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Send EmailLutetium Oxide, Lutetium Sesquioxide, Lutetium Trioxide, Lutetia, 12032-20-1
LUTETIUM OXIDE (LU₂O₃)
LUTETIUM OXIDE / LUTETIA / LUTETIUM SESQUIOXIDE / LUTETIUM TRIOXIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY
| Parameter | Information |
|---|---|
| Product Name | Lutetium Oxide |
| Chemical Name | Lutetium(III) Oxide, Lutetium Trioxide, Lutetium Sesquioxide |
| Other Names | Lutetia, Lu₂O₃ |
| CAS Number | 12032-20-1 |
| EC Number (EINECS) | 234-931-9 |
| Chemical Formula | Lu₂O₃ |
| Molecular Weight | 397.93 g/mol |
| Appearance | White powder |
| Odor | Odorless |
| Physical State (20°C) | Solid (powder) |
2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Lutetium oxide is a high-purity oxide of the rare earth element lutetium and oxygen. Lutetium ions (Lu³⁺) and oxide ions (O²⁻) are present in a 2:3 ratio. It has a cubic crystal structure (bixbyite type). It has the highest density among rare earth oxides. It is known for its high thermal stability, chemical inertness, and excellent optical properties. It is insoluble in water but soluble in strong acids.
Structural Features:
LUTETIUM OXIDE [Lu₂O₃]
|
Lu³⁺ - O²⁻ Ionic Bonds
|
+----------------+----------------+
| | |
Cubic (Bixbyite) White Powder Highest
Crystal Structure Density
2.2. Structural Properties
| Parameter | Value |
|---|---|
| Crystal Structure | Cubic (bixbyite type) |
| Chemical Formula | Lu₂O₃ |
| Molecular Weight | 397.93 g/mol |
| Density | ~9.4 g/cm³ |
| Appearance | White powder |
| Melting Point | ~2,490 °C |
| Boiling Point | ~3,980 °C |
| Refractive Index | ~1.94 |
3. PHYSICAL AND CHEMICAL PROPERTIES
| Property | Value | Description |
|---|---|---|
| Appearance | White powder | Color shade depends on purity |
| Odor | Odorless | - |
| Chemical Formula | Lu₂O₃ | - |
| Molecular Weight | 397.93 g/mol | - |
| Density | ~9.4 g/cm³ | Highest among rare earth oxides |
| Melting Point | ~2,490 °C | - |
| Solubility in Water (25°C) | Insoluble | - |
| Solubility in Acids | Soluble | Forms lutetium salts |
| Solubility in Alcohol | Insoluble | - |
| Crystal Structure | Cubic (bixbyite) | - |
| Thermal Stability | High | - |
| Chemical Inertness | High | - |
| Hygroscopicity | Low | - |
4. PURITY GRADES
| Parameter | Technical Grade | High Purity Grade | Analytical Grade | Ultra-High Purity Grade |
|---|---|---|---|---|
| Purity (Lu₂O₃) | ≥ 99.0% | ≥ 99.9% | ≥ 99.99% | ≥ 99.999% |
| Other Rare Earths | ≤ 1.0% | ≤ 0.1% | ≤ 0.01% | ≤ 0.001% |
| Iron (Fe) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Calcium (Ca) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Silicon (Si) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Heavy Metals (Pb) | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm | ≤ 5 ppm |
| Chloride (Cl⁻) | ≤ 0.1% | ≤ 0.05% | ≤ 0.02% | ≤ 0.01% |
| Loss on Drying | ≤ 1.0% | ≤ 0.5% | ≤ 0.3% | ≤ 0.1% |
| Particle Size (D50) | 5-20 µm | 1-10 µm | 0.5-5 µm | 0.2-2 µm |
| BET Surface Area | 5-15 m²/g | 10-20 m²/g | 15-30 m²/g | 20-50 m²/g |
5. STABILITY AND REACTIVITY
| Parameter | Information |
|---|---|
| Chemical Stability | Stable at high temperatures; chemically inert. |
| Conditions to Avoid | Strong acids, high humidity (prolonged). |
| Incompatible Materials | Strong acids, strong reducing agents, halogens. |
| Hazardous Decomposition Products | Upon oxidation at high temperatures: lutetium oxide (Lu₂O₃) is stable; with acids: lutetium salts. |
| Hazardous Polymerization | Will not occur. |
| Hygroscopicity | Low. |
5.1. Chemical Reactions
Reaction with Acids:
Lu₂O₃ + 6HCl → 2LuCl₃ + 3H₂O
Lu₂O₃ + 6HNO₃ → 2Lu(NO₃)₃ + 3H₂O
Lu₂O₃ + 3H₂SO₄ → Lu₂(SO₄)₃ + 3H₂O
Carbonation (Over Time):
Lu₂O₃ + 3CO₂ + 3H₂O → Lu₂(CO₃)₃·3H₂O (slow)
6. APPLICATION AREAS
6.1. Optics and Laser Applications
| Application | Function | Details |
|---|---|---|
| Transparent Ceramics | Optical material | IR windows, high temperature optics |
| Laser Host Materials | Optical host | Nd³⁺, Yb³⁺ doped laser crystals |
| Laser Crystals | Dopant | High-power laser systems |
| IR Windows | Infrared transparency | Defense and industrial applications |
6.2. Electronics
| Application | Function | Details |
|---|---|---|
| Dielectric Material | High purity dielectric | Sensors |
