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AlMn Manganese Aluminium Master Alloy, AlMn10, AlMn20, AlMn30, 7439-96-5, 7429-90-5, 7440-21-3, 7439-89-6, 7440-02-0, 7440-50-8

AlMn Manganese Aluminium Master Alloy, AlMn10, AlMn20, AlMn30, 7439-96-5, 7429-90-5, 7440-21-3, 7439-89-6, 7440-02-0, 7440-50-8

MANGANESE-ADDED ALUMINUM MASTER ALLOY (AlMn)
ALMN MANGANESE ALUMINIUM MASTER ALLOY / COIL / STICK / WAFFLE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Manganese-Added Aluminum Master Alloy
Chemical Name Aluminum-Manganese Alloy, AlMn Master Alloy
Other Names Manganese-Aluminum Modifier, Mn-Added Aluminum Alloy, AlMn Waffle, AlMn Additive Rod, Mn Alloy Block
Chemical Composition Al + Mn (Manganese content varies by variant)
CAS Numbers (Component Based) Manganese (Mn): 7439-96-5, Aluminum (Al): 7429-90-5, Silicon (Si): 7440-21-3, Iron (Fe): 7439-89-6, Nickel (Ni): 7440-02-0, Copper (Cu): 7440-50-8
Appearance Silver-gray metallic waffle, rod or wire
Odor Odorless
Physical State (20°C) Solid (metallic)

2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Manganese-Added Aluminum master alloy consists of manganese phases homogeneously distributed within an aluminum matrix. Manganese dissolves in aluminum or forms Al₆Mn intermetallic phases, increasing the alloy's mechanical strength, corrosion resistance, and recrystallization control. It also functions as a grain stabilizer and iron neutralizer, improving alloy cleanliness and performance.

Structural Features:

                MANGANESE-ADDED ALUMINUM MASTER ALLOY (AlMn)
                          |
                Al Matrix + Mn Phases / Al₆Mn
                          |
        +----------------+----------------+
        |                |                |
    Al₆Mn Phase       Grain            Iron
    (Strength)       Stabilizer      Neutralizer

2.2. Structural Properties

Parameter Value
Crystal Structure Al matrix (FCC) + Al₆Mn intermetallic phases
Density ~2.7 g/cm³ (Al-based matrix)
Melting Point ~660 °C
Appearance Silver-gray metallic waffle, rod or wire
Physical Forms Coil, Stick, Waffle Ingot

3. COMMERCIAL VARIANTS AND COMPOSITIONS

3.1. AlMn Master Alloy Variants

Variant Manganese (Mn) Content Aluminum (Al) Content Description
AlMn10 9.0 – 11.0% Remainder Low manganese content, standard applications
AlMn20 18.0 – 22.0% Remainder Medium manganese content, special applications
AlMn30 28.0 – 32.0% Remainder High manganese content, special alloy production

3.2. Typical Impurity Limits (All Variants)

Parameter Max. Value
Silicon (Si) ≤ 0.30%
Iron (Fe) ≤ 0.30%
Nickel (Ni) ≤ 0.05%
Copper (Cu) ≤ 0.05%
Other Total Impurities ≤ 0.10%

4. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance Silver-gray metallic -
Odor Odorless -
Chemical Composition Al + Mn Varies depending on variant
Density ~2.7 g/cm³ -
Melting Point ~660 °C -
Solubility in Water (25°C) Insoluble -
Solubility in Acids Soluble Releases hydrogen gas
Physical Forms Coil, Stick, Waffle -
Packaging Boxed waffle ingots, boxed wire/rod, optional vacuum packaging -

5. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Stable under normal conditions; forms a passive oxide layer on the surface.
Conditions to Avoid Oxidizing atmosphere at high temperatures, strong acids, moisture.
Incompatible Materials Strong acids, strong bases, oxidizing agents.
Hazardous Decomposition Products Upon oxidation at high temperatures: aluminum oxide (Al₂O₃) and manganese oxide (MnO₂).
Hazardous Polymerization Will not occur.
Hygroscopicity Low; does not absorb moisture under normal conditions.

5.1. Chemical Reactions

  • Oxidation (at High Temperature):
    4Al + 3O₂ → 2Al₂O₃
    2Mn + O₂ → 2MnO
    Mn + O₂ → MnO₂

  • Reaction with Acids:
    2Al + 6HCl → 2AlCl₃ + 3H₂↑
    Mn + 2HCl → MnCl₂ + H₂↑

6. APPLICATION AREAS
6.1. Manganese Source in Aluminum Alloys

Application Function Details
Mechanical Strength Increase Alloy strengthening Manganese addition increases strength
Corrosion Resistance Passivation and durability Improves corrosion resistance
Recrystallization Control Grain stabilization Controls grain structure during heat treatment
Iron Neutralization Impurity control Neutralizes iron-containing phases

6.2. Sectoral Applications

Application Sector
Automotive Radiators, Body Panels Automotive
Roofing, Facade Panels, Structural Sheets Construction
Beverage Cans, Food Packaging Food Packaging
Corrosion-Resistant Aluminum Alloys Marine
Rolled Products, Structural Profiles Industrial Applications

