Do you have questions? Let's talk! Get in Contact
info@betakim.com.tr

Scandium Oxide, Scandium Trioxide, Scandium Sesquioxide, Skandia, Scandia, 12060-08-1

Scandium Oxide, Scandium Trioxide, Scandium Sesquioxide, Skandia, Scandia, 12060-08-1

SCANDIUM OXIDE (SC₂O₃)
SCANDIUM OXIDE / SCANDIA / SCANDIUM TRIOXIDE / SCANDIUM SESQUIOXIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Scandium Oxide
Chemical Name Scandium(III) Oxide, Scandium Trioxide, Scandium Sesquioxide
Other Names Scandia, Sc₂O₃
CAS Number 12060-08-1
EC Number (EINECS) 235-042-0
Chemical Formula Sc₂O₃
Molecular Weight 137.91 g/mol
Appearance White powder
Odor Odorless
Physical State (20°C) Solid (powder)

2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Scandium oxide is the oxide compound of the rare earth element scandium. Scandium ions (Sc³⁺) and oxide ions (O²⁻) are present in a 2:3 ratio. It has a cubic crystal structure (bixbyite type; space group Ia3). It is known for its high thermal stability, good chemical inertness, and suitable dielectric properties. It is insoluble in water but soluble in concentrated acid solutions.

Structural Features:

                    SCANDIUM OXIDE [Sc₂O₃]
                          |
                Sc³⁺ - O²⁻ Ionic Bonds
                          |
        +----------------+----------------+
        |                |                |
    Cubic (Bixbyite)   White Powder     High Thermal
    Crystal Structure                   Stability

2.2. Structural Properties

Parameter Value
Crystal Structure Cubic (bixbyite; space group Ia3)
Lattice Constant ~0.9846 nm
Chemical Formula Sc₂O₃
Molecular Weight 137.91 g/mol
Density ~3.86 g/cm³
Appearance White powder
Melting Point ~2,485 °C
Boiling Point ~3,900 °C
Dielectric Constant Suitable

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance White powder Color shade depends on purity
Odor Odorless -
Chemical Formula Sc₂O₃ -
Molecular Weight 137.91 g/mol -
Density ~3.86 g/cm³ -
Melting Point ~2,485 °C -
Solubility in Water (25°C) Insoluble -
Solubility in Acids Soluble in concentrated acids Accelerated by complexation
Solubility in Alcohol Insoluble -
Crystal Structure Cubic (bixbyite) -
Thermal Stability High -
Chemical Inertness High -
Hygroscopicity Low Surface hydroxylation/carbonate formation with moisture and CO₂

4. PURITY GRADES

Parameter Technical Grade High Purity Grade Analytical Grade Ultra-High Purity Grade
Purity (Sc₂O₃) ≥ 99.0% (3N) ≥ 99.9% (3N) ≥ 99.99% (4N) ≥ 99.999% (5N)
Other Rare Earths ≤ 1.0% ≤ 0.1% ≤ 0.01% ≤ 0.001%
Iron (Fe) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Calcium (Ca) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Silicon (Si) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Aluminum (Al) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Sodium (Na) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Heavy Metals (Pb) ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm ≤ 5 ppm
Chloride (Cl⁻) ≤ 0.1% ≤ 0.05% ≤ 0.02% ≤ 0.01%
Sulfate (SO₄²⁻) ≤ 0.1% ≤ 0.05% ≤ 0.02% ≤ 0.01%
Loss on Ignition (LOI) ≤ 1.0% ≤ 0.5% ≤ 0.3% ≤ 0.1%
Particle Size (D50) 5-20 µm 1-10 µm 0.5-5 µm 0.2-2 µm
BET Surface Area 5-15 m²/g 10-20 m²/g 15-30 m²/g 20-50 m²/g

5. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability High thermal stability; good chemical inertness.
Conditions to Avoid Strong acids, high humidity (prolonged), CO₂.
Incompatible Materials Strong acids, strong reducing agents, halogens.
Hazardous Decomposition Products Upon oxidation at high temperatures: scandium oxide (Sc₂O₃) is stable; with acids: scandium salts.
Hazardous Polymerization Will not occur.
Hygroscopicity Low; surface hydroxylation and carbonate formation should be prevented.