| Thin Film Coatings | Surface engineering | Optoelectronic applications |
| Semiconductor Components | Dopant | Special electronic applications |
6.3. Nuclear Technology
| Application | Function | Details |
|---|---|---|
| Radiation Shielding | High density | Research applications |
| Nuclear Materials | Radiation shield | Special nuclear applications |
6.4. Ceramics
| Application | Function | Details |
|---|---|---|
| Refractory Ceramics | High temperature resistance | Thermal protection systems |
| Ceramic Additive | Thermal stability | High temperature applications |
| Thermal Barrier Coatings | Thermal insulation | Gas turbines, engines |
6.5. Chemical Precursor
| Application | Function | Details |
|---|---|---|
| Lutetium Salts | Starting material | Nitrate, chloride production |
| Chemical Synthesis | High purity intermediate | Special chemical applications |
6.6. Sectoral Suitability Table
| Sector | Suitability | Explanation |
|---|---|---|
| Optics and Laser | Suitable | Transparent ceramics, laser hosts, IR windows |
| Electronics | Suitable | Dielectrics, thin film coatings |
| Nuclear | Suitable | Radiation shielding materials |
| Ceramics | Suitable | Refractory ceramics, thermal barrier coatings |
| Chemicals | Suitable | Precursor for lutetium salts |
| Food | Not Suitable | Rare earth oxide, not suitable |
| Cosmetics | Not Suitable | Rare earth oxide, not suitable |
7. PRODUCTION PROCESS
| Stage | Process | Description |
|---|---|---|
| 1. Raw Material Preparation | Rare earth concentrates | Extraction from monazite or bastnäsite ores |
| 2. Separation | Solvent extraction | Separation of lutetium from other rare earths |
| 3. Precipitation | Chemical precipitation | Precipitation of lutetium salts |
| 4. Calcination | Thermal treatment | Conversion to oxide form (800-1000°C) |
| 5. Milling | Mechanical processing | Achieving desired particle size |
| 6. Quality Control | Analysis and testing | ICP-OES, XRD, BET surface area |
7.1. Major Producing Countries
| Country | Description |
|---|---|
| China | Major producer |
| USA | Rare earth production |
| Australia | Rare earth mining |
8. ALTERNATIVE / SUBSTITUTE PRODUCTS
| Alternative | Description | When to Use |
|---|---|---|
| Lutetium Nitrate | For solution chemistry | When liquid form of lutetium is required |
| Lutetium Chloride | For solution chemistry | When liquid form of lutetium is required |
| Yttrium Oxide (Y₂O₃) | Optical applications | When different optical properties are required |
| Gadolinium Oxide (Gd₂O₃) | Magnetic applications | When different magnetic properties are required |
| Scandium Oxide (Sc₂O₃) | Ceramic applications | When different properties are required |
9. SAFETY AND TOXICOLOGY
| Parameter | Value |
|---|---|
| Acute Oral Toxicity (LD50, Rat) | > 2,000 mg/kg (low toxicity) |
| Dermal Toxicity | Low |
| Skin Irritation | Mild irritant |
| Eye Irritation | Mild to moderate irritant |
| Inhalation | Fine dust inhalation may cause respiratory tract irritation. |
| Carcinogenicity | Not classified as carcinogenic. |
| Mutagenicity | Not mutagenic. |
| Chronic Effects | Rare earth oxides have low bioavailability; prolonged exposure may cause lung effects. |
| Environmental Hazards | Low aquatic toxicity. |
9.1. GHS Classification
| Hazard Class | Category | H-Statement |
|---|---|---|
| Skin Irritation | Category 2 | H315: Causes skin irritation. |
| Eye Irritation | Category 2A | H319: Causes serious eye irritation. |
| Specific Target Organ Toxicity | Category 3 | H335: May cause respiratory irritation. |
Signal Word: WARNING
Hazard Pictograms: GHS07 (Exclamation Mark)
10. PRECAUTIONARY STATEMENTS (P-CODES)
| Code | Statement |
|---|---|
| P261 | Avoid breathing dust. |
| P264 | Wash thoroughly after handling. |
| P271 | Use only in well-ventilated areas. |
| P280 | Wear protective gloves/eye protection/face protection. |
| P302+P352 | IF ON SKIN: Wash with plenty of soap and water. |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing. |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. |
| P337+P313 | If eye irritation persists: Get medical advice/attention. |
| P501 | Dispose of contents/container in accordance with local regulations. |
11. FIRST AID MEASURES
| Exposure Route | Action to Take |
|---|---|
