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Send EmailAlTiC Master Alloy, AlTi5C, AlTi3C, Carbon Grain Refiner, AlTiC Stick, Coil, AlTi Wire, AlTiC Rod, 7440-32-6, 7440-44-0, 7429-90-5
| Property | Information |
|---|---|
| Product Name | Aluminum Titanium Carbon Master Alloy (AlTiC) |
| Synonyms | AlTiC master alloy, Carbon-added grain refiner, AlTiC stick, AlTiC coil, Grain refiner with carbon |
| Composition | Aluminum (Al) + Titanium (Ti) + Carbon (C) |
| CAS Numbers | 7429-90-5 (Aluminum) 7440-32-6 (Titanium) 7440-44-0 (Carbon) |
| Appearance | Gray metallic solid |
| Forms | Rod (stick), Coil (spiral/wire), Waffle ingot |
Note: The alloy itself does not have a dedicated CAS number; the constituent elements are used for identification.
| Grade | Titanium (Ti) % | Carbon (C) % | Aluminum (Al) % | Ti:C Ratio (approx) |
|---|---|---|---|---|
| AlTi5C0.15 | 4.5 – 5.5 | 0.12 – 0.20 | Balance | ~30:1 |
| AlTi3C0.15 | 2.6 – 3.5 | 0.10 – 0.18 | Balance | ~20:1 |
| AlTi5C0.2 | 4.5 – 5.5 | 0.15 – 0.25 | Balance | ~25:1 |
| AlTi3C0.1 | 2.6 – 3.5 | 0.08 – 0.15 | Balance | ~25:1 |
Typical Specifications (AlTi5C0.15):
| Element | Specification (wt%) |
|---|---|
| Titanium (Ti) | 4.5 – 5.5 |
| Carbon (C) | 0.12 – 0.20 |
| Iron (Fe) | ≤ 0.30 |
| Silicon (Si) | ≤ 0.20 |
| Vanadium (V) | ≤ 0.10 |
| Other (each) | ≤ 0.03 |
| Aluminum (Al) | Balance |
| Property | Value |
|---|---|
| Density (20°C) | ~2.7 g/cm³ (similar to pure aluminum) |
| Melting Point | ~660 °C (1,220 °F) – similar to aluminum |
| Appearance | Gray, metallic luster |
| Forms | Rod (stick), Coil (spiral/wire), Waffle ingot |
| Thermal Conductivity | Similar to aluminum (~237 W/(m·K)) |
| Electrical Conductivity | Similar to aluminum (good conductor) |
| Property | Information |
|---|---|
| Chemical Class | Metal alloy (Al-Ti-C system) |
| Active Phase | TiC (Titanium Carbide) particles |
| TiC Particle Size | 0.5 – 5 µm (typically) |
| Reactivity | Reacts with oxygen at high temperatures (oxidation) |
| Solubility in Aluminum | Ti and C form stable TiC particles; minimal dissolution |
| Stability | TiC particles are thermodynamically stable in molten Al |
| Poisoning Resistance | Excellent (no Si poisoning) |
Key Intermetallic Phase:
| Phase | Formula | Role |
|---|---|---|
| TiC | Titanium Carbide | Primary nucleation site for α-Al grains |
Comparison of Active Phases:
| Master Alloy | Active Phase | Particle Size | Stability in Molten Al |
|---|---|---|---|
| AlTiC | TiC | 0.5-5 µm | Very stable |
| AlTiB | TiB₂ | 0.5-5 µm | Stable, but poisoned by Si |
| AlTi | TiAl₃ | 10-50 µm | Dissolves in melt |
| Stage | Description |
|---|---|
| 1. Addition | AlTiC master alloy is added to molten aluminum (typically 700-750°C) |
| 2. Dissolution | The aluminum matrix dissolves, releasing TiC particles |
| 3. Particle Distribution | TiC particles disperse uniformly in the melt |
| 4. Nucleation | TiC particles act as heterogeneous nucleation sites for α-Al grains |
| 5. Grain Growth Restriction | Dissolved Ti creates a growth-restricting zone |
| 6. Refined Structure | Result: Fine, equiaxed grain structure |
Why AlTiC is Preferred for High-Si Alloys:
| Alloy Type | AlTiB Performance | AlTiC Performance |
|---|---|---|
| Low Si (<3%) | Excellent | Good |
| Medium Si (3-7%) | Moderate (some poisoning) | Excellent |
| High Si (>7%) | Poor (severe poisoning) | Excellent |
| Hyper-eutectic (>12% Si) | Very Poor (ineffective) | Good to Excellent |
