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Send EmailVanadium Pentoxide, Vanadic Anhydride, Divanadium Pentaoxide, 1314‑62‑1
VANADIUM PENTOXIDE (V₂O₅)
VANADIUM PENTOXIDE / VANADIC ANHYDRIDE / DIVANADIUM PENTAOXIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY
| Parameter | Information |
|---|---|
| Product Name | Vanadium Pentoxide |
| Chemical Name | Vanadium(V) Oxide, Vanadic Anhydride |
| Other Names | Divanadium Pentaoxide, V₂O₅, Vanadium Oxide |
| CAS Number | 1314-62-1 |
| EC Number (EINECS) | 215-239-8 |
| Chemical Formula | V₂O₅ |
| Molecular Weight | 181.88 g/mol |
| Appearance | Orange-yellow crystalline powder |
| Odor | Odorless |
| Physical State (20°C) | Solid (powder) |
2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Vanadium pentoxide is an inorganic compound of vanadium and oxygen. Vanadium ions (V⁵⁺) and oxide ions (O²⁻) are present in a 2:5 ratio. It has an orthorhombic crystal structure. It decomposes at high temperatures (above 800°C). It is sparingly soluble in water; soluble in acids and alkalis. It is an important catalyst and metallurgical material.
Structural Features:
VANADIUM PENTOXIDE [V₂O₅]
|
V⁵⁺ - O²⁻ Ionic/Covalent Bonds
|
+----------------+----------------+
| | |
Orthorhombic Orange-Yellow High
Crystal Structure Powder Form Catalytic Activity
2.2. Structural Properties
| Parameter | Value |
|---|---|
| Crystal Structure | Orthorhombic |
| Chemical Formula | V₂O₅ |
| Molecular Weight | 181.88 g/mol |
| Density | ~3.36 g/cm³ |
| Appearance | Orange-yellow crystalline powder |
| Melting Point | ~690 °C |
| Decomposition Temperature | Above ~800 °C |
| Band Gap | ~2.0–2.2 eV |
3. PHYSICAL AND CHEMICAL PROPERTIES
| Property | Value | Description |
|---|---|---|
| Appearance | Orange-yellow crystalline powder | Color shade depends on particle size |
| Odor | Odorless | - |
| Chemical Formula | V₂O₅ | - |
| Molecular Weight | 181.88 g/mol | - |
| Density | ~3.36 g/cm³ | - |
| Melting Point | ~690 °C | - |
| Solubility in Water (25°C) | Sparingly soluble | Approximately 0.8 g/L |
| Solubility in Acids | Soluble | Forms vanadium salts |
| Solubility in Alkalis | Soluble | Forms vanadates |
| Crystal Structure | Orthorhombic | - |
| Hygroscopicity | Low | - |
4. PURITY GRADES
| Parameter | Technical Grade | High Purity Grade | Catalyst Grade |
|---|---|---|---|
| Purity (V₂O₅) | ≥ 99.0% | ≥ 99.5% | ≥ 99.9% |
| Vanadium (V) Content | ≥ 56.0% | ≥ 56.2% | ≥ 56.5% |
| Iron (Fe) | ≤ 0.3% | ≤ 0.1% | ≤ 0.05% |
| Silicon (Si) | ≤ 0.3% | ≤ 0.1% | ≤ 0.05% |
| Phosphorus (P) | ≤ 0.3% | ≤ 0.1% | ≤ 0.05% |
| Sulfate (SO₄²⁻) | ≤ 0.5% | ≤ 0.3% | ≤ 0.1% |
| Chloride (Cl⁻) | ≤ 0.1% | ≤ 0.05% | ≤ 0.02% |
| Heavy Metals (Pb) | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Loss on Drying | ≤ 0.5% | ≤ 0.3% | ≤ 0.2% |
| Particle Size (D50) | 10-50 µm | 5-20 µm | 1-10 µm |
| BET Surface Area | 5-10 m²/g | 10-20 m²/g | 15-30 m²/g |
5. STABILITY AND REACTIVITY
| Parameter | Information |
|---|---|
| Chemical Stability | Stable under ambient conditions; decomposes at high temperatures (above 800°C). |
| Conditions to Avoid | High temperatures, strong reducing agents, moisture, acid and alkaline solutions. |
| Incompatible Materials | Strong reducing agents (H₂, C, CO), strong acids, alkaline metals. |
| Hazardous Decomposition Products | Upon oxidation at high temperatures: vanadium oxide (V₂O₅) is stable; upon reduction: vanadium sub-oxides (VO₂, V₂O₃). |
