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Send EmailNeodymium Carbonate, Neodymium Carbonate Hydrate, Neodymium Tricarbonate, 38245-38-4
NEODYMIUM CARBONATE HYDRATE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY
| Parameter | Information |
|---|---|
| Product Name | Neodymium Carbonate Hydrate |
| Chemical Name | Neodymium(III) Carbonate Hydrate |
| Other Names | Neodymium Carbonate Salt, NdFeB Precursor, Glass Additive Carbonate, Light Purple Crystalline Powder |
| CAS Number | 38245-38-4 |
| EC Number (EINECS) | 253-808-2 |
| Chemical Formula | Nd₂(CO₃)₃·xH₂O (x = 2 to 8) |
| Molecular Weight | ~468.5 g/mol (depending on the degree of hydration) |
| Appearance | Light purple-white crystalline powder |
| Odor | Odorless |
| Physical State (20°C) | Solid (crystalline powder) |
2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Neodymium carbonate hydrate is the carbonate salt of the rare earth element neodymium. It consists of neodymium ions (Nd³⁺) and carbonate ions (CO₃²⁻) in a 2:3 ratio. The molecule contains a variable number of water molecules of hydration (typically 2-8 moles of H₂O). It is insoluble in water but readily dissolves in mineral acids, releasing carbon dioxide gas and forming neodymium salts. It is not hygroscopic and is stable under dry conditions.
Structural Features:
NEODYMIUM CARBONATE HYDRATE [Nd₂(CO₃)₃·xH₂O]
|
Nd³⁺ - CO₃²⁻ Ionic Bonds
|
+----------------+----------------+
| | |
Trigonal Insoluble Soluble in
Crystal in Mineral
Structure Water Acids
2.2. Structural Properties
| Parameter | Value |
|---|---|
| Crystal System | Trigonal |
| Molecular Weight | ~468.5 g/mol (depending on hydration) |
| Density | ~3.5 g/cm³ |
| Appearance | Light purple-white crystalline powder |
| Melting Point | Decomposes upon heating (thermal decomposition) |
| pH (suspension) | Slightly basic (~7.5-8.5) |
3. PHYSICAL AND CHEMICAL PROPERTIES
| Property | Value | Description |
|---|---|---|
| Appearance | Light purple-white crystalline powder | Color intensity depends on purity |
| Odor | Odorless | - |
| Chemical Formula | Nd₂(CO₃)₃·xH₂O | - |
| Molecular Weight | ~468.5 g/mol | Depends on the degree of hydration |
| Density | ~3.5 g/cm³ | - |
| Melting Point | Decomposes upon heating (thermal decomposition) | - |
| Solubility in Water (25°C) | Insoluble | - |
| Solubility in Mineral Acids | Soluble | Dissolves releasing CO₂ gas |
| Solubility in Alcohol | Insoluble | - |
| pH (suspension) | Slightly basic (~7.5-8.5) | - |
| Stability | Not hygroscopic; stable under dry conditions | - |
| Hygroscopicity | Low | - |
4. PURITY GRADES
| Parameter | Technical Grade | High Purity Grade | Analytical Grade | Ultra-High Purity Grade |
|---|---|---|---|---|
| Purity | ≥ 99.0% | ≥ 99.5% | ≥ 99.9% | ≥ 99.99% |
| Nd₂(CO₃)₃ Content | ≥ 99.0% | ≥ 99.5% | ≥ 99.9% | ≥ 99.99% |
| Other Rare Earths | ≤ 1.0% | ≤ 0.5% | ≤ 0.1% | ≤ 0.01% |
| Heavy Metals (Pb) | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm | ≤ 5 ppm |
| Iron (Fe) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Calcium (Ca) | ≤ 100 ppm | ≤ 50 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Sodium (Na) | ≤ 1000 ppm | ≤ 500 ppm | ≤ 100 ppm | ≤ 50 ppm |
| Chloride (Cl⁻) | ≤ 0.1% | ≤ 0.05% | ≤ 0.02% | ≤ 0.01% |
| Sulfate (SO₄²⁻) | ≤ 0.2% | ≤ 0.1% | ≤ 0.05% | ≤ 0.02% |
| Nitrate (NO₃⁻) | ≤ 0.2% | ≤ 0.1% | ≤ 0.05% | ≤ 0.02% |
| Loss on Drying (H₂O) | Variable | Variable | Variable | Variable |
