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Send EmailScandium Oxide, Scandium Trioxide, Scandium Sesquioxide, Skandia, Scandia, 12060-08-1
SCANDIUM OXIDE (SC₂O₃)
SCANDIUM OXIDE / SCANDIA / SCANDIUM TRIOXIDE / SCANDIUM SESQUIOXIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY
| Parameter | Information |
|---|---|
| Product Name | Scandium Oxide |
| Chemical Name | Scandium(III) Oxide, Scandium Trioxide, Scandium Sesquioxide |
| Other Names | Scandia, Sc₂O₃ |
| CAS Number | 12060-08-1 |
| EC Number (EINECS) | 235-042-0 |
| Chemical Formula | Sc₂O₃ |
| Molecular Weight | 137.91 g/mol |
| Appearance | White powder |
| Odor | Odorless |
| Physical State (20°C) | Solid (powder) |
2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Scandium oxide is the oxide compound of the rare earth element scandium. Scandium ions (Sc³⁺) and oxide ions (O²⁻) are present in a 2:3 ratio. It has a cubic crystal structure (bixbyite type; space group Ia3). It is known for its high thermal stability, good chemical inertness, and suitable dielectric properties. It is insoluble in water but soluble in concentrated acid solutions.
Structural Features:
SCANDIUM OXIDE [Sc₂O₃]
|
Sc³⁺ - O²⁻ Ionic Bonds
|
+----------------+----------------+
| | |
Cubic (Bixbyite) White Powder High Thermal
Crystal Structure Stability
2.2. Structural Properties
| Parameter | Value |
|---|---|
| Crystal Structure | Cubic (bixbyite; space group Ia3) |
| Lattice Constant | ~0.9846 nm |
| Chemical Formula | Sc₂O₃ |
| Molecular Weight | 137.91 g/mol |
| Density | ~3.86 g/cm³ |
| Appearance | White powder |
| Melting Point | ~2,485 °C |
| Boiling Point | ~3,900 °C |
| Dielectric Constant | Suitable |
3. PHYSICAL AND CHEMICAL PROPERTIES
| Property | Value | Description |
|---|---|---|
| Appearance | White powder | Color shade depends on purity |
| Odor | Odorless | - |
| Chemical Formula | Sc₂O₃ | - |
| Molecular Weight | 137.91 g/mol | - |
| Density | ~3.86 g/cm³ | - |
| Melting Point | ~2,485 °C | - |
| Solubility in Water (25°C) | Insoluble | - |
| Solubility in Acids | Soluble in concentrated acids | Accelerated by complexation |
| Solubility in Alcohol | Insoluble | - |
| Crystal Structure | Cubic (bixbyite) | - |
| Thermal Stability | High | - |
| Chemical Inertness | High | - |
| Hygroscopicity | Low | Surface hydroxylation/carbonate formation with moisture and CO₂ |
4. PURITY GRADES
| Parameter | Technical Grade | High Purity Grade | Analytical Grade | Ultra-High Purity Grade |
|---|---|---|---|---|
| Purity (Sc₂O₃) | ≥ 99.0% (3N) | ≥ 99.9% (3N) | ≥ 99.99% (4N) | ≥ 99.999% (5N) |
| Other Rare Earths | ≤ 1.0% | ≤ 0.1% | ≤ 0.01% | ≤ 0.001% |
| Iron (Fe) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Calcium (Ca) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Silicon (Si) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Aluminum (Al) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Sodium (Na) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Heavy Metals (Pb) | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm | ≤ 5 ppm |
| Chloride (Cl⁻) | ≤ 0.1% | ≤ 0.05% | ≤ 0.02% | ≤ 0.01% |
| Sulfate (SO₄²⁻) | ≤ 0.1% | ≤ 0.05% | ≤ 0.02% | ≤ 0.01% |
| Loss on Ignition (LOI) | ≤ 1.0% | ≤ 0.5% | ≤ 0.3% | ≤ 0.1% |
| Particle Size (D50) | 5-20 µm | 1-10 µm | 0.5-5 µm | 0.2-2 µm |
| BET Surface Area | 5-15 m²/g | 10-20 m²/g | 15-30 m²/g | 20-50 m²/g |
5. STABILITY AND REACTIVITY
| Parameter | Information |
|---|---|
| Chemical Stability | High thermal stability; good chemical inertness. |
| Conditions to Avoid | Strong acids, high humidity (prolonged), CO₂. |
| Incompatible Materials | Strong acids, strong reducing agents, halogens. |
| Hazardous Decomposition Products | Upon oxidation at high temperatures: scandium oxide (Sc₂O₃) is stable; with acids: scandium salts. |
| Hazardous Polymerization | Will not occur. |
| Hygroscopicity | Low; surface hydroxylation and carbonate formation should be prevented. |
5.1. Chemical Reactions
Reaction with Acids:
Sc₂O₃ + 6HCl → 2ScCl₃ + 3H₂O
Sc₂O₃ + 6HNO₃ → 2Sc(NO₃)₃ + 3H₂O
Sc₂O₃ + 3H₂SO₄ → Sc₂(SO₄)₃ + 3H₂O
Carbonation (Over Time):
Sc₂O₃ + 3CO₂ + 3H₂O → Sc₂(CO₃)₃·3H₂O (slow)
6. APPLICATION AREAS
6.1. Advanced Ceramics
| Application | Function | Details |
|---|---|---|
| Refractory Ceramics | High temperature resistance | Sintered components |
| Ceramic Additive | Thermal stability | High temperature applications |
| Thermal Barrier Coatings | Thermal insulation | High temperature systems |
6.2. Electronics and Dielectrics
