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Send EmailYttrium Oxide, Yttria Yttrium Sesquioxide, Yttrium Trioxide, 1314-36-9
YTRIUM OXIDE (Y₂O₃)
YTRIUM OXIDE / YTTRIA / YTRIUM SESQUIOXIDE / YTRIUM TRIOXIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY
| Parameter | Information |
|---|---|
| Product Name | Yttrium Oxide |
| Chemical Name | Yttrium(III) Oxide, Yttrium Trioxide, Yttrium Sesquioxide |
| Other Names | Yttria, Y₂O₃ |
| CAS Number | 1314-36-9 |
| EC Number (EINECS) | 215-233-5 |
| Chemical Formula | Y₂O₃ |
| Molecular Weight | 225.81 g/mol |
| Appearance | White, fine powder |
| Odor | Odorless |
| Physical State (20°C) | Solid (powder) |
2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Yttrium oxide is the oxide compound of the rare earth element yttrium. Yttrium ions (Y³⁺) and oxide ions (O²⁻) are present in a 2:3 ratio. It has a cubic crystal structure (bixbyite type). It is known for its high melting point and thermal stability. It is insoluble in water but slowly soluble in strong acids. It is stable at high temperatures and in oxidative environments.
Structural Features:
YTRIUM OXIDE [Y₂O₃]
|
Y³⁺ - O²⁻ Ionic Bonds
|
+----------------+----------------+
| | |
Cubic (Bixbyite) White Powder High Thermal
Crystal Structure Stability
2.2. Structural Properties
| Parameter | Value |
|---|---|
| Crystal Structure | Cubic (bixbyite type) |
| Chemical Formula | Y₂O₃ |
| Molecular Weight | 225.81 g/mol |
| Density | ~5.01 g/cm³ |
| Appearance | White, fine powder |
| Melting Point | ~2,425 °C |
| Boiling Point | ~4,300 °C |
| Refractive Index | ~1.93 |
| Dielectric Constant | ~12-14 |
| Band Gap | ~5.6 eV |
3. PHYSICAL AND CHEMICAL PROPERTIES
| Property | Value | Description |
|---|---|---|
| Appearance | White, fine powder | Color shade depends on purity |
| Odor | Odorless | - |
| Chemical Formula | Y₂O₃ | - |
| Molecular Weight | 225.81 g/mol | - |
| Density | ~5.01 g/cm³ | - |
| Melting Point | ~2,425 °C | - |
| Solubility in Water (25°C) | Insoluble | - |
| Solubility in Acids | Slowly soluble | Soluble in strong acids |
| Solubility in Alcohol | Insoluble | - |
| Crystal Structure | Cubic (bixbyite) | - |
| Thermal Stability | High | Stable up to 2400°C |
| Hygroscopicity | Low | - |
| Ionic Conductivity | High (in YSZ) | - |
4. PURITY GRADES
| Parameter | Technical Grade | High Purity Grade | Analytical Grade | Ultra-High Purity Grade |
|---|---|---|---|---|
| Purity (Y₂O₃) | ≥ 99.0% | ≥ 99.9% | ≥ 99.99% | ≥ 99.999% |
| Other Rare Earths | ≤ 1.0% | ≤ 0.1% | ≤ 0.01% | ≤ 0.001% |
| Iron (Fe) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Calcium (Ca) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Silicon (Si) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Heavy Metals (Pb) | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm | ≤ 5 ppm |
| Chloride (Cl⁻) | ≤ 0.1% | ≤ 0.05% | ≤ 0.02% | ≤ 0.01% |
| Loss on Drying | ≤ 1.0% | ≤ 0.5% | ≤ 0.3% | ≤ 0.1% |
| Particle Size (D50) | 5-20 µm | 1-10 µm | 0.5-5 µm | 0.2-2 µm |
| BET Surface Area | 5-15 m²/g | 10-20 m²/g | 15-30 m²/g | 20-50 m²/g |
5. STABILITY AND REACTIVITY
| Parameter | Information |
|---|---|
| Chemical Stability | Stable at high temperatures and in oxidative environments. |
| Conditions to Avoid | Strong acids, high humidity (prolonged), reducing environments. |
| Incompatible Materials | Strong acids, strong reducing agents, halogens. |
| Hazardous Decomposition Products | Upon oxidation at high temperatures: yttrium oxide (Y₂O₃) is stable; with acids: yttrium salts. |
| Hazardous Polymerization | Will not occur. |
| Hygroscopicity | Low. |
5.1. Chemical Reactions
Reaction with Acids:
Y₂O₃ + 6HCl → 2YCl₃ + 3H₂O
Y₂O₃ + 6HNO₃ → 2Y(NO₃)₃ + 3H₂O
Y₂O₃ + 3H₂SO₄ → Y₂(SO₄)₃ + 3H₂O
Reaction with Bases:
Y₂O₃ + 2NaOH → 2NaYO₂ + H₂O (at high temperature)
Carbonation (Over Time):
Y₂O₃ + 3CO₂ + 3H₂O → Y₂(CO₃)₃·3H₂O (slow)
6. APPLICATION AREAS
6.1. Phosphors and Lighting
| Application | Function | Details |
|---|---|---|
| Red Phosphor (Eu³⁺ doped) | Light conversion | LED and display technologies |
| Fluorescent Materials | Light emitter | Lighting systems |
| Cathode Ray Tubes (CRT) | Phosphor component | Legacy display technologies |
6.2. Optical and Laser Applications
| Application | Function | Details |
|---|---|---|
| Transparent Ceramics | Optical material | High temperature optics |
| IR Windows | Infrared transparency | Defense and industrial applications |
| Laser Optics | Optical component | High-power laser systems |
| Nd:YAG Laser Dopant | Optical dopant | Laser crystals |