| Hazardous Polymerization | Will not occur. |
| Hygroscopicity | Low. |
5.1. Chemical Reactions
Reaction with Acids:
V₂O₅ + 6HCl → 2VOCl₂ + Cl₂↑ + 3H₂O
V₂O₅ + 2HNO₃ → 2V₂O₅·H₂O (Vanadic acid)
Reaction with Alkalis (Vanadate Formation):
V₂O₅ + 2NaOH → 2NaVO₃ + H₂O
V₂O₅ + 6NaOH → 2Na₃VO₄ + 3H₂O
Reduction (at High Temperature):
V₂O₅ + 2H₂ → V₂O₃ + 2H₂O
V₂O₅ + 5C → 2V + 5CO
6. APPLICATION AREAS
6.1. Catalyst Applications
| Application | Function | Details |
|---|---|---|
| Sulfuric Acid Production | Catalyst | Contact process (SO₂ → SO₃ oxidation) |
| Oxidation Catalysts | Catalytic activity | Petrochemical and organic synthesis reactions |
| NOx Reduction | Environmental catalyst | Emission control systems |
6.2. Metallurgy
| Application | Function | Details |
|---|---|---|
| Steel Alloys | Strength enhancer | Microalloyed steels |
| Titanium Alloys | Corrosion resistance | Aerospace and defense applications |
| Vanadium Metal Production | Precursor | Primary source of vanadium metal |
6.3. Ceramic and Glass Industry
| Application | Function | Details |
|---|---|---|
| Ceramic Pigments | Colorant | Orange-yellow pigments |
| Glass Coloring | Optical coloring | Specialty glasses |
| Optical Coatings | Thin film | Optical applications |
6.4. Battery Applications
| Application | Function | Details |
|---|---|---|
| Vanadium Redox Flow Batteries (VRFB) | Electrolyte component | Energy storage systems |
| Battery Electrolytes | Redox active material | Large-scale energy storage |
6.5. Chemical Production
| Application | Function | Details |
|---|---|---|
| Vanadium Salts | Precursor | Ammonium vanadate, sodium vanadate |
| Vanadium Compounds | Intermediate | Organic and inorganic synthesis |
6.6. Sectoral Suitability Table
| Sector | Suitability | Explanation |
|---|---|---|
| Catalyst | Suitable | Sulfuric acid production, oxidation catalysts |
| Metallurgy | Suitable | Steel/titanium alloys |
| Ceramics and Glass | Suitable | Pigment, optical coloring |
| Batteries | Suitable | Vanadium redox flow batteries |
| Chemical Production | Suitable | Precursor for vanadium salts and compounds |
| Food | Not Suitable | Toxic heavy metal oxide |
| Cosmetics | Not Suitable | Toxic heavy metal oxide |
7. PRODUCTION PROCESS
| Stage | Process | Description |
|---|---|---|
| 1. Raw Material Preparation | Vanadium ore | Extraction from vanadinite or titano-magnetite ores |
| 2. Roasting | Thermal oxidation | Roasting of ore with air |
| 3. Leaching | Chemical extraction | Dissolution of vanadium into solution |
| 4. Purification | Chemical treatments | Removal of trace metals |
| 5. Precipitation | Ammonium metavanadate | Precipitation of ammonium metavanadate |
| 6. Calcination | Thermal treatment | Conversion of ammonium metavanadate to V₂O₅ (400-500°C) |
| 7. Quality Control | Analysis and testing | ICP-OES, XRD, BET surface area |
7.1. Major Producing Countries
| Country | Description |
|---|---|
| China | Major producer |
| South Africa | Vanadium mining |
| Russia | Vanadium mining and production |
| USA | Vanadium mining and production |
8. ALTERNATIVE / SUBSTITUTE PRODUCTS
| Alternative | Description | When to Use |
|---|---|---|
| Ammonium Metavanadate | Vanadium precursor | When aqueous solution form is required |
| Vanadium Trioxide (V₂O₃) | Lower oxide form | When reduced form is required |
| Molybdenum Oxide (MoO₃) | Catalyst applications | When different catalytic properties are required |
