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Lanthanum Acetate, Lanthanum (III) Acetate, 917-70-4

Lanthanum Acetate, Lanthanum (III) Acetate, 917-70-4

LANTHANUM ACETATE 

1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Lanthanum Acetate
Chemical Name Lanthanum(III) Acetate
Other Names La(CH₃COO)₃, Acetate Form Lanthanum Salt, Organic Grade Lanthanum Acetate
CAS Number 917-70-4
EC Number (EINECS) 213-028-6
Chemical Formula La(CH₃COO)₃
Molecular Weight 316.06 g/mol
Appearance White crystalline powder or granules
Odor Slight acetic acid odor
Physical State (20°C) Solid (crystalline powder/granules)

2. CHEMICAL STRUCTURE

2.1. Molecular Structure

Lanthanum acetate is the acetate salt of lanthanum. Lanthanum ions (La³⁺) and acetate ions (CH₃COO⁻) are present in a 1:3 ratio. The compound is an organic salt that is soluble in water and alcohol, with low to moderate hygroscopicity compared to other lanthanum salts such as chloride and nitrate.

Structural Features:

                    LANTHANUM ACETATE [La(CH₃COO)₃]
                          |
                La³⁺ - CH₃COO⁻ Ionic Bonds
                          |
        +----------------+----------------+
        |                |                |
    Organic Salt      Moderate        Thermal Stability
    Structure         Hygroscopicity   Up to 500°C

2.2. Structural Properties

Parameter Value
Crystal System Monoclinic (typical for acetates)
Molecular Weight 316.06 g/mol
Hydration States Anhydrous and hydrate forms exist
Appearance White, crystalline powder
pH (1% solution) Slightly acidic

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance White crystalline powder or granules -
Odor Slight acetic acid odor -
Chemical Formula La(CH₃COO)₃ -
Molecular Weight 316.06 g/mol -
Melting Point ~150 °C (decomposes to oxide) -
Decomposition Temperature ~500 °C (to La₂O₃) -
Water Solubility (25°C) Completely soluble (>500 g/L) -
Solubility in Ethanol Soluble -
Solubility in Acetone Slightly soluble -
pH (1% solution) Slightly acidic (~5-6) -
Hygroscopicity Low to moderate Less hygroscopic than chloride/nitrate
Stability Stable under normal conditions -
Thermal Stability Stable up to 500°C Decomposes at higher temperatures

4. PURITY GRADES

Parameter Industrial Grade High Purity Grade Ultra High Purity Grade
Purity ≥ 99.0% ≥ 99.9% ≥ 99.99%
La(CH₃COO)₃ Content ≥ 99.0% ≥ 99.9% ≥ 99.99%
Heavy Metals (as Pb) ≤ 50 ppm ≤ 10 ppm ≤ 5 ppm
Iron (Fe) ≤ 50 ppm ≤ 10 ppm ≤ 5 ppm
Calcium (Ca) ≤ 100 ppm ≤ 20 ppm ≤ 10 ppm
Sodium (Na) ≤ 100 ppm ≤ 20 ppm ≤ 10 ppm
Chloride (Cl⁻) ≤ 0.1% ≤ 0.05% ≤ 0.02%
Sulfate (SO₄²⁻) ≤ 0.1% ≤ 0.05% ≤ 0.02%
Nitrate (NO₃⁻) ≤ 0.1% ≤ 0.05% ≤ 0.02%
Other Rare Earths ≤ 1.0% ≤ 0.1% ≤ 0.01%
Loss on Drying ≤ 1.0% ≤ 0.5% ≤ 0.3%

5. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Stable under normal conditions
Conditions to Avoid High temperature (>500°C), strong oxidizing agents, strong acids
Incompatible Materials Strong oxidizing agents, strong bases, strong acids
Hazardous Decomposition Products Lanthanum oxide (La₂O₃), carbon dioxide (CO₂), acetic acid vapors
Hazardous Polymerization Will not occur
Hygroscopicity Low to moderate
Thermal Stability Stable up to 500°C

5.1. Chemical Reactions

Thermal Decomposition:

2La(CH₃COO)₃ → La₂O₃ + 3CO₂↑ + 3CH₃COCH₃↑ (acetone)

Reaction with Alkali:

La(CH₃COO)₃ + 3NaOH → La(OH)₃↓ + 3CH₃COONa

Reaction with Phosphate:

La(CH₃COO)₃ + Na₃PO₄ → LaPO₄↓ + 3CH₃COONa

Reaction with Oxalate:

2La(CH₃COO)₃ + 3Na₂C₂O₄ → La₂(C₂O₄)₃↓ + 6CH₃COONa

6. APPLICATION AREAS

6.1. Organic Synthesis

Application Function Details
Lewis Acid Catalyst Acid catalyst Organic synthesis reactions
Catalyst Carrier Support material Catalyst support for various reactions
Organic Reactions Catalyst Various organic syntheses
Polymerization Catalyst additive Polymer production

6.2. Coating Systems

Application Function Details
Optical Coatings Optical quality Enhances optical properties
Protective Coatings Corrosion resistance Surface protection
Thin Film Coatings Film quality Specialty coating applications
Anti-reflective Coatings Optical performance Reduces reflection
Nano Coatings Nanostructure Nanotechnology applications

6.3. Laboratory Reagent

Application Function Details
Analytical Reagent Standard solution Preparation of rare earth solutions
Synthesis Precursor Starting material Synthesis of other lanthanum compounds
Research Laboratory chemical Chemical research and development
Standard Preparation Reference material Calibration and analysis

6.4. Ceramics and Glass

Application Function Details
Dielectric Additive Electrical properties Improves dielectric properties
UV Resistance UV protection Absorbs ultraviolet light
Glass Additive Optical properties Enhances glass characteristics
Ceramic Components Performance enhancer Improves mechanical and electrical properties
High Temperature Ceramics Thermal stability High temperature applications

6.5. Electronics

Application Function Details
Thin Film Technologies Film quality Semiconductor manufacturing
Nano Coating Systems Nanostructure Electronic component protection
Dielectric Layers Insulating material Electronic components
Capacitors Dielectric additive Ceramic capacitors

6.6. Other Applications

Application Function Details
Nanomaterial Precursor Synthesis precursor Lanthanum-containing nanomaterials
Battery Materials Additive Electrode performance enhancement
Phosphor Precursor Phosphor production Lanthanum-based phosphors
Water Treatment Phosphate removal Environmental applications

7. PRODUCTION PROCESS

7.1. Ore Sources

Lanthanum acetate is derived from lanthanum-containing ores:

Ore Type Lanthanum Content Main Locations
Monazite 10-30% of REE content Australia, Brazil, India, China
Bastnäsite 20-30% of REE content China, USA (Mountain Pass), Vietnam
Xenotime 5-10% of REE content China, Malaysia, Australia

7.2. Production Process Flow

Lanthanum Oxide (La₂O₃) or Lanthanum Carbonate
         ↓
Dissolution in Acetic Acid (CH₃COOH)
         ↓
La(CH₃COO)₃ Solution Formation
         ↓
Filtration → Purification
         ↓
Evaporation → Crystallization
         ↓
La(CH₃COO)₃ Crystals
         ↓
Drying → Classification → Packaging

7.3. Process Stages

Stage Description
1. Raw Material Lanthanum oxide (La₂O₃) or lanthanum carbonate is used as starting material
2. Acid Dissolution Lanthanum oxide is dissolved in acetic acid (CH₃COOH)
3. Solution Formation La(CH₃COO)₃ solution is formed
4. Filtration Solution is filtered to remove impurities
5. Evaporation Water is evaporated to concentrate the solution
6. Crystallization La(CH₃COO)₃ crystals are formed
7. Drying Crystals are dried under controlled conditions
8. Packaging Packaged in standard containers due to low hygroscopicity

8. ALTERNATIVE MATERIALS COMPARISON

Application Area Alternative Materials Notes
Coating Systems Cerium Acetate, Yttrium Acetate Similar solubility and optical properties
Organic Synthesis Lanthanum Nitrate, Lanthanum Chloride Different ionic structure and solubility profile
Laboratory Solutions Lanthanum Oxide, Lanthanum Sulfate Can be prepared from solid form
Ceramics Yttrium Acetate, Cerium Acetate Different thermal and electrical properties

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 2,000 mg/kg (low toxicity)
Dermal Toxicity Low
Skin Irritation Mild irritant
Eye Irritation Mild irritant
Inhalation Dust may cause respiratory irritation
Carcinogenicity Not classified as a carcinogen
Mutagenicity Not mutagenic
Chronic Effects May cause liver effects at high doses
Environmental Hazards Low toxicity to aquatic life

