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Lanthanum Nitrate, Lanthanum Nitrate Hexahydrate, Lanthanum Trinitrate, 10277-43-7

Lanthanum Nitrate, Lanthanum Nitrate Hexahydrate, Lanthanum Trinitrate, 10277-43-7

LANTAN NİTRAT

1. ÜRÜN TANIMI VE KİMYASAL KİMLİK

Parametre Bilgi
Ürün Adı Lantan Nitrat
Kimyasal Adı Lantan(III) Nitrat Hekzahidrat, Lantan Trinitrat
Diğer İsimleri Lanthanum Nitrate Hexahydrate, La(NO₃)₃·6H₂O, Nadir Toprak Nitratı, Optik Sınıf Lantan Nitrat
CAS Numarası 10277-43-7
EC Numarası (EINECS) 233-238-0
Kimyasal Formül La(NO₃)₃·6H₂O
Moleküler Ağırlık 433.01 g/mol
Görünüm Beyaz, kristalimsi, higroskopik katı
Koku Kokusuz
Fiziksel Hal (20°C) Katı (kristal)

2. KİMYASAL YAPI

2.1. Moleküler Yapı

Lantan nitrat, lantanın nitrat tuzudur. Lantan iyonları (La³⁺) ve nitrat iyonları (NO₃⁻) 1:3 oranında bulunur. Bileşik tipik olarak hekzahidrat formunda (La(NO₃)₃·6H₂O) olup, altı su molekülü kristal kafese dahil olur. Higroskopik özelliği ile bilinir ve havadaki nemi kolayca emer.

Yapısal Özellikler:

                    LANTAN NİTRAT (La(NO₃)₃·6H₂O)
                          |
                La³⁺ - NO₃⁻ İyonik Bağlar
                          |
        +----------------+----------------+
        |                |                |
    Kristal Yapı    6 Hidrat Suyu    Higroskopik
                    (6H₂O)           Özellik

2.2. Yapısal Özellikler

Parametre Değer
Kristal Sistemi Monoklinik
Moleküler Ağırlık 433.01 g/mol (hekzahidrat)
Su İçeriği 6 mol H₂O
Yoğunluk ~2.5 g/cm³
Görünüm Beyaz, higroskopik kristaller
pH (1% çözelti) Hafif asidik (~3-4)

3. FİZİKSEL VE KİMYASAL ÖZELLİKLER

Özellik Değer Açıklama
Görünüm Beyaz, kristalimsi, higroskopik katı -
Koku Kokusuz -
Kimyasal Formül La(NO₃)₃·6H₂O -
Moleküler Ağırlık 433.01 g/mol -
Yoğunluk ~2.5 g/cm³ -
Erime Noktası ~40-50 °C (kristal suyunu kaybeder) -
Bozunma Sıcaklığı ~150-200 °C (nitrat ayrışması) -
Suda Çözünürlük (25°C) Tamamen çözünür (>1000 g/L) -
Etanolde Çözünürlük Çözünür -
Asetonde Çözünürlük Çözünür -
pH (1% çözelti) Hafif asidik (~3-4) -
Higroskopiklik Yüksek Havadan nem emer
Stabilite Normal koşullarda kararlı -
Kırılma İndisi ~1.55 -

4. SAFLIK DERECELERİ

Parametre Endüstriyel Sınıf Yüksek Saflık Sınıfı Optik / Ultra Sınıf
Saflık ≥ %99.0 ≥ %99.9 ≥ %99.99
La(NO₃)₃·6H₂O İçeriği ≥ %99.0 ≥ %99.9 ≥ %99.99
Ağır Metaller (Pb) ≤ 50 ppm ≤ 10 ppm ≤ 5 ppm
Demir (Fe) ≤ 50 ppm ≤ 10 ppm ≤ 5 ppm
Kalsiyum (Ca) ≤ 100 ppm ≤ 20 ppm ≤ 10 ppm
Sodyum (Na) ≤ 100 ppm ≤ 20 ppm ≤ 10 ppm
Klorür (Cl⁻) ≤ 0.05% ≤ 0.02% ≤ 0.01%
Sülfat (SO₄²⁻) ≤ 0.1% ≤ 0.05% ≤ 0.02%
Diğer Nadir Topraklar ≤ %1.0 ≤ %0.1 ≤ %0.01
Kurutma Kaybı ≤ %0.5 ≤ %0.3 ≤ %0.2

5. KARARLILIK VE REAKTİVİTE

Parametre Bilgi
Kimyasal Kararlılık Normal koşullarda kararlı; nemli ortamda sıvılaşabilir
Kaçınılması Gereken Koşullar Yüksek sıcaklık (>150°C), nem, güçlü indirgeyiciler
Uyumsuz Maddeler Güçlü indirgeyiciler, organik maddeler, asit anhidritler
Tehlikeli Bozunma Ürünleri Lantan oksit (La₂O₃), azot oksitler (NOₓ)
Tehlikeli Polimerizasyon Gerçekleşmez
Higroskopiklik Yüksek; havadan nem emer, sıvılaşabilir
Fotosensitivite Düşük

5.1. Kimyasal Reaksiyonlar

Termal Bozunma:

4La(NO₃)₃·6H₂O → 2La₂O₃ + 12NO₂↑ + 3O₂↑ + 24H₂O↑

Alkali ile Reaksiyon:

La(NO₃)₃ + 3NaOH → La(OH)₃↓ + 3NaNO₃

Fosfat ile Reaksiyon:

La(NO₃)₃ + Na₃PO₄ → LaPO₄↓ + 3NaNO₃

6. UYGULAMA ALANLARI

6.1. Cam Üretimi

Uygulama Fonksiyon Detaylar
Optik Cam Kırılma indeksi artırıcı Yüksek kırılma indeksi ve düşük dağılım sağlar
Fotoğraf Lensleri Optik kalite Renk sapmasını azaltır
UV Emici Cam UV absorpsiyonu Ultraviyole ışığı emer
Özel