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Neodymium Oxide, Neodymium Sesquioxide, Neodymium Trioxide, 1313‑97‑9

Neodymium Oxide, Neodymium Sesquioxide, Neodymium Trioxide, 1313‑97‑9

NEODYMIUM OXIDE (ND₂O₃)
NEODYMIUM OXIDE / NEODYMIA / NEODYMIUM TRIOXIDE / NEODYMIUM(III) OXIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Neodymium Oxide
Chemical Name Neodymium(III) Oxide, Neodymium Trioxide, Neodymium Sesquioxide
Other Names Neodymia, Nd₂O₃
CAS Number 1313-97-9
EC Number (EINECS) 215-214-1
Chemical Formula Nd₂O₃
Molecular Weight 336.48 g/mol
Appearance Purple-violet powder (light purple shades at high purity)
Odor Odorless
Physical State (20°C) Solid (powder)

2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Neodymium oxide is the oxide compound of the rare earth element neodymium. Neodymium ions (Nd³⁺) and oxide ions (O²⁻) are present in a 2:3 ratio. It exists in hexagonal and monoclinic polymorphic forms. It is known for its high melting point and thermal stability. It is insoluble in water but soluble in acids.

Structural Features:

                    NEODYMIUM OXIDE [Nd₂O₃]
                          |
                Nd³⁺ - O²⁻ Ionic Bonds
                          |
        +----------------+----------------+
        |                |                |
    Hexagonal /        Purple-Violet    High Thermal
    Monoclinic         Powder Form      Stability
    Crystal Structure

2.2. Structural Properties

Parameter Value
Crystal Structure Hexagonal and monoclinic polymorphic forms
Chemical Formula Nd₂O₃
Molecular Weight 336.48 g/mol
Density ~7.24 g/cm³
Appearance Purple-violet powder
Melting Point ~1900–1950 °C
Boiling Point ~4300 °C
Magnetic Susceptibility Paramagnetic

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance Purple-violet powder Color shade depends on purity
Odor Odorless -
Chemical Formula Nd₂O₃ -
Molecular Weight 336.48 g/mol -
Density ~7.24 g/cm³ -
Melting Point ~1900–1950 °C -
Solubility in Water (25°C) Insoluble -
Solubility in Acids Soluble Forms neodymium salts
Solubility in Alcohol Insoluble -
Crystal Structure Hexagonal and monoclinic -
Thermal Stability High Stable up to 1950°C
Hygroscopicity Low -
Magnetic Properties Paramagnetic -

4. PURITY GRADES

Parameter Technical Grade High Purity Grade Analytical Grade Ultra-High Purity Grade
Purity (Nd₂O₃) ≥ 99.0% ≥ 99.9% ≥ 99.99% ≥ 99.999%
Other Rare Earths ≤ 1.0% ≤ 0.1% ≤ 0.01% ≤ 0.001%
Iron (Fe) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Calcium (Ca) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Silicon (Si) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Heavy Metals (Pb) ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm ≤ 5 ppm
Chloride (Cl⁻) ≤ 0.1% ≤ 0.05% ≤ 0.02% ≤ 0.01%
Loss on Drying ≤ 1.0% ≤ 0.5% ≤ 0.3% ≤ 0.1%
Particle Size (D50) 5-20 µm 1-10 µm 0.5-5 µm 0.2-2 µm
BET Surface Area 5-15 m²/g 10-20 m²/g 15-30 m²/g 20-50 m²/g

5. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Stable under ambient conditions; stable up to high temperatures.
Conditions to Avoid Strong acids, high humidity, prolonged CO₂ exposure (carbonate formation).
Incompatible Materials Strong acids, strong oxidizing agents.
Hazardous Decomposition Products Upon oxidation at high temperatures: neodymium oxide (Nd₂O₃) is stable; with acids: neodymium salts.
Hazardous Polymerization Will not occur.
Hygroscopicity Low.

