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Yttrium Oxide, Yttria Yttrium Sesquioxide, Yttrium Trioxide, 1314-36-9

Yttrium Oxide, Yttria Yttrium Sesquioxide, Yttrium Trioxide, 1314-36-9

YTRIUM OXIDE (Y₂O₃)
YTRIUM OXIDE / YTTRIA / YTRIUM SESQUIOXIDE / YTRIUM TRIOXIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Yttrium Oxide
Chemical Name Yttrium(III) Oxide, Yttrium Trioxide, Yttrium Sesquioxide
Other Names Yttria, Y₂O₃
CAS Number 1314-36-9
EC Number (EINECS) 215-233-5
Chemical Formula Y₂O₃
Molecular Weight 225.81 g/mol
Appearance White, fine powder
Odor Odorless
Physical State (20°C) Solid (powder)

2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Yttrium oxide is the oxide compound of the rare earth element yttrium. Yttrium ions (Y³⁺) and oxide ions (O²⁻) are present in a 2:3 ratio. It has a cubic crystal structure (bixbyite type). It is known for its high melting point and thermal stability. It is insoluble in water but slowly soluble in strong acids. It is stable at high temperatures and in oxidative environments.

Structural Features:

                    YTRIUM OXIDE [Y₂O₃]
                          |
                Y³⁺ - O²⁻ Ionic Bonds
                          |
        +----------------+----------------+
        |                |                |
    Cubic (Bixbyite)   White Powder     High Thermal
    Crystal Structure                  Stability

2.2. Structural Properties

Parameter Value
Crystal Structure Cubic (bixbyite type)
Chemical Formula Y₂O₃
Molecular Weight 225.81 g/mol
Density ~5.01 g/cm³
Appearance White, fine powder
Melting Point ~2,425 °C
Boiling Point ~4,300 °C
Refractive Index ~1.93
Dielectric Constant ~12-14
Band Gap ~5.6 eV

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance White, fine powder Color shade depends on purity
Odor Odorless -
Chemical Formula Y₂O₃ -
Molecular Weight 225.81 g/mol -
Density ~5.01 g/cm³ -
Melting Point ~2,425 °C -
Solubility in Water (25°C) Insoluble -
Solubility in Acids Slowly soluble Soluble in strong acids
Solubility in Alcohol Insoluble -
Crystal Structure Cubic (bixbyite) -
Thermal Stability High Stable up to 2400°C
Hygroscopicity Low -
Ionic Conductivity High (in YSZ) -

4. PURITY GRADES

Parameter Technical Grade High Purity Grade Analytical Grade Ultra-High Purity Grade
Purity (Y₂O₃) ≥ 99.0% ≥ 99.9% ≥ 99.99% ≥ 99.999%
Other Rare Earths ≤ 1.0% ≤ 0.1% ≤ 0.01% ≤ 0.001%
Iron (Fe) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Calcium (Ca) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Silicon (Si) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Heavy Metals (Pb) ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm ≤ 5 ppm
Chloride (Cl⁻) ≤ 0.1% ≤ 0.05% ≤ 0.02% ≤ 0.01%
Loss on Drying ≤ 1.0% ≤ 0.5% ≤ 0.3% ≤ 0.1%
Particle Size (D50) 5-20 µm 1-10 µm 0.5-5 µm 0.2-2 µm
BET Surface Area 5-15 m²/g 10-20 m²/g 15-30 m²/g 20-50 m²/g

5. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Stable at high temperatures and in oxidative environments.
Conditions to Avoid Strong acids, high humidity (prolonged), reducing environments.
Incompatible Materials Strong acids, strong reducing agents, halogens.
Hazardous Decomposition Products Upon oxidation at high temperatures: yttrium oxide (Y₂O₃) is stable; with acids: yttrium salts.
Hazardous Polymerization Will not occur.
Hygroscopicity Low.

