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Lutetium Oxide, Lutetium Sesquioxide, Lutetium Trioxide, Lutetia, 12032-20-1

Lutetium Oxide, Lutetium Sesquioxide, Lutetium Trioxide, Lutetia, 12032-20-1

LUTETIUM OXIDE (LU₂O₃)
LUTETIUM OXIDE / LUTETIA / LUTETIUM SESQUIOXIDE / LUTETIUM TRIOXIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Lutetium Oxide
Chemical Name Lutetium(III) Oxide, Lutetium Trioxide, Lutetium Sesquioxide
Other Names Lutetia, Lu₂O₃
CAS Number 12032-20-1
EC Number (EINECS) 234-931-9
Chemical Formula Lu₂O₃
Molecular Weight 397.93 g/mol
Appearance White powder
Odor Odorless
Physical State (20°C) Solid (powder)

2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Lutetium oxide is a high-purity oxide of the rare earth element lutetium and oxygen. Lutetium ions (Lu³⁺) and oxide ions (O²⁻) are present in a 2:3 ratio. It has a cubic crystal structure (bixbyite type). It has the highest density among rare earth oxides. It is known for its high thermal stability, chemical inertness, and excellent optical properties. It is insoluble in water but soluble in strong acids.

Structural Features:

                    LUTETIUM OXIDE [Lu₂O₃]
                          |
                Lu³⁺ - O²⁻ Ionic Bonds
                          |
        +----------------+----------------+
        |                |                |
    Cubic (Bixbyite)   White Powder     Highest
    Crystal Structure                   Density

2.2. Structural Properties

Parameter Value
Crystal Structure Cubic (bixbyite type)
Chemical Formula Lu₂O₃
Molecular Weight 397.93 g/mol
Density ~9.4 g/cm³
Appearance White powder
Melting Point ~2,490 °C
Boiling Point ~3,980 °C
Refractive Index ~1.94

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance White powder Color shade depends on purity
Odor Odorless -
Chemical Formula Lu₂O₃ -
Molecular Weight 397.93 g/mol -
Density ~9.4 g/cm³ Highest among rare earth oxides
Melting Point ~2,490 °C -
Solubility in Water (25°C) Insoluble -
Solubility in Acids Soluble Forms lutetium salts
Solubility in Alcohol Insoluble -
Crystal Structure Cubic (bixbyite) -
Thermal Stability High -
Chemical Inertness High -
Hygroscopicity Low -

4. PURITY GRADES

Parameter Technical Grade High Purity Grade Analytical Grade Ultra-High Purity Grade
Purity (Lu₂O₃) ≥ 99.0% ≥ 99.9% ≥ 99.99% ≥ 99.999%
Other Rare Earths ≤ 1.0% ≤ 0.1% ≤ 0.01% ≤ 0.001%
Iron (Fe) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Calcium (Ca) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Silicon (Si) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Heavy Metals (Pb) ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm ≤ 5 ppm
Chloride (Cl⁻) ≤ 0.1% ≤ 0.05% ≤ 0.02% ≤ 0.01%
Loss on Drying ≤ 1.0% ≤ 0.5% ≤ 0.3% ≤ 0.1%
Particle Size (D50) 5-20 µm 1-10 µm 0.5-5 µm 0.2-2 µm
BET Surface Area 5-15 m²/g 10-20 m²/g 15-30 m²/g 20-50 m²/g

5. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Stable at high temperatures; chemically inert.
Conditions to Avoid Strong acids, high humidity (prolonged).
Incompatible Materials Strong acids, strong reducing agents, halogens.
Hazardous Decomposition Products Upon oxidation at high temperatures: lutetium oxide (Lu₂O₃) is stable; with acids: lutetium salts.
Hazardous Polymerization Will not occur.
Hygroscopicity Low.