6.3. Electronics and Magnetic Materials
| Application | Function | Details |
|---|---|---|
| Yttrium Iron Garnet (YIG) | Microwave filters | Magneto-optic devices |
| Dielectric Materials | Electronic component | Capacitors and resonators |
| Magneto-Optic Devices | Optical isolators | Fiber optic communication |
6.4. Ceramics and Coatings
| Application | Function | Details |
|---|---|---|
| Zirconia Stabilizer (YSZ) | Phase stabilization | Fuel cells, thermal barrier coatings |
| Thermal Barrier Coatings | Thermal insulation | Gas turbines, engines |
| Solid Oxide Fuel Cells (SOFC) | Oxygen ion conductivity | Energy generation |
6.5. Metallurgy
| Application | Function | Details |
|---|---|---|
| Steel Production | Oxygen/sulfur remover | Deoxidation and desulfurization |
| Titanium Alloys | Polishing additive | Surface quality improvement |
| Rare Earth Alloys | Alloying element | Special metallurgical applications |
6.6. Defense Industry
| Application | Function | Details |
|---|---|---|
| Laser Systems | Optical component | High-energy lasers |
| High Temperature Optical Components | Thermal stability | Infrared and visible optics |
| Protective Coatings | Thermal and mechanical resistance | High temperature applications |
6.7. Sectoral Suitability Table
| Sector | Suitability | Explanation |
|---|---|---|
| Phosphor/Lighting | Suitable | Eu³⁺ doped red phosphor, LED, displays |
| Optics and Laser | Suitable | Transparent ceramics, IR windows, laser optics |
| Electronics | Suitable | YIG, dielectrics, magneto-optic devices |
| Ceramics | Suitable | YSZ, thermal barrier coatings, SOFC |
| Metallurgy | Suitable | Steel production, titanium alloys |
| Defense Industry | Suitable | Laser systems, optical components |
| Food | Not Suitable | Rare earth oxide, not suitable |
| Cosmetics | Not Suitable | Rare earth oxide, not suitable |
7. PRODUCTION PROCESS
| Stage | Process | Description |
|---|---|---|
| 1. Raw Material Preparation | Rare earth concentrates | Extraction from monazite or bastnäsite ores |
| 2. Acid Leaching | Chemical extraction | Dissolution of yttrium into solution |
| 3. Purification | Solution purification | Removal of trace metals |
| 4. Precipitation | Chemical precipitation | Precipitation of yttrium salts |
| 5. Calcination | Thermal treatment | Conversion to oxide form (800-1000°C) |
| 6. Milling | Mechanical processing | Achieving desired particle size |
| 7. Quality Control | Analysis and testing | ICP-OES, XRD, BET surface area |
7.1. Major Producing Countries
| Country | Description |
|---|---|
| China | Major producer |
| USA | Rare earth production |
| Australia | Rare earth mining |
| India | Rare earth mining |
8. ALTERNATIVE / SUBSTITUTE PRODUCTS
| Alternative | Description | When to Use |
|---|---|---|
| Yttrium Nitrate | For solution chemistry | When liquid form of yttrium is required |
| Yttrium Chloride | For solution chemistry | When liquid form of yttrium is required |
| Gadolinium Oxide (Gd₂O₃) | Magnetic applications | When different magnetic properties are required |
| Lanthanum Oxide (La₂O₃) | Optical glasses | When different optical properties are required |
| Cerium Oxide (CeO₂) | Catalyst and YSZ alternative | When different application requirements exist |
9. SAFETY AND TOXICOLOGY
| Parameter | Value |
|---|---|
| Acute Oral Toxicity (LD50, Rat) | > 2,000 mg/kg (low toxicity) |
| Dermal Toxicity | Low |
| Skin Irritation | Mild irritant |
| Eye Irritation | Mild to moderate irritant |
| Inhalation | Fine dust inhalation may cause respiratory tract irritation. |
| Carcinogenicity | Not classified as carcinogenic. |
| Mutagenicity | Not mutagenic. |
| Chronic Effects | Rare earth oxides have low bioavailability; prolonged exposure may cause lung effects. |
| Environmental Hazards | Low to moderate aquatic toxicity. |
9.1. GHS Classification
| Hazard Class | Category | H-Statement |
|---|---|---|
| Skin Irritation | Category 2 | H315: Causes skin irritation. |
| Eye Irritation | Category 2A | H319: Causes serious eye irritation. |
| Specific Target Organ Toxicity | Category 3 | H335: May cause respiratory irritation. |
Signal Word: WARNING
Hazard Pictograms: GHS07 (Exclamation Mark)
10. PRECAUTIONARY STATEMENTS (P-CODES)
| Code | Statement |
|---|---|
| P261 | Avoid breathing dust. |
| P264 | Wash thoroughly after handling. |
| P271 | Use only in well-ventilated areas. |
| P280 | Wear protective gloves/eye protection/face protection. |