| Application | Function | Details |
|---|---|---|
| Oxide Layers | High purity dielectric | Sensor substrates |
| Capacitors | Dielectric material | High frequency applications |
| Semiconductor Components | Dopant | Electronic circuits |
6.3. Alloys
| Application | Function | Details |
|---|---|---|
| Aluminum Alloys | Micrograin control | Mechanical property improvement |
| Magnesium Alloys | Strength enhancer | Aerospace and automotive applications |
| Sc-Added Al Alloys | Precursor material | High performance alloys |
6.4. Optics and Coatings
| Application | Function | Details |
|---|---|---|
| Thin Film Oxide Layers | Optical coatings | Surface engineering |
| Surface Coatings | Protective layer | Systems requiring low ionic contaminants |
| Optical Components | High transparency | Special optical applications |
6.5. Chemical Intermediate
| Application | Function | Details |
|---|---|---|
| Scandium Salts | Starting material | Nitrate/chloride conversion |
| Catalytic Applications | Sc source | Organometallic syntheses |
| Chemical Synthesis | High purity intermediate | Special chemical applications |
6.6. Sectoral Suitability Table
| Sector | Suitability | Explanation |
|---|---|---|
| Ceramics | Suitable | Refractory ceramics, high temperature resistance |
| Electronics | Suitable | Dielectrics, sensor substrates |
| Metallurgy | Suitable | Aluminum and magnesium alloys |
| Optics | Suitable | Thin film coatings, surface engineering |
| Chemicals | Suitable | Intermediate, catalyst precursor |
| Food | Not Suitable | Rare earth oxide, not suitable |
| Cosmetics | Not Suitable | Rare earth oxide, not suitable |
7. PRODUCTION PROCESS
| Stage | Process | Description |
|---|---|---|
| 1. Raw Material Preparation | Rare earth concentrates | Extraction from bastnäsite/monazite ores |
| 2. Acid Leaching | Chemical extraction | Dissolution of scandium into solution |
| 3. Separation | Solvent extraction/ion exchange | Separation of scandium from other rare earths |
| 4. Selective Precipitation | Chemical precipitation | Precipitation of scandium salts |
| 5. Calcination | Thermal treatment | Conversion to oxide form |
| 6. Milling and Classification | Mechanical processing | Achieving desired particle size |
| 7. Quality Control | Analysis and testing | ICP-OES, XRD, BET surface area, LOI |
7.1. Major Producing Countries
| Country | Description |
|---|---|
| China | Major producer |
| Australia | Rare earth mining |
| Russia | Scandium production |
| USA | Rare earth production |
8. ALTERNATIVE / SUBSTITUTE PRODUCTS
| Alternative | Description | When to Use |
|---|---|---|
| Scandium Nitrate | For solution chemistry | When liquid form of scandium is required |
| Scandium Chloride | For solution chemistry | When liquid form of scandium is required |
| Yttrium Oxide (Y₂O₃) | Ceramic applications | When different properties are required |
| Lanthanum Oxide (La₂O₃) | Optical applications | When different optical properties are required |
| Aluminum Oxide (Al₂O₃) | Ceramic applications | Lower cost alternative |
9. SAFETY AND TOXICOLOGY
| Parameter | Value |
|---|---|
| Acute Oral Toxicity (LD50, Rat) | > 2,000 mg/kg (low toxicity) |
| Dermal Toxicity | Low |
| Skin Irritation | Mild irritant |
| Eye Irritation | Mild to moderate irritant |
| Inhalation | Fine dust inhalation may cause respiratory tract irritation. |
| Carcinogenicity | Not classified as carcinogenic. |
| Mutagenicity | Not mutagenic. |
| Chronic Effects | Rare earth oxides have low bioavailability; prolonged exposure may cause lung effects. |
| Environmental Hazards | Low aquatic toxicity. |
9.1. GHS Classification
| Hazard Class | Category | H-Statement |
|---|---|---|
| Skin Irritation | Category 2 | H315: Causes skin irritation. |
| Eye Irritation | Category 2A | H319: Causes serious eye irritation. |
| Specific Target Organ Toxicity | Category 3 | H335: May cause respiratory irritation. |
Signal Word: WARNING
Hazard Pictograms: GHS07 (Exclamation Mark)
10. PRECAUTIONARY STATEMENTS (P-CODES)
| Code | Statement |
|---|---|
| P261 | Avoid breathing dust. |
| P264 | Wash thoroughly after handling. |
| P271 | Use only in well-ventilated areas. |
| P280 | Wear protective gloves/eye protection/face protection. |
| P302+P352 | IF ON SKIN: Wash with plenty of soap and water. |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing. |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. |
| P337+P313 | If eye irritation persists: Get medical advice/attention. |
| P501 | Dispose of contents/container in accordance with local regulations. |
