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Send EmailLanthanum Sulfate, Lanthanum(III) Sulfate, 10099-60-2
| Parameter | Information |
|---|---|
| Product Name | Lanthanum Sulfate |
| Chemical Name | Lanthanum(III) Sulfate |
| Other Names | La₂(SO₄)₃, Rare Earth Sulfate, Sulfate Form Lanthanum Salt |
| CAS Number | 10099-60-2 |
| EC Number (EINECS) | 233-239-6 |
| Chemical Formula | La₂(SO₄)₃ |
| Molecular Weight | 548.06 g/mol |
| Appearance | White, crystalline or powder form |
| Odor | Odorless |
| Physical State (20°C) | Solid (crystalline/powder) |
Lanthanum sulfate is the sulfate salt of lanthanum. Lanthanum ions (La³⁺) and sulfate ions (SO₄²⁻) are present in a 2:3 ratio. The compound typically exists in anhydrous form (La₂(SO₄)₃) but can also form hydrates. It is characterized by ionic bonding between lanthanum and sulfate ions, with moderate hygroscopic properties.
Structural Features:
LANTHANUM SULFATE (La₂(SO₄)₃)
|
La³⁺ - SO₄²⁻ Ionic Bonds
|
+----------------+----------------+
| | |
Ionic Crystal Moderate Thermal Stability
Structure Hygroscopicity Up to 600°C
| Parameter | Value |
|---|---|
| Crystal System | Monoclinic / Orthorhombic (depends on hydration state) |
| Molecular Weight | 548.06 g/mol (anhydrous) |
| Hydration States | Anhydrous, monohydrate, and other hydrates exist |
| Density | ~3.5 g/cm³ (anhydrous) |
| Appearance | White, crystalline powder |
| pH (1% solution) | Slightly acidic |
| Property | Value | Description |
|---|---|---|
| Appearance | White, crystalline or powder form | - |
| Odor | Odorless | - |
| Chemical Formula | La₂(SO₄)₃ | - |
| Molecular Weight | 548.06 g/mol | - |
| Density | ~3.5 g/cm³ | - |
| Melting Point | ~1200 °C (decomposes) | - |
| Water Solubility (25°C) | Soluble (~3 g/L, limited solubility) | - |
| Solubility in Acids | Soluble | - |
| pH (1% solution) | Slightly acidic | - |
| Hygroscopicity | Moderate | Absorbs moisture from air |
| Thermal Stability | Stable up to 600°C | Decomposes at higher temperatures |
| Decomposition | La₂(SO₄)₃ → La₂O₃ + 3SO₃ (above 600°C) | - |
| Parameter | Industrial Grade | High Purity Grade | Ultra High Purity Grade |
|---|---|---|---|
| Purity | ≥ 99.0% | ≥ 99.9% | ≥ 99.99% |
| La₂(SO₄)₃ Content | ≥ 99.0% | ≥ 99.9% | ≥ 99.99% |
| Heavy Metals (as Pb) | ≤ 50 ppm | ≤ 10 ppm | ≤ 5 ppm |
| Iron (Fe) | ≤ 50 ppm | ≤ 10 ppm | ≤ 5 ppm |
| Calcium (Ca) | ≤ 100 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Sodium (Na) | ≤ 100 ppm | ≤ 20 ppm | ≤ 10 ppm |
| Chloride (Cl⁻) | ≤ 0.1% | ≤ 0.05% | ≤ 0.02% |
| Nitrate (NO₃⁻) | ≤ 0.2% | ≤ 0.1% | ≤ 0.05% |
| Other Rare Earths | ≤ 1.0% | ≤ 0.1% | ≤ 0.01% |
| Loss on Drying | ≤ 1.0% | ≤ 0.5% | ≤ 0.3% |
| Parameter | Information |
|---|---|
| Chemical Stability | Stable under normal conditions |
| Conditions to Avoid | High temperature (>600°C), moisture (moderate sensitivity) |
| Incompatible Materials | Strong acids, strong bases, reducing agents |
| Hazardous Decomposition Products | Lanthanum oxide (La₂O₃), sulfur trioxide (SO₃) |
| Hazardous Polymerization | Will not occur |
| Hygroscopicity | Moderate; absorbs moisture from air |
| Thermal Stability | Stable up to 600°C |
Thermal Decomposition:
La₂(SO₄)₃ → La₂O₃ + 3SO₃↑ (above 600°C)
Reaction with Alkali:
La₂(SO₄)₃ + 6NaOH → 2La(OH)₃↓ + 3Na₂SO₄
Reaction with Phosphate:
La₂(SO₄)₃ + 2Na₃PO₄ → 2LaPO₄↓ + 3Na₂SO₄
| Application | Function | Details |
|---|---|---|
| White Pigment Additive | Pigment modifier | Enhances opacity and brightness |
| Ceramic Pigments | Color additive | Precursor for lanthanum-based pigments |
| Specialty Pigments | Performance enhancer | Improves pigment properties |
| Application | Function | Details |
|---|---|---|
| Petroleum Refining | Catalyst support | FCC catalysts |
| Chemical Synthesis | Active phase | Oxidation and reduction reactions |
| Environmental Catalysis | DeNOx systems | Emission control |
| Hydrocarbon Conversion | Catalyst additive | Petrochemical processes |
| Application | Function | Details |
|---|---|---|
