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Lanthanum Sulfate, Lanthanum(III) Sulfate, 10099-60-2

Lanthanum Sulfate, Lanthanum(III) Sulfate, 10099-60-2

LANTHANUM SULFATE 

1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Information
Product Name Lanthanum Sulfate
Chemical Name Lanthanum(III) Sulfate
Other Names La₂(SO₄)₃, Rare Earth Sulfate, Sulfate Form Lanthanum Salt
CAS Number 10099-60-2
EC Number (EINECS) 233-239-6
Chemical Formula La₂(SO₄)₃
Molecular Weight 548.06 g/mol
Appearance White, crystalline or powder form
Odor Odorless
Physical State (20°C) Solid (crystalline/powder)

2. CHEMICAL STRUCTURE

2.1. Molecular Structure

Lanthanum sulfate is the sulfate salt of lanthanum. Lanthanum ions (La³⁺) and sulfate ions (SO₄²⁻) are present in a 2:3 ratio. The compound typically exists in anhydrous form (La₂(SO₄)₃) but can also form hydrates. It is characterized by ionic bonding between lanthanum and sulfate ions, with moderate hygroscopic properties.

Structural Features:

                    LANTHANUM SULFATE (La₂(SO₄)₃)
                          |
                La³⁺ - SO₄²⁻ Ionic Bonds
                          |
        +----------------+----------------+
        |                |                |
    Ionic Crystal     Moderate          Thermal Stability
    Structure         Hygroscopicity    Up to 600°C

2.2. Structural Properties

Parameter Value
Crystal System Monoclinic / Orthorhombic (depends on hydration state)
Molecular Weight 548.06 g/mol (anhydrous)
Hydration States Anhydrous, monohydrate, and other hydrates exist
Density ~3.5 g/cm³ (anhydrous)
Appearance White, crystalline powder
pH (1% solution) Slightly acidic

3. PHYSICAL AND CHEMICAL PROPERTIES

Property Value Description
Appearance White, crystalline or powder form -
Odor Odorless -
Chemical Formula La₂(SO₄)₃ -
Molecular Weight 548.06 g/mol -
Density ~3.5 g/cm³ -
Melting Point ~1200 °C (decomposes) -
Water Solubility (25°C) Soluble (~3 g/L, limited solubility) -
Solubility in Acids Soluble -
pH (1% solution) Slightly acidic -
Hygroscopicity Moderate Absorbs moisture from air
Thermal Stability Stable up to 600°C Decomposes at higher temperatures
Decomposition La₂(SO₄)₃ → La₂O₃ + 3SO₃ (above 600°C) -

4. PURITY GRADES

Parameter Industrial Grade High Purity Grade Ultra High Purity Grade
Purity ≥ 99.0% ≥ 99.9% ≥ 99.99%
La₂(SO₄)₃ Content ≥ 99.0% ≥ 99.9% ≥ 99.99%
Heavy Metals (as Pb) ≤ 50 ppm ≤ 10 ppm ≤ 5 ppm
Iron (Fe) ≤ 50 ppm ≤ 10 ppm ≤ 5 ppm
Calcium (Ca) ≤ 100 ppm ≤ 20 ppm ≤ 10 ppm
Sodium (Na) ≤ 100 ppm ≤ 20 ppm ≤ 10 ppm
Chloride (Cl⁻) ≤ 0.1% ≤ 0.05% ≤ 0.02%
Nitrate (NO₃⁻) ≤ 0.2% ≤ 0.1% ≤ 0.05%
Other Rare Earths ≤ 1.0% ≤ 0.1% ≤ 0.01%
Loss on Drying ≤ 1.0% ≤ 0.5% ≤ 0.3%

5. STABILITY AND REACTIVITY

Parameter Information
Chemical Stability Stable under normal conditions
Conditions to Avoid High temperature (>600°C), moisture (moderate sensitivity)
Incompatible Materials Strong acids, strong bases, reducing agents
Hazardous Decomposition Products Lanthanum oxide (La₂O₃), sulfur trioxide (SO₃)
Hazardous Polymerization Will not occur
Hygroscopicity Moderate; absorbs moisture from air
Thermal Stability Stable up to 600°C

5.1. Chemical Reactions

Thermal Decomposition:

La₂(SO₄)₃ → La₂O₃ + 3SO₃↑ (above 600°C)