5.1. Chemical Reactions

  • Reaction with Acids:
    Nd₂O₃ + 6HCl → 2NdCl₃ + 3H₂O
    Nd₂O₃ + 6HNO₃ → 2Nd(NO₃)₃ + 3H₂O
    Nd₂O₃ + 3H₂SO₄ → Nd₂(SO₄)₃ + 3H₂O

  • Carbonation (Over Time):
    Nd₂O₃ + 3CO₂ + 3H₂O → Nd₂(CO₃)₃·3H₂O

6. APPLICATION AREAS
6.1. Glass and Ceramic Industry

Application Function Details
Special Optical Glasses UV absorber, colorant Purple colored glass and filters
Ceramic Pigments Purple-violet tones High temperature pigments
UV Absorbing Glass UV filtering Special optical glasses
Glass Coloring Purple pigment Decorative and industrial glass

6.2. Laser Technology

Application Function Details
Nd:YAG Lasers Active ion source Used as Nd³⁺ dopant
Nd:Glass Lasers Optical dopant High power laser systems
Optical Amplifiers Signal amplification Fiber optic communication

6.3. Magnet Production (NdFeB)

Application Function Details
NdFeB Magnet Production Precursor Primary source of neodymium metal
Magnet Alloying Nd source Essential component of NdFeB magnets

6.4. Phosphor and Lighting

Application Function Details
Phosphor Formulations Light conversion Special phosphor applications
LED Applications Color conversion Rare earth-doped LEDs

6.5. Research and Catalysis

Application Function Details
Nanopowder Forms Nanoscale material Optoelectronics and catalysis studies
High Purity Research Reference material Materials science and physics research
Catalyst Catalytic activity Component in some catalytic systems

6.6. Sectoral Suitability Table

Sector Suitability Explanation
Glass and Ceramics Suitable UV absorber, purple pigment, optical glass
Laser Technology Suitable Nd:YAG laser dopant
Magnets/Metallurgy Suitable NdFeB magnet precursor
Phosphor/Lighting Suitable Special phosphor formulations
Research and Catalysis Suitable Nanopowder, catalysis, optoelectronics
Food Not Suitable Rare earth oxide, not suitable
Cosmetics Not Suitable Rare earth oxide, not suitable

7. PRODUCTION PROCESS

Stage Process Description
1. Raw Material Preparation Rare earth concentrates Extraction from monazite or bastnäsite ores
2. Separation Solvent extraction Separation of neodymium from other rare earths
3. Purification Recrystallization Thermal treatment for 3N–5N purity (99.0–99.999%)
4. Calcination Thermal treatment Conversion of neodymium salts to oxide form
5. Nano Form Production Physical/chemical route Optional nanopowder production
6. Quality Control Analysis and testing ICP-OES, XRD, BET surface area

7.1. Major Producing Countries

Country Description
China Major producer
USA Rare earth production
Europe Rare earth refineries
India Rare earth mining

8. ALTERNATIVE / SUBSTITUTE PRODUCTS

Alternative Description When to Use
Neodymium Nitrate For solution chemistry When liquid form of neodymium is required
Neodymium Chloride For solution chemistry When liquid form of neodymium is required
Praseodymium Oxide (Pr₂O₃) Optical applications When different optical properties are required
Cerium Oxide (Ce₂O₃) Magnet applications When different magnetic properties are required
Lanthanum Oxide (La₂O₃) Optical glasses When different optical properties are required

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 2,000 mg/kg (low toxicity)
Dermal Toxicity Low
Skin Irritation Mild irritant
Eye Irritation Mild to moderate irritant
Inhalation Dust inhalation may cause respiratory tract irritation.
Carcinogenicity Not classified as carcinogenic.
Mutagenicity Not mutagenic.
Chronic Effects Rare earth oxides have low bioavailability; however, high doses may cause liver effects.
Environmental Hazards Low to moderate aquatic toxicity.

