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Send EmailLanthanum Acetate, Lanthanum (III) Acetate, 917-70-4
| Parameter | Information |
|---|---|
| Product Name | Lanthanum Acetate |
| Chemical Name | Lanthanum(III) Acetate |
| Other Names | La(CH₃COO)₃, Acetate Form Lanthanum Salt, Organic Grade Lanthanum Acetate |
| CAS Number | 917-70-4 |
| EC Number (EINECS) | 213-028-6 |
| Chemical Formula | La(CH₃COO)₃ |
| Molecular Weight | 316.06 g/mol |
| Appearance | White crystalline powder or granules |
| Odor | Slight acetic acid odor |
| Physical State (20°C) | Solid (crystalline powder/granules) |
Lanthanum acetate is the acetate salt of lanthanum. Lanthanum ions (La³⁺) and acetate ions (CH₃COO⁻) are present in a 1:3 ratio. The compound is an organic salt that is soluble in water and alcohol, with low to moderate hygroscopicity compared to other lanthanum salts such as chloride and nitrate.
Structural Features:
LANTHANUM ACETATE [La(CH₃COO)₃]
|
La³⁺ - CH₃COO⁻ Ionic Bonds
|
+----------------+----------------+
| | |
Organic Salt Moderate Thermal Stability
Structure Hygroscopicity Up to 500°C
| Parameter | Value |
|---|---|
| Crystal System | Monoclinic (typical for acetates) |
| Molecular Weight | 316.06 g/mol |
| Hydration States | Anhydrous and hydrate forms exist |
| Appearance | White, crystalline powder |
| pH (1% solution) | Slightly acidic |
| Property | Value | Description |
|---|---|---|
| Appearance | White crystalline powder or granules | - |
| Odor | Slight acetic acid odor | - |
| Chemical Formula | La(CH₃COO)₃ | - |
| Molecular Weight | 316.06 g/mol | - |
| Melting Point | ~150 °C (decomposes to oxide) | - |
| Decomposition Temperature | ~500 °C (to La₂O₃) | - |
| Water Solubility (25°C) | Completely soluble (>500 g/L) | - |
| Solubility in Ethanol | Soluble | - |
| Solubility in Acetone | Slightly soluble | - |
| pH (1% solution) | Slightly acidic (~5-6) | - |
| Hygroscopicity | Low to moderate | Less hygroscopic than chloride/nitrate |
| Stability | Stable under normal conditions | - |
| Thermal Stability | Stable up to 500°C | Decomposes at higher temperatures |
| Parameter | Industrial Grade | High Purity Grade | Ultra High Purity Grade |
|---|---|---|---|
| Purity | ≥ 99.0% | ≥ 99.9% | ≥ 99.99% |
| La(CH₃COO)₃ Content | ≥ 99.0% | ≥ 99.9% | ≥ 99.99% |
| Heavy Metals (as Pb) | ≤ 50 ppm | ≤ 10 ppm | ≤ 5 ppm |
| Iron (Fe) | ≤ 50 ppm | ≤ 10 ppm | ≤ 5 ppm |
| Calcium (Ca) | ≤ 100 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Sodium (Na) | ≤ 100 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Chloride (Cl⁻) | ≤ 0.1% | ≤ 0.05% | ≤ 0.02% |
| Sulfate (SO₄²⁻) | ≤ 0.1% | ≤ 0.05% | ≤ 0.02% |
| Nitrate (NO₃⁻) | ≤ 0.1% | ≤ 0.05% | ≤ 0.02% |
| Other Rare Earths | ≤ 1.0% | ≤ 0.1% | ≤ 0.01% |
| Loss on Drying | ≤ 1.0% | ≤ 0.5% | ≤ 0.3% |
| Parameter | Information |
|---|---|
| Chemical Stability | Stable under normal conditions |
| Conditions to Avoid | High temperature (>500°C), strong oxidizing agents, strong acids |
| Incompatible Materials | Strong oxidizing agents, strong bases, strong acids |
| Hazardous Decomposition Products | Lanthanum oxide (La₂O₃), carbon dioxide (CO₂), acetic acid vapors |
| Hazardous Polymerization | Will not occur |
| Hygroscopicity | Low to moderate |
| Thermal Stability | Stable up to 500°C |
Thermal Decomposition:
2La(CH₃COO)₃ → La₂O₃ + 3CO₂↑ + 3CH₃COCH₃↑ (acetone)
Reaction with Alkali:
La(CH₃COO)₃ + 3NaOH → La(OH)₃↓ + 3CH₃COONa
Reaction with Phosphate:
La(CH₃COO)₃ + Na₃PO₄ → LaPO₄↓ + 3CH₃COONa
Reaction with Oxalate:
2La(CH₃COO)₃ + 3Na₂C₂O₄ → La₂(C₂O₄)₃↓ + 6CH₃COONa
| Application | Function | Details |
|---|---|---|
| Lewis Acid Catalyst | Acid catalyst | Organic synthesis reactions |
| Catalyst Carrier | Support material | Catalyst support for various reactions |
| Organic Reactions | Catalyst | Various organic syntheses |
| Polymerization | Catalyst additive | Polymer production |
| Application | Function | Details |
|---|---|---|
| Optical Coatings | Optical quality | Enhances optical properties |
| Protective Coatings | Corrosion resistance | Surface protection |
| Thin Film Coatings | Film quality | Specialty coating applications |