5.1. Chemical Reactions

  • Reaction with Acids:
    Lu₂O₃ + 6HCl → 2LuCl₃ + 3H₂O
    Lu₂O₃ + 6HNO₃ → 2Lu(NO₃)₃ + 3H₂O
    Lu₂O₃ + 3H₂SO₄ → Lu₂(SO₄)₃ + 3H₂O

  • Carbonation (Over Time):
    Lu₂O₃ + 3CO₂ + 3H₂O → Lu₂(CO₃)₃·3H₂O (slow)

6. APPLICATION AREAS
6.1. Optics and Laser Applications

Application Function Details
Transparent Ceramics Optical material IR windows, high temperature optics
Laser Host Materials Optical host Nd³⁺, Yb³⁺ doped laser crystals
Laser Crystals Dopant High-power laser systems
IR Windows Infrared transparency Defense and industrial applications

6.2. Electronics

Application Function Details
Dielectric Material High purity dielectric Sensors
Thin Film Coatings Surface engineering Optoelectronic applications
Semiconductor Components Dopant Special electronic applications

6.3. Nuclear Technology

Application Function Details
Radiation Shielding High density Research applications
Nuclear Materials Radiation shield Special nuclear applications

6.4. Ceramics

Application Function Details
Refractory Ceramics High temperature resistance Thermal protection systems
Ceramic Additive Thermal stability High temperature applications
Thermal Barrier Coatings Thermal insulation Gas turbines, engines

6.5. Chemical Precursor

Application Function Details
Lutetium Salts Starting material Nitrate, chloride production
Chemical Synthesis High purity intermediate Special chemical applications

6.6. Sectoral Suitability Table

Sector Suitability Explanation
Optics and Laser Suitable Transparent ceramics, laser hosts, IR windows
Electronics Suitable Dielectrics, thin film coatings
Nuclear Suitable Radiation shielding materials
Ceramics Suitable Refractory ceramics, thermal barrier coatings
Chemicals Suitable Precursor for lutetium salts
Food Not Suitable Rare earth oxide, not suitable
Cosmetics Not Suitable Rare earth oxide, not suitable

7. PRODUCTION PROCESS

Stage Process Description
1. Raw Material Preparation Rare earth concentrates Extraction from monazite or bastnäsite ores
2. Separation Solvent extraction Separation of lutetium from other rare earths
3. Precipitation Chemical precipitation Precipitation of lutetium salts
4. Calcination Thermal treatment Conversion to oxide form (800-1000°C)
5. Milling Mechanical processing Achieving desired particle size
6. Quality Control Analysis and testing ICP-OES, XRD, BET surface area

7.1. Major Producing Countries

Country Description
China Major producer
USA Rare earth production
Australia Rare earth mining

8. ALTERNATIVE / SUBSTITUTE PRODUCTS

Alternative Description When to Use
Lutetium Nitrate For solution chemistry When liquid form of lutetium is required
Lutetium Chloride For solution chemistry When liquid form of lutetium is required
Yttrium Oxide (Y₂O₃) Optical applications When different optical properties are required
Gadolinium Oxide (Gd₂O₃) Magnetic applications When different magnetic properties are required
Scandium Oxide (Sc₂O₃) Ceramic applications When different properties are required

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 2,000 mg/kg (low toxicity)
Dermal Toxicity Low
Skin Irritation Mild irritant
Eye Irritation Mild to moderate irritant
Inhalation Fine dust inhalation may cause respiratory tract irritation.
Carcinogenicity Not classified as carcinogenic.
Mutagenicity Not mutagenic.
Chronic Effects Rare earth oxides have low bioavailability; prolonged exposure may cause lung effects.
Environmental Hazards Low aquatic toxicity.

9.1. GHS Classification

Hazard Class Category H-Statement
Skin Irritation Category 2 H315: Causes skin irritation.
Eye Irritation Category 2A H319: Causes serious eye irritation.
Specific Target Organ Toxicity Category 3 H335: May cause respiratory irritation.