5.1. Chemical Reactions

  • Reaction with Acids:
    Y₂O₃ + 6HCl → 2YCl₃ + 3H₂O
    Y₂O₃ + 6HNO₃ → 2Y(NO₃)₃ + 3H₂O
    Y₂O₃ + 3H₂SO₄ → Y₂(SO₄)₃ + 3H₂O

  • Reaction with Bases:
    Y₂O₃ + 2NaOH → 2NaYO₂ + H₂O (at high temperature)

  • Carbonation (Over Time):
    Y₂O₃ + 3CO₂ + 3H₂O → Y₂(CO₃)₃·3H₂O (slow)

6. APPLICATION AREAS
6.1. Phosphors and Lighting

Application Function Details
Red Phosphor (Eu³⁺ doped) Light conversion LED and display technologies
Fluorescent Materials Light emitter Lighting systems
Cathode Ray Tubes (CRT) Phosphor component Legacy display technologies

6.2. Optical and Laser Applications

Application Function Details
Transparent Ceramics Optical material High temperature optics
IR Windows Infrared transparency Defense and industrial applications
Laser Optics Optical component High-power laser systems
Nd:YAG Laser Dopant Optical dopant Laser crystals

6.3. Electronics and Magnetic Materials

Application Function Details
Yttrium Iron Garnet (YIG) Microwave filters Magneto-optic devices
Dielectric Materials Electronic component Capacitors and resonators
Magneto-Optic Devices Optical isolators Fiber optic communication

6.4. Ceramics and Coatings

Application Function Details
Zirconia Stabilizer (YSZ) Phase stabilization Fuel cells, thermal barrier coatings
Thermal Barrier Coatings Thermal insulation Gas turbines, engines
Solid Oxide Fuel Cells (SOFC) Oxygen ion conductivity Energy generation

6.5. Metallurgy

Application Function Details
Steel Production Oxygen/sulfur remover Deoxidation and desulfurization
Titanium Alloys Polishing additive Surface quality improvement
Rare Earth Alloys Alloying element Special metallurgical applications

6.6. Defense Industry

Application Function Details
Laser Systems Optical component High-energy lasers
High Temperature Optical Components Thermal stability Infrared and visible optics
Protective Coatings Thermal and mechanical resistance High temperature applications

6.7. Sectoral Suitability Table

Sector Suitability Explanation
Phosphor/Lighting Suitable Eu³⁺ doped red phosphor, LED, displays
Optics and Laser Suitable Transparent ceramics, IR windows, laser optics
Electronics Suitable YIG, dielectrics, magneto-optic devices
Ceramics Suitable YSZ, thermal barrier coatings, SOFC
Metallurgy Suitable Steel production, titanium alloys
Defense Industry Suitable Laser systems, optical components
Food Not Suitable Rare earth oxide, not suitable
Cosmetics Not Suitable Rare earth oxide, not suitable

7. PRODUCTION PROCESS

Stage Process Description
1. Raw Material Preparation Rare earth concentrates Extraction from monazite or bastnäsite ores
2. Acid Leaching Chemical extraction Dissolution of yttrium into solution
3. Purification Solution purification Removal of trace metals
4. Precipitation Chemical precipitation Precipitation of yttrium salts
5. Calcination Thermal treatment Conversion to oxide form (800-1000°C)
6. Milling Mechanical processing Achieving desired particle size
7. Quality Control Analysis and testing ICP-OES, XRD, BET surface area

7.1. Major Producing Countries

Country Description
China Major producer
USA Rare earth production
Australia Rare earth mining
India Rare earth mining

8. ALTERNATIVE / SUBSTITUTE PRODUCTS

Alternative Description When to Use
Yttrium Nitrate For solution chemistry When liquid form of yttrium is required
Yttrium Chloride For solution chemistry When liquid form of yttrium is required
Gadolinium Oxide (Gd₂O₃) Magnetic applications When different magnetic properties are required
Lanthanum Oxide (La₂O₃) Optical glasses When different optical properties are required
Cerium Oxide (CeO₂) Catalyst and YSZ alternative When different application requirements exist

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 2,000 mg/kg (low toxicity)
Dermal Toxicity Low
Skin Irritation Mild irritant
Eye Irritation Mild to moderate irritant
Inhalation Fine dust inhalation may cause respiratory tract irritation.
Carcinogenicity Not classified as carcinogenic.
Mutagenicity Not mutagenic.
Chronic Effects Rare earth oxides have low bioavailability; prolonged exposure may cause lung effects.
Environmental Hazards Low to moderate aquatic toxicity.