| Inhalation | Remove to fresh air. If symptoms persist, seek medical attention. |
| Skin Contact | Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention. |
| Eye Contact | Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention. |
| Ingestion | Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention. |
12. STORAGE AND SHELF LIFE
| Parameter | Condition |
|---|---|
| Storage Conditions | Store in a cool, dry, and well-ventilated area. Ensure a moisture-free environment. |
| Container Requirements | Moisture-proof, tightly closed containers. |
| Temperature | Room temperature (15-25°C). |
| Shelf Life | 24-36 months under appropriate conditions. |
| Stability Note | Stable under normal conditions; should be stored in closed packaging to prevent moisture and CO₂ absorption. |
13. PACKAGING OPTIONS
| Packaging Type | Quantity | Material |
|---|---|---|
| Laboratory Packaging | 5 g, 10 g, 25 g, 50 g, 100 g | HDPE bottle, aluminum foil bag |
| Industrial Packaging | 25 kg | PE-lined kraft bag, moisture-proof |
| Drum | 25 kg, 50 kg | HDPE drum, moisture-proof |
| IBC (Intermediate Bulk Container) | 500 kg, 1000 kg | Moisture-proof, palletized |
14. TRANSPORT INFORMATION
| Parameter | Information |
|---|---|
| UN Number | Not classified (specific regulations apply for rare earth oxides) |
| Hazard Class | - |
| Packing Group | - |
| ADR/RID | Not regulated (special precautions may be required for powder form) |
| IMDG | Not regulated |
| IATA | Not regulated |
| HS Code | 2846.90.00.00.19 (Other rare earth compounds) |
15. REGULATORY STATUS
| Region / Authority | Status |
|---|---|
| European Union (REACH) | Registered |
| Turkey (KKDIK) | Compliance required |
| TSCA (USA) | Registered |
| EINECS | 234-931-9 |
| China (REACH equivalent) | Registered; major production and export country |
16. OTHER NAMES AND SYNONYMS
| Name | Description |
|---|---|
| Lutetia | Common short name |
| Lutetium Trioxide | Chemical name |
| Lutetium Sesquioxide | Chemical name |
| Lutetium(III) Oxide | Chemical name |
| Lu₂O₃ | Chemical abbreviation |
| Rare Earth Oxide | Category name |
| Lutetium Oxide | English name |
17. QUICK REFERENCE TABLE
| Property | Value |
|---|---|
| CAS Number | 12032-20-1 |
| EC Number | 234-931-9 |
| Chemical Formula | Lu₂O₃ |
| Molecular Weight | 397.93 g/mol |
| Appearance | White powder |
| Density | ~9.4 g/cm³ |
| Melting Point | ~2,490 °C |
| Crystal Structure | Cubic (bixbyite) |
| HS Code | 2846.90.00.00.19 |
| GHS Signal Word | WARNING |
18. CRITICAL WARNINGS AND BEST PRACTICES
CRITICAL WARNINGS:
Highest Density: Lutetium oxide has the highest density among rare earth oxides (~9.4 g/cm³); this property provides advantages for radiation shielding and optical applications.
High Value and Critical Importance: Lutetium is a critical and valuable rare earth element for optical, laser, and electronic applications. Losses should be minimized and recycling options explored.
High Purity Requirement: Optical, laser, and electronic applications require high purity (>99.9%). Purity level directly affects application performance.
Optical Applications: Used as transparent ceramics, IR windows, and laser host materials; doped with Nd³⁺, Yb³⁺ ions for laser crystals.
Powder Hazard: Fine powder form may cause respiratory tract irritation. Dust control measures must be taken.
BEST PRACTICE RECOMMENDATIONS:
Storage:
Store in a cool, dry, and well-ventilated area.
Use moisture-proof, tightly closed containers.
Keep away from acids and oxidizing agents.
Store at room temperature (15-25°C).
Handling:
Use in well-ventilated areas with local exhaust ventilation.
Use a dust mask (N95 or better), protective goggles, and gloves.
Avoid dust formation and inhalation.
Wash hands thoroughly after handling.
For dissolution in acids, add oxide to acid slowly with cooling and stirring.
Waste Management:
Dispose of in accordance with local regulations.
Do not discharge into water sources.
For large quantities, rare earth recycling and recovery should be considered (economically viable).
LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Lutetium oxide is a critical rare earth material for laser, optical ceramics, electronics, and advanced material applications; careful handling, storage, and recycling planning are required due to high purity requirements and value.