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Dysprosium Oxide, Dysprosia, Dysprosium Sesquioxide, 1308-87-8

Dysprosium Oxide, Dysprosia, Dysprosium Sesquioxide, 1308-87-8

DYSPROSIUM OXIDE (DY₂O₃)
DYSPROSIUM OXIDE / DYSPROSIA / DYSPROSIUM SESQUIOXIDE / DYSPROSIUM(III) OXIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Dysprosium Oxide
Chemical Name Dysprosium(III) Oxide, Dysprosium Trioxide, Dysprosium Sesquioxide
Other Names Dysprosia, Dy₂O₃
CAS Number 1308-87-8
EC Number (EINECS) 215-164-2
Chemical Formula Dy₂O₃
Molecular Weight 372.998 g/mol
Appearance White to off-white powder
Odor Odorless
Physical State (20°C) Solid (powder)

2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Dysprosium oxide is an oxide of the rare earth element dysprosium and oxygen. Dysprosium ions (Dy³⁺) and oxide ions (O²⁻) are present in a 2:3 ratio. It has a cubic crystal structure (bixbyite type). It is known for its strong paramagnetic properties, high thermal stability, and role in nuclear applications. It is insoluble in water but soluble in strong acids.

Structural Features:

                    DYSPROSIUM OXIDE [Dy₂O₃]
                          |
                Dy³⁺ - O²⁻ Ionic Bonds
                          |
        +----------------+----------------+
        |                |                |
    Cubic (Bixbyite)   White Powder      Magnetic/Nuclear
    Crystal Structure                   Active

2.2. Structural Properties

Parameter Value
Crystal Structure Cubic (bixbyite type)
Chemical Formula Dy₂O₃
Molecular Weight 372.998 g/mol
Density ~7.81 g/cm³
Appearance White to off-white powder
Melting Point ~2,340 °C
Boiling Point ~3,900 °C
Magnetic Susceptibility Paramagnetic (strong)
Refractive Index ~1.95

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance White to off-white powder Color shade depends on purity
Odor Odorless -
Chemical Formula Dy₂O₃ -
Molecular Weight 372.998 g/mol -
Density ~7.81 g/cm³ -
Melting Point ~2,340 °C -
Solubility in Water (25°C) Insoluble -
Solubility in Acids Soluble Forms dysprosium salts
Solubility in Alcohol Insoluble -
Crystal Structure Cubic (bixbyite) -
Magnetic Behavior Paramagnetic (strong) Due to Dy³⁺ ions
Thermal Stability High -
Hygroscopicity Low -

4. PURITY GRADES

Parameter Technical Grade High Purity Grade Analytical Grade Ultra-High Purity Grade
Purity (Dy₂O₃) ≥ 99.0% ≥ 99.9% ≥ 99.99% ≥ 99.999%
Other Rare Earths ≤ 1.0% ≤ 0.1% ≤ 0.01% ≤ 0.001%
Iron (Fe) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Calcium (Ca) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Silicon (Si) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Heavy Metals (Pb) ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm ≤ 5 ppm
Chloride (Cl⁻) ≤ 0.1% ≤ 0.05% ≤ 0.02% ≤ 0.01%
Loss on Drying ≤ 1.0% ≤ 0.5% ≤ 0.3% ≤ 0.1%
Particle Size (D50) 5-20 µm 1-10 µm 0.5-5 µm 0.2-2 µm
BET Surface Area 5-15 m²/g 10-20 m²/g 15-30 m²/g 20-50 m²/g

5. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Stable in air; stable at high temperatures.
Conditions to Avoid Strong acids, high humidity (prolonged), reducing environments.
Incompatible Materials Strong acids, strong reducing agents, halogens.
Hazardous Decomposition Products Upon oxidation at high temperatures: dysprosium oxide (Dy₂O₃) is stable; with acids: dysprosium salts.
Hazardous Polymerization Will not occur.
Hygroscopicity Low.