6.3. Sectoral Suitability Table

Sector Suitability Explanation
Automotive Suitable Used in radiators and body panels
Construction Suitable Roofing, facades and structural sheets
Food Packaging Suitable Mandatory in beverage can alloys
Marine Suitable In corrosion-resistant aluminum alloys
Aerospace Limited Limited to non-structural components
Electrical/Electronics Limited Limited use in special thermal and structural alloys

7. STANDARDS AND COMPLIANCE

Standard Description
EN 573 European aluminum alloy standards
ASTM B209 American aluminum sheet and plate standards
JIS H4000 Japanese aluminum sheet standards

8. ALTERNATIVE / SUBSTITUTE PRODUCTS

Alternative Description When to Use
AlMn10 Low manganese content Standard applications
AlMn20 Medium manganese content Applications requiring higher Mn
AlMn30 High manganese content Special alloy production
Pure Manganese Elemental Mn Direct alloying, more difficult to dissolve
AlMnFe Iron-containing alternative Applications requiring iron neutralization

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 2,000 mg/kg (low toxicity)
Dermal Toxicity Low
Skin Irritation Mild irritant
Eye Irritation Mild to moderate irritant
Inhalation Metal dust inhalation may cause respiratory tract irritation.
Carcinogenicity Not classified as carcinogenic.
Mutagenicity Not mutagenic.
Chronic Effects Long-term data on aluminum and manganese compounds is limited.
Environmental Hazards Low to moderate aquatic toxicity.

9.1. GHS Classification

Hazard Class Category H-Statement
Flammable Solid (Metal Dust) Category 1 H228: Flammable solid.
Skin Irritation Category 2 H315: Causes skin irritation.
Eye Irritation Category 2A H319: Causes serious eye irritation.
Specific Target Organ Toxicity Category 3 H335: May cause respiratory irritation.

Signal Word: WARNING

Hazard Pictograms: GHS02 (Flame), GHS07 (Exclamation Mark)

10. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, and well-ventilated area.
Container Requirements Dry, moisture-free environment; store in original packaging.
Temperature Room temperature (15-25°C).
Shelf Life Unlimited under appropriate conditions (except surface oxidation).
Stability Note Stable under normal conditions; forms a passive oxide layer on the surface.

11. PACKAGING OPTIONS

Packaging Type Quantity Material
Waffle Ingot 5 kg, 10 kg, 20 kg Boxed protected, optional vacuum packaging
Stick / Rod 1 kg, 5 kg, 10 kg Boxed, plastic wrap or coated metal cases
Wire / Coil 1 kg, 5 kg, 10 kg, 25 kg Boxed, moisture-proof plastic bags or drums
Granule 1 kg, 5 kg, 10 kg, 25 kg Moisture-proof plastic bags or drums

12. TRANSPORT INFORMATION

Parameter Information
UN Number Not classified (specific regulations apply for metal alloys)
Hazard Class -
Packing Group -
ADR/RID Not regulated (except powder form)
IMDG Not regulated (except powder form)
IATA Not regulated (except powder form)
HS Code 7601.20.00.00.00 (Unwrought aluminum alloys)

13. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Registered as an alloy; evaluated by components
Turkey (KKDIK) Compliance required
TSCA (USA) Registered
China Registered; major production and export country

14. OTHER NAMES AND SYNONYMS

Name Description
AlMn Master Alloy Common name
AlMn10 / AlMn20 / AlMn30 Manganese-containing variants
Manganese-Aluminum Modifier Functional name
Mn-Added Aluminum Alloy Descriptive name
AlMn Waffle Physical form name
AlMn Additive Rod Usage description
Mn Alloy Block Usage description

15. QUICK REFERENCE TABLE

Property Value
Density ~2.7 g/cm³
Melting Point ~660 °C
Manganese Content (Variant Dependent) 9% – 32%
Physical Forms Coil, Stick, Waffle, Granule
HS Code 7601.20.00.00.00
GHS Signal Word WARNING

16. CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • Manganese Addition: AlMn master alloy provides mechanical strength, corrosion resistance, and recrystallization control in aluminum alloys. It is a critical additive especially in 3xxx series alloys.

  • Iron Neutralization: Manganese neutralizes iron impurities in the alloy, reducing their negative effects and improving alloy quality.

  • Quality and Origin: Phase stability and impurity control are critical for corrosion resistance and mechanical performance. Trader-sourced products may show variability in purity and origin.

  • Oxidation: Oxidizes in oxidizing atmospheres at high temperatures; inert atmosphere or vacuum is required for melting operations.

  • Acid Reactivity: Reacts with strong acids releasing hydrogen gas.

BEST PRACTICE RECOMMENDATIONS:

  • Storage:

    • Store in a cool, dry, and well-ventilated area.

    • Store in original packaging, moisture-free environment.

    • Keep away from acids and oxidizing agents.

    • Store at room temperature (15-25°C).

  • Handling:

    • Add to molten aluminum bath in controlled amounts.

    • Calculate correct dosage to achieve target Mn ratio.

    • Ensure proper mixing conditions for optimum homogenization.

    • Use vacuum or inert atmosphere (Ar, N₂) for melting operations.

  • Waste Management:

    • Dispose of in accordance with local regulations.

    • Do not discharge into water sources.

    • For large quantities, aluminum and manganese recovery should be considered.

LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Manganese-Added Aluminum master alloy is a critical additive material for corrosion resistance and mechanical strength in the aluminum industry; correct variant selection and application conditions directly affect final alloy performance.

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