| Tungsten Oxide (WO₃) | Catalyst applications | When different catalytic properties are required |
| Cerium Oxide (CeO₂) | Catalyst applications | When different catalytic properties are required |
9. SAFETY AND TOXICOLOGY
| Parameter | Value |
|---|---|
| Acute Oral Toxicity (LD50, Rat) | ~10 mg/kg (very toxic) |
| Dermal Toxicity | Toxic |
| Skin Irritation | Irritant |
| Eye Irritation | Serious irritant |
| Inhalation | Dust inhalation may cause respiratory tract irritation, lung damage, and systemic toxicity. |
| Carcinogenicity | Category 1B (Carcinogenic) |
| Mutagenicity | May be mutagenic |
| Chronic Effects | Lung diseases, respiratory system damage, blood changes |
| Environmental Hazards | Very toxic to aquatic life; high bioaccumulation potential |
9.1. GHS Classification
| Hazard Class | Category | H-Statement |
|---|---|---|
| Acute Toxicity | Category 2 (Oral) | H300: Fatal if swallowed |
| Acute Toxicity | Category 2 (Inhalation) | H330: Fatal if inhaled |
| Carcinogenicity | Category 1B | H350: May cause cancer |
| Specific Target Organ Toxicity | Category 1 | H372: Causes damage to organs through prolonged or repeated exposure |
| Hazardous to the Aquatic Environment | Category 1 | H410: Very toxic to aquatic life with long lasting effects |
| Skin Sensitizer | Category 1 | H317: May cause allergic skin reaction |
| Respiratory Sensitizer | Category 1 | H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled |
Signal Word: DANGER
Hazard Pictograms: GHS06 (Toxic), GHS08 (Health Hazard), GHS09 (Environment)
10. PRECAUTIONARY STATEMENTS (P-CODES)
| Code | Statement |
|---|---|
| P201 | Obtain special instructions before use |
| P202 | Do not handle until all safety precautions have been read and understood |
| P260 | Do not breathe dust |
| P264 | Wash thoroughly after handling |
| P270 | Do not eat, drink or smoke when using this product |
| P271 | Use only in well-ventilated areas |
| P280 | Wear protective gloves/eye protection/face protection/protective clothing |
| P284 | Wear respiratory protection |
| P302+P352 | IF ON SKIN: Wash with plenty of soap and water |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing |
| P308+P313 | IF exposed or concerned: Get medical advice/attention |
| P342+P311 | If experiencing respiratory symptoms: Call a POISON CENTER or doctor |
| P391 | Collect spillage |
| P405 | Store locked up |
| P501 | Dispose of contents/container in accordance with local regulations |
11. FIRST AID MEASURES
| Exposure Route | Action to Take |
|---|---|
| Inhalation | Remove to fresh air. If symptoms persist, seek medical attention. |
| Skin Contact | Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention. |
| Eye Contact | Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention. |
| Ingestion | Rinse mouth. Do not induce vomiting. Drink plenty of water. If large amount is swallowed, seek medical attention. |
12. STORAGE AND SHELF LIFE
| Parameter | Condition |
|---|---|
| Storage Conditions | Store in a cool, dry, and well-ventilated area. Ensure a moisture-free environment. |
| Container Requirements | Moisture-proof, tightly closed containers. |
| Temperature | Room temperature (15-25°C). |
| Shelf Life | 12-24 months under appropriate conditions. |
| Stability Note | Stable under normal conditions; keep away from reducing agents, moisture, and acids. |
13. PACKAGING OPTIONS
| Packaging Type | Quantity | Material |
|---|---|---|