| Application | Alloy Series | Function |
|---|---|---|
| Engine Blocks | AlSi7Mg, AlSi9Cu3, AlSi12Cu | Grain refinement without poisoning |
| Cylinder Heads | AlSi7Mg, AlSi10Mg | Improved mechanical properties |
| Pistons | AlSi12, AlSi18 (hyper-eutectic) | Fine grain structure |
| Cylinder Liners | AlSi17Cu4Mg | Wear resistance improvement |
| Application | Alloy Series | Function |
|---|---|---|
| Wheels (Rims) | A356, A357 | Improved fatigue resistance |
| Chassis Components | AlSi10Mg | Better ductility |
| Suspension Parts | AlSi7Mg | Enhanced mechanical properties |
| Heat Exchangers | 3xxx series | Improved formability |
| Application | Alloy Series | Function |
|---|---|---|
| High-Strength Castings | A356, A357 | Grain refinement for critical components |
| Structural Parts | 2xxx, 6xxx, 7xxx | Homogeneous microstructure |
| Application | Function |
|---|---|
| Sand Casting | Grain refinement for various alloys |
| Permanent Mold Casting | Improved mechanical properties |
| Low Pressure Die Casting (LPDC) | Uniform grain structure |
| High Pressure Die Casting (HPDC) | Reduced hot tearing |
| Application | Function |
|---|---|
| Extrusion Billets | Grain refinement for 6xxx series |
| Rolling Ingots | Uniform grain structure for sheet and plate |
| Wire Rods | Fine grain for drawing |
| Property | AlTiC | AlTiB |
|---|---|---|
| Active Phase | TiC (Titanium Carbide) | TiB₂ (Titanium Diboride) |
| Ti Content | 3-5% | 3-5% |
| Active Element | 0.1-0.2% C | 0.8-1.2% B |
| Grain Refining Efficiency (Low Si) | Good | Excellent |
| Grain Refining Efficiency (High Si) | Excellent | Poor (poisoned by Si) |
| Fading Resistance | Excellent | Moderate |
| Poisoning by Si | None | Severe (>7% Si) |
| Cost | Higher | Lower |
| Primary Application | High-Si alloys, critical castings | General aluminum alloys |
Selection Guide:
| Condition | Recommended Master Alloy |
|---|---|
| Si < 3% | AlTiB (lower cost) or AlTiC |
| Si = 3-7% | AlTiC (safer) or AlTiB (test first) |
| Si > 7% | AlTiC (required) |
| Hyper-eutectic (>12% Si) | AlTiC (only option) |
| Long holding times | AlTiC (better fading resistance) |
| Critical castings (aerospace) | AlTiC (more reliable) |
| Application | Typical Addition Rate (kg/ton) | Notes |
|---|---|---|
| Low Si Alloys (<3% Si) | 0.5 – 1.5 | Similar to AlTiB |
| Medium Si Alloys (3-7% Si) | 1.0 – 2.0 | Higher rate recommended |
| High Si Alloys (>7% Si) | 1.5 – 2.5 | Required for effective refinement |
| Hyper-eutectic Alloys | 2.0 – 3.0 | Specialized application |
Target Titanium Level in Melt: 0.005 – 0.020% Ti (50-200 ppm)
Formula:
Addition rate (kg/ton) = (Target Ti% - Initial Ti%) × 1000 / Ti% in master alloy
Example: Target Ti = 0.015%, Initial Ti = 0%, Master alloy Ti = 5%
Addition = (0.015 - 0) × 1000 / 5 = 3 kg/ton
| Form | Dimensions | Application |
|---|---|---|
| Rod (Stick) | Ø9.5 mm, Ø12.5 mm, Ø15 mm | Manual addition, continuous wire feeder |
| Coil (Spiral) | Various diameters, continuous length | Automated feeding systems |
| Waffle Ingot | 5-10 kg pieces | Manual addition to furnaces |
| Button (Pig) | 0.5-1 kg pieces | Small batch addition |
| Cut Pieces | 10-50 mm length | Pre-measured addition |
| Advantage | Description |
|---|---|
| No Silicon Poisoning | TiC particles are stable in high-Si melts; no loss of efficiency |
| Superior Fading Resistance | TiC particles do not settle or agglomerate; longer holding times possible |
