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Send EmailDysprosium Oxide, Dysprosium Trioxide, Dysprosia, Dysprosium Sesquioxide, Didysprosium Trioxide, 1308‑87‑8
DYSPROSIUM OXIDE (DY₂O₃)
DYSPROSIUM OXIDE / DYSPROSIA / DYSPROSIUM SESQUIOXIDE / DYSPROSIUM TRIOXIDE / DIDYSPROSIUM TRIOXIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY
| Parameter | Information |
|---|---|
| Product Name | Dysprosium Oxide |
| Chemical Name | Dysprosium(III) Oxide, Dysprosium Sesquioxide, Dysprosium Trioxide |
| Other Names | Dysprosia, Didysprosium Trioxide, Dy₂O₃ |
| CAS Number | 1308-87-8 |
| EC Number (EINECS) | 215-164-0 |
| Chemical Formula | Dy₂O₃ |
| Molecular Weight | 373.00 g/mol |
| Appearance | White to light pink powder (near white at high purity) |
| Odor | Odorless |
| Physical State (20°C) | Solid (powder) |
2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Dysprosium oxide is the oxide compound of the rare earth element dysprosium. Dysprosium ions (Dy³⁺) and oxide ions (O²⁻) are present in a 2:3 ratio. It has a cubic crystal structure (Ia3 space group). It is known for its high melting point and thermal stability. It is insoluble in water but soluble in acids. It is slightly hygroscopic and stable under ambient conditions.
Structural Features:
DYSPROSIUM OXIDE [Dy₂O₃]
|
Dy³⁺ - O²⁻ Ionic Bonds
|
+----------------+----------------+
| | |
Cubic Crystal White-Pink High Thermal
Structure (Ia3) Powder Form Stability
2.2. Structural Properties
| Parameter | Value |
|---|---|
| Crystal Structure | Cubic (Ia3 space group) |
| Chemical Formula | Dy₂O₃ |
| Molecular Weight | 373.00 g/mol |
| Density | ~7.8–7.81 g/cm³ (25°C) |
| Appearance | White to light pink powder |
| Melting Point | ~2330–2350 °C |
| Boiling Point | ~3900 °C |
| Magnetic Susceptibility | Paramagnetic |
3. PHYSICAL AND CHEMICAL PROPERTIES
| Property | Value | Description |
|---|---|---|
| Appearance | White to light pink powder | Color depends on purity |
| Odor | Odorless | - |
| Chemical Formula | Dy₂O₃ | - |
| Molecular Weight | 373.00 g/mol | - |
| Density | ~7.8–7.81 g/cm³ | - |
| Melting Point | ~2330–2350 °C | - |
| Solubility in Water (25°C) | Insoluble | - |
| Solubility in Acids | Soluble | Forms dysprosium salts |
| Solubility in Alcohol | Insoluble | - |
| Crystal Structure | Cubic (Ia3 space group) | - |
| Thermal Stability | High | Stable up to 2350°C |
| Hygroscopicity | Slight | May absorb moisture; store in dry conditions |
| Magnetic Properties | Paramagnetic | - |
4. PURITY GRADES
| Parameter | Technical Grade | High Purity Grade | Analytical Grade | Ultra-High Purity Grade |
|---|---|---|---|---|
| Purity (Dy₂O₃) | ≥ 99.0% | ≥ 99.9% | ≥ 99.99% | ≥ 99.999% |
| Other Rare Earths | ≤ 1.0% | ≤ 0.1% | ≤ 0.01% | ≤ 0.001% |
| Iron (Fe) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Calcium (Ca) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Silicon (Si) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Heavy Metals (Pb) | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm | ≤ 5 ppm |
| Chloride (Cl⁻) | ≤ 0.1% | ≤ 0.05% | ≤ 0.02% | ≤ 0.01% |
| Loss on Drying | ≤ 1.0% | ≤ 0.5% | ≤ 0.3% | ≤ 0.1% |
| Particle Size (D50) | 5-20 µm | 1-10 µm | 0.5-5 µm | 0.2-2 µm |
| BET Surface Area | 5-15 m²/g | 10-20 m²/g | 15-30 m²/g | 20-50 m²/g |
5. STABILITY AND REACTIVITY
| Parameter | Information |
|---|---|
| Chemical Stability | Stable under ambient conditions; stable up to high temperatures. |
| Conditions to Avoid | High humidity, strong acids, prolonged CO₂ exposure (carbonate formation). |
| Incompatible Materials | Strong acids, strong oxidizing agents. |
| Hazardous Decomposition Products | Upon oxidation at high temperatures: dysprosium oxide (Dy₂O₃) is stable; with acids: dysprosium salts. |
| Hazardous Polymerization | Will not occur. |
| Hygroscopicity | Slight; may absorb CO₂ and moisture over time, forming basic carbonate. |
5.1. Chemical Reactions
Reaction with Acids:
Dy₂O₃ + 6HCl → 2DyCl₃ + 3H₂O
Dy₂O₃ + 6HNO₃ → 2Dy(NO₃)₃ + 3H₂O
Dy₂O₃ + 3H₂SO₄ → Dy₂(SO₄)₃ + 3H₂O
Carbonation (Over Time):
Dy₂O₃ + 3CO₂ + 3H₂O → Dy₂(CO₃)₃·3H₂O
6. APPLICATION AREAS
6.1. Ceramic and Glass Industry
| Application | Function | Details |
|---|---|---|
| Laser Glasses | Optical dopant | Used in high-power laser systems |
| Special Optical Glasses | Refractive index adjuster | Rare earth-doped optical glasses |
| Phosphors | Light conversion | LED and lighting applications |
