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Send EmailDysprosium Oxide, Dysprosia, Dysprosium Sesquioxide, 1308-87-8
DYSPROSIUM OXIDE (DY₂O₃)
DYSPROSIUM OXIDE / DYSPROSIA / DYSPROSIUM SESQUIOXIDE / DYSPROSIUM(III) OXIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY
| Parameter | Information |
|---|---|
| Product Name | Dysprosium Oxide |
| Chemical Name | Dysprosium(III) Oxide, Dysprosium Trioxide, Dysprosium Sesquioxide |
| Other Names | Dysprosia, Dy₂O₃ |
| CAS Number | 1308-87-8 |
| EC Number (EINECS) | 215-164-2 |
| Chemical Formula | Dy₂O₃ |
| Molecular Weight | 372.998 g/mol |
| Appearance | White to off-white powder |
| Odor | Odorless |
| Physical State (20°C) | Solid (powder) |
2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Dysprosium oxide is an oxide of the rare earth element dysprosium and oxygen. Dysprosium ions (Dy³⁺) and oxide ions (O²⁻) are present in a 2:3 ratio. It has a cubic crystal structure (bixbyite type). It is known for its strong paramagnetic properties, high thermal stability, and role in nuclear applications. It is insoluble in water but soluble in strong acids.
Structural Features:
DYSPROSIUM OXIDE [Dy₂O₃]
|
Dy³⁺ - O²⁻ Ionic Bonds
|
+----------------+----------------+
| | |
Cubic (Bixbyite) White Powder Magnetic/Nuclear
Crystal Structure Active
2.2. Structural Properties
| Parameter | Value |
|---|---|
| Crystal Structure | Cubic (bixbyite type) |
| Chemical Formula | Dy₂O₃ |
| Molecular Weight | 372.998 g/mol |
| Density | ~7.81 g/cm³ |
| Appearance | White to off-white powder |
| Melting Point | ~2,340 °C |
| Boiling Point | ~3,900 °C |
| Magnetic Susceptibility | Paramagnetic (strong) |
| Refractive Index | ~1.95 |
3. PHYSICAL AND CHEMICAL PROPERTIES
| Property | Value | Description |
|---|---|---|
| Appearance | White to off-white powder | Color shade depends on purity |
| Odor | Odorless | - |
| Chemical Formula | Dy₂O₃ | - |
| Molecular Weight | 372.998 g/mol | - |
| Density | ~7.81 g/cm³ | - |
| Melting Point | ~2,340 °C | - |
| Solubility in Water (25°C) | Insoluble | - |
| Solubility in Acids | Soluble | Forms dysprosium salts |
| Solubility in Alcohol | Insoluble | - |
| Crystal Structure | Cubic (bixbyite) | - |
| Magnetic Behavior | Paramagnetic (strong) | Due to Dy³⁺ ions |
| Thermal Stability | High | - |
| Hygroscopicity | Low | - |
4. PURITY GRADES
| Parameter | Technical Grade | High Purity Grade | Analytical Grade | Ultra-High Purity Grade |
|---|---|---|---|---|
| Purity (Dy₂O₃) | ≥ 99.0% | ≥ 99.9% | ≥ 99.99% | ≥ 99.999% |
| Other Rare Earths | ≤ 1.0% | ≤ 0.1% | ≤ 0.01% | ≤ 0.001% |
| Iron (Fe) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Calcium (Ca) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Silicon (Si) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Heavy Metals (Pb) | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm | ≤ 5 ppm |
| Chloride (Cl⁻) | ≤ 0.1% | ≤ 0.05% | ≤ 0.02% | ≤ 0.01% |
| Loss on Drying | ≤ 1.0% | ≤ 0.5% | ≤ 0.3% | ≤ 0.1% |
| Particle Size (D50) | 5-20 µm | 1-10 µm | 0.5-5 µm | 0.2-2 µm |
| BET Surface Area | 5-15 m²/g | 10-20 m²/g | 15-30 m²/g | 20-50 m²/g |
5. STABILITY AND REACTIVITY
| Parameter | Information |
|---|---|
| Chemical Stability | Stable in air; stable at high temperatures. |
| Conditions to Avoid | Strong acids, high humidity (prolonged), reducing environments. |
| Incompatible Materials | Strong acids, strong reducing agents, halogens. |
| Hazardous Decomposition Products | Upon oxidation at high temperatures: dysprosium oxide (Dy₂O₃) is stable; with acids: dysprosium salts. |
| Hazardous Polymerization | Will not occur. |
| Hygroscopicity | Low. |
5.1. Chemical Reactions
Reaction with Acids:
Dy₂O₃ + 6HCl → 2DyCl₃ + 3H₂O
Dy₂O₃ + 6HNO₃ → 2Dy(NO₃)₃ + 3H₂O
Dy₂O₃ + 3H₂SO₄ → Dy₂(SO₄)₃ + 3H₂O
Carbonation (Over Time):
Dy₂O₃ + 3CO₂ + 3H₂O → Dy₂(CO₃)₃·3H₂O (slow)
6. APPLICATION AREAS
6.1. Magnets
| Application | Function | Details |
|---|---|---|
| Dysprosium Metal Production | Precursor material | Raw material for NdFeB magnets |
| NdFeB Magnets | High temperature resistance | Dy addition improves temperature stability |
| High Performance Magnets | Magnetic properties | Special magnetic applications |
6.2. Ceramic and Glass Industry
| Application | Function | Details |