| Finer Grain Structure | Produces more uniform, finer grains than AlTiB in many alloys |
| Improved Mechanical Properties | Higher strength, ductility, and fatigue resistance |
| Better Surface Quality | Reduced surface defects in castings |
| Compatible with Alloy Types | Works with AlSi, AlMg, AlCu, AlZn alloys |
| Reduced Scrap Rates | More consistent grain refinement |
| Parameter | Information |
|---|---|
| Storage Conditions | Cool, dry, well-ventilated area |
| Container Requirements | Original packaging (cartons, vacuum bags, wooden crates) |
| Protect From | Moisture, water, corrosive environments |
| Shelf Life | Indefinite (when stored properly in dry conditions) |
| Packaging Options | Cartons (rods), vacuum-sealed bags (coils), wooden crates (waffle ingots) |
| Hazard Class | Category |
|---|---|
| Not classified as hazardous (for solid bulk form) | – |
Notes:
The solid master alloy is not classified as hazardous under normal handling conditions.
Fine dust (from grinding or machining) may be combustible.
Fumes from melting may cause metal fume fever.
| Exposure Route | Action |
|---|---|
| Inhalation (Dust/Fumes) | Remove to fresh air. Seek medical attention if respiratory irritation occurs. |
| Skin Contact | Wash with soap and water. |
| Eye Contact | Rinse with plenty of water for 15 minutes. |
| Ingestion | Unlikely for solid form. Seek medical attention if large pieces swallowed. |
| Equipment | Recommendation |
|---|---|
| Respiratory Protection | Dust mask (when grinding); fume respirator (when melting) |
| Hand Protection | Heat-resistant gloves (for handling hot ingots) |
| Eye Protection | Safety glasses with side shields |
| Body Protection | Heat-resistant apron, protective clothing |
| Parameter | Information |
|---|---|
| Biodegradability | Not applicable (inorganic metal alloy) |
| Aquatic Toxicity | Low; aluminum, titanium, carbon are naturally occurring elements |
| Recyclability | 100% recyclable |
| Waste Disposal | Recycle as scrap metal. Dispose according to local regulations. |
| Parameter | Information |
|---|---|
| UN Number | Not regulated (solid metal) |
| Hazard Class | None |
| Packing Group | Not applicable |
| Marine Pollutant | No |
| Sector | Compatibility | Description |
|---|---|---|
| Automotive | High | Engine blocks, cylinder heads, wheels, chassis components |
| Aerospace | High | High-strength aluminum alloy castings |
| General Casting | High | Sand, permanent mold, low/high pressure die casting |
| Extrusion | Limited | Primarily for billet casting; not added during extrusion |
| Construction | Limited | Not typically required for standard profiles |
| Food Packaging | Not suitable | Not used in food contact applications |
| Electrical/Electronics | Limited | Some specialty alloy applications |
| Turkish Name | English Name |
|---|---|
| Alüminyum Titanyum Karbon Alaşımı | Aluminum Titanium Carbon Alloy |
| AlTiC Master Alaşımı | AlTiC Master Alloy |
| Karbonlu Tane İnceltici | Carbon-added Grain Refiner |
| AlTiC Çubuk / Tel | AlTiC Rod / Wire |
| AlTiC Spiral | AlTiC Coil |
| AlTiC Petek Külçe | AlTiC Waffle Ingot |
| AlTi5C0.15 / AlTi3C0.15 | AlTi5C0.15 / AlTi3C0.15 |
Aluminum Titanium Carbon (AlTiC) Master Alloy is a carbon-added grain refiner for aluminum and aluminum alloys, specifically designed for applications where AlTiB is ineffective due to silicon poisoning.