| High Temperature Pigments | Colorant | Used in ceramic pigments |
6.2. Phosphor and Lighting
| Application | Function | Details |
|---|---|---|
| Metal Halide Lamps | Rare earth component | High-efficiency lighting systems |
| Phosphor Formulations | Light emitter | LED and fluorescent lighting |
6.3. Metal Production and Magnets
| Application | Function | Details |
|---|---|---|
| Dysprosium Metal Production | Primary raw material | For Dy alloying in NdFeB magnets |
| NdFeB Magnet Additive | Strength enhancer | Improves high temperature performance |
| Terfenol-D Production | Magnetostrictive material | Actuator and sensor systems |
6.4. Research and Nano-Applications
| Application | Function | Details |
|---|---|---|
| Nanopowder Forms | Nanoscale material | Optoelectronics and catalysis studies |
| High Purity Research | Reference material | Materials science and physics research |
6.5. Sectoral Suitability Table
| Sector | Suitability | Explanation |
|---|---|---|
| Ceramics and Glass | Suitable | High melting point and thermal stability; optical glass/laser glass applications |
| Phosphor/Lighting | Suitable | Phosphor component; metal halide lamp formulations |
| Magnets/Metallurgy | Suitable | Primary raw material for Dy metal production; NdFeB strength enhancer |
| Research and Nano | Suitable | High purity nanopowder applications |
| Food | Not Suitable | Rare earth oxide, not suitable in this field |
| Cosmetics | Not Suitable | Rare earth oxide, not suitable in this field |
7. PRODUCTION PROCESS
| Stage | Process | Description |
|---|---|---|
| 1. Raw Material Preparation | Rare earth concentrates | Extraction from monazite or bastnäsite ores |
| 2. Separation | Precipitation/extraction | Separation of dysprosium from other rare earths |
| 3. Purification | Recrystallization | Thermal treatment for 4N–6N purity (99.99–99.999%) |
| 4. Oxide Conversion | Thermal treatment | Conversion to oxide form |
| 5. Nano Form Production | Physical/chemical route | Optional nanopowder production |
| 6. Quality Control | Analysis and testing | ICP-OES, XRD, BET surface area |
7.1. Major Producing Countries
| Country | Description |
|---|---|
| China | Major producer |
| Australia | Rare earth mining |
| USA | Rare earth production |
| India | Rare earth mining |
8. ALTERNATIVE / SUBSTITUTE PRODUCTS
| Alternative | Description | When to Use |
|---|---|---|
| Dysprosium Nitrate | For solution chemistry | When liquid form of dysprosium is required |
| Dysprosium Chloride | For solution chemistry | When liquid form of dysprosium is required |
| Erbium Oxide (Er₂O₃) | Optical applications | When different optical properties are required |
| Terbium Oxide (Tb₂O₃) | Phosphor applications | When different phosphor properties are required |
| Holmium Oxide (Ho₂O₃) | Magnetic applications | When different magnetic properties are required |
9. SAFETY AND TOXICOLOGY
| Parameter | Value |
|---|---|
| Acute Oral Toxicity (LD50, Rat) | > 2,000 mg/kg (low toxicity) |
| Dermal Toxicity | Low |
| Skin Irritation | Mild irritant |
| Eye Irritation | Mild to moderate irritant |
| Inhalation | Dust inhalation may cause respiratory tract irritation. |
| Carcinogenicity | Not classified as carcinogenic. |
| Mutagenicity | Not mutagenic. |
| Chronic Effects | Rare earth oxides have low bioavailability; however, high doses may cause liver effects. |
| Environmental Hazards | Low to moderate aquatic toxicity. |
9.1. GHS Classification
| Hazard Class | Category | H-Statement |
|---|---|---|
| Skin Irritation | Category 2 | H315: Causes skin irritation. |
| Eye Irritation | Category 2A | H319: Causes serious eye irritation. |
| Specific Target Organ Toxicity | Category 3 | H335: May cause respiratory irritation. |
Signal Word: WARNING
Hazard Pictograms: GHS07 (Exclamation Mark)
10. PRECAUTIONARY STATEMENTS (P-CODES)
| Code | Statement |
|---|---|
| P261 | Avoid breathing dust. |
| P264 | Wash thoroughly after handling. |
| P271 | Use only in well-ventilated areas. |
| P280 | Wear protective gloves/eye protection/face protection. |
| P302+P352 | IF ON SKIN: Wash with plenty of soap and water. |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing. |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. |
| P337+P313 | If eye irritation persists: Get medical advice/attention. |
| P501 | Dispose of contents/container in accordance with local regulations. |
