Do you have questions? Let's talk! Get in Contact
info@betakim.com.tr

Neodymium Phosphate, Neodymium Laser Salt, Nd Phosphate Crystal, 13768-24-0

Neodymium Phosphate, Neodymium Laser Salt, Nd Phosphate Crystal, 13768-24-0

NEODYMIUM PHOSPHATE (NDPO₄)
NEODYMIUM PHOSPHATE / ND PHOSPHATE CRYSTAL / PURPLE PHOSPHATE ADDITIVE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Neodymium Phosphate
Chemical Name Neodymium Phosphate, Neodymium(III) Phosphate
Other Names Neodymium-Doped Laser Salt, Nd Phosphate Crystal, Purple Phosphate Additive, NdPO₄
Chemical Formula NdPO₄
CAS Number 13768-24-0
EC Number (EINECS) None (considered as a mixture)
Appearance Light purple-white crystal or powder
Odor Odorless
Physical State (20°C) Solid (crystal or powder)

2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Neodymium phosphate is the phosphate salt of the rare earth element neodymium. It has the formula NdPO₄ and exists in a monoclinic crystal structure. It is known for its high refractive index and optical properties suitable for laser transmission. It has excellent thermal stability at high temperatures and is used in optical and ceramic applications.

Structural Features:

                    NEODYMIUM PHOSPHATE [NdPO₄]
                          |
                Nd³⁺ - PO₄³⁻ Ionic Bonds
                          |
        +----------------+----------------+
        |                |                |
    Monoclinic         High            Suitable for
    Crystal           Refractive       Laser
    Structure         Index           Transmission

2.2. Structural Properties

Parameter Value
Crystal Structure Monoclinic
Chemical Formula NdPO₄
Molecular Weight ~239.2 g/mol
Density ~4.5–5.0 g/cm³
Appearance Light purple-white crystal or powder
Melting Point >1500 °C
Refractive Index High

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance Light purple-white crystal or powder Varies depending on particle size
Odor Odorless -
Chemical Formula NdPO₄ -
Molecular Weight ~239.2 g/mol -
Density ~4.5–5.0 g/cm³ -
Melting Point >1500 °C -
Solubility in Water (25°C) Insoluble -
Solubility in Acids Limited solubility -
Solubility in Alcohol Insoluble -
Optical Properties High refractive index Suitable for laser transmission
Thermal Stability Stable at high temperatures Stable up to >1500°C
Hygroscopicity Low -

4. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Thermally stable at high temperatures; inert under normal conditions.
Conditions to Avoid Strong acids, highly reducing environments.
Incompatible Materials Strong acids, strong reducing agents.
Hazardous Decomposition Products Upon oxidation at high temperatures: neodymium oxide (Nd₂O₃) and phosphorus oxide (P₂O₅).
Hazardous Polymerization Will not occur.
Hygroscopicity Low; does not absorb moisture under normal conditions.

4.1. Chemical Reactions

  • Thermal Stability: NdPO₄ is stable up to >1500°C; may decompose to oxides at higher temperatures.

  • Reaction with Acids: Shows limited solubility in strong acids.

5. PRODUCTION PROCESS

Stage Process Description
1. Raw Material Preparation Neodymium oxide (Nd₂O₃) and phosphoric acid (H₃PO₄) High purity materials obtained
2. Reaction Nd₂O₃ reacted with H₃PO₄ NdPO₄ precipitate formed
3. Precipitation Phosphate precipitate obtained Controlled pH and temperature
4. Filtration Precipitate separated and washed Impurities removed
5. Drying Product dried Under controlled conditions
6. Sintering (Optional) Crystal form achieved High temperature treatment
7. Quality Control Phase analysis and optical testing XRD, spectroscopy
8. Packaging Packaged in moisture-proof containers -

5.1. Major Producing Countries and Companies

Country Companies
China Various rare earth producers
Germany Treibacher, Alfa Aesar
Japan Advanced ceramic and optical producers
USA Sigma-Aldrich, Alfa Aesar

6. APPLICATION AREAS
6.1. Laser and Optical Applications

Application Function Details
Laser Crystal Production Dopant Used in Nd:YAG and Nd:Glass systems.
Optical Fiber Amplifiers Signal amplification Used in fiber optic communication systems.
Optical Coatings Surface treatment Special optical applications.

6.2. Defense and Medical

Application Function Details
Defense Electronics High-power laser systems Radar and targeting systems.
Medical Laser Devices Surgery and imaging Eye and skin surgery.

6.3. Ceramic and Glass Additive

Application Function Details
Ceramic Additive Optical property improvement Phosphate-based magnetic ceramics.
Glass Additive Refractive index adjustment Special optical glasses.

6.4. Nuclear and Environmental Applications

Application Function Details
Nuclear Waste Immobilization Phosphate matrix Safe storage of waste.
Ion Exchange Systems Water treatment Special filtration applications.

