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Send EmailAlMn Manganese Aluminium Master Alloy, AlMn10, AlMn20, AlMn30, 7439-96-5, 7429-90-5, 7440-21-3, 7439-89-6, 7440-02-0, 7440-50-8
MANGANESE-ADDED ALUMINUM MASTER ALLOY (AlMn)
ALMN MANGANESE ALUMINIUM MASTER ALLOY / COIL / STICK / WAFFLE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY
| Parameter | Information |
|---|---|
| Product Name | Manganese-Added Aluminum Master Alloy |
| Chemical Name | Aluminum-Manganese Alloy, AlMn Master Alloy |
| Other Names | Manganese-Aluminum Modifier, Mn-Added Aluminum Alloy, AlMn Waffle, AlMn Additive Rod, Mn Alloy Block |
| Chemical Composition | Al + Mn (Manganese content varies by variant) |
| CAS Numbers (Component Based) | Manganese (Mn): 7439-96-5, Aluminum (Al): 7429-90-5, Silicon (Si): 7440-21-3, Iron (Fe): 7439-89-6, Nickel (Ni): 7440-02-0, Copper (Cu): 7440-50-8 |
| Appearance | Silver-gray metallic waffle, rod or wire |
| Odor | Odorless |
| Physical State (20°C) | Solid (metallic) |
2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Manganese-Added Aluminum master alloy consists of manganese phases homogeneously distributed within an aluminum matrix. Manganese dissolves in aluminum or forms Al₆Mn intermetallic phases, increasing the alloy's mechanical strength, corrosion resistance, and recrystallization control. It also functions as a grain stabilizer and iron neutralizer, improving alloy cleanliness and performance.
Structural Features:
MANGANESE-ADDED ALUMINUM MASTER ALLOY (AlMn)
|
Al Matrix + Mn Phases / Al₆Mn
|
+----------------+----------------+
| | |
Al₆Mn Phase Grain Iron
(Strength) Stabilizer Neutralizer
2.2. Structural Properties
| Parameter | Value |
|---|---|
| Crystal Structure | Al matrix (FCC) + Al₆Mn intermetallic phases |
| Density | ~2.7 g/cm³ (Al-based matrix) |
| Melting Point | ~660 °C |
| Appearance | Silver-gray metallic waffle, rod or wire |
| Physical Forms | Coil, Stick, Waffle Ingot |
3. COMMERCIAL VARIANTS AND COMPOSITIONS
3.1. AlMn Master Alloy Variants
| Variant | Manganese (Mn) Content | Aluminum (Al) Content | Description |
|---|---|---|---|
| AlMn10 | 9.0 – 11.0% | Remainder | Low manganese content, standard applications |
| AlMn20 | 18.0 – 22.0% | Remainder | Medium manganese content, special applications |
| AlMn30 | 28.0 – 32.0% | Remainder | High manganese content, special alloy production |
3.2. Typical Impurity Limits (All Variants)
| Parameter | Max. Value |
|---|---|
| Silicon (Si) | ≤ 0.30% |
| Iron (Fe) | ≤ 0.30% |
| Nickel (Ni) | ≤ 0.05% |
| Copper (Cu) | ≤ 0.05% |
| Other Total Impurities | ≤ 0.10% |
4. PHYSICAL AND CHEMICAL PROPERTIES
| Property | Value | Description |
|---|---|---|
| Appearance | Silver-gray metallic | - |
| Odor | Odorless | - |
| Chemical Composition | Al + Mn | Varies depending on variant |
| Density | ~2.7 g/cm³ | - |
| Melting Point | ~660 °C | - |
| Solubility in Water (25°C) | Insoluble | - |
| Solubility in Acids | Soluble | Releases hydrogen gas |
| Physical Forms | Coil, Stick, Waffle | - |
| Packaging | Boxed waffle ingots, boxed wire/rod, optional vacuum packaging | - |
5. STABILITY AND REACTIVITY
| Parameter | Information |
|---|---|
| Chemical Stability | Stable under normal conditions; forms a passive oxide layer on the surface. |
| Conditions to Avoid | Oxidizing atmosphere at high temperatures, strong acids, moisture. |
| Incompatible Materials | Strong acids, strong bases, oxidizing agents. |
| Hazardous Decomposition Products | Upon oxidation at high temperatures: aluminum oxide (Al₂O₃) and manganese oxide (MnO₂). |