5.1. Chemical Reactions

  • Reaction with Acids:
    Dy₂O₃ + 6HCl → 2DyCl₃ + 3H₂O
    Dy₂O₃ + 6HNO₃ → 2Dy(NO₃)₃ + 3H₂O
    Dy₂O₃ + 3H₂SO₄ → Dy₂(SO₄)₃ + 3H₂O

  • Carbonation (Over Time):
    Dy₂O₃ + 3CO₂ + 3H₂O → Dy₂(CO₃)₃·3H₂O (slow)

6. APPLICATION AREAS
6.1. Magnets

Application Function Details
Dysprosium Metal Production Precursor material Raw material for NdFeB magnets
NdFeB Magnets High temperature resistance Dy addition improves temperature stability
High Performance Magnets Magnetic properties Special magnetic applications

6.2. Ceramic and Glass Industry

Application Function Details
Ceramic Additive Mechanical and thermal properties Refractory ceramics
Glass Additive Color and optical effect Specialty glasses
Thermal Barrier Coatings Thermal insulation High temperature applications

6.3. Nuclear Technology

Application Function Details
Control Rods Neutron absorption High neutron capture cross-section
Radiation Shielding Radiation shield Nuclear reactors
Nuclear Materials Special nuclear applications Research and energy

6.4. Electronics and Optics

Application Function Details
Thin Film Coatings Surface engineering Optoelectronic applications
Dielectric Material High purity dielectric Sensors and capacitors
IR Applications Optical material Infrared optics

6.5. Sectoral Suitability Table

Sector Suitability Explanation
Magnets Suitable NdFeB magnets, high temperature resistance
Ceramics and Glass Suitable Mechanical/thermal properties, color/optical effect
Nuclear Suitable Control rods, radiation shielding
Electronics Suitable Thin film, dielectric applications
Optics Suitable IR applications, specialty optical materials
Food Not Suitable Rare earth oxide, not suitable
Cosmetics Not Suitable Rare earth oxide, not suitable

7. PRODUCTION PROCESS

Stage Process Description
1. Raw Material Preparation Rare earth concentrates Extraction from monazite or bastnäsite ores
2. Separation Solvent extraction Separation of dysprosium from other rare earths
3. Precipitation Chemical precipitation Precipitation of dysprosium salts
4. Calcination Thermal treatment Conversion to oxide form (800-1000°C)
5. Milling Mechanical processing Achieving desired particle size
6. Quality Control Analysis and testing ICP-OES, XRD, BET surface area

7.1. Major Producing Countries

Country Description
China Major producer
Australia Rare earth mining
USA Rare earth production

8. ALTERNATIVE / SUBSTITUTE PRODUCTS

Alternative Description When to Use
Dysprosium Nitrate For solution chemistry When liquid form of dysprosium is required
Dysprosium Chloride For solution chemistry When liquid form of dysprosium is required
Terbium Oxide (Tb₄O₇) Magnetic applications When different magnetic properties are required
Holmium Oxide (Ho₂O₃) Laser applications When different laser properties are required
Gadolinium Oxide (Gd₂O₃) Nuclear applications When different neutron absorption properties are required

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 2,000 mg/kg (low toxicity)
Dermal Toxicity Low
Skin Irritation Mild irritant
Eye Irritation Mild to moderate irritant
Inhalation Fine dust inhalation may cause respiratory tract irritation.
Carcinogenicity Not classified as carcinogenic.
Mutagenicity Not mutagenic.
Chronic Effects Rare earth oxides have low bioavailability; prolonged exposure may cause lung effects.
Environmental Hazards Low to moderate aquatic toxicity.

9.1. GHS Classification

Hazard Class Category H-Statement
Skin Irritation Category 2 H315: Causes skin irritation.
Eye Irritation Category 2A H319: Causes serious eye irritation.
Specific Target Organ Toxicity Category 3 H335: May cause respiratory irritation.

