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Vanadium Pentoxide, Vanadic Anhydride, Divanadium Pentaoxide, 1314‑62‑1

Vanadium Pentoxide, Vanadic Anhydride, Divanadium Pentaoxide, 1314‑62‑1

VANADIUM PENTOXIDE (V₂O₅)
VANADIUM PENTOXIDE / VANADIC ANHYDRIDE / DIVANADIUM PENTAOXIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Vanadium Pentoxide
Chemical Name Vanadium(V) Oxide, Vanadic Anhydride
Other Names Divanadium Pentaoxide, V₂O₅, Vanadium Oxide
CAS Number 1314-62-1
EC Number (EINECS) 215-239-8
Chemical Formula V₂O₅
Molecular Weight 181.88 g/mol
Appearance Orange-yellow crystalline powder
Odor Odorless
Physical State (20°C) Solid (powder)

2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Vanadium pentoxide is an inorganic compound of vanadium and oxygen. Vanadium ions (V⁵⁺) and oxide ions (O²⁻) are present in a 2:5 ratio. It has an orthorhombic crystal structure. It decomposes at high temperatures (above 800°C). It is sparingly soluble in water; soluble in acids and alkalis. It is an important catalyst and metallurgical material.

Structural Features:

                    VANADIUM PENTOXIDE [V₂O₅]
                          |
                V⁵⁺ - O²⁻ Ionic/Covalent Bonds
                          |
        +----------------+----------------+
        |                |                |
    Orthorhombic       Orange-Yellow    High
    Crystal Structure  Powder Form     Catalytic Activity

2.2. Structural Properties

Parameter Value
Crystal Structure Orthorhombic
Chemical Formula V₂O₅
Molecular Weight 181.88 g/mol
Density ~3.36 g/cm³
Appearance Orange-yellow crystalline powder
Melting Point ~690 °C
Decomposition Temperature Above ~800 °C
Band Gap ~2.0–2.2 eV

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance Orange-yellow crystalline powder Color shade depends on particle size
Odor Odorless -
Chemical Formula V₂O₅ -
Molecular Weight 181.88 g/mol -
Density ~3.36 g/cm³ -
Melting Point ~690 °C -
Solubility in Water (25°C) Sparingly soluble Approximately 0.8 g/L
Solubility in Acids Soluble Forms vanadium salts
Solubility in Alkalis Soluble Forms vanadates
Crystal Structure Orthorhombic -
Hygroscopicity Low -

4. PURITY GRADES

Parameter Technical Grade High Purity Grade Catalyst Grade
Purity (V₂O₅) ≥ 99.0% ≥ 99.5% ≥ 99.9%
Vanadium (V) Content ≥ 56.0% ≥ 56.2% ≥ 56.5%
Iron (Fe) ≤ 0.3% ≤ 0.1% ≤ 0.05%
Silicon (Si) ≤ 0.3% ≤ 0.1% ≤ 0.05%
Phosphorus (P) ≤ 0.3% ≤ 0.1% ≤ 0.05%
Sulfate (SO₄²⁻) ≤ 0.5% ≤ 0.3% ≤ 0.1%
Chloride (Cl⁻) ≤ 0.1% ≤ 0.05% ≤ 0.02%
Heavy Metals (Pb) ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Loss on Drying ≤ 0.5% ≤ 0.3% ≤ 0.2%
Particle Size (D50) 10-50 µm 5-20 µm 1-10 µm
BET Surface Area 5-10 m²/g 10-20 m²/g 15-30 m²/g

5. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Stable under ambient conditions; decomposes at high temperatures (above 800°C).
Conditions to Avoid High temperatures, strong reducing agents, moisture, acid and alkaline solutions.
Incompatible Materials Strong reducing agents (H₂, C, CO), strong acids, alkaline metals.
Hazardous Decomposition Products Upon oxidation at high temperatures: vanadium oxide (V₂O₅) is stable; upon reduction: vanadium sub-oxides (VO₂, V₂O₃).
Hazardous Polymerization Will not occur.
Hygroscopicity Low.

