride-type cores

6.6. Sectoral Suitability Table

Sector Suitability Explanation
Glass Industry Suitable Coloring, decolorizing, optical filters
Electronics Suitable Capacitors, electronic circuits
Metallurgy Suitable Stainless steel, alloy additives
Textile Suitable Special textile processes
Lighting Suitable Carbon arc lamps
Food Not Suitable Not suitable
Cosmetics Not Suitable Not suitable

7. PRODUCTION PROCESS

Stage Process Description
1. Raw Material Preparation Rare earth concentrates From monazite or bastnäsite ores
2. Separation Partial separation Co-separation of neodymium and praseodymium
3. Precipitation Chemical precipitation Oxalate or carbonate precipitation
4. Calcination Thermal treatment Conversion to oxide form (800-1000°C)
5. Milling Mechanical processing Achieving desired particle size
6. Quality Control Analysis and testing ICP-OES, XRD, spectrophotometry

7.1. Major Producing Countries

Country Description
China Major producer
India Rare earth production
USA Rare earth production

8. ALTERNATIVE / SUBSTITUTE PRODUCTS

Alternative Description When to Use
Neodymium Oxide (Nd₂O₃) Single component When only Nd properties are required
Praseodymium Oxide (Pr₆O₁₁) Single component When only Pr properties are required
Neodymium Nitrate For solution chemistry When liquid form is required
Praseodymium Nitrate For solution chemistry When liquid form is required
Other Mixed Rare Earths Different ratios Special application requirements

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 2,000 mg/kg (low toxicity)
Dermal Toxicity Low
Skin Irritation Mild irritant
Eye Irritation Mild to moderate irritant
Inhalation Fine dust inhalation may cause respiratory tract irritation.
Carcinogenicity Not classified as carcinogenic.
Mutagenicity Not mutagenic.
Chronic Effects Rare earth oxides have low bioavailability.
Environmental Hazards Low to moderate aquatic toxicity.

9.1. GHS Classification

Hazard Class Category H-Statement
Skin Irritation Category 2 H315: Causes skin irritation.
Eye Irritation Category 2A H319: Causes serious eye irritation.
Specific Target Organ Toxicity Category 3 H335: May cause respiratory irritation.

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

10. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in dry, closed containers; 2-8°C recommended.
Container Requirements Moisture-proof, tightly closed containers.
Temperature 2-8°C (supplier recommendation) or room temperature (15-25°C).
Shelf Life 24-36 months under appropriate conditions.
Stability Note Stable under normal conditions; should be stored in closed packaging to prevent moisture and CO₂ absorption.

11. QUICK REFERENCE TABLE

Property Value
CAS Number 11141-21-2
Chemical Formula Nd₂O₃ + Pr₆O₁₁ (mixture)
Molecular Weight ~666 g/mol
Appearance Brown powder
Typical Nd₂O₃ Ratio 70–80%
Typical Pr₆O₁₁ Ratio 20–30%
GHS Signal Word WARNING

12. CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • Mixture Product: Didymium oxide is not a single element compound but a mixture of neodymium and praseodymium oxides. Composition ratios vary by manufacturer and application.

  • Optical Properties: Valued for optical filters and welder's goggles due to strong absorption bands in visible light.

  • Historical Name: "Didymium" is a historical term used before neodymium and praseodymium were separated; it is still used commercially today.

  • Compatibility: Used in glass coloring and decolorizing applications to neutralize iron impurities.

  • Storage: Storage at 2-8°C is recommended; protect from moisture and CO₂ absorption.

BEST PRACTICE RECOMMENDATIONS:

  • Storage:

    • Store in a cool, dry, and well-ventilated area or at 2-8°C.

    • Use moisture-proof, tightly closed containers.

    • Keep away from acids and oxidizing agents.

  • Handling:

    • Use in well-ventilated areas with local exhaust ventilation.

    • Use a dust mask (N95 or better), protective goggles, and gloves.

    • Avoid dust formation and inhalation.

    • Wash hands thoroughly after handling.

  • Waste Management:

    • Dispose of in accordance with local regulations.

    • Do not discharge into water sources.

    • For large quantities, rare earth recovery should be considered.

LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Didymium oxide is a commercial rare earth product used in glass, optical, and electronic applications as a mixture of neodymium and praseodymium oxides; composition ratios may vary depending on the application.

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