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Dysprosium Oxide, Dysprosium Trioxide, Dysprosia, Dysprosium Sesquioxide, Didysprosium Trioxide, 1308‑87‑8

Dysprosium Oxide, Dysprosium Trioxide, Dysprosia, Dysprosium Sesquioxide, Didysprosium Trioxide, 1308‑87‑8

DYSPROSIUM OXIDE (DY₂O₃)
DYSPROSIUM OXIDE / DYSPROSIA / DYSPROSIUM SESQUIOXIDE / DYSPROSIUM TRIOXIDE / DIDYSPROSIUM TRIOXIDE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Dysprosium Oxide
Chemical Name Dysprosium(III) Oxide, Dysprosium Sesquioxide, Dysprosium Trioxide
Other Names Dysprosia, Didysprosium Trioxide, Dy₂O₃
CAS Number 1308-87-8
EC Number (EINECS) 215-164-0
Chemical Formula Dy₂O₃
Molecular Weight 373.00 g/mol
Appearance White to light pink powder (near white at high purity)
Odor Odorless
Physical State (20°C) Solid (powder)

2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Dysprosium oxide is the oxide compound of the rare earth element dysprosium. Dysprosium ions (Dy³⁺) and oxide ions (O²⁻) are present in a 2:3 ratio. It has a cubic crystal structure (Ia3 space group). It is known for its high melting point and thermal stability. It is insoluble in water but soluble in acids. It is slightly hygroscopic and stable under ambient conditions.

Structural Features:

                    DYSPROSIUM OXIDE [Dy₂O₃]
                          |
                Dy³⁺ - O²⁻ Ionic Bonds
                          |
        +----------------+----------------+
        |                |                |
    Cubic Crystal     White-Pink       High Thermal
    Structure (Ia3)   Powder Form      Stability

2.2. Structural Properties

Parameter Value
Crystal Structure Cubic (Ia3 space group)
Chemical Formula Dy₂O₃
Molecular Weight 373.00 g/mol
Density ~7.8–7.81 g/cm³ (25°C)
Appearance White to light pink powder
Melting Point ~2330–2350 °C
Boiling Point ~3900 °C
Magnetic Susceptibility Paramagnetic

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance White to light pink powder Color depends on purity
Odor Odorless -
Chemical Formula Dy₂O₃ -
Molecular Weight 373.00 g/mol -
Density ~7.8–7.81 g/cm³ -
Melting Point ~2330–2350 °C -
Solubility in Water (25°C) Insoluble -
Solubility in Acids Soluble Forms dysprosium salts
Solubility in Alcohol Insoluble -
Crystal Structure Cubic (Ia3 space group) -
Thermal Stability High Stable up to 2350°C
Hygroscopicity Slight May absorb moisture; store in dry conditions
Magnetic Properties Paramagnetic -

4. PURITY GRADES

Parameter Technical Grade High Purity Grade Analytical Grade Ultra-High Purity Grade
Purity (Dy₂O₃) ≥ 99.0% ≥ 99.9% ≥ 99.99% ≥ 99.999%
Other Rare Earths ≤ 1.0% ≤ 0.1% ≤ 0.01% ≤ 0.001%
Iron (Fe) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Calcium (Ca) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Silicon (Si) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Heavy Metals (Pb) ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm ≤ 5 ppm
Chloride (Cl⁻) ≤ 0.1% ≤ 0.05% ≤ 0.02% ≤ 0.01%
Loss on Drying ≤ 1.0% ≤ 0.5% ≤ 0.3% ≤ 0.1%
Particle Size (D50) 5-20 µm 1-10 µm 0.5-5 µm 0.2-2 µm
BET Surface Area 5-15 m²/g 10-20 m²/g 15-30 m²/g 20-50 m²/g

5. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Stable under ambient conditions; stable up to high temperatures.
Conditions to Avoid High humidity, strong acids, prolonged CO₂ exposure (carbonate formation).
Incompatible Materials Strong acids, strong oxidizing agents.
Hazardous Decomposition Products Upon oxidation at high temperatures: dysprosium oxide (Dy₂O₃) is stable; with acids: dysprosium salts.
Hazardous Polymerization Will not occur.
Hygroscopicity Slight; may absorb CO₂ and moisture over time, forming basic carbonate.