Reaction with Alkali:

La₂(SO₄)₃ + 6NaOH → 2La(OH)₃↓ + 3Na₂SO₄

Reaction with Phosphate:

La₂(SO₄)₃ + 2Na₃PO₄ → 2LaPO₄↓ + 3Na₂SO₄

6. APPLICATION AREAS

6.1. Pigment Production

Application Function Details
White Pigment Additive Pigment modifier Enhances opacity and brightness
Ceramic Pigments Color additive Precursor for lanthanum-based pigments
Specialty Pigments Performance enhancer Improves pigment properties

6.2. Catalyst Systems

Application Function Details
Petroleum Refining Catalyst support FCC catalysts
Chemical Synthesis Active phase Oxidation and reduction reactions
Environmental Catalysis DeNOx systems Emission control
Hydrocarbon Conversion Catalyst additive Petrochemical processes

6.3. Laboratory Reagent

Application Function Details
Analytical Reagent Standard solution Preparation of rare earth solutions
Synthesis Precursor Starting material Synthesis of other lanthanum compounds
Research Laboratory chemical Chemical research and development
Standard Preparation Reference material Calibration and analysis

6.4. Ceramics and Glass

Application Function Details
High Temperature Additive Thermal stability High temperature applications
Ionic Conductivity Electrical properties Solid electrolytes
Ceramic Components Performance enhancer Improves mechanical and electrical properties
Glass Additive Optical properties Enhances glass characteristics

6.5. Electroplating

Application Function Details
Ionic Solution Preparation Coating solution Metal surface treatments
Surface Modification Surface treatment Specialty coating applications
Lanthanum Coatings Protective coating Corrosion resistance

6.6. Other Applications

Application Function Details
Phosphate Binder Research Phosphate binding studies
Nanomaterial Precursor Synthesis precursor Lanthanum-containing nanomaterials
Battery Materials Additive Electrode performance enhancement
Water Treatment Phosphate removal Environmental applications

7. PRODUCTION PROCESS

7.1. Ore Sources

Lanthanum sulfate is derived from lanthanum-containing ores:

Ore Type Lanthanum Content Main Locations
Monazite 10-30% of REE content Australia, Brazil, India, China
Bastnäsite 20-30% of REE content China, USA (Mountain Pass), Vietnam
Xenotime 5-10% of REE content China, Malaysia, Australia

7.2. Production Process Flow

Lanthanum Oxide (La₂O₃) or Lanthanum Carbonate
         ↓
Dissolution in Sulfuric Acid (H₂SO₄)
         ↓
La₂(SO₄)₃ Solution Formation
         ↓
Filtration → Purification
         ↓
Evaporation → Crystallization
         ↓
La₂(SO₄)₃ Crystals
         ↓
Drying → Classification → Packaging

7.3. Process Stages

Stage Description
1. Raw Material Lanthanum oxide (La₂O₃) or lanthanum carbonate is used as starting material
2. Acid Dissolution Lanthanum oxide is dissolved in sulfuric acid (H₂SO₄)
3. Solution Formation La₂(SO₄)₃ solution is formed
4. Filtration Solution is filtered to remove impurities
5. Evaporation Water is evaporated to concentrate the solution
6. Crystallization La₂(SO₄)₃ crystals are formed
7. Drying Crystals are dried under controlled conditions
8. Packaging Packaged in moisture-proof containers due to moderate hygroscopic nature

8. ALTERNATIVE MATERIALS COMPARISON

Application Area Alternative Materials Notes
Pigment Additive Titanium Dioxide, Zinc Oxide Different opacity and color properties
Catalyst Support Alumina, Zirconium Sulfate Different surface area and acid character
Laboratory Solutions Lanthanum Nitrate, Lanthanum Chloride Different solubility and ionic behavior
Ceramics Yttrium Oxide, Cerium Sulfate Different thermal and electrical properties

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 2,000 mg/kg (low toxicity)
Dermal Toxicity Low
Skin Irritation Mild irritant
Eye Irritation Mild irritant
Inhalation Dust may cause respiratory irritation
Carcinogenicity Not classified as a carcinogen
Mutagenicity Not mutagenic
Chronic Effects May cause liver and lung effects at high doses
Environmental Hazards Low to moderate toxicity to aquatic life