9.1. GHS Classification

Hazard Class Category H-Statement
Skin Irritation Category 2 H315: Causes skin irritation.
Eye Irritation Category 2A H319: Causes serious eye irritation.
Specific Target Organ Toxicity Category 3 H335: May cause respiratory irritation.

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

10. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust.
P264 Wash thoroughly after handling.
P271 Use only in well-ventilated areas.
P280 Wear protective gloves/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
P337+P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local regulations.

11. FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air. If symptoms persist, seek medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention.
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention.
Ingestion Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention.

12. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, and well-ventilated area. Ensure a moisture-free environment.
Container Requirements Moisture-proof, tightly closed containers.
Temperature Room temperature (15-25°C).
Shelf Life 24-36 months under appropriate conditions.
Stability Note Stable under normal conditions; should be stored in closed packaging to prevent moisture and CO₂ absorption.

13. PACKAGING OPTIONS

Packaging Type Quantity Material
Laboratory Packaging 5 g, 10 g, 25 g, 50 g, 100 g HDPE bottle, aluminum foil bag
Industrial Packaging 25 kg PE-lined kraft bag, moisture-proof
Drum 25 kg, 50 kg HDPE drum, moisture-proof
IBC (Intermediate Bulk Container) 500 kg, 1000 kg Moisture-proof, palletized

14. TRANSPORT INFORMATION

Parameter Information
UN Number Not classified (specific regulations apply for rare earth oxides)
Hazard Class -
Packing Group -
ADR/RID Not regulated (special precautions may be required for powder form)
IMDG Not regulated
IATA Not regulated
HS Code 2846.90.00.00.19 (Other rare earth compounds)

15. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Registered
Turkey (KKDIK) Compliance required
TSCA (USA) Registered
EINECS 215-214-1
China (REACH equivalent) Registered; major production and export country

16. OTHER NAMES AND SYNONYMS

Name Description
Neodymia Common short name
Neodymium Trioxide Chemical name
Neodymium(III) Oxide Chemical name
Neodymium Sesquioxide Chemical name
Nd₂O₃ Chemical abbreviation
Rare Earth Oxide Category name

17. QUICK REFERENCE TABLE

Property Value
CAS Number 1313-97-9
EC Number 215-214-1
Chemical Formula Nd₂O₃
Molecular Weight 336.48 g/mol
Appearance Purple-violet powder
Density ~7.24 g/cm³
Melting Point ~1900–1950 °C
Crystal Structure Hexagonal and monoclinic
HS Code 2846.90.00.00.19
GHS Signal Word WARNING

18. CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • High Value: Neodymium is a critical and valuable rare earth element for NdFeB magnets and laser applications. Losses should be minimized and recycling options explored.

  • High Purity Requirement: Laser, optical, and NdFeB magnet applications require high purity (>99.9%). Purity level directly affects application performance.

  • Incompatibility: Reacts with strong acids. Acid use must be controlled.

  • Powder Hazard: Fine powder form may cause respiratory tract irritation. Dust control measures must be taken.

  • Recycling: Neodymium-containing waste (especially NdFeB magnets) can be recycled; this should be considered in waste management planning.

BEST PRACTICE RECOMMENDATIONS:

  • Storage:

    • Store in a cool, dry, and well-ventilated area.

    • Use moisture-proof, tightly closed containers.

    • Keep away from acids and oxidizing agents.

    • Store at room temperature (15-25°C).

  • Handling:

    • Use in well-ventilated areas with local exhaust ventilation.

    • Use a dust mask (N95 or better), protective goggles, and gloves.

    • Avoid dust formation and inhalation.

    • Wash hands thoroughly after handling.

    • For dissolution in acids, add oxide to acid slowly with cooling and stirring.

  • Waste Management:

    • Dispose of in accordance with local regulations.

    • Do not discharge into water sources.

    • For large quantities, rare earth recycling and recovery should be considered (especially NdFeB magnet waste is valuable).

LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Neodymium oxide is a critical rare earth material for NdFeB magnets and laser applications; careful handling, storage, and recycling planning are required due to high purity requirements and value.

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