11. FIRST AID MEASURES
| Exposure Route | Action to Take |
|---|---|
| Inhalation | Remove to fresh air. If symptoms persist, seek medical attention. |
| Skin Contact | Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention. |
| Eye Contact | Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention. |
| Ingestion | Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention. |
12. STORAGE AND SHELF LIFE
| Parameter | Condition |
|---|---|
| Storage Conditions | Store under inert atmosphere (nitrogen/argon), at 2-8°C, in dry and closed containers. |
| Container Requirements | Moisture barrier, antistatic (nano grade), tightly closed containers. |
| Temperature | 2-8°C (supplier recommendation) or room temperature (15-25°C). |
| Shelf Life | 24-36 months under appropriate conditions. |
| Stability Note | Surface hydroxylation and carbonate formation with moisture and CO₂ should be prevented. |
13. PACKAGING OPTIONS
| Packaging Type | Quantity | Material |
|---|---|---|
| Laboratory Packaging | 5 g, 10 g, 25 g, 50 g, 100 g | HDPE bottle, aluminum foil bag, inert atmosphere |
| Industrial Packaging | 25 kg | PE-lined kraft bag, moisture barrier |
| Drum | 25 kg, 50 kg | HDPE drum, moisture barrier |
| IBC (Intermediate Bulk Container) | 500 kg, 1000 kg | Moisture barrier, palletized |
14. TRANSPORT INFORMATION
| Parameter | Information |
|---|---|
| UN Number | Not classified (specific regulations apply for rare earth oxides) |
| Hazard Class | - |
| Packing Group | - |
| ADR/RID | Not regulated (special precautions may be required for powder form) |
| IMDG | Not regulated |
| IATA | Not regulated |
| HS Code | 2846.90.00.00.19 (Other rare earth compounds) |
15. REGULATORY STATUS
| Region / Authority | Status |
|---|---|
| European Union (REACH) | Registered |
| Turkey (KKDIK) | Compliance required |
| TSCA (USA) | Registered |
| EINECS | 235-042-0 |
| China (REACH equivalent) | Registered; major production and export country |
16. OTHER NAMES AND SYNONYMS
| Name | Description |
|---|---|
| Scandia | Common short name |
| Scandium Trioxide | Chemical name |
| Scandium Sesquioxide | Chemical name |
| Scandium(III) Oxide | Chemical name |
| Sc₂O₃ | Chemical abbreviation |
| Rare Earth Oxide | Category name |
| Scandium Oxide | English name |
17. QUICK REFERENCE TABLE
| Property | Value |
|---|---|
| CAS Number | 12060-08-1 |
| EC Number | 235-042-0 |
| Chemical Formula | Sc₂O₃ |
| Molecular Weight | 137.91 g/mol |
| Appearance | White powder |
| Density | ~3.86 g/cm³ |
| Melting Point | ~2,485 °C |
| Crystal Structure | Cubic (bixbyite) |
| HS Code | 2846.90.00.00.19 |
| GHS Signal Word | WARNING |
18. CRITICAL WARNINGS AND BEST PRACTICES
CRITICAL WARNINGS:
High Value and Critical Importance: Scandium is a critical and valuable rare earth element for electronic, ceramic, and alloy applications. Losses should be minimized and recycling options explored.
High Purity Requirement: Electronic, optical, and alloy applications require high purity (>99.9%). Purity level directly affects application performance.
Storage Conditions: Storage under inert atmosphere (nitrogen/argon) at 2-8°C is recommended; surface hydroxylation and carbonate formation with moisture and CO₂ should be prevented.
Alloy Applications: Scandium provides micrograin control and mechanical property improvement in aluminum and magnesium alloys; Sc₂O₃ is used as a precursor.
Powder Hazard: Fine powder form may cause respiratory tract irritation. Dust control measures must be taken.
BEST PRACTICE RECOMMENDATIONS:
Storage:
Store under inert atmosphere (nitrogen/argon) at 2-8°C, in dry and closed containers.
Use moisture barrier, tightly closed containers.
Keep away from acids and oxidizing agents.
Handling:
Use in well-ventilated areas with local exhaust ventilation.
Use a dust mask (FFP2/FFP3 for nano/submicron), protective goggles, and gloves.
Avoid dust formation and inhalation.
Wash hands thoroughly after handling.
For dissolution in acids, add oxide to acid slowly with cooling and stirring.
Waste Management:
Dispose of in accordance with local regulations.
Do not discharge into water sources.
For large quantities, rare earth recycling and recovery should be considered (economically viable).
LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Scandium oxide is a critical rare earth material for electronic, ceramic, and alloy applications; careful handling, storage, and recycling planning are required due to high purity requirements and value.