| Particle Size (D50) | 10-50 µm | 5-20 µm | 1-10 µm | < 5 µm |
5. STABILITY AND REACTIVITY
| Parameter | Information |
|---|---|
| Chemical Stability | Not hygroscopic; stable under dry, closed conditions. |
| Conditions to Avoid | High temperatures (>300°C), strong acids, moisture (low sensitivity). |
| Incompatible Materials | Strong acids (releases CO₂ gas), strong oxidizing agents. |
| Hazardous Decomposition Products | At high temperatures: neodymium oxide (Nd₂O₃) and carbon dioxide (CO₂). |
| Hazardous Polymerization | Will not occur. |
| Hygroscopicity | Low; does not absorb moisture under normal conditions. |
5.1. Chemical Reactions
Thermal Decomposition:
Nd₂(CO₃)₃·xH₂O → Nd₂O₃ + 3CO₂↑ + xH₂O (at ~300-400°C)
Reaction with Acids:
Nd₂(CO₃)₃ + 6HCl → 2NdCl₃ + 3CO₂↑ + 3H₂O
Nd₂(CO₃)₃ + 6HNO₃ → 2Nd(NO₃)₃ + 3CO₂↑ + 3H₂O
6. APPLICATION AREAS
6.1. NdFeB Magnet Production
| Application | Function | Details |
|---|---|---|
| NdFeB Magnet Production | Precursor for Nd₂O₃ via thermal conversion | Converted to Nd₂O₃ by calcination, used in Nd metal production. |
| Magnet Alloying | Nd source | Used as Nd₂O₃ after thermal decomposition in metallurgical processes. |
6.2. Glass and Ceramic Industry
| Application | Function | Details |
|---|---|---|
| Glass Coloring | Colorant | Imparts purplish tones to glass. |
| UV Filtering | UV absorber | Controls UV transmittance of glass. |
| Ceramic Glazes | Color and gloss | Provides purplish tones and gloss to ceramic glazes. |
6.3. Pigment and Paint Industry
| Application | Function | Details |
|---|---|---|
| Pigment Production | Colorant additive | Used in pigment production for purplish tones. |
| Paint Additive | Colorant | Used as a color tone adjuster in specialty paints. |
6.4. Laboratory and Research
| Application | Function | Details |
|---|---|---|
| Analytical Reagent | Rare earth precipitation | Used in precipitation of rare earth elements. |
| Rare Earth Separation | Carbonate precipitation | Used in purification processes. |
| Synthesis Precursor | Starting material | Synthesis of other neodymium compounds. |
| Standard Preparation | Reference material | Used as a reference for calibration and analysis. |
6.5. Organic Synthesis
| Application | Function | Details |
|---|---|---|
| Nd Source | Soluble in acidic media | Provides Nd³⁺ ion source by dissolving in acidic media. |
7. PRODUCTION PROCESS
7.1. Raw Material Sources
Neodymium carbonate is produced from neodymium-containing solutions:
| Source Type | Neodymium Form | Major Regions |
|---|---|---|
| Neodymium Nitrate (Nd(NO₃)₃) | Soluble salt | China, India, USA |
| Neodymium Chloride (NdCl₃) | Soluble salt | China, India |
| Neodymium Sulfate | Soluble salt | China, Brazil |
7.2. Production Process Flow
Neodymium Nitrate or Chloride Solution
↓
Precipitation with Sodium Carbonate (Na₂CO₃) or Ammonium Carbonate
↓
Reaction: 2Nd³⁺ + 3CO₃²⁻ + xH₂O → Nd₂(CO₃)₃·xH₂O↓
↓
Filtration (Separation of Precipitate)
↓
Washing (Removal of Impurities)
↓
Drying (Under Controlled Conditions)
↓
Neodymium Carbonate Hydrate Powder
↓
Packaging (Moisture-Proof)
7.3. Process Stages
| Stage | Description |
|---|---|
| 1. Solution Preparation | Neodymium nitrate or chloride is dissolved in pure water. |
| 2. Precipitation | Sodium carbonate (Na₂CO₃) or ammonium carbonate solution is added to the solution. |
| 3. Reaction | Nd₂(CO₃)₃·xH₂O precipitate is formed. |
| 4. Filtration | The precipitate is separated by vacuum filtration. |