| P302+P352 | IF ON SKIN: Wash with plenty of soap and water. |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing. |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. |
| P337+P313 | If eye irritation persists: Get medical advice/attention. |
| P501 | Dispose of contents/container in accordance with local regulations. |
11. FIRST AID MEASURES
| Exposure Route | Action to Take |
|---|---|
| Inhalation | Remove to fresh air. If symptoms persist, seek medical attention. |
| Skin Contact | Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention. |
| Eye Contact | Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention. |
| Ingestion | Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention. |
12. STORAGE AND SHELF LIFE
| Parameter | Condition |
|---|---|
| Storage Conditions | Store in a cool, dry, and well-ventilated area. Ensure a moisture-free environment. |
| Container Requirements | Moisture-proof, tightly closed containers. |
| Temperature | Room temperature (15-25°C). |
| Shelf Life | 24-36 months under appropriate conditions. |
| Stability Note | Stable under normal conditions; should be stored in closed packaging to prevent moisture and CO₂ absorption. |
13. PACKAGING OPTIONS
| Packaging Type | Quantity | Material |
|---|---|---|
| Laboratory Packaging | 5 g, 10 g, 25 g, 50 g, 100 g | HDPE bottle, aluminum foil bag |
| Industrial Packaging | 25 kg | PE-lined kraft bag, moisture-proof |
| Drum | 25 kg, 50 kg | HDPE drum, moisture-proof |
| IBC (Intermediate Bulk Container) | 500 kg, 1000 kg | Moisture-proof, palletized |
14. TRANSPORT INFORMATION
| Parameter | Information |
|---|---|
| UN Number | Not classified (specific regulations apply for rare earth oxides) |
| Hazard Class | - |
| Packing Group | - |
| ADR/RID | Not regulated (special precautions may be required for powder form) |
| IMDG | Not regulated |
| IATA | Not regulated |
| HS Code | 2846.90.00.00.19 (Other rare earth compounds) |
15. REGULATORY STATUS
| Region / Authority | Status |
|---|---|
| European Union (REACH) | Registered |
| Turkey (KKDIK) | Compliance required |
| TSCA (USA) | Registered |
| EINECS | 215-233-5 |
| China (REACH equivalent) | Registered; major production and export country |
16. OTHER NAMES AND SYNONYMS
| Name | Description |
|---|---|
| Yttria | Common short name |
| Yttrium Trioxide | Chemical name |
| Yttrium Sesquioxide | Chemical name |
| Yttrium(III) Oxide | Chemical name |
| Y₂O₃ | Chemical abbreviation |
| Rare Earth Oxide | Category name |
| Yttrium Dioxide | Occasionally appears in commercial documents (incorrect) |
17. QUICK REFERENCE TABLE
| Property | Value |
|---|---|
| CAS Number | 1314-36-9 |
| EC Number | 215-233-5 |
| Chemical Formula | Y₂O₃ |
| Molecular Weight | 225.81 g/mol |
| Appearance | White, fine powder |
| Density | ~5.01 g/cm³ |
| Melting Point | ~2,425 °C |
| Crystal Structure | Cubic (bixbyite) |
| HS Code | 2846.90.00.00.19 |
| GHS Signal Word | WARNING |
18. CRITICAL WARNINGS AND BEST PRACTICES
CRITICAL WARNINGS:
High Value: Yttrium is a critical and valuable rare earth element for phosphor, optical, and ceramic applications. Losses should be minimized and recycling options explored.
High Purity Requirement: Phosphor, optical, and electronic applications require high purity (>99.9%). Purity level directly affects application performance.
Incompatibility: Reacts with strong acids. Acid use must be controlled.
Powder Hazard: Fine powder form may cause respiratory tract irritation. Dust control measures must be taken.
Recycling: Yttrium-containing waste (especially phosphors and YIG materials) can be recycled; this should be considered in waste management planning.
BEST PRACTICE RECOMMENDATIONS:
Storage:
Store in a cool, dry, and well-ventilated area.
Use moisture-proof, tightly closed containers.
Keep away from acids and oxidizing agents.
Store at room temperature (15-25°C).
Handling:
Use in well-ventilated areas with local exhaust ventilation.
Use a dust mask (N95 or better), protective goggles, and gloves.
Avoid dust formation and inhalation.
Wash hands thoroughly after handling.
For dissolution in acids, add oxide to acid slowly with cooling and stirring.
Waste Management:
Dispose of in accordance with local regulations.
Do not discharge into water sources.
For large quantities, rare earth recycling and recovery should be considered (economically viable).
LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Yttrium oxide is a critical rare earth material for phosphor, optical, and ceramic applications; careful handling, storage, and recycling planning are required due to high purity requirements and value.