| Anti-reflective Coatings | Optical performance | Reduces reflection |
| Nano Coatings | Nanostructure | Nanotechnology applications |
| Application | Function | Details |
|---|---|---|
| Analytical Reagent | Standard solution | Preparation of rare earth solutions |
| Synthesis Precursor | Starting material | Synthesis of other lanthanum compounds |
| Research | Laboratory chemical | Chemical research and development |
| Standard Preparation | Reference material | Calibration and analysis |
| Application | Function | Details |
|---|---|---|
| Dielectric Additive | Electrical properties | Improves dielectric properties |
| UV Resistance | UV protection | Absorbs ultraviolet light |
| Glass Additive | Optical properties | Enhances glass characteristics |
| Ceramic Components | Performance enhancer | Improves mechanical and electrical properties |
| High Temperature Ceramics | Thermal stability | High temperature applications |
| Application | Function | Details |
|---|---|---|
| Thin Film Technologies | Film quality | Semiconductor manufacturing |
| Nano Coating Systems | Nanostructure | Electronic component protection |
| Dielectric Layers | Insulating material | Electronic components |
| Capacitors | Dielectric additive | Ceramic capacitors |
| Application | Function | Details |
|---|---|---|
| Nanomaterial Precursor | Synthesis precursor | Lanthanum-containing nanomaterials |
| Battery Materials | Additive | Electrode performance enhancement |
| Phosphor Precursor | Phosphor production | Lanthanum-based phosphors |
| Water Treatment | Phosphate removal | Environmental applications |
Lanthanum acetate is derived from lanthanum-containing ores:
| Ore Type | Lanthanum Content | Main Locations |
|---|---|---|
| Monazite | 10-30% of REE content | Australia, Brazil, India, China |
| Bastnäsite | 20-30% of REE content | China, USA (Mountain Pass), Vietnam |
| Xenotime | 5-10% of REE content | China, Malaysia, Australia |
Lanthanum Oxide (La₂O₃) or Lanthanum Carbonate
↓
Dissolution in Acetic Acid (CH₃COOH)
↓
La(CH₃COO)₃ Solution Formation
↓
Filtration → Purification
↓
Evaporation → Crystallization
↓
La(CH₃COO)₃ Crystals
↓
Drying → Classification → Packaging
| Stage | Description |
|---|---|
| 1. Raw Material | Lanthanum oxide (La₂O₃) or lanthanum carbonate is used as starting material |
| 2. Acid Dissolution | Lanthanum oxide is dissolved in acetic acid (CH₃COOH) |
| 3. Solution Formation | La(CH₃COO)₃ solution is formed |
| 4. Filtration | Solution is filtered to remove impurities |
| 5. Evaporation | Water is evaporated to concentrate the solution |
| 6. Crystallization | La(CH₃COO)₃ crystals are formed |
| 7. Drying | Crystals are dried under controlled conditions |
| 8. Packaging | Packaged in standard containers due to low hygroscopicity |
| Application Area | Alternative Materials | Notes |
|---|---|---|
| Coating Systems | Cerium Acetate, Yttrium Acetate | Similar solubility and optical properties |
| Organic Synthesis | Lanthanum Nitrate, Lanthanum Chloride | Different ionic structure and solubility profile |
| Laboratory Solutions | Lanthanum Oxide, Lanthanum Sulfate | Can be prepared from solid form |
| Ceramics | Yttrium Acetate, Cerium Acetate | Different thermal and electrical properties |
| Parameter | Value |
|---|---|
| Acute Oral Toxicity (LD50, Rat) | > 2,000 mg/kg (low toxicity) |
| Dermal Toxicity | Low |
| Skin Irritation | Mild irritant |
| Eye Irritation | Mild irritant |
| Inhalation | Dust may cause respiratory irritation |
| Carcinogenicity | Not classified as a carcinogen |
| Mutagenicity | Not mutagenic |
| Chronic Effects | May cause liver effects at high doses |
| Environmental Hazards | Low toxicity to aquatic life |
| Hazard Class | Category | H-Statement |
|---|---|---|
| Skin Irritation | Category 2 | H315: Causes skin irritation |
| Eye Irritation | Category 2 | H319: Causes serious eye irritation |
| Specific Target Organ Toxicity | Category 3 | H335: May cause respiratory irritation |
Signal Word: WARNING
Hazard Pictograms: GHS07 (Exclamation Mark)
| Code | Statement |
|---|---|
| P261 | Avoid breathing dust |
| P264 | Wash hands thoroughly after handling |