|---|---|---|
| Ceramic Additive | Mechanical and thermal properties | Refractory ceramics |
| Glass Additive | Color and optical effect | Specialty glasses |
| Thermal Barrier Coatings | Thermal insulation | High temperature applications |
6.3. Nuclear Technology
| Application | Function | Details |
|---|---|---|
| Control Rods | Neutron absorption | High neutron capture cross-section |
| Radiation Shielding | Radiation shield | Nuclear reactors |
| Nuclear Materials | Special nuclear applications | Research and energy |
6.4. Electronics and Optics
| Application | Function | Details |
|---|---|---|
| Thin Film Coatings | Surface engineering | Optoelectronic applications |
| Dielectric Material | High purity dielectric | Sensors and capacitors |
| IR Applications | Optical material | Infrared optics |
6.5. Sectoral Suitability Table
| Sector | Suitability | Explanation |
|---|---|---|
| Magnets | Suitable | NdFeB magnets, high temperature resistance |
| Ceramics and Glass | Suitable | Mechanical/thermal properties, color/optical effect |
| Nuclear | Suitable | Control rods, radiation shielding |
| Electronics | Suitable | Thin film, dielectric applications |
| Optics | Suitable | IR applications, specialty optical materials |
| Food | Not Suitable | Rare earth oxide, not suitable |
| Cosmetics | Not Suitable | Rare earth oxide, not suitable |
7. PRODUCTION PROCESS
| Stage | Process | Description |
|---|---|---|
| 1. Raw Material Preparation | Rare earth concentrates | Extraction from monazite or bastnäsite ores |
| 2. Separation | Solvent extraction | Separation of dysprosium from other rare earths |
| 3. Precipitation | Chemical precipitation | Precipitation of dysprosium salts |
| 4. Calcination | Thermal treatment | Conversion to oxide form (800-1000°C) |
| 5. Milling | Mechanical processing | Achieving desired particle size |
| 6. Quality Control | Analysis and testing | ICP-OES, XRD, BET surface area |
7.1. Major Producing Countries
| Country | Description |
|---|---|
| China | Major producer |
| Australia | Rare earth mining |
| USA | Rare earth production |
8. ALTERNATIVE / SUBSTITUTE PRODUCTS
| Alternative | Description | When to Use |
|---|---|---|
| Dysprosium Nitrate | For solution chemistry | When liquid form of dysprosium is required |
| Dysprosium Chloride | For solution chemistry | When liquid form of dysprosium is required |
| Terbium Oxide (Tb₄O₇) | Magnetic applications | When different magnetic properties are required |
| Holmium Oxide (Ho₂O₃) | Laser applications | When different laser properties are required |
| Gadolinium Oxide (Gd₂O₃) | Nuclear applications | When different neutron absorption properties are required |
9. SAFETY AND TOXICOLOGY
| Parameter | Value |
|---|---|
| Acute Oral Toxicity (LD50, Rat) | > 2,000 mg/kg (low toxicity) |
| Dermal Toxicity | Low |
| Skin Irritation | Mild irritant |
| Eye Irritation | Mild to moderate irritant |
| Inhalation | Fine dust inhalation may cause respiratory tract irritation. |
| Carcinogenicity | Not classified as carcinogenic. |
| Mutagenicity | Not mutagenic. |
| Chronic Effects | Rare earth oxides have low bioavailability; prolonged exposure may cause lung effects. |
| Environmental Hazards | Low to moderate aquatic toxicity. |
9.1. GHS Classification
| Hazard Class | Category | H-Statement |
|---|---|---|
| Skin Irritation | Category 2 | H315: Causes skin irritation. |
| Eye Irritation | Category 2A | H319: Causes serious eye irritation. |
| Specific Target Organ Toxicity | Category 3 | H335: May cause respiratory irritation. |
Signal Word: WARNING
Hazard Pictograms: GHS07 (Exclamation Mark)
10. PRECAUTIONARY STATEMENTS (P-CODES)
| Code | Statement |
|---|---|
| P261 | Avoid breathing dust. |
| P264 | Wash thoroughly after handling. |
| P271 | Use only in well-ventilated areas. |
| P280 | Wear protective gloves/eye protection/face protection. |
| P302+P352 | IF ON SKIN: Wash with plenty of soap and water. |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing. |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. |
| P337+P313 | If eye irritation persists: Get medical advice/attention. |
| P501 | Dispose of contents/container in accordance with local regulations. |
11. FIRST AID MEASURES