5.1. Chemical Reactions

  • Reaction with Acids:
    Sc₂O₃ + 6HCl → 2ScCl₃ + 3H₂O
    Sc₂O₃ + 6HNO₃ → 2Sc(NO₃)₃ + 3H₂O
    Sc₂O₃ + 3H₂SO₄ → Sc₂(SO₄)₃ + 3H₂O

  • Carbonation (Over Time):
    Sc₂O₃ + 3CO₂ + 3H₂O → Sc₂(CO₃)₃·3H₂O (slow)

6. APPLICATION AREAS
6.1. Advanced Ceramics

Application Function Details
Refractory Ceramics High temperature resistance Sintered components
Ceramic Additive Thermal stability High temperature applications
Thermal Barrier Coatings Thermal insulation High temperature systems

6.2. Electronics and Dielectrics

Application Function Details
Oxide Layers High purity dielectric Sensor substrates
Capacitors Dielectric material High frequency applications
Semiconductor Components Dopant Electronic circuits

6.3. Alloys

Application Function Details
Aluminum Alloys Micrograin control Mechanical property improvement
Magnesium Alloys Strength enhancer Aerospace and automotive applications
Sc-Added Al Alloys Precursor material High performance alloys

6.4. Optics and Coatings

Application Function Details
Thin Film Oxide Layers Optical coatings Surface engineering
Surface Coatings Protective layer Systems requiring low ionic contaminants
Optical Components High transparency Special optical applications

6.5. Chemical Intermediate

Application Function Details
Scandium Salts Starting material Nitrate/chloride conversion
Catalytic Applications Sc source Organometallic syntheses
Chemical Synthesis High purity intermediate Special chemical applications

6.6. Sectoral Suitability Table

Sector Suitability Explanation
Ceramics Suitable Refractory ceramics, high temperature resistance
Electronics Suitable Dielectrics, sensor substrates
Metallurgy Suitable Aluminum and magnesium alloys
Optics Suitable Thin film coatings, surface engineering
Chemicals Suitable Intermediate, catalyst precursor
Food Not Suitable Rare earth oxide, not suitable
Cosmetics Not Suitable Rare earth oxide, not suitable

7. PRODUCTION PROCESS

Stage Process Description
1. Raw Material Preparation Rare earth concentrates Extraction from bastnäsite/monazite ores
2. Acid Leaching Chemical extraction Dissolution of scandium into solution
3. Separation Solvent extraction/ion exchange Separation of scandium from other rare earths
4. Selective Precipitation Chemical precipitation Precipitation of scandium salts
5. Calcination Thermal treatment Conversion to oxide form
6. Milling and Classification Mechanical processing Achieving desired particle size
7. Quality Control Analysis and testing ICP-OES, XRD, BET surface area, LOI

7.1. Major Producing Countries

Country Description
China Major producer
Australia Rare earth mining
Russia Scandium production
USA Rare earth production

8. ALTERNATIVE / SUBSTITUTE PRODUCTS

Alternative Description When to Use
Scandium Nitrate For solution chemistry When liquid form of scandium is required
Scandium Chloride For solution chemistry When liquid form of scandium is required
Yttrium Oxide (Y₂O₃) Ceramic applications When different properties are required
Lanthanum Oxide (La₂O₃) Optical applications When different optical properties are required
Aluminum Oxide (Al₂O₃) Ceramic applications Lower cost alternative

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 2,000 mg/kg (low toxicity)
Dermal Toxicity Low
Skin Irritation Mild irritant
Eye Irritation Mild to moderate irritant
Inhalation Fine dust inhalation may cause respiratory tract irritation.
Carcinogenicity Not classified as carcinogenic.
Mutagenicity Not mutagenic.
Chronic Effects Rare earth oxides have low bioavailability; prolonged exposure may cause lung effects.
Environmental Hazards Low aquatic toxicity.

9.1. GHS Classification

Hazard Class Category H-Statement
Skin Irritation Category 2 H315: Causes skin irritation.
Eye Irritation Category 2A H319: Causes serious eye irritation.
Specific Target Organ Toxicity Category 3 H335: May cause respiratory irritation.

