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Neodymium Carbonate, Neodymium Carbonate Hydrate, Neodymium Tricarbonate, 38245-38-4

Neodymium Carbonate, Neodymium Carbonate Hydrate, Neodymium Tricarbonate, 38245-38-4

NEODYMIUM CARBONATE HYDRATE
1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Neodymium Carbonate Hydrate
Chemical Name Neodymium(III) Carbonate Hydrate
Other Names Neodymium Carbonate Salt, NdFeB Precursor, Glass Additive Carbonate, Light Purple Crystalline Powder
CAS Number 38245-38-4
EC Number (EINECS) 253-808-2
Chemical Formula Nd₂(CO₃)₃·xH₂O (x = 2 to 8)
Molecular Weight ~468.5 g/mol (depending on the degree of hydration)
Appearance Light purple-white crystalline powder
Odor Odorless
Physical State (20°C) Solid (crystalline powder)

2. CHEMICAL STRUCTURE
2.1. Molecular Structure
Neodymium carbonate hydrate is the carbonate salt of the rare earth element neodymium. It consists of neodymium ions (Nd³⁺) and carbonate ions (CO₃²⁻) in a 2:3 ratio. The molecule contains a variable number of water molecules of hydration (typically 2-8 moles of H₂O). It is insoluble in water but readily dissolves in mineral acids, releasing carbon dioxide gas and forming neodymium salts. It is not hygroscopic and is stable under dry conditions.

Structural Features:

          NEODYMIUM CARBONATE HYDRATE [Nd₂(CO₃)₃·xH₂O]
                          |
                Nd³⁺ - CO₃²⁻ Ionic Bonds
                          |
        +----------------+----------------+
        |                |                |
    Trigonal          Insoluble       Soluble in
    Crystal             in             Mineral
    Structure          Water           Acids

2.2. Structural Properties

Parameter Value
Crystal System Trigonal
Molecular Weight ~468.5 g/mol (depending on hydration)
Density ~3.5 g/cm³
Appearance Light purple-white crystalline powder
Melting Point Decomposes upon heating (thermal decomposition)
pH (suspension) Slightly basic (~7.5-8.5)

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance Light purple-white crystalline powder Color intensity depends on purity
Odor Odorless -
Chemical Formula Nd₂(CO₃)₃·xH₂O -
Molecular Weight ~468.5 g/mol Depends on the degree of hydration
Density ~3.5 g/cm³ -
Melting Point Decomposes upon heating (thermal decomposition) -
Solubility in Water (25°C) Insoluble -
Solubility in Mineral Acids Soluble Dissolves releasing CO₂ gas
Solubility in Alcohol Insoluble -
pH (suspension) Slightly basic (~7.5-8.5) -
Stability Not hygroscopic; stable under dry conditions -
Hygroscopicity Low -

4. PURITY GRADES

Parameter Technical Grade High Purity Grade Analytical Grade Ultra-High Purity Grade
Purity ≥ 99.0% ≥ 99.5% ≥ 99.9% ≥ 99.99%
Nd₂(CO₃)₃ Content ≥ 99.0% ≥ 99.5% ≥ 99.9% ≥ 99.99%
Other Rare Earths ≤ 1.0% ≤ 0.5% ≤ 0.1% ≤ 0.01%
Heavy Metals (Pb) ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm ≤ 5 ppm
Iron (Fe) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Calcium (Ca) ≤ 100 ppm ≤ 50 ppm ≤ 20 ppm ≤ 10 ppm
Sodium (Na) ≤ 1000 ppm ≤ 500 ppm ≤ 100 ppm ≤ 50 ppm
Chloride (Cl⁻) ≤ 0.1% ≤ 0.05% ≤ 0.02% ≤ 0.01%
Sulfate (SO₄²⁻) ≤ 0.2% ≤ 0.1% ≤ 0.05% ≤ 0.02%
Nitrate (NO₃⁻) ≤ 0.2% ≤ 0.1% ≤ 0.05% ≤ 0.02%
Loss on Drying (H₂O) Variable Variable Variable Variable
Particle Size (D50) 10-50 µm 5-20 µm 1-10 µm < 5 µm

5. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Not hygroscopic; stable under dry, closed conditions.
Conditions to Avoid High temperatures (>300°C), strong acids, moisture (low sensitivity).
Incompatible Materials Strong acids (releases CO₂ gas), strong oxidizing agents.
Hazardous Decomposition Products At high temperatures: neodymium oxide (Nd₂O₃) and carbon dioxide (CO₂).
Hazardous Polymerization Will not occur.
Hygroscopicity Low; does not absorb moisture under normal conditions.