| Hazardous Polymerization | Will not occur. |
| Hygroscopicity | Low; does not absorb moisture under normal conditions. |
5.1. Chemical Reactions
Oxidation (at High Temperature):
4Al + 3O₂ → 2Al₂O₃
2Mn + O₂ → 2MnO
Mn + O₂ → MnO₂
Reaction with Acids:
2Al + 6HCl → 2AlCl₃ + 3H₂↑
Mn + 2HCl → MnCl₂ + H₂↑
6. APPLICATION AREAS
6.1. Manganese Source in Aluminum Alloys
| Application | Function | Details |
|---|---|---|
| Mechanical Strength Increase | Alloy strengthening | Manganese addition increases strength |
| Corrosion Resistance | Passivation and durability | Improves corrosion resistance |
| Recrystallization Control | Grain stabilization | Controls grain structure during heat treatment |
| Iron Neutralization | Impurity control | Neutralizes iron-containing phases |
6.2. Sectoral Applications
| Application | Sector |
|---|---|
| Automotive Radiators, Body Panels | Automotive |
| Roofing, Facade Panels, Structural Sheets | Construction |
| Beverage Cans, Food Packaging | Food Packaging |
| Corrosion-Resistant Aluminum Alloys | Marine |
| Rolled Products, Structural Profiles | Industrial Applications |
6.3. Sectoral Suitability Table
| Sector | Suitability | Explanation |
|---|---|---|
| Automotive | Suitable | Used in radiators and body panels |
| Construction | Suitable | Roofing, facades and structural sheets |
| Food Packaging | Suitable | Mandatory in beverage can alloys |
| Marine | Suitable | In corrosion-resistant aluminum alloys |
| Aerospace | Limited | Limited to non-structural components |
| Electrical/Electronics | Limited | Limited use in special thermal and structural alloys |
7. STANDARDS AND COMPLIANCE
| Standard | Description |
|---|---|
| EN 573 | European aluminum alloy standards |
| ASTM B209 | American aluminum sheet and plate standards |
| JIS H4000 | Japanese aluminum sheet standards |
8. ALTERNATIVE / SUBSTITUTE PRODUCTS
| Alternative | Description | When to Use |
|---|---|---|
| AlMn10 | Low manganese content | Standard applications |
| AlMn20 | Medium manganese content | Applications requiring higher Mn |
| AlMn30 | High manganese content | Special alloy production |
| Pure Manganese | Elemental Mn | Direct alloying, more difficult to dissolve |
| AlMnFe | Iron-containing alternative | Applications requiring iron neutralization |
9. SAFETY AND TOXICOLOGY
| Parameter | Value |
|---|---|
| Acute Oral Toxicity (LD50, Rat) | > 2,000 mg/kg (low toxicity) |
| Dermal Toxicity | Low |
| Skin Irritation | Mild irritant |
| Eye Irritation | Mild to moderate irritant |
| Inhalation | Metal dust inhalation may cause respiratory tract irritation. |
| Carcinogenicity | Not classified as carcinogenic. |
| Mutagenicity | Not mutagenic. |
| Chronic Effects | Long-term data on aluminum and manganese compounds is limited. |
| Environmental Hazards | Low to moderate aquatic toxicity. |
9.1. GHS Classification
| Hazard Class | Category | H-Statement |
|---|---|---|
| Flammable Solid (Metal Dust) | Category 1 | H228: Flammable solid. |
| Skin Irritation | Category 2 | H315: Causes skin irritation. |
| Eye Irritation | Category 2A | H319: Causes serious eye irritation. |
| Specific Target Organ Toxicity | Category 3 | H335: May cause respiratory irritation. |
Signal Word: WARNING
Hazard Pictograms: GHS02 (Flame), GHS07 (Exclamation Mark)
10. STORAGE AND SHELF LIFE
| Parameter | Condition |
|---|---|
| Storage Conditions | Store in a cool, dry, and well-ventilated area. |
| Container Requirements | Dry, moisture-free environment; store in original packaging. |
| Temperature | Room temperature (15-25°C). |