| Analytical Reagent | Standard solution | Preparation of rare earth solutions |
| Synthesis Precursor | Starting material | Synthesis of other lanthanum compounds |
| Research | Laboratory chemical | Chemical research and development |
| Standard Preparation | Reference material | Calibration and analysis |
| Application | Function | Details |
|---|---|---|
| High Temperature Additive | Thermal stability | High temperature applications |
| Ionic Conductivity | Electrical properties | Solid electrolytes |
| Ceramic Components | Performance enhancer | Improves mechanical and electrical properties |
| Glass Additive | Optical properties | Enhances glass characteristics |
| Application | Function | Details |
|---|---|---|
| Ionic Solution Preparation | Coating solution | Metal surface treatments |
| Surface Modification | Surface treatment | Specialty coating applications |
| Lanthanum Coatings | Protective coating | Corrosion resistance |
| Application | Function | Details |
|---|---|---|
| Phosphate Binder | Research | Phosphate binding studies |
| Nanomaterial Precursor | Synthesis precursor | Lanthanum-containing nanomaterials |
| Battery Materials | Additive | Electrode performance enhancement |
| Water Treatment | Phosphate removal | Environmental applications |
Lanthanum sulfate is derived from lanthanum-containing ores:
| Ore Type | Lanthanum Content | Main Locations |
|---|---|---|
| Monazite | 10-30% of REE content | Australia, Brazil, India, China |
| Bastnäsite | 20-30% of REE content | China, USA (Mountain Pass), Vietnam |
| Xenotime | 5-10% of REE content | China, Malaysia, Australia |
Lanthanum Oxide (La₂O₃) or Lanthanum Carbonate
↓
Dissolution in Sulfuric Acid (H₂SO₄)
↓
La₂(SO₄)₃ Solution Formation
↓
Filtration → Purification
↓
Evaporation → Crystallization
↓
La₂(SO₄)₃ Crystals
↓
Drying → Classification → Packaging
| Stage | Description |
|---|---|
| 1. Raw Material | Lanthanum oxide (La₂O₃) or lanthanum carbonate is used as starting material |
| 2. Acid Dissolution | Lanthanum oxide is dissolved in sulfuric acid (H₂SO₄) |
| 3. Solution Formation | La₂(SO₄)₃ solution is formed |
| 4. Filtration | Solution is filtered to remove impurities |
| 5. Evaporation | Water is evaporated to concentrate the solution |
| 6. Crystallization | La₂(SO₄)₃ crystals are formed |
| 7. Drying | Crystals are dried under controlled conditions |
| 8. Packaging | Packaged in moisture-proof containers due to moderate hygroscopic nature |
| Application Area | Alternative Materials | Notes |
|---|---|---|
| Pigment Additive | Titanium Dioxide, Zinc Oxide | Different opacity and color properties |
| Catalyst Support | Alumina, Zirconium Sulfate | Different surface area and acid character |
| Laboratory Solutions | Lanthanum Nitrate, Lanthanum Chloride | Different solubility and ionic behavior |
| Ceramics | Yttrium Oxide, Cerium Sulfate | Different thermal and electrical properties |
| Parameter | Value |
|---|---|
| Acute Oral Toxicity (LD50, Rat) | > 2,000 mg/kg (low toxicity) |
| Dermal Toxicity | Low |
| Skin Irritation | Mild irritant |
| Eye Irritation | Mild irritant |
| Inhalation | Dust may cause respiratory irritation |
| Carcinogenicity | Not classified as a carcinogen |
| Mutagenicity | Not mutagenic |
| Chronic Effects | May cause liver and lung effects at high doses |
| Environmental Hazards | Low to moderate toxicity to aquatic life |
| Hazard Class | Category | H-Statement |
|---|---|---|
| Skin Irritation | Category 2 | H315: Causes skin irritation |
| Eye Irritation | Category 2 | H319: Causes serious eye irritation |
| Specific Target Organ Toxicity | Category 3 | H335: May cause respiratory irritation |
Signal Word: WARNING
Hazard Pictograms: GHS07 (Exclamation Mark)
| Code | Statement |
|---|---|
| P261 | Avoid breathing dust |
| P264 | Wash hands thoroughly after handling |
| P271 | Use only in well-ventilated areas |
| P280 | Wear protective gloves/eye protection/face protection |
| P302+P352 | IF ON SKIN: Wash with plenty of soap and water |