10. GHS CLASSIFICATION

Hazard Class Category H-Statement
Skin Irritation Category 2 H315: Causes skin irritation
Eye Irritation Category 2 H319: Causes serious eye irritation
Specific Target Organ Toxicity Category 3 H335: May cause respiratory irritation

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

11. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust
P264 Wash hands thoroughly after handling
P271 Use only in well-ventilated areas
P280 Wear protective gloves/eye protection/face protection
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present
P337+P313 If eye irritation persists: Get medical advice/attention
P501 Dispose of contents/container in accordance with local regulations

12. FIRST AID MEASURES

Route of Exposure Action to Be Taken
Inhalation Move to fresh air. If symptoms persist, seek medical attention
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention
Ingestion Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention

13. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, well-ventilated area
Container Requirements Moisture-proof, tightly sealed containers
Moisture Protection Store with desiccant (silica gel) recommended
Temperature Room temperature (15-25°C)
Shelf Life 24 months under proper conditions
Stability Note Low to moderate hygroscopicity; stable under normal conditions

14. PACKAGING OPTIONS

Packaging Type Quantity Material
PE Bag 1 kg, 5 kg, 10 kg Polyethylene, moisture-proof
Glass Bottle 100 g, 500 g Amber glass with desiccant
Fiber Drum 25 kg, 50 kg PE-lined, moisture-proof
Plastic Drum 25 kg, 50 kg HDPE drum, moisture-proof
Aluminum Foil Bag 1 kg, 5 kg Light-proof, moisture-proof

15. TRANSPORT INFORMATION

Parameter Information
UN Number Not applicable (not dangerous goods)
Hazard Class Not applicable
Packing Group Not applicable
ADR/RID Not regulated
IMDG Not regulated
IATA Not regulated

16. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Registered
Turkey (KKDIK) Compliance required
TSCA (USA) Registered
EINECS 213-028-6
HS Code 2915.29

17. OTHER NAMES AND SYNONYMS

  • Lanthanum(III) Acetate

  • Lanthanum Acetate

  • La(CH₃COO)₃

  • Acetate Form Lanthanum Salt

  • Organic Grade Lanthanum Acetate

18. QUICK REFERENCE TABLE

Property Value
CAS Number 917-70-4
EC Number 213-028-6
Chemical Formula La(CH₃COO)₃
Molecular Weight 316.06 g/mol
Appearance White crystalline powder or granules
Melting Point ~150 °C (decomposes)
Water Solubility Completely soluble (>500 g/L)
pH (1% solution) ~5-6 (slightly acidic)
Purity ≥ 99.9% (high purity grade)
Hygroscopicity Low to moderate
Thermal Stability Stable up to 500°C
HS Code 2915.29
GHS Signal Word WARNING
UN Number Not applicable

19. CRITICAL NOTICES AND BEST PRACTICES

CRITICAL NOTICES:

  1. Low to Moderate Hygroscopicity: Lanthanum acetate has lower hygroscopicity compared to chloride and nitrate salts, making it easier to handle and store.

  2. Thermal Stability: Stable up to 500°C; decomposes at higher temperatures to lanthanum oxide.

  3. Organic Nature: Acetate salt with low toxicity and good solubility in organic solvents.

  4. Skin and Eye Irritation: Causes skin and eye irritation. Use appropriate personal protective equipment.

  5. Inhalation Hazard: Dust may cause respiratory irritation. Use in well-ventilated areas.

  6. Acetic Acid Odor: May have slight acetic acid odor, especially when exposed to moisture.

  7. Suitable for Organic Systems: More suitable for organic applications compared to inorganic salts.

BEST PRACTICE RECOMMENDATIONS:

Storage:

  • Store in a cool, dry, well-ventilated area

  • Use moisture-proof containers

  • Store at room temperature (15-25°C)

  • Keep away from strong acids and strong bases

Handling:

  • Use in well-ventilated areas

  • Use dust mask, protective goggles, and gloves

  • Avoid dust formation

  • Wash hands after handling

  • Reseal container after use

Waste Management:

  • Dispose in accordance with local regulations

  • Do not discharge into water bodies

  • Consider rare earth recovery for large quantities

LEGAL DISCLAIMER

This Technical Data Sheet (TDS) is for informational purposes only and is prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific application and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, waste, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Lanthanum acetate is a moderately hygroscopic material; appropriate precautions must be taken during handling.

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