5.1. Chemical Reactions

  • Reaction with Acids:
    V₂O₅ + 6HCl → 2VOCl₂ + Cl₂↑ + 3H₂O
    V₂O₅ + 2HNO₃ → 2V₂O₅·H₂O (Vanadic acid)

  • Reaction with Alkalis (Vanadate Formation):
    V₂O₅ + 2NaOH → 2NaVO₃ + H₂O
    V₂O₅ + 6NaOH → 2Na₃VO₄ + 3H₂O

  • Reduction (at High Temperature):
    V₂O₅ + 2H₂ → V₂O₃ + 2H₂O
    V₂O₅ + 5C → 2V + 5CO

6. APPLICATION AREAS
6.1. Catalyst Applications

Application Function Details
Sulfuric Acid Production Catalyst Contact process (SO₂ → SO₃ oxidation)
Oxidation Catalysts Catalytic activity Petrochemical and organic synthesis reactions
NOx Reduction Environmental catalyst Emission control systems

6.2. Metallurgy

Application Function Details
Steel Alloys Strength enhancer Microalloyed steels
Titanium Alloys Corrosion resistance Aerospace and defense applications
Vanadium Metal Production Precursor Primary source of vanadium metal

6.3. Ceramic and Glass Industry

Application Function Details
Ceramic Pigments Colorant Orange-yellow pigments
Glass Coloring Optical coloring Specialty glasses
Optical Coatings Thin film Optical applications

6.4. Battery Applications

Application Function Details
Vanadium Redox Flow Batteries (VRFB) Electrolyte component Energy storage systems
Battery Electrolytes Redox active material Large-scale energy storage

6.5. Chemical Production

Application Function Details
Vanadium Salts Precursor Ammonium vanadate, sodium vanadate
Vanadium Compounds Intermediate Organic and inorganic synthesis

6.6. Sectoral Suitability Table

Sector Suitability Explanation
Catalyst Suitable Sulfuric acid production, oxidation catalysts
Metallurgy Suitable Steel/titanium alloys
Ceramics and Glass Suitable Pigment, optical coloring
Batteries Suitable Vanadium redox flow batteries
Chemical Production Suitable Precursor for vanadium salts and compounds
Food Not Suitable Toxic heavy metal oxide
Cosmetics Not Suitable Toxic heavy metal oxide

7. PRODUCTION PROCESS

Stage Process Description
1. Raw Material Preparation Vanadium ore Extraction from vanadinite or titano-magnetite ores
2. Roasting Thermal oxidation Roasting of ore with air
3. Leaching Chemical extraction Dissolution of vanadium into solution
4. Purification Chemical treatments Removal of trace metals
5. Precipitation Ammonium metavanadate Precipitation of ammonium metavanadate
6. Calcination Thermal treatment Conversion of ammonium metavanadate to V₂O₅ (400-500°C)
7. Quality Control Analysis and testing ICP-OES, XRD, BET surface area

7.1. Major Producing Countries

Country Description
China Major producer
South Africa Vanadium mining
Russia Vanadium mining and production
USA Vanadium mining and production

8. ALTERNATIVE / SUBSTITUTE PRODUCTS

Alternative Description When to Use
Ammonium Metavanadate Vanadium precursor When aqueous solution form is required
Vanadium Trioxide (V₂O₃) Lower oxide form When reduced form is required
Molybdenum Oxide (MoO₃) Catalyst applications When different catalytic properties are required
Tungsten Oxide (WO₃) Catalyst applications When different catalytic properties are required
Cerium Oxide (CeO₂) Catalyst applications When different catalytic properties are required

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) ~10 mg/kg (very toxic)
Dermal Toxicity Toxic
Skin Irritation Irritant
Eye Irritation Serious irritant
Inhalation Dust inhalation may cause respiratory tract irritation, lung damage, and systemic toxicity.
Carcinogenicity Category 1B (Carcinogenic)
Mutagenicity May be mutagenic
Chronic Effects Lung diseases, respiratory system damage, blood changes
Environmental Hazards Very toxic to aquatic life; high bioaccumulation potential

9.1. GHS Classification

Hazard Class Category H-Statement
Acute Toxicity Category 2 (Oral) H300: Fatal if swallowed
Acute Toxicity Category 2 (Inhalation) H330: Fatal if inhaled
Carcinogenicity Category 1B H350: May cause cancer
Specific Target Organ Toxicity Category 1 H372: Causes damage to organs through prolonged or repeated exposure
Hazardous to the Aquatic Environment Category 1 H410: Very toxic to aquatic life with long lasting effects
Skin Sensitizer Category 1 H317: May cause allergic skin reaction
Respiratory Sensitizer Category 1 H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled

Signal Word: DANGER

Hazard Pictograms: GHS06 (Toxic), GHS08 (Health Hazard), GHS09 (Environment)

10. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P260 Do not breathe dust
P264 Wash thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only in well-ventilated areas
P280 Wear protective gloves/eye protection/face protection/protective clothing
P284 Wear respiratory protection
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P308+P313 IF exposed or concerned: Get medical advice/attention
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor
P391 Collect spillage
P405 Store locked up
P501 Dispose of contents/container in accordance with local regulations

11. FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air. If symptoms persist, seek medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention.
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention.
Ingestion Rinse mouth. Do not induce vomiting. Drink plenty of water. If large amount is swallowed, seek medical attention.

12. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, and well-ventilated area. Ensure a moisture-free environment.
Container Requirements Moisture-proof, tightly closed containers.
Temperature Room temperature (15-25°C).
Shelf Life 12-24 months under appropriate conditions.
Stability Note Stable under normal conditions; keep away from reducing agents, moisture, and acids.

13. PACKAGING OPTIONS

Packaging Type Quantity Material
Laboratory Packaging 100 g, 500 g, 1 kg HDPE bottle, aluminum foil bag
Industrial Packaging 25 kg PE-lined kraft bag, moisture-proof
Drum 50 kg HDPE drum, moisture-proof
IBC (Intermediate Bulk Container) 500 kg, 1000 kg Moisture-proof, palletized

14. TRANSPORT INFORMATION

Parameter Information
UN Number 2861 (Vanadium pentoxide)
Hazard Class 6.1 (Toxic substances)
Packing Group II
ADR/RID Regulated
IMDG Regulated
IATA Regulated
HS Code 2825.30.00.00.00 (Vanadium oxides and hydroxides)

15. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Registered; carcinogenic, toxic
Turkey (KKDIK) Compliance required
TSCA (USA) Registered
CLP/GHS Toxic Category 2, Carcinogen Category 1B
EINECS 215-239-8
China Registered; major production and export country

16. OTHER NAMES AND SYNONYMS

Name Description
Vanadium Pentoxide Chemical name
Vanadic Anhydride Chemical name
Divanadium Pentaoxide Chemical name
Vanadium(V) Oxide Chemical name
V₂O₅ Chemical abbreviation
Vanadic Oxide Trade name
Vanadium Oxide Short name

17. QUICK REFERENCE TABLE

Property Value
CAS Number 1314-62-1
EC Number 215-239-8
Chemical Formula V₂O₅
Molecular Weight 181.88 g/mol
Appearance Orange-yellow crystalline powder
Density ~3.36 g/cm³
Melting Point ~690 °C
Crystal Structure Orthorhombic
UN Number 2861
HS Code 2825.30.00.00.00
GHS Signal Word DANGER

18. CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • Highly Toxic: Vanadium pentoxide is fatal if swallowed or inhaled (H300, H330). Exposure must be strictly minimized.

  • Carcinogenic: Classified as Carcinogen Category 1B (H350) under GHS. Prolonged exposure carries cancer risk.

  • Environmental Hazard: Very toxic to aquatic life (H410). Release into water sources must be strictly prevented.

  • Incompatibility: Reacts with strong reducing agents (H₂, C, CO) generating heat; may create fire and explosion risk.

  • Powder Hazard: Fine powder form may cause respiratory tract irritation and systemic toxicity. Strict dust control measures must be taken.

  • Recycling: Vanadium is a valuable metal; recovery from spent catalysts and vanadium redox batteries is possible.

BEST PRACTICE RECOMMENDATIONS:

  • Storage:

    • Store in a cool, dry, and well-ventilated area.

    • Use moisture-proof, tightly closed containers.

    • Keep away from reducing agents, acids, and oxidizing agents.

    • Store at room temperature (15-25°C).

    • Store locked up.

  • Handling:

    • Use in well-ventilated areas with local exhaust ventilation or under a fume hood.

    • Use a dust mask (P3 filter), protective goggles, chemically resistant gloves, and protective clothing.

    • Avoid dust formation and inhalation.

    • Wash hands thoroughly after handling.

    • Remove contaminated clothing and wash before reuse.

    • Ensure controlled conditions when working with acids and alkalis.

  • Waste Management:

    • Dispose of in accordance with local regulations at licensed disposal facilities.

    • Do not discharge into water sources.

    • For large quantities, vanadium recycling and recovery should be considered (valuable metal).

LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Vanadium pentoxide is a highly toxic and carcinogenic substance; strict safety measures must be taken during handling, transport, and disposal.

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