| Shelf Life | Unlimited under appropriate conditions (except surface oxidation). |
| Stability Note | Stable under normal conditions; forms a passive oxide layer on the surface. |
11. PACKAGING OPTIONS
| Packaging Type | Quantity | Material |
|---|---|---|
| Waffle Ingot | 5 kg, 10 kg, 20 kg | Boxed protected, optional vacuum packaging |
| Stick / Rod | 1 kg, 5 kg, 10 kg | Boxed, plastic wrap or coated metal cases |
| Wire / Coil | 1 kg, 5 kg, 10 kg, 25 kg | Boxed, moisture-proof plastic bags or drums |
| Granule | 1 kg, 5 kg, 10 kg, 25 kg | Moisture-proof plastic bags or drums |
12. TRANSPORT INFORMATION
| Parameter | Information |
|---|---|
| UN Number | Not classified (specific regulations apply for metal alloys) |
| Hazard Class | - |
| Packing Group | - |
| ADR/RID | Not regulated (except powder form) |
| IMDG | Not regulated (except powder form) |
| IATA | Not regulated (except powder form) |
| HS Code | 7601.20.00.00.00 (Unwrought aluminum alloys) |
13. REGULATORY STATUS
| Region / Authority | Status |
|---|---|
| European Union (REACH) | Registered as an alloy; evaluated by components |
| Turkey (KKDIK) | Compliance required |
| TSCA (USA) | Registered |
| China | Registered; major production and export country |
14. OTHER NAMES AND SYNONYMS
| Name | Description |
|---|---|
| AlMn Master Alloy | Common name |
| AlMn10 / AlMn20 / AlMn30 | Manganese-containing variants |
| Manganese-Aluminum Modifier | Functional name |
| Mn-Added Aluminum Alloy | Descriptive name |
| AlMn Waffle | Physical form name |
| AlMn Additive Rod | Usage description |
| Mn Alloy Block | Usage description |
15. QUICK REFERENCE TABLE
| Property | Value |
|---|---|
| Density | ~2.7 g/cm³ |
| Melting Point | ~660 °C |
| Manganese Content (Variant Dependent) | 9% – 32% |
| Physical Forms | Coil, Stick, Waffle, Granule |
| HS Code | 7601.20.00.00.00 |
| GHS Signal Word | WARNING |
16. CRITICAL WARNINGS AND BEST PRACTICES
CRITICAL WARNINGS:
Manganese Addition: AlMn master alloy provides mechanical strength, corrosion resistance, and recrystallization control in aluminum alloys. It is a critical additive especially in 3xxx series alloys.
Iron Neutralization: Manganese neutralizes iron impurities in the alloy, reducing their negative effects and improving alloy quality.
Quality and Origin: Phase stability and impurity control are critical for corrosion resistance and mechanical performance. Trader-sourced products may show variability in purity and origin.
Oxidation: Oxidizes in oxidizing atmospheres at high temperatures; inert atmosphere or vacuum is required for melting operations.
Acid Reactivity: Reacts with strong acids releasing hydrogen gas.
BEST PRACTICE RECOMMENDATIONS:
Storage:
Store in a cool, dry, and well-ventilated area.
Store in original packaging, moisture-free environment.
Keep away from acids and oxidizing agents.
Store at room temperature (15-25°C).
Handling:
Add to molten aluminum bath in controlled amounts.
Calculate correct dosage to achieve target Mn ratio.
Ensure proper mixing conditions for optimum homogenization.
Use vacuum or inert atmosphere (Ar, N₂) for melting operations.
Waste Management:
Dispose of in accordance with local regulations.
Do not discharge into water sources.
For large quantities, aluminum and manganese recovery should be considered.
LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Manganese-Added Aluminum master alloy is a critical additive material for corrosion resistance and mechanical strength in the aluminum industry; correct variant selection and application conditions directly affect final alloy performance.