| Laboratory Packaging | 100 g, 500 g, 1 kg | HDPE bottle, aluminum foil bag |
| Industrial Packaging | 25 kg | PE-lined kraft bag, moisture-proof |
| Drum | 50 kg | HDPE drum, moisture-proof |
| IBC (Intermediate Bulk Container) | 500 kg, 1000 kg | Moisture-proof, palletized |
14. TRANSPORT INFORMATION
| Parameter | Information |
|---|---|
| UN Number | 2861 (Vanadium pentoxide) |
| Hazard Class | 6.1 (Toxic substances) |
| Packing Group | II |
| ADR/RID | Regulated |
| IMDG | Regulated |
| IATA | Regulated |
| HS Code | 2825.30.00.00.00 (Vanadium oxides and hydroxides) |
15. REGULATORY STATUS
| Region / Authority | Status |
|---|---|
| European Union (REACH) | Registered; carcinogenic, toxic |
| Turkey (KKDIK) | Compliance required |
| TSCA (USA) | Registered |
| CLP/GHS | Toxic Category 2, Carcinogen Category 1B |
| EINECS | 215-239-8 |
| China | Registered; major production and export country |
16. OTHER NAMES AND SYNONYMS
| Name | Description |
|---|---|
| Vanadium Pentoxide | Chemical name |
| Vanadic Anhydride | Chemical name |
| Divanadium Pentaoxide | Chemical name |
| Vanadium(V) Oxide | Chemical name |
| V₂O₅ | Chemical abbreviation |
| Vanadic Oxide | Trade name |
| Vanadium Oxide | Short name |
17. QUICK REFERENCE TABLE
| Property | Value |
|---|---|
| CAS Number | 1314-62-1 |
| EC Number | 215-239-8 |
| Chemical Formula | V₂O₅ |
| Molecular Weight | 181.88 g/mol |
| Appearance | Orange-yellow crystalline powder |
| Density | ~3.36 g/cm³ |
| Melting Point | ~690 °C |
| Crystal Structure | Orthorhombic |
| UN Number | 2861 |
| HS Code | 2825.30.00.00.00 |
| GHS Signal Word | DANGER |
18. CRITICAL WARNINGS AND BEST PRACTICES
CRITICAL WARNINGS:
Highly Toxic: Vanadium pentoxide is fatal if swallowed or inhaled (H300, H330). Exposure must be strictly minimized.
Carcinogenic: Classified as Carcinogen Category 1B (H350) under GHS. Prolonged exposure carries cancer risk.
Environmental Hazard: Very toxic to aquatic life (H410). Release into water sources must be strictly prevented.
Incompatibility: Reacts with strong reducing agents (H₂, C, CO) generating heat; may create fire and explosion risk.
Powder Hazard: Fine powder form may cause respiratory tract irritation and systemic toxicity. Strict dust control measures must be taken.
Recycling: Vanadium is a valuable metal; recovery from spent catalysts and vanadium redox batteries is possible.
BEST PRACTICE RECOMMENDATIONS:
Storage:
Store in a cool, dry, and well-ventilated area.
Use moisture-proof, tightly closed containers.
Keep away from reducing agents, acids, and oxidizing agents.
Store at room temperature (15-25°C).
Store locked up.
Handling:
Use in well-ventilated areas with local exhaust ventilation or under a fume hood.
Use a dust mask (P3 filter), protective goggles, chemically resistant gloves, and protective clothing.
Avoid dust formation and inhalation.
Wash hands thoroughly after handling.
Remove contaminated clothing and wash before reuse.
Ensure controlled conditions when working with acids and alkalis.
Waste Management:
Dispose of in accordance with local regulations at licensed disposal facilities.
Do not discharge into water sources.
For large quantities, vanadium recycling and recovery should be considered (valuable metal).
LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Vanadium pentoxide is a highly toxic and carcinogenic substance; strict safety measures must be taken during handling, transport, and disposal.