11. FIRST AID MEASURES
| Exposure Route | Action to Take |
|---|---|
| Inhalation | Remove to fresh air. If symptoms persist, seek medical attention. |
| Skin Contact | Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention. |
| Eye Contact | Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention. |
| Ingestion | Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention. |
12. STORAGE AND SHELF LIFE
| Parameter | Condition |
|---|---|
| Storage Conditions | Store in a cool, dry, and well-ventilated area. Ensure a moisture-free environment. |
| Container Requirements | Moisture-proof, tightly closed containers. Vacuum-sealed or inert gas (N₂, Ar) packaging is recommended. |
| Temperature | Room temperature (15-25°C). |
| Shelf Life | 24-36 months under appropriate conditions. |
| Stability Note | Slightly hygroscopic; should be stored in closed packaging to prevent CO₂ and moisture absorption. |
13. PACKAGING OPTIONS
| Packaging Type | Quantity | Material |
|---|---|---|
| Laboratory Packaging | 5 g, 10 g, 25 g, 50 g, 100 g | HDPE bottle, aluminum foil bag, inert atmosphere |
| Industrial Packaging | 25 kg | PE-lined kraft bag, moisture-proof |
| Drum | 25 kg, 50 kg | HDPE drum, moisture-proof |
| IBC (Intermediate Bulk Container) | 500 kg, 1000 kg | Moisture-proof, palletized |
14. TRANSPORT INFORMATION
| Parameter | Information |
|---|---|
| UN Number | Not classified (specific regulations apply for rare earth oxides) |
| Hazard Class | - |
| Packing Group | - |
| ADR/RID | Not regulated (special precautions may be required for powder form) |
| IMDG | Not regulated |
| IATA | Not regulated |
| HS Code | 2846.90.00.00.19 (Other rare earth compounds) |
15. REGULATORY STATUS
| Region / Authority | Status |
|---|---|
| European Union (REACH) | Registered; presented as high purity chemical |
| Turkey (KKDIK) | Compliance required |
| TSCA (USA) | Registered |
| EINECS | 215-164-0 |
| China (REACH equivalent) | Registered; major production and export country |
16. OTHER NAMES AND SYNONYMS
| Name | Description |
|---|---|
| Dysprosia | Common short name |
| Dysprosium Sesquioxide | Chemical name |
| Dysprosium Trioxide | Chemical name |
| Didysprosium Trioxide | Chemical name |
| Dysprosium(III) Oxide | Chemical name |
| Dy₂O₃ | Chemical abbreviation |
| Rare Earth Oxide | Category name |
17. QUICK REFERENCE TABLE
| Property | Value |
|---|---|
| CAS Number | 1308-87-8 |
| EC Number | 215-164-0 |
| Chemical Formula | Dy₂O₃ |
| Molecular Weight | 373.00 g/mol |
| Appearance | White to light pink powder |
| Density | ~7.8–7.81 g/cm³ |
| Melting Point | ~2330–2350 °C |
| Crystal Structure | Cubic (Ia3) |
| HS Code | 2846.90.00.00.19 |
| GHS Signal Word | WARNING |
18. CRITICAL WARNINGS AND BEST PRACTICES
CRITICAL WARNINGS:
Hygroscopic Nature: Dysprosium oxide is slightly hygroscopic; it may absorb CO₂ and moisture over time, forming basic carbonate. This may affect purity and performance. Vacuum-sealed or inert atmosphere packaging is recommended.
High Value: Dysprosium is a critical and valuable rare earth element. Losses should be minimized and recycling options explored.
High Purity Requirement: Optical, phosphor, and laser applications require high purity (>99.9%). Purity level directly affects application performance.
Incompatibility: Reacts with strong acids. Acid use must be controlled.
Powder Hazard: Fine powder form may cause respiratory tract irritation. Dust control measures must be taken.
BEST PRACTICE RECOMMENDATIONS:
Storage:
Store in a cool, dry, and well-ventilated area.
Use vacuum-sealed or inert gas (N₂ or Ar) filled containers.
Avoid exposure to humid and CO₂-rich environments.
Store at room temperature (15-25°C).
Handling:
Use in well-ventilated areas with local exhaust ventilation.
Use a dust mask (N95 or better), protective goggles, and gloves.
Avoid dust formation and inhalation.
Wash hands thoroughly after handling.
For dissolution in acids, add oxide to acid slowly with cooling and stirring.
Waste Management:
Dispose of in accordance with local regulations.
Do not discharge into water sources.
For large quantities, rare earth recycling and recovery should be considered (economically viable).
LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Dysprosium oxide is a critical rare earth material for optical and magnetic applications; careful handling and storage are required due to high purity requirements and hygroscopic nature.