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Lanthanum Bromide, Lanthanum (III) Bromide, 13536-79-3

Lanthanum Bromide, Lanthanum (III) Bromide, 13536-79-3

🔢 Lanthanum Bromide

CAS No: 13536-79-3 Chemical Formula: LaBr₃

A) Technical Properties

Property Value
Molecular Weight 378.62 g/mol
Appearance White to pale yellow crystalline powder
Solubility Soluble in water, alcohol, and acids
Melting Point ~783 °C
Density ~5.06 g/cm³
Purity ≥99.99% (scintillation-grade)
Thermal Stability High
Hygroscopicity High — requires moisture protection
Packaging Vacuum-sealed or inert atmosphere containers

B) Application Areas

  • Scintillators: Used in gamma-ray spectroscopy and radiation detectors (e.g., LaBr₃:Ce) for high light yield and fast response.

  • Nuclear Medicine & Security: Applied in portable detectors and medical imaging systems.

  • Optical Crystals: Used in laser systems and precision optical devices.

  • Research & Defense: Preferred in high-resolution radiation measurement systems.

C) Alternatives

Application Area Alternatives Notes
Scintillators Lanthanum Fluoride, Barium Fluoride Different light yield and decay profiles
Optical Crystals Cerium Bromide, Yttrium Bromide Varying optical windows and hardness
Nuclear Detectors NaI(Tl), CsI(Tl) Lower resolution but more cost-effective

D) Production Process

  1. Source: Typically derived from lanthanum oxide or carbonate.

  2. Reaction: Reacted with hydrobromic acid (HBr) to form LaBr₃ solution.

  3. Crystallization: Controlled evaporation yields high-purity crystalline form.

  4. Drying & Packaging: Due to hygroscopicity, packed under inert conditions.

E) Synonyms / Other Names

  • Lanthanum(III) bromide

  • LaBr₃

  • Scintillation-grade lanthanum bromide

  • Bromide form of rare earth compound

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