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Cerium Oxalate Hydrate, Cerium Oxalate, Cerous Oxalate, Cerium (III) Oxalate, 139-42-4, 1570-47-7

Cerium Oxalate Hydrate, Cerium Oxalate, Cerous Oxalate, Cerium (III) Oxalate, 139-42-4, 1570-47-7

🧪 CERIUM OXALATE

1️⃣ Physical and Chemical Properties

  • Chemical Name: Cerium(III) Oxalate Hydrate

  • Chemical Formula: Ce₂(C₂O₄)₃·xH₂O

  • CAS Number: 139-42-4 / 1570-47-7

  • EC Number: 205-348-4

  • Molecular Weight: ~544.29 g/mol (depends on hydration level)

  • Appearance: White crystalline powder

  • Melting Point: Decomposes before melting

  • Solubility: Very low in water, soluble in acids

  • Stability: Stable at room temperature

  • Density: ~3.7 g/cm³

  • Ksp: Extremely low, ideal for precipitation

2️⃣ Detailed Applications

  • CeO₂ production: Direct thermal decomposition yields cerium oxide

  • Laboratory reagent: Used for precipitation of rare earth elements

  • Nanomaterial synthesis: Starting material for CeO₂ nanoparticles

  • Ceramic additive: For refractive index tuning and surface modification

  • Electrochemical applications: Thin-film additive

  • Defense industry: Precision polishing in laser optics

3️⃣ Synonyms, CAS, EC, and Codes

Descriptor Value
CAS Number 139-42-4 / 1570-47-7
EC Number 205-348-4
UN Number 3077 (environmentally hazardous)
Customs HS Code 2846.90.00.00.19
Other Names Cerium Oxalate, Cerous Oxalate, Cerium(III) Oxalate

4️⃣ Alternatives / Substitutes

  • Cerium Hydroxide (Ce(OH)₃): Alternative intermediate for CeO₂

  • Cerium Carbonate (Ce₂(CO₃)₃): Substitute in precipitation and pigment applications

  • Lanthanum Oxalate (La₂(C₂O₄)₃): Similar precipitation and analysis use

  • Zirconium Oxalate: Substitute in ceramics and electrochemical systems

5️⃣ Sectoral Compatibility Table

Sector Compatibility Notes
Laboratory & R&D Used as reagent and precipitant
Nanotechnology Precursor for CeO₂ nanoparticles
Ceramics & Glass Refractive and surface additive
Electronics Thin-film additive
Cosmetics Not suitable for direct use
Food & Pharma Prohibited due to oxalate content

6️⃣ Common Names

  • Cerium-based precipitant

  • White cerium salt

  • CeO₂ precursor

  • Cerium oxalate crystal

7️⃣ Production

  • Starting Material: Cerium-containing solutions

  • Process: Precipitation with oxalic acid → Filtration → Drying

  • Grades Available: Technical and high-purity grades

  • Main Producer Countries: China, India, USA

  • Commercial Purity Grades: 99% to 99.999%

8️⃣ Mandatory Sectors and Processes

  • CeO₂ production: Direct thermal decomposition route

  • Nanomaterial synthesis: Starting material for CeO₂ nanoparticles

  • Laboratory precipitation: Used for rare earth separation

  • Defense optics: Precision polishing in laser systems

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