5.1. Chemical Reactions

  • Thermal Decomposition:
    Nd₂(CO₃)₃·xH₂O → Nd₂O₃ + 3CO₂↑ + xH₂O (at ~300-400°C)

  • Reaction with Acids:
    Nd₂(CO₃)₃ + 6HCl → 2NdCl₃ + 3CO₂↑ + 3H₂O
    Nd₂(CO₃)₃ + 6HNO₃ → 2Nd(NO₃)₃ + 3CO₂↑ + 3H₂O

6. APPLICATION AREAS
6.1. NdFeB Magnet Production

Application Function Details
NdFeB Magnet Production Precursor for Nd₂O₃ via thermal conversion Converted to Nd₂O₃ by calcination, used in Nd metal production.
Magnet Alloying Nd source Used as Nd₂O₃ after thermal decomposition in metallurgical processes.

6.2. Glass and Ceramic Industry

Application Function Details
Glass Coloring Colorant Imparts purplish tones to glass.
UV Filtering UV absorber Controls UV transmittance of glass.
Ceramic Glazes Color and gloss Provides purplish tones and gloss to ceramic glazes.

6.3. Pigment and Paint Industry

Application Function Details
Pigment Production Colorant additive Used in pigment production for purplish tones.
Paint Additive Colorant Used as a color tone adjuster in specialty paints.

6.4. Laboratory and Research

Application Function Details
Analytical Reagent Rare earth precipitation Used in precipitation of rare earth elements.
Rare Earth Separation Carbonate precipitation Used in purification processes.
Synthesis Precursor Starting material Synthesis of other neodymium compounds.
Standard Preparation Reference material Used as a reference for calibration and analysis.

6.5. Organic Synthesis

Application Function Details
Nd Source Soluble in acidic media Provides Nd³⁺ ion source by dissolving in acidic media.

7. PRODUCTION PROCESS
7.1. Raw Material Sources
Neodymium carbonate is produced from neodymium-containing solutions:

Source Type Neodymium Form Major Regions
Neodymium Nitrate (Nd(NO₃)₃) Soluble salt China, India, USA
Neodymium Chloride (NdCl₃) Soluble salt China, India
Neodymium Sulfate Soluble salt China, Brazil

7.2. Production Process Flow

Neodymium Nitrate or Chloride Solution
         ↓
Precipitation with Sodium Carbonate (Na₂CO₃) or Ammonium Carbonate
         ↓
Reaction: 2Nd³⁺ + 3CO₃²⁻ + xH₂O → Nd₂(CO₃)₃·xH₂O↓
         ↓
Filtration (Separation of Precipitate)
         ↓
Washing (Removal of Impurities)
         ↓
Drying (Under Controlled Conditions)
         ↓
Neodymium Carbonate Hydrate Powder
         ↓
Packaging (Moisture-Proof)

7.3. Process Stages

Stage Description
1. Solution Preparation Neodymium nitrate or chloride is dissolved in pure water.
2. Precipitation Sodium carbonate (Na₂CO₃) or ammonium carbonate solution is added to the solution.
3. Reaction Nd₂(CO₃)₃·xH₂O precipitate is formed.
4. Filtration The precipitate is separated by vacuum filtration.
5. Washing The precipitate is washed with pure water to remove impurities.
6. Drying The precipitate is dried under controlled conditions at appropriate temperature.
7. Packaging Packaged in moisture-proof containers.

8. SECTORAL SUITABILITY TABLE

Sector Suitability Explanation
Electronics Suitable Used in magnets, lasers, and optoelectronic systems.
Glass and Ceramics Suitable Used as a color and UV control additive.
Pigment and Paint Suitable Used as a purplish tone additive.
Laboratory and R&D Suitable Used as a precipitation and analytical reagent.
Cosmetics Not Suitable Direct use is not appropriate.
Food and Pharmaceutical Not Suitable Prohibited due to carbonate structure and metal content.
Nuclear Limited Limited use in specialized applications.

9. COMPARISON WITH ALTERNATIVE MATERIALS

Application Area Alternative Materials Remarks
Soluble Nd Source Neodymium Nitrate (Nd(NO₃)₃) Water-soluble form; carbonate is insoluble.
Glass and Pigment Additive Neodymium Sulfate (Nd₂(SO₄)₃) Similar optical properties; different solubility.
Thermal Conversion Neodymium Oxalate Similarly used for Nd₂O₃ production.
Optical Applications Praseodymium Carbonate (Pr₂(CO₃)₃) Similar optical applications; different color tones.

10. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 2,000 mg/kg (low toxicity)
Dermal Toxicity Low
Skin Irritation Mild irritant
Eye Irritation Mild to moderate irritant
Inhalation Dust inhalation may cause respiratory tract irritation.
Carcinogenicity Not classified as carcinogenic.
Mutagenicity Not mutagenic.
Chronic Effects Rare earth compounds have low bioavailability; however, high doses may cause liver effects.
Environmental Hazards Moderate aquatic toxicity.

11. GHS CLASSIFICATION

Hazard Class Category H-Statement
Skin Irritation Category 2 H315: Causes skin irritation.
Eye Irritation Category 2A H319: Causes serious eye irritation.
Specific Target Organ Toxicity Category 3 H335: May cause respiratory irritation.
Hazardous to the Aquatic Environment Category 3 H402: Harmful to aquatic life.

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

UN Number: 3077 (Environmentally hazardous substance)

12. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust.
P264 Wash thoroughly after handling.
P271 Use only in well-ventilated areas.
P280 Wear protective gloves/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
P337+P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with local regulations.

13. FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air. If symptoms persist, seek medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, seek medical attention.
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention.
Ingestion Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention.

14. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, and well-ventilated area.
Container Requirements Moisture-proof, tightly closed containers.
Temperature Room temperature (15-25°C).
Shelf Life 24-36 months under appropriate conditions (due to stable structure).
Stability Note Not hygroscopic; stable under normal conditions. Avoid contact with acids.

15. PACKAGING OPTIONS

Packaging Type Quantity Material
Aluminum Foil Bag 1 kg, 5 kg, 10 kg Double-layered, moisture-proof.
Fiber Drum 25 kg, 50 kg PE-lined, moisture-proof.
Plastic Barrel 25 kg, 50 kg HDPE barrel, moisture-proof.
Glass Bottle 100 g, 500 g, 1 kg Amber glass bottle, sealed with airtight cap.

16. TRANSPORT INFORMATION

Parameter Information
UN Number 3077 (Environmentally hazardous substance)
Hazard Class 9 (Miscellaneous dangerous substances)
Packing Group III
ADR/RID Regulated.
IMDG Regulated.
IATA Regulated.
HS Code 2846.90.00.00.19 (Other rare earth compounds)

17. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Registered.
Turkey (KKDIK) Compliance required.
TSCA (USA) Registered.
EINECS 253-808-2.
China (REACH equivalent) Registered; major production and export country.

18. OTHER NAMES AND SYNONYMS

  • Neodymium Carbonate Salt

  • Light Purple Crystalline Powder

  • NdFeB Precursor

  • Glass Additive Carbonate

  • Neodymium(III) Carbonate

  • Neodim Carbonate

19. QUICK REFERENCE TABLE

Property Value
CAS Number 38245-38-4
EC Number 253-808-2
Chemical Formula Nd₂(CO₃)₃·xH₂O
Molecular Weight ~468.5 g/mol (depends on hydration)
Appearance Light purple-white crystalline powder
Density ~3.5 g/cm³
Melting Point Decomposes upon heating (thermal decomposition)
Solubility in Water Insoluble
UN Number 3077
HS Code 2846.90.00.00.19
GHS Signal Word WARNING

20. CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • Thermal Decomposition: Above ~300°C, calcination releases neodymium oxide (Nd₂O₃) and carbon dioxide (CO₂) gas. Ventilation is important during thermal processing.

  • Acid Reactivity: Reacts vigorously with strong acids, releasing CO₂ gas. Acid addition must be controlled and performed slowly.

  • Incompatibility: Reacts with strong acids and oxidizing agents.

  • Eye and Skin Irritation: Powder form may cause irritation to skin and eyes. Protective equipment is recommended during use.

  • Environmental Impact: Release into aquatic environments must be prevented.

BEST PRACTICE RECOMMENDATIONS:

  • Storage:

    • Store in a cool, dry, and well-ventilated area.

    • Use moisture-proof containers.

    • Keep away from acids and oxidizing agents.

    • Store at room temperature (15-25°C).

  • Handling:

    • Use in well-ventilated areas.

    • Use a dust mask (N95 or better), protective goggles, and gloves.

    • Avoid dust formation and inhalation.

    • Wash hands thoroughly after handling.

    • When dissolving in acids, add acid slowly and allow CO₂ release.

  • Waste Management:

    • Dispose of in accordance with local regulations.

    • Do not discharge into water sources.

    • For large quantities, rare earth recovery should be considered (valuable metal).

LEGAL DISCLAIMER
This Technical Data Sheet (TDS) is for informational purposes only and has been prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific applications and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, disposal, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Neodymium carbonate hydrate, although stable under dry conditions, releases CO₂ gas upon reaction with acids; it is classified as an environmentally hazardous substance (UN 3077).

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