| 5. Washing | The precipitate is washed with pure water to remove impurities. |
| 6. Drying | The precipitate is dried under controlled conditions at appropriate temperature. |
| 7. Packaging | Packaged in moisture-proof containers. |
8. SECTORAL SUITABILITY TABLE
| Sector | Suitability | Explanation |
|---|---|---|
| Electronics | Suitable | Used in magnets, lasers, and optoelectronic systems. |
| Glass and Ceramics | Suitable | Used as a color and UV control additive. |
| Pigment and Paint | Suitable | Used as a purplish tone additive. |
| Laboratory and R&D | Suitable | Used as a precipitation and analytical reagent. |
| Cosmetics | Not Suitable | Direct use is not appropriate. |
| Food and Pharmaceutical | Not Suitable | Prohibited due to carbonate structure and metal content. |
| Nuclear | Limited | Limited use in specialized applications. |
9. COMPARISON WITH ALTERNATIVE MATERIALS
| Application Area | Alternative Materials | Remarks |
|---|---|---|
| Soluble Nd Source | Neodymium Nitrate (Nd(NO₃)₃) | Water-soluble form; carbonate is insoluble. |
| Glass and Pigment Additive | Neodymium Sulfate (Nd₂(SO₄)₃) | Similar optical properties; different solubility. |
| Thermal Conversion | Neodymium Oxalate | Similarly used for Nd₂O₃ production. |
| Optical Applications | Praseodymium Carbonate (Pr₂(CO₃)₃) | Similar optical applications; different color tones. |
10. SAFETY AND TOXICOLOGY
| Parameter | Value |
|---|---|
| Acute Oral Toxicity (LD50, Rat) | > 2,000 mg/kg (low toxicity) |
| Dermal Toxicity | Low |
| Skin Irritation | Mild irritant |
| Eye Irritation | Mild to moderate irritant |
| Inhalation | Dust inhalation may cause respiratory tract irritation. |
| Carcinogenicity | Not classified as carcinogenic. |
| Mutagenicity | Not mutagenic. |
| Chronic Effects | Rare earth compounds have low bioavailability; however, high doses may cause liver effects. |
| Environmental Hazards | Moderate aquatic toxicity. |
11. GHS CLASSIFICATION
| Hazard Class | Category | H-Statement |
|---|---|---|
| Skin Irritation | Category 2 | H315: Causes skin irritation. |
| Eye Irritation | Category 2A | H319: Causes serious eye irritation. |
| Specific Target Organ Toxicity | Category 3 | H335: May cause respiratory irritation. |
| Hazardous to the Aquatic Environment | Category 3 | H402: Harmful to aquatic life. |
Signal Word: WARNING
Hazard Pictograms: GHS07 (Exclamation Mark)
UN Number: 3077 (Environmentally hazardous substance)
12. PRECAUTIONARY STATEMENTS (P-CODES)
| Code | Statement |
|---|---|
| P261 | Avoid breathing dust. |
| P264 | Wash thoroughly after handling. |
| P271 | Use only in well-ventilated areas. |
| P280 | Wear protective gloves/eye protection/face protection. |
| P302+P352 | IF ON SKIN: Wash with plenty of soap and water. |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing. |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. |
| P337+P313 | If eye irritation persists: Get medical advice/attention. |
| P501 | Dispose of contents/container in accordance with local regulations. |
13. FIRST AID MEASURES
| Exposure Route | Action to Take |
|---|---|
| Inhalation | Remove to fresh air. If symptoms persist, seek medical attention. |
| Skin Contact | Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention. |
| Eye Contact | Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention. |
| Ingestion | Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention. |
14. STORAGE AND SHELF LIFE
| Parameter | Condition |
|---|---|