| Exposure Route | Action to Take |
|---|---|
| Inhalation | Remove to fresh air. If symptoms persist, seek medical attention. |
| Skin Contact | Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention. |
| Eye Contact | Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention. |
| Ingestion | Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention. |
12. STORAGE AND SHELF LIFE
| Parameter | Condition |
|---|---|
| Storage Conditions | Store in a cool, dry, and well-ventilated area. Ensure a moisture-free environment. |
| Container Requirements | Moisture-proof, tightly closed containers. |
| Temperature | Room temperature (15-25°C). |
| Shelf Life | 24-36 months under appropriate conditions. |
| Stability Note | Stable under normal conditions; should be stored in closed packaging to prevent moisture and CO₂ absorption. |
13. PACKAGING OPTIONS
| Packaging Type | Quantity | Material |
|---|---|---|
| Laboratory Packaging | 5 g, 10 g, 25 g, 50 g, 100 g | HDPE bottle, aluminum foil bag |
| Industrial Packaging | 25 kg | PE-lined kraft bag, moisture-proof |
| Drum | 25 kg, 50 kg | HDPE drum, moisture-proof |
| IBC (Intermediate Bulk Container) | 500 kg, 1000 kg | Moisture-proof, palletized |
14. TRANSPORT INFORMATION
| Parameter | Information |
|---|---|
| UN Number | Not classified (specific regulations apply for rare earth oxides) |
| Hazard Class | - |
| Packing Group | - |
| ADR/RID | Not regulated (special precautions may be required for powder form) |
| IMDG | Not regulated |
| IATA | Not regulated |
| HS Code | 2846.90.00.00.19 (Other rare earth compounds) |
15. REGULATORY STATUS
| Region / Authority | Status |
|---|---|
| European Union (REACH) | Registered |
| Turkey (KKDIK) | Compliance required |
| TSCA (USA) | Registered |
| EINECS | 215-164-2 |
| China (REACH equivalent) | Registered; major production and export country |
16. OTHER NAMES AND SYNONYMS
| Name | Description |
|---|---|
| Dysprosia | Common short name |
| Dysprosium Trioxide | Chemical name |
| Dysprosium Sesquioxide | Chemical name |
| Dysprosium(III) Oxide | Chemical name |
| Dy₂O₃ | Chemical abbreviation |
| Rare Earth Oxide | Category name |
| Dysprosium Oxide | English name |
17. QUICK REFERENCE TABLE
| Property | Value |
|---|---|
| CAS Number | 1308-87-8 |
| EC Number | 215-164-2 |
| Chemical Formula | Dy₂O₃ |
| Molecular Weight | 372.998 g/mol |
| Appearance | White to off-white powder |
| Density | ~7.81 g/cm³ |
| Melting Point | ~2,340 °C |
| Magnetic Behavior | Paramagnetic (strong) |
| HS Code | 2846.90.00.00.19 |
| GHS Signal Word | WARNING |
18. CRITICAL WARNINGS AND BEST PRACTICES
CRITICAL WARNINGS:
Magnetic Properties: Dysprosium is added to NdFeB magnets to improve high-temperature resistance. This property is critical for applications such as electric vehicle motors and wind turbines.
Nuclear Applications: Dysprosium isotopes have high neutron capture cross-sections; used in nuclear control rods and radiation shielding materials.
High Purity Requirement: Magnetic, optical, and nuclear applications require high purity (>99.9%).
High Value: Dysprosium is a critical and valuable rare earth element. Losses should be minimized and recycling options explored.
Powder Hazard: Fine powder form may cause respiratory tract irritation. Dust control measures must be taken.
BEST PRACTICE RECOMMENDATIONS:
Storage:
Store in a cool, dry, and well-ventilated area.
Use moisture-proof, tightly closed containers.
Keep away from acids and oxidizing agents.
Store at room temperature (15-25°C).
Handling:
Use in well-ventilated areas with local exhaust ventilation.
Use a dust mask (N95 or better), protective goggles, and gloves.
Avoid dust formation and inhalation.
Wash hands thoroughly after handling.
For dissolution in acids, add oxide to acid slowly with cooling and stirring.
Waste Management:
Dispose of in accordance with local regulations.
Do not discharge into water sources.
For large quantities, rare earth recycling and recovery should be considered.
LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Dysprosium oxide is a critical rare earth material for magnetic and nuclear applications; careful handling, storage, and recycling planning are required due to high purity requirements and value.