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Lanthanum Fluoride, Lanthanum (III) Fluoride, 13709-38-1

Lanthanum Fluoride, Lanthanum (III) Fluoride, 13709-38-1

🔢 Lanthanum Fluoride

CAS No: 13709-38-1 Chemical Formula: LaF₃

A) Technical Properties

Property Value
Molecular Weight 195.90 g/mol
Appearance White crystalline powder
Solubility Insoluble in water; soluble in acids
Melting Point ~1493 °C
Density ~5.94 g/cm³
Purity ≥99.9% (high-purity optical/electronic grade)
Thermal Stability Excellent
Refractive Index High (used in optical applications)
Packaging Moisture-proof, sealed containers

B) Application Areas

  • Optical Glass & Crystals: Used in fluoride-based laser crystals and high-transparency optics.

  • Scintillators: Key component in radiation detectors and gamma spectroscopy (e.g., LaBr₃:Ce, LaF₃:Ce).

  • Ceramics: Enhances ionic conductivity in fluoride-based solid electrolytes.

  • Metallurgy: Used as a flux in aluminum and rare earth metal processing.

  • Thin Films: Applied in anti-reflective and UV-resistant coatings.

C) Alternatives

Application Area Alternatives Notes
Optical Crystals Yttrium Fluoride, Calcium Fluoride Different optical windows and hardness
Scintillators Lanthanum Bromide, Barium Fluoride Varying light yield and decay time
Ceramic Electrolytes Lithium Fluoride, Zirconium Fluoride Different ionic mobility and stability

D) Production Process

  1. Source: Typically synthesized from lanthanum oxide or carbonate.

  2. Reaction: Reacted with hydrofluoric acid (HF) to form LaF₃.

  3. Filtration & Drying: Precipitate is filtered, washed, and dried under controlled conditions.

  4. Calcination (optional): For high-purity or crystalline forms, thermal treatment may be applied.

  5. Packaging: Packed in sealed containers to prevent moisture uptake.

E) Synonyms / Other Names

  • Lanthanum(III) fluoride

  • LaF₃

  • Rare earth fluoride

  • Fluoride form of lanthanum

  • Optical-grade lanthanum fluoride

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