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

10. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust.
P264 Wash thoroughly after handling.
P271 Use only in well-ventilated areas.
P280 Wear protective gloves/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
P337+P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local regulations.

11. FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air. If symptoms persist, seek medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention.
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention.
Ingestion Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention.

12. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, and well-ventilated area. Ensure a moisture-free environment.
Container Requirements Moisture-proof, tightly closed containers.
Temperature Room temperature (15-25°C).
Shelf Life 24-36 months under appropriate conditions.
Stability Note Stable under normal conditions; should be stored in closed packaging to prevent moisture and CO₂ absorption.

13. PACKAGING OPTIONS

Packaging Type Quantity Material
Laboratory Packaging 5 g, 10 g, 25 g, 50 g, 100 g HDPE bottle, aluminum foil bag
Industrial Packaging 25 kg PE-lined kraft bag, moisture-proof
Drum 25 kg, 50 kg HDPE drum, moisture-proof
IBC (Intermediate Bulk Container) 500 kg, 1000 kg Moisture-proof, palletized

14. TRANSPORT INFORMATION

Parameter Information
UN Number Not classified (specific regulations apply for rare earth oxides)
Hazard Class -
Packing Group -
ADR/RID Not regulated (special precautions may be required for powder form)
IMDG Not regulated
IATA Not regulated
HS Code 2846.90.00.00.19 (Other rare earth compounds)

15. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Registered
Turkey (KKDIK) Compliance required
TSCA (USA) Registered
EINECS 234-931-9
China (REACH equivalent) Registered; major production and export country

16. OTHER NAMES AND SYNONYMS

Name Description
Lutetia Common short name
Lutetium Trioxide Chemical name
Lutetium Sesquioxide Chemical name
Lutetium(III) Oxide Chemical name
Lu₂O₃ Chemical abbreviation
Rare Earth Oxide Category name
Lutetium Oxide English name

17. QUICK REFERENCE TABLE

Property Value
CAS Number 12032-20-1
EC Number 234-931-9
Chemical Formula Lu₂O₃
Molecular Weight 397.93 g/mol
Appearance White powder
Density ~9.4 g/cm³
Melting Point ~2,490 °C
Crystal Structure Cubic (bixbyite)
HS Code 2846.90.00.00.19
GHS Signal Word WARNING

18. CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • Highest Density: Lutetium oxide has the highest density among rare earth oxides (~9.4 g/cm³); this property provides advantages for radiation shielding and optical applications.

  • High Value and Critical Importance: Lutetium is a critical and valuable rare earth element for optical, laser, and electronic applications. Losses should be minimized and recycling options explored.

  • High Purity Requirement: Optical, laser, and electronic applications require high purity (>99.9%). Purity level directly affects application performance.

  • Optical Applications: Used as transparent ceramics, IR windows, and laser host materials; doped with Nd³⁺, Yb³⁺ ions for laser crystals.

  • Powder Hazard: Fine powder form may cause respiratory tract irritation. Dust control measures must be taken.

BEST PRACTICE RECOMMENDATIONS:

  • Storage:

    • Store in a cool, dry, and well-ventilated area.

    • Use moisture-proof, tightly closed containers.

    • Keep away from acids and oxidizing agents.

    • Store at room temperature (15-25°C).

  • Handling:

    • Use in well-ventilated areas with local exhaust ventilation.

    • Use a dust mask (N95 or better), protective goggles, and gloves.

    • Avoid dust formation and inhalation.

    • Wash hands thoroughly after handling.

    • For dissolution in acids, add oxide to acid slowly with cooling and stirring.

  • Waste Management:

    • Dispose of in accordance with local regulations.

    • Do not discharge into water sources.

    • For large quantities, rare earth recycling and recovery should be considered (economically viable).

LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Lutetium oxide is a critical rare earth material for laser, optical ceramics, electronics, and advanced material applications; careful handling, storage, and recycling planning are required due to high purity requirements and value.

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