| P304+P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing |
| P305+P351+P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present |
| P337+P313 | If eye irritation persists: Get medical advice/attention |
| P501 | Dispose of contents/container in accordance with local regulations |
| Route of Exposure | Action to Be Taken |
|---|---|
| Inhalation | Move to fresh air. If symptoms persist, seek medical attention |
| Skin Contact | Wash with plenty of soap and water. Remove contaminated clothing |
| Eye Contact | Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention |
| Ingestion | Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention |
| Parameter | Condition |
|---|---|
| Storage Conditions | Store in a cool, dry, well-ventilated area |
| Container Requirements | Moisture-proof, tightly sealed containers |
| Moisture Protection | Store with desiccant (silica gel) recommended |
| Temperature | Room temperature (15-25°C) |
| Shelf Life | 24 months under proper conditions |
| Stability Note | Moderately hygroscopic; may absorb moisture if exposed to humid air |
| Packaging Type | Quantity | Material |
|---|---|---|
| PE Bag | 1 kg, 5 kg, 10 kg | Polyethylene, moisture-proof |
| Glass Bottle | 100 g, 500 g | Amber glass with desiccant |
| Fiber Drum | 25 kg, 50 kg | PE-lined, moisture-proof |
| Plastic Drum | 25 kg, 50 kg | HDPE drum, moisture-proof |
| Parameter | Information |
|---|---|
| UN Number | Not applicable (not dangerous goods) |
| Hazard Class | Not applicable |
| Packing Group | Not applicable |
| ADR/RID | Not regulated |
| IMDG | Not regulated |
| IATA | Not regulated |
| Region / Authority | Status |
|---|---|
| European Union (REACH) | Registered |
| Turkey (KKDIK) | Compliance required |
| TSCA (USA) | Registered |
| EINECS | 233-239-6 |
| HS Code | 2833.29 |
Lanthanum(III) Sulfate
Lanthanum Sulfate
La₂(SO₄)₃
Rare Earth Sulfate
Sulfate Form Lanthanum Salt
Lanthanum Sulfate Anhydrous
| Property | Value |
|---|---|
| CAS Number | 10099-60-2 |
| EC Number | 233-239-6 |
| Chemical Formula | La₂(SO₄)₃ |
| Molecular Weight | 548.06 g/mol |
| Appearance | White, crystalline or powder form |
| Density | ~3.5 g/cm³ |
| Water Solubility | Soluble (~3 g/L) |
| pH (1% solution) | Slightly acidic |
| Purity | 99.0-99.99% |
| Hygroscopicity | Moderate |
| Thermal Stability | Stable up to 600°C |
| HS Code | 2833.29 |
| GHS Signal Word | WARNING |
| UN Number | Not applicable |
Solubility Characteristics: Lanthanum sulfate has limited solubility in water (~3 g/L). This property should be considered when preparing solutions.
Moderate Hygroscopicity: Absorbs moisture from the air. Should be stored in moisture-proof containers with desiccant.
Thermal Decomposition: Decomposes at temperatures above 600°C, releasing sulfur trioxide (SO₃). Should not be heated above this temperature.
Skin and Eye Irritation: Causes skin and eye irritation. Use appropriate personal protective equipment.
Inhalation Hazard: Dust may cause respiratory irritation. Use in well-ventilated areas.
pH Sensitivity: Aqueous solutions are slightly acidic; may react with bases.
Storage:
Store in a cool, dry, well-ventilated area
Use moisture-proof, tightly sealed containers
Store with desiccant (silica gel)
Keep away from strong acids and bases
Store at room temperature (15-25°C)
Handling:
Use in well-ventilated areas
Use dust mask, protective goggles, and gloves
Avoid dust formation
Wash hands after handling
Immediately reseal container after use
Waste Management:
Dispose in accordance with local regulations
Do not discharge into water bodies
Consider rare earth recovery for large quantities
This Technical Data Sheet (TDS) is for informational purposes only and is prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific application and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, waste, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Lanthanum sulfate is a moderately hygroscopic material; appropriate precautions must be taken during handling.