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

10. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust.
P264 Wash thoroughly after handling.
P271 Use only in well-ventilated areas.
P280 Wear protective gloves/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
P337+P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local regulations.

11. FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air. If symptoms persist, seek medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention.
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention.
Ingestion Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention.

12. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store under inert atmosphere (nitrogen/argon), at 2-8°C, in dry and closed containers.
Container Requirements Moisture barrier, antistatic (nano grade), tightly closed containers.
Temperature 2-8°C (supplier recommendation) or room temperature (15-25°C).
Shelf Life 24-36 months under appropriate conditions.
Stability Note Surface hydroxylation and carbonate formation with moisture and CO₂ should be prevented.

13. PACKAGING OPTIONS

Packaging Type Quantity Material
Laboratory Packaging 5 g, 10 g, 25 g, 50 g, 100 g HDPE bottle, aluminum foil bag, inert atmosphere
Industrial Packaging 25 kg PE-lined kraft bag, moisture barrier
Drum 25 kg, 50 kg HDPE drum, moisture barrier
IBC (Intermediate Bulk Container) 500 kg, 1000 kg Moisture barrier, palletized

14. TRANSPORT INFORMATION

Parameter Information
UN Number Not classified (specific regulations apply for rare earth oxides)
Hazard Class -
Packing Group -
ADR/RID Not regulated (special precautions may be required for powder form)
IMDG Not regulated
IATA Not regulated
HS Code 2846.90.00.00.19 (Other rare earth compounds)

15. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Registered
Turkey (KKDIK) Compliance required
TSCA (USA) Registered
EINECS 235-042-0
China (REACH equivalent) Registered; major production and export country

16. OTHER NAMES AND SYNONYMS

Name Description
Scandia Common short name
Scandium Trioxide Chemical name
Scandium Sesquioxide Chemical name
Scandium(III) Oxide Chemical name
Sc₂O₃ Chemical abbreviation
Rare Earth Oxide Category name
Scandium Oxide English name

17. QUICK REFERENCE TABLE

Property Value
CAS Number 12060-08-1
EC Number 235-042-0
Chemical Formula Sc₂O₃
Molecular Weight 137.91 g/mol
Appearance White powder
Density ~3.86 g/cm³
Melting Point ~2,485 °C
Crystal Structure Cubic (bixbyite)
HS Code 2846.90.00.00.19
GHS Signal Word WARNING

18. CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • High Value and Critical Importance: Scandium is a critical and valuable rare earth element for electronic, ceramic, and alloy applications. Losses should be minimized and recycling options explored.

  • High Purity Requirement: Electronic, optical, and alloy applications require high purity (>99.9%). Purity level directly affects application performance.

  • Storage Conditions: Storage under inert atmosphere (nitrogen/argon) at 2-8°C is recommended; surface hydroxylation and carbonate formation with moisture and CO₂ should be prevented.

  • Alloy Applications: Scandium provides micrograin control and mechanical property improvement in aluminum and magnesium alloys; Sc₂O₃ is used as a precursor.

  • Powder Hazard: Fine powder form may cause respiratory tract irritation. Dust control measures must be taken.

BEST PRACTICE RECOMMENDATIONS:

  • Storage:

    • Store under inert atmosphere (nitrogen/argon) at 2-8°C, in dry and closed containers.

    • Use moisture barrier, tightly closed containers.

    • Keep away from acids and oxidizing agents.

  • Handling:

    • Use in well-ventilated areas with local exhaust ventilation.

    • Use a dust mask (FFP2/FFP3 for nano/submicron), protective goggles, and gloves.

    • Avoid dust formation and inhalation.

    • Wash hands thoroughly after handling.

    • For dissolution in acids, add oxide to acid slowly with cooling and stirring.

  • Waste Management:

    • Dispose of in accordance with local regulations.

    • Do not discharge into water sources.

    • For large quantities, rare earth recycling and recovery should be considered (economically viable).

LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Scandium oxide is a critical rare earth material for electronic, ceramic, and alloy applications; careful handling, storage, and recycling planning are required due to high purity requirements and value.

Images

Do you have questions? Let us help!

Effective Business Solutions? — Get in Contact
Scroll