| Storage Conditions | Store in a cool, dry, and well-ventilated area. |
| Container Requirements | Moisture-proof, tightly closed containers. |
| Temperature | Room temperature (15-25°C). |
| Shelf Life | 24-36 months under appropriate conditions (due to stable structure). |
| Stability Note | Not hygroscopic; stable under normal conditions. Avoid contact with acids. |
15. PACKAGING OPTIONS
| Packaging Type | Quantity | Material |
|---|---|---|
| Aluminum Foil Bag | 1 kg, 5 kg, 10 kg | Double-layered, moisture-proof. |
| Fiber Drum | 25 kg, 50 kg | PE-lined, moisture-proof. |
| Plastic Barrel | 25 kg, 50 kg | HDPE barrel, moisture-proof. |
| Glass Bottle | 100 g, 500 g, 1 kg | Amber glass bottle, sealed with airtight cap. |
16. TRANSPORT INFORMATION
| Parameter | Information |
|---|---|
| UN Number | 3077 (Environmentally hazardous substance) |
| Hazard Class | 9 (Miscellaneous dangerous substances) |
| Packing Group | III |
| ADR/RID | Regulated. |
| IMDG | Regulated. |
| IATA | Regulated. |
| HS Code | 2846.90.00.00.19 (Other rare earth compounds) |
17. REGULATORY STATUS
| Region / Authority | Status |
|---|---|
| European Union (REACH) | Registered. |
| Turkey (KKDIK) | Compliance required. |
| TSCA (USA) | Registered. |
| EINECS | 253-808-2. |
| China (REACH equivalent) | Registered; major production and export country. |
18. OTHER NAMES AND SYNONYMS
Neodymium Carbonate Salt
Light Purple Crystalline Powder
NdFeB Precursor
Glass Additive Carbonate
Neodymium(III) Carbonate
Neodim Carbonate
19. QUICK REFERENCE TABLE
| Property | Value |
|---|---|
| CAS Number | 38245-38-4 |
| EC Number | 253-808-2 |
| Chemical Formula | Nd₂(CO₃)₃·xH₂O |
| Molecular Weight | ~468.5 g/mol (depends on hydration) |
| Appearance | Light purple-white crystalline powder |
| Density | ~3.5 g/cm³ |
| Melting Point | Decomposes upon heating (thermal decomposition) |
| Solubility in Water | Insoluble |
| UN Number | 3077 |
| HS Code | 2846.90.00.00.19 |
| GHS Signal Word | WARNING |
20. CRITICAL WARNINGS AND BEST PRACTICES
CRITICAL WARNINGS:
Thermal Decomposition: Above ~300°C, calcination releases neodymium oxide (Nd₂O₃) and carbon dioxide (CO₂) gas. Ventilation is important during thermal processing.
Acid Reactivity: Reacts vigorously with strong acids, releasing CO₂ gas. Acid addition must be controlled and performed slowly.
Incompatibility: Reacts with strong acids and oxidizing agents.
Eye and Skin Irritation: Powder form may cause irritation to skin and eyes. Protective equipment is recommended during use.
Environmental Impact: Release into aquatic environments must be prevented.
BEST PRACTICE RECOMMENDATIONS:
Storage:
Store in a cool, dry, and well-ventilated area.
Use moisture-proof containers.
Keep away from acids and oxidizing agents.
Store at room temperature (15-25°C).
Handling:
Use in well-ventilated areas.
Use a dust mask (N95 or better), protective goggles, and gloves.
Avoid dust formation and inhalation.
Wash hands thoroughly after handling.
When dissolving in acids, add acid slowly and allow CO₂ release.
Waste Management:
Dispose of in accordance with local regulations.
Do not discharge into water sources.
For large quantities, rare earth recovery should be considered (valuable metal).
LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Neodymium carbonate hydrate, although stable under dry conditions, releases CO₂ gas upon reaction with acids; it is classified as an environmentally hazardous substance (UN 3077).