9.1. GHS Classification

Hazard Class Category H-Statement
Skin Irritation Category 2 H315: Causes skin irritation.
Eye Irritation Category 2A H319: Causes serious eye irritation.
Specific Target Organ Toxicity Category 3 H335: May cause respiratory irritation.

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

10. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust.
P264 Wash thoroughly after handling.
P271 Use only in well-ventilated areas.
P280 Wear protective gloves/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
P337+P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local regulations.

11. FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air. If symptoms persist, seek medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention.
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention.
Ingestion Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention.

12. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, and well-ventilated area. Ensure a moisture-free environment.
Container Requirements Moisture-proof, tightly closed containers.
Temperature Room temperature (15-25°C).
Shelf Life 24-36 months under appropriate conditions.
Stability Note Stable under normal conditions; should be stored in closed packaging to prevent moisture and CO₂ absorption.

13. PACKAGING OPTIONS

Packaging Type Quantity Material
Laboratory Packaging 5 g, 10 g, 25 g, 50 g, 100 g HDPE bottle, aluminum foil bag
Industrial Packaging 25 kg PE-lined kraft bag, moisture-proof
Drum 25 kg, 50 kg HDPE drum, moisture-proof
IBC (Intermediate Bulk Container) 500 kg, 1000 kg Moisture-proof, palletized

14. TRANSPORT INFORMATION

Parameter Information
UN Number Not classified (specific regulations apply for rare earth oxides)
Hazard Class -
Packing Group -
ADR/RID Not regulated (special precautions may be required for powder form)
IMDG Not regulated
IATA Not regulated
HS Code 2846.90.00.00.19 (Other rare earth compounds)

15. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Registered
Turkey (KKDIK) Compliance required
TSCA (USA) Registered
EINECS 215-233-5
China (REACH equivalent) Registered; major production and export country

16. OTHER NAMES AND SYNONYMS

Name Description
Yttria Common short name
Yttrium Trioxide Chemical name
Yttrium Sesquioxide Chemical name
Yttrium(III) Oxide Chemical name
Y₂O₃ Chemical abbreviation
Rare Earth Oxide Category name
Yttrium Dioxide Occasionally appears in commercial documents (incorrect)

17. QUICK REFERENCE TABLE

Property Value
CAS Number 1314-36-9
EC Number 215-233-5
Chemical Formula Y₂O₃
Molecular Weight 225.81 g/mol
Appearance White, fine powder
Density ~5.01 g/cm³
Melting Point ~2,425 °C
Crystal Structure Cubic (bixbyite)
HS Code 2846.90.00.00.19
GHS Signal Word WARNING

18. CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • High Value: Yttrium is a critical and valuable rare earth element for phosphor, optical, and ceramic applications. Losses should be minimized and recycling options explored.

  • High Purity Requirement: Phosphor, optical, and electronic applications require high purity (>99.9%). Purity level directly affects application performance.

  • Incompatibility: Reacts with strong acids. Acid use must be controlled.

  • Powder Hazard: Fine powder form may cause respiratory tract irritation. Dust control measures must be taken.

  • Recycling: Yttrium-containing waste (especially phosphors and YIG materials) can be recycled; this should be considered in waste management planning.

BEST PRACTICE RECOMMENDATIONS:

  • Storage:

    • Store in a cool, dry, and well-ventilated area.

    • Use moisture-proof, tightly closed containers.

    • Keep away from acids and oxidizing agents.

    • Store at room temperature (15-25°C).

  • Handling:

    • Use in well-ventilated areas with local exhaust ventilation.

    • Use a dust mask (N95 or better), protective goggles, and gloves.

    • Avoid dust formation and inhalation.

    • Wash hands thoroughly after handling.

    • For dissolution in acids, add oxide to acid slowly with cooling and stirring.

  • Waste Management:

    • Dispose of in accordance with local regulations.

    • Do not discharge into water sources.

    • For large quantities, rare earth recycling and recovery should be considered (economically viable).

LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Yttrium oxide is a critical rare earth material for phosphor, optical, and ceramic applications; careful handling, storage, and recycling planning are required due to high purity requirements and value.

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