10. GHS CLASSIFICATION

Hazard Class Category H-Statement
Skin Irritation Category 2 H315: Causes skin irritation
Eye Irritation Category 2 H319: Causes serious eye irritation
Specific Target Organ Toxicity Category 3 H335: May cause respiratory irritation

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

11. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust
P264 Wash hands thoroughly after handling
P271 Use only in well-ventilated areas
P280 Wear protective gloves/eye protection/face protection
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present
P337+P313 If eye irritation persists: Get medical advice/attention
P501 Dispose of contents/container in accordance with local regulations

12. FIRST AID MEASURES

Route of Exposure Action to Be Taken
Inhalation Move to fresh air. If symptoms persist, seek medical attention
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention
Ingestion Rinse mouth. Drink plenty of water. If large amount is swallowed, seek medical attention

13. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, well-ventilated area
Container Requirements Moisture-proof, tightly sealed containers
Moisture Protection Store with desiccant (silica gel) recommended
Temperature Room temperature (15-25°C)
Shelf Life 24 months under proper conditions
Stability Note Moderately hygroscopic; may absorb moisture if exposed to humid air

14. PACKAGING OPTIONS

Packaging Type Quantity Material
PE Bag 1 kg, 5 kg, 10 kg Polyethylene, moisture-proof
Glass Bottle 100 g, 500 g Amber glass with desiccant
Fiber Drum 25 kg, 50 kg PE-lined, moisture-proof
Plastic Drum 25 kg, 50 kg HDPE drum, moisture-proof

15. TRANSPORT INFORMATION

Parameter Information
UN Number Not applicable (not dangerous goods)
Hazard Class Not applicable
Packing Group Not applicable
ADR/RID Not regulated
IMDG Not regulated
IATA Not regulated

16. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Registered
Turkey (KKDIK) Compliance required
TSCA (USA) Registered
EINECS 233-239-6
HS Code 2833.29

17. OTHER NAMES AND SYNONYMS

  • Lanthanum(III) Sulfate

  • Lanthanum Sulfate

  • La₂(SO₄)₃

  • Rare Earth Sulfate

  • Sulfate Form Lanthanum Salt

  • Lanthanum Sulfate Anhydrous

18. QUICK REFERENCE TABLE

Property Value
CAS Number 10099-60-2
EC Number 233-239-6
Chemical Formula La₂(SO₄)₃
Molecular Weight 548.06 g/mol
Appearance White, crystalline or powder form
Density ~3.5 g/cm³
Water Solubility Soluble (~3 g/L)
pH (1% solution) Slightly acidic
Purity 99.0-99.99%
Hygroscopicity Moderate
Thermal Stability Stable up to 600°C
HS Code 2833.29
GHS Signal Word WARNING
UN Number Not applicable

19. CRITICAL NOTICES AND BEST PRACTICES

CRITICAL NOTICES:

  1. Solubility Characteristics: Lanthanum sulfate has limited solubility in water (~3 g/L). This property should be considered when preparing solutions.

  2. Moderate Hygroscopicity: Absorbs moisture from the air. Should be stored in moisture-proof containers with desiccant.

  3. Thermal Decomposition: Decomposes at temperatures above 600°C, releasing sulfur trioxide (SO₃). Should not be heated above this temperature.

  4. Skin and Eye Irritation: Causes skin and eye irritation. Use appropriate personal protective equipment.

  5. Inhalation Hazard: Dust may cause respiratory irritation. Use in well-ventilated areas.

  6. pH Sensitivity: Aqueous solutions are slightly acidic; may react with bases.

BEST PRACTICE RECOMMENDATIONS:

Storage:

  • Store in a cool, dry, well-ventilated area

  • Use moisture-proof, tightly sealed containers

  • Store with desiccant (silica gel)

  • Keep away from strong acids and bases

  • Store at room temperature (15-25°C)

Handling:

  • Use in well-ventilated areas

  • Use dust mask, protective goggles, and gloves

  • Avoid dust formation

  • Wash hands after handling

  • Immediately reseal container after use

Waste Management:

  • Dispose in accordance with local regulations

  • Do not discharge into water bodies

  • Consider rare earth recovery for large quantities

LEGAL DISCLAIMER

This Technical Data Sheet (TDS) is for informational purposes only and is prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific application and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, waste, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Lanthanum sulfate is a moderately hygroscopic material; appropriate precautions must be taken during handling.

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