Key Features:
| Feature | Value |
|---|---|
| Appearance | Gray metallic solid |
| Density | ~2.7 g/cm³ |
| Melting Point | ~660°C |
| Forms | Rod (stick), Coil, Waffle ingot |
Standard Grades:
| Grade | Ti (%) | C (%) | Primary Application |
|---|---|---|---|
| AlTi5C0.15 | 4.5-5.5 | 0.12-0.20 | High-performance, general use |
| AlTi3C0.15 | 2.6-3.5 | 0.10-0.18 | Lower cost, less demanding |
Main Application Areas:
| Sector | Applications |
|---|---|
| Automotive | Engine blocks, cylinder heads, wheels, chassis |
| Aerospace | High-strength aluminum alloy castings |
| General Casting | Sand, permanent mold, HPDC, LPDC |
| AlSi Alloys | All AlSi alloys (especially >7% Si) |
Key Advantages over AlTiB:
No silicon poisoning – Effective in high-Si alloys
Superior fading resistance – Longer holding times
More consistent results – Reliable grain refinement
Primary Application – High-Si Alloys: AlTiC is specifically designed for aluminum-silicon alloys where AlTiB suffers from "silicon poisoning." For alloys with >7% Si, AlTiC is the recommended grain refiner.
Silicon Poisoning Mechanism: In AlTiB, silicon reacts with TiB₂ particles to form TiSi₂ and release boron, which reduces or eliminates grain refining efficiency. TiC particles in AlTiC are not attacked by silicon, maintaining their effectiveness.
Fading Resistance: TiC particles have excellent stability in molten aluminum. They do not settle, agglomerate, or dissolve over time. This allows longer holding times (up to 2-3 hours) without loss of grain refining efficiency.
TiC Particle Size: The grain refining efficiency of AlTiC depends on TiC particle size. Optimal particle size range is 0.5-5 µm. Particles that are too large (>10 µm) are less effective; particles that are too small (<0.2 µm) may agglomerate.
Addition Temperature: Recommended addition temperature is 700-750°C (similar to AlTiB). Lower temperatures may cause incomplete dissolution of the aluminum matrix. Higher temperatures increase oxidation and hydrogen pickup.
Dosage Comparison with AlTiB: For high-Si alloys, AlTiC may require slightly higher addition rates (1.5-2.5 kg/ton) compared to AlTiB in low-Si alloys (0.5-1.5 kg/ton). This is due to the lower active element content (C vs B).
Cost Consideration: AlTiC is generally more expensive than AlTiB due to higher raw material cost (carbon source) and more complex manufacturing. However, for high-Si applications where AlTiB fails, AlTiC is the only effective option.
Forms Selection:
Rod (Stick): For manual addition and continuous wire feeders
Coil (Spiral): For automated feeding systems
Waffle Ingot: For manual addition to large furnaces
Storage: Store in dry conditions. Aluminum master alloys can develop aluminum hydroxide (white powder) on the surface if stored in humid conditions. Vacuum-sealed packaging is recommended for long-term storage.
Recycling: AlTiC master alloys are 100% recyclable. Scrap material can be returned to the manufacturer or recycled as aluminum scrap.
Important Disclaimer: This Technical Data Sheet (TDS) is for informational purposes only. For complete safety, handling, storage, and regulatory compliance information, always refer to the official Safety Data Sheet (SDS) provided by the manufacturer/supplier.