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

10. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust.
P264 Wash thoroughly after handling.
P271 Use only in well-ventilated areas.
P280 Wear protective gloves/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
P337+P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local regulations.

11. FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air. If symptoms persist, seek medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention.
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention.
Ingestion Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention.

12. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, and well-ventilated area. Ensure a moisture-free environment.
Container Requirements Moisture-proof, tightly closed containers.
Temperature Room temperature (15-25°C).
Shelf Life 24-36 months under appropriate conditions.
Stability Note Stable under normal conditions; should be stored in closed packaging to prevent moisture and CO₂ absorption.

13. PACKAGING OPTIONS

Packaging Type Quantity Material
Laboratory Packaging 5 g, 10 g, 25 g, 50 g, 100 g HDPE bottle, aluminum foil bag
Industrial Packaging 25 kg PE-lined kraft bag, moisture-proof
Drum 25 kg, 50 kg HDPE drum, moisture-proof
IBC (Intermediate Bulk Container) 500 kg, 1000 kg Moisture-proof, palletized

14. TRANSPORT INFORMATION

Parameter Information
UN Number Not classified (specific regulations apply for rare earth oxides)
Hazard Class -
Packing Group -
ADR/RID Not regulated (special precautions may be required for powder form)
IMDG Not regulated
IATA Not regulated
HS Code 2846.90.00.00.19 (Other rare earth compounds)

15. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Registered
Turkey (KKDIK) Compliance required
TSCA (USA) Registered
EINECS 215-164-2
China (REACH equivalent) Registered; major production and export country

16. OTHER NAMES AND SYNONYMS

Name Description
Dysprosia Common short name
Dysprosium Trioxide Chemical name
Dysprosium Sesquioxide Chemical name
Dysprosium(III) Oxide Chemical name
Dy₂O₃ Chemical abbreviation
Rare Earth Oxide Category name
Dysprosium Oxide English name

17. QUICK REFERENCE TABLE

Property Value
CAS Number 1308-87-8
EC Number 215-164-2
Chemical Formula Dy₂O₃
Molecular Weight 372.998 g/mol
Appearance White to off-white powder
Density ~7.81 g/cm³
Melting Point ~2,340 °C
Magnetic Behavior Paramagnetic (strong)
HS Code 2846.90.00.00.19
GHS Signal Word WARNING

18. CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • Magnetic Properties: Dysprosium is added to NdFeB magnets to improve high-temperature resistance. This property is critical for applications such as electric vehicle motors and wind turbines.

  • Nuclear Applications: Dysprosium isotopes have high neutron capture cross-sections; used in nuclear control rods and radiation shielding materials.

  • High Purity Requirement: Magnetic, optical, and nuclear applications require high purity (>99.9%).

  • High Value: Dysprosium is a critical and valuable rare earth element. Losses should be minimized and recycling options explored.

  • Powder Hazard: Fine powder form may cause respiratory tract irritation. Dust control measures must be taken.

BEST PRACTICE RECOMMENDATIONS:

  • Storage:

    • Store in a cool, dry, and well-ventilated area.

    • Use moisture-proof, tightly closed containers.

    • Keep away from acids and oxidizing agents.

    • Store at room temperature (15-25°C).

  • Handling:

    • Use in well-ventilated areas with local exhaust ventilation.

    • Use a dust mask (N95 or better), protective goggles, and gloves.

    • Avoid dust formation and inhalation.

    • Wash hands thoroughly after handling.

    • For dissolution in acids, add oxide to acid slowly with cooling and stirring.

  • Waste Management:

    • Dispose of in accordance with local regulations.

    • Do not discharge into water sources.

    • For large quantities, rare earth recycling and recovery should be considered.

LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Dysprosium oxide is a critical rare earth material for magnetic and nuclear applications; careful handling, storage, and recycling planning are required due to high purity requirements and value.

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