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Send EmailCerium Oxalate Hydrate, Cerium Oxalate, Cerous Oxalate, Cerium (III) Oxalate, 139-42-4, 1570-47-7
Chemical Name: Cerium(III) Oxalate Hydrate
Chemical Formula: Ce₂(C₂O₄)₃·xH₂O
CAS Number: 139-42-4 / 1570-47-7
EC Number: 205-348-4
Molecular Weight: ~544.29 g/mol (depends on hydration level)
Appearance: White crystalline powder
Melting Point: Decomposes before melting
Solubility: Very low in water, soluble in acids
Stability: Stable at room temperature
Density: ~3.7 g/cm³
Ksp: Extremely low, ideal for precipitation
CeO₂ production: Direct thermal decomposition yields cerium oxide
Laboratory reagent: Used for precipitation of rare earth elements
Nanomaterial synthesis: Starting material for CeO₂ nanoparticles
Ceramic additive: For refractive index tuning and surface modification
Electrochemical applications: Thin-film additive
Defense industry: Precision polishing in laser optics
| Descriptor | Value |
|---|---|
| CAS Number | 139-42-4 / 1570-47-7 |
| EC Number | 205-348-4 |
| UN Number | 3077 (environmentally hazardous) |
| Customs HS Code | 2846.90.00.00.19 |
| Other Names | Cerium Oxalate, Cerous Oxalate, Cerium(III) Oxalate |
Cerium Hydroxide (Ce(OH)₃): Alternative intermediate for CeO₂
Cerium Carbonate (Ce₂(CO₃)₃): Substitute in precipitation and pigment applications
Lanthanum Oxalate (La₂(C₂O₄)₃): Similar precipitation and analysis use
Zirconium Oxalate: Substitute in ceramics and electrochemical systems
| Sector | Compatibility | Notes |
|---|---|---|
| Laboratory & R&D | ✅ | Used as reagent and precipitant |
| Nanotechnology | ✅ | Precursor for CeO₂ nanoparticles |
| Ceramics & Glass | ✅ | Refractive and surface additive |
| Electronics | ✅ | Thin-film additive |
| Cosmetics | ❌ | Not suitable for direct use |
| Food & Pharma | ❌ | Prohibited due to oxalate content |
Cerium-based precipitant
White cerium salt
CeO₂ precursor
Cerium oxalate crystal
Starting Material: Cerium-containing solutions
Process: Precipitation with oxalic acid → Filtration → Drying
Grades Available: Technical and high-purity grades
Main Producer Countries: China, India, USA
Commercial Purity Grades: 99% to 99.999%
CeO₂ production: Direct thermal decomposition route
Nanomaterial synthesis: Starting material for CeO₂ nanoparticles
Laboratory precipitation: Used for rare earth separation
Defense optics: Precision polishing in laser systems