6.5. Sectoral Suitability Table

Sector Suitability Explanation
Optics Suitable Laser crystal doping, optical fiber
Electronics Suitable Fiber amplifiers, ceramics
Defense Suitable Laser systems, radar optics
Medical Suitable Laser surgery, imaging
Nuclear Suitable Waste immobilization
Food Not Suitable Not suitable
Textile Not Suitable Not suitable

7. ALTERNATIVE / SUBSTITUTE PRODUCTS

Alternative Description When to Use
Lanthanum Phosphate (LaPO₄) Similar optical properties Alternative rare earth compound
Samarium Phosphate (SmPO₄) Alternative rare earth dopant Different optical properties
Yttrium Phosphate (YPO₄) Common in laser crystals More widespread use
Neodymium Oxide + Phosphoric Acid In-situ synthesis alternative Applications requiring on-site synthesis

8. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 2,000 mg/kg (low toxicity)
Dermal Toxicity Low
Skin Irritation Mild irritant
Eye Irritation Mild to moderate irritant
Inhalation Dust inhalation may cause respiratory tract irritation.
Carcinogenicity Not classified as carcinogenic.
Mutagenicity Not mutagenic.
Chronic Effects Long-term data on rare earth and phosphate compounds is limited.
Environmental Hazards Low to moderate aquatic toxicity; phosphate content may cause eutrophication risk.

8.1. GHS Classification

Hazard Class Category H-Statement
Skin Irritation Category 2 H315: Causes skin irritation.
Eye Irritation Category 2A H319: Causes serious eye irritation.
Specific Target Organ Toxicity Category 3 H335: May cause respiratory irritation.

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

9. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, and well-ventilated area.
Container Requirements Moisture-proof, tightly closed containers.
Temperature Room temperature (15-25°C).
Shelf Life Unlimited under appropriate conditions (due to stable crystal structure).
Stability Note Stable under normal conditions; keep away from acids.

10. PACKAGING OPTIONS

Packaging Type Quantity Material
Plastic Bag 100 g, 500 g, 1 kg, 5 kg Moisture-proof, sealed bag
Plastic Drum 10 kg, 25 kg HDPE drum, moisture-proof
Glass Bottle 10 g, 50 g, 100 g Amber glass bottle, sealed with airtight cap

11. TRANSPORT INFORMATION

Parameter Information
UN Number Not classified
Hazard Class -
Packing Group -
ADR/RID Not regulated
IMDG Not regulated
IATA Not regulated
HS Code 2846.90.00.00.00 (Rare earth compounds)

12. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Generally not registered; used in special optical applications
Turkey (KKDIK) Compliance required
TSCA (USA) Registered
China Registered; major production and export country

13. OTHER NAMES AND SYNONYMS

Name Description
NdPO₄ Chemical formula
Neodymium-Doped Laser Salt Application description
Nd Phosphate Crystal Commercial name
Purple Phosphate Additive Color description
Neodymium Phosphate English name
Neodymium(III) Phosphate Chemical name

Database Identifiers:

  • CAS: 13768-24-0

  • HS Code: 2846.90.00.00.00

14. QUICK REFERENCE TABLE

Property Value
CAS Number 13768-24-0
Chemical Formula NdPO₄
Molecular Weight ~239.2 g/mol
Appearance Light purple-white crystal or powder
Density ~4.5–5.0 g/cm³
Melting Point >1500 °C
Crystal Structure Monoclinic
HS Code 2846.90.00.00.00

15. CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • High Temperature Stability: NdPO₄ is stable up to >1500°C; suitable for high-temperature optical and ceramic applications.

  • Optical Properties: With its high refractive index and properties suitable for laser transmission, it is a critical dopant in Nd:YAG and Nd:Glass systems.

  • Chemical Resistance: Shows limited solubility in acidic environments; chemically inert.

  • Phosphate Content: Environmental phosphate release may cause eutrophication; waste management should be carefully considered.

  • Powder Hazard: Powder form may cause respiratory tract irritation; appropriate dust control measures must be taken.

BEST PRACTICE RECOMMENDATIONS:

  • Storage:

    • Store in a cool, dry, and well-ventilated area.

    • Use moisture-proof containers.

    • Keep away from acids and reducing agents.

    • Store at room temperature (15-25°C).

  • Handling:

    • If in powder form, use in well-ventilated areas.

    • Use a dust mask (N95 or better), protective goggles, and gloves.

    • Avoid dust formation and inhalation.

    • Wash hands thoroughly after handling.

    • Use controlled sintering conditions for laser crystal production.

  • Waste Management:

    • Dispose of in accordance with local regulations.

    • Do not discharge into water sources (phosphate eutrophication risk).

    • For large quantities, rare earth recovery should be considered.

LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Neodymium phosphate is a specialty material for optical and laser applications, notable for its high-temperature stability and optical properties; environmental effects due to phosphate content should be carefully considered.

Images

Do you have questions? Let us help!

Effective Business Solutions? — Get in Contact
Scroll