5.1. Chemical Reactions

  • Reaction with Acids:
    Dy₂O₃ + 6HCl → 2DyCl₃ + 3H₂O
    Dy₂O₃ + 6HNO₃ → 2Dy(NO₃)₃ + 3H₂O
    Dy₂O₃ + 3H₂SO₄ → Dy₂(SO₄)₃ + 3H₂O

  • Carbonation (Over Time):
    Dy₂O₃ + 3CO₂ + 3H₂O → Dy₂(CO₃)₃·3H₂O

6. APPLICATION AREAS
6.1. Ceramic and Glass Industry

Application Function Details
Laser Glasses Optical dopant Used in high-power laser systems
Special Optical Glasses Refractive index adjuster Rare earth-doped optical glasses
Phosphors Light conversion LED and lighting applications
High Temperature Pigments Colorant Used in ceramic pigments

6.2. Phosphor and Lighting

Application Function Details
Metal Halide Lamps Rare earth component High-efficiency lighting systems
Phosphor Formulations Light emitter LED and fluorescent lighting

6.3. Metal Production and Magnets

Application Function Details
Dysprosium Metal Production Primary raw material For Dy alloying in NdFeB magnets
NdFeB Magnet Additive Strength enhancer Improves high temperature performance
Terfenol-D Production Magnetostrictive material Actuator and sensor systems

6.4. Research and Nano-Applications

Application Function Details
Nanopowder Forms Nanoscale material Optoelectronics and catalysis studies
High Purity Research Reference material Materials science and physics research

6.5. Sectoral Suitability Table

Sector Suitability Explanation
Ceramics and Glass Suitable High melting point and thermal stability; optical glass/laser glass applications
Phosphor/Lighting Suitable Phosphor component; metal halide lamp formulations
Magnets/Metallurgy Suitable Primary raw material for Dy metal production; NdFeB strength enhancer
Research and Nano Suitable High purity nanopowder applications
Food Not Suitable Rare earth oxide, not suitable in this field
Cosmetics Not Suitable Rare earth oxide, not suitable in this field

7. PRODUCTION PROCESS

Stage Process Description
1. Raw Material Preparation Rare earth concentrates Extraction from monazite or bastnäsite ores
2. Separation Precipitation/extraction Separation of dysprosium from other rare earths
3. Purification Recrystallization Thermal treatment for 4N–6N purity (99.99–99.999%)
4. Oxide Conversion Thermal treatment Conversion to oxide form
5. Nano Form Production Physical/chemical route Optional nanopowder production
6. Quality Control Analysis and testing ICP-OES, XRD, BET surface area

7.1. Major Producing Countries

Country Description
China Major producer
Australia Rare earth mining
USA Rare earth production
India Rare earth mining

8. ALTERNATIVE / SUBSTITUTE PRODUCTS

Alternative Description When to Use
Dysprosium Nitrate For solution chemistry When liquid form of dysprosium is required
Dysprosium Chloride For solution chemistry When liquid form of dysprosium is required
Erbium Oxide (Er₂O₃) Optical applications When different optical properties are required
Terbium Oxide (Tb₂O₃) Phosphor applications When different phosphor properties are required
Holmium Oxide (Ho₂O₃) Magnetic applications When different magnetic properties are required

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 2,000 mg/kg (low toxicity)
Dermal Toxicity Low
Skin Irritation Mild irritant
Eye Irritation Mild to moderate irritant
Inhalation Dust inhalation may cause respiratory tract irritation.
Carcinogenicity Not classified as carcinogenic.
Mutagenicity Not mutagenic.
Chronic Effects Rare earth oxides have low bioavailability; however, high doses may cause liver effects.
Environmental Hazards Low to moderate aquatic toxicity.

9.1. GHS Classification

Hazard Class Category H-Statement
Skin Irritation Category 2 H315: Causes skin irritation.
Eye Irritation Category 2A H319: Causes serious eye irritation.
Specific Target Organ Toxicity Category 3 H335: May cause respiratory irritation.