| P271 | Use only in well-ventilated areas |
| P280 | Wear protective gloves/eye protection/face protection |
| P302+P352 | IF ON SKIN: Wash with plenty of soap and water |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present |
| P337+P313 | If eye irritation persists: Get medical advice/attention |
| P501 | Dispose of contents/container in accordance with local regulations |
| Route of Exposure | Action to Be Taken |
|---|---|
| Inhalation | Move to fresh air. If symptoms persist, seek medical attention |
| Skin Contact | Wash with plenty of soap and water. Remove contaminated clothing |
| Eye Contact | Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention |
| Ingestion | Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention |
| Parameter | Condition |
|---|---|
| Storage Conditions | Store in a cool, dry, well-ventilated area |
| Container Requirements | Moisture-proof, tightly sealed containers |
| Moisture Protection | Store with desiccant (silica gel) recommended |
| Temperature | Room temperature (15-25°C) |
| Shelf Life | 24 months under proper conditions |
| Stability Note | Low to moderate hygroscopicity; stable under normal conditions |
| Packaging Type | Quantity | Material |
|---|---|---|
| PE Bag | 1 kg, 5 kg, 10 kg | Polyethylene, moisture-proof |
| Glass Bottle | 100 g, 500 g | Amber glass with desiccant |
| Fiber Drum | 25 kg, 50 kg | PE-lined, moisture-proof |
| Plastic Drum | 25 kg, 50 kg | HDPE drum, moisture-proof |
| Aluminum Foil Bag | 1 kg, 5 kg | Light-proof, moisture-proof |
| Parameter | Information |
|---|---|
| UN Number | Not applicable (not dangerous goods) |
| Hazard Class | Not applicable |
| Packing Group | Not applicable |
| ADR/RID | Not regulated |
| IMDG | Not regulated |
| IATA | Not regulated |
| Region / Authority | Status |
|---|---|
| European Union (REACH) | Registered |
| Turkey (KKDIK) | Compliance required |
| TSCA (USA) | Registered |
| EINECS | 213-028-6 |
| HS Code | 2915.29 |
Lanthanum(III) Acetate
Lanthanum Acetate
La(CH₃COO)₃
Acetate Form Lanthanum Salt
Organic Grade Lanthanum Acetate
| Property | Value |
|---|---|
| CAS Number | 917-70-4 |
| EC Number | 213-028-6 |
| Chemical Formula | La(CH₃COO)₃ |
| Molecular Weight | 316.06 g/mol |
| Appearance | White crystalline powder or granules |
| Melting Point | ~150 °C (decomposes) |
| Water Solubility | Completely soluble (>500 g/L) |
| pH (1% solution) | ~5-6 (slightly acidic) |
| Purity | ≥ 99.9% (high purity grade) |
| Hygroscopicity | Low to moderate |
| Thermal Stability | Stable up to 500°C |
| HS Code | 2915.29 |
| GHS Signal Word | WARNING |
| UN Number | Not applicable |
Low to Moderate Hygroscopicity: Lanthanum acetate has lower hygroscopicity compared to chloride and nitrate salts, making it easier to handle and store.
Thermal Stability: Stable up to 500°C; decomposes at higher temperatures to lanthanum oxide.
Organic Nature: Acetate salt with low toxicity and good solubility in organic solvents.
Skin and Eye Irritation: Causes skin and eye irritation. Use appropriate personal protective equipment.
Inhalation Hazard: Dust may cause respiratory irritation. Use in well-ventilated areas.
Acetic Acid Odor: May have slight acetic acid odor, especially when exposed to moisture.
Suitable for Organic Systems: More suitable for organic applications compared to inorganic salts.
Storage:
Store in a cool, dry, well-ventilated area
Use moisture-proof containers
Store at room temperature (15-25°C)
Keep away from strong acids and strong bases
Handling:
Use in well-ventilated areas
Use dust mask, protective goggles, and gloves
Avoid dust formation
Wash hands after handling
Reseal container after use
Waste Management:
Dispose in accordance with local regulations
Do not discharge into water bodies
Consider rare earth recovery for large quantities
This Technical Data Sheet (TDS) is for informational purposes only and is prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific application and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, waste, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Lanthanum acetate is a moderately hygroscopic material; appropriate precautions must be taken during handling.