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

10. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust.
P264 Wash thoroughly after handling.
P271 Use only in well-ventilated areas.
P280 Wear protective gloves/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
P337+P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local regulations.

11. FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air. If symptoms persist, seek medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention.
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention.
Ingestion Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention.

12. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, and well-ventilated area. Ensure a moisture-free environment.
Container Requirements Moisture-proof, tightly closed containers. Vacuum-sealed or inert gas (N₂, Ar) packaging is recommended.
Temperature Room temperature (15-25°C).
Shelf Life 24-36 months under appropriate conditions.
Stability Note Slightly hygroscopic; should be stored in closed packaging to prevent CO₂ and moisture absorption.

13. PACKAGING OPTIONS

Packaging Type Quantity Material
Laboratory Packaging 5 g, 10 g, 25 g, 50 g, 100 g HDPE bottle, aluminum foil bag, inert atmosphere
Industrial Packaging 25 kg PE-lined kraft bag, moisture-proof
Drum 25 kg, 50 kg HDPE drum, moisture-proof
IBC (Intermediate Bulk Container) 500 kg, 1000 kg Moisture-proof, palletized

14. TRANSPORT INFORMATION

Parameter Information
UN Number Not classified (specific regulations apply for rare earth oxides)
Hazard Class -
Packing Group -
ADR/RID Not regulated (special precautions may be required for powder form)
IMDG Not regulated
IATA Not regulated
HS Code 2846.90.00.00.19 (Other rare earth compounds)

15. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Registered; presented as high purity chemical
Turkey (KKDIK) Compliance required
TSCA (USA) Registered
EINECS 215-164-0
China (REACH equivalent) Registered; major production and export country

16. OTHER NAMES AND SYNONYMS

Name Description
Dysprosia Common short name
Dysprosium Sesquioxide Chemical name
Dysprosium Trioxide Chemical name
Didysprosium Trioxide Chemical name
Dysprosium(III) Oxide Chemical name
Dy₂O₃ Chemical abbreviation
Rare Earth Oxide Category name

17. QUICK REFERENCE TABLE

Property Value
CAS Number 1308-87-8
EC Number 215-164-0
Chemical Formula Dy₂O₃
Molecular Weight 373.00 g/mol
Appearance White to light pink powder
Density ~7.8–7.81 g/cm³
Melting Point ~2330–2350 °C
Crystal Structure Cubic (Ia3)
HS Code 2846.90.00.00.19
GHS Signal Word WARNING

18. CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • Hygroscopic Nature: Dysprosium oxide is slightly hygroscopic; it may absorb CO₂ and moisture over time, forming basic carbonate. This may affect purity and performance. Vacuum-sealed or inert atmosphere packaging is recommended.

  • High Value: Dysprosium is a critical and valuable rare earth element. Losses should be minimized and recycling options explored.

  • High Purity Requirement: Optical, phosphor, and laser applications require high purity (>99.9%). Purity level directly affects application performance.

  • Incompatibility: Reacts with strong acids. Acid use must be controlled.

  • Powder Hazard: Fine powder form may cause respiratory tract irritation. Dust control measures must be taken.

BEST PRACTICE RECOMMENDATIONS:

  • Storage:

    • Store in a cool, dry, and well-ventilated area.

    • Use vacuum-sealed or inert gas (N₂ or Ar) filled containers.

    • Avoid exposure to humid and CO₂-rich environments.

    • Store at room temperature (15-25°C).

  • Handling:

    • Use in well-ventilated areas with local exhaust ventilation.

    • Use a dust mask (N95 or better), protective goggles, and gloves.

    • Avoid dust formation and inhalation.

    • Wash hands thoroughly after handling.

    • For dissolution in acids, add oxide to acid slowly with cooling and stirring.

  • Waste Management:

    • Dispose of in accordance with local regulations.

    • Do not discharge into water sources.

    • For large quantities, rare earth recycling and recovery should be considered (economically viable).

LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Dysprosium oxide is a critical rare earth material for optical and magnetic applications; careful handling and storage are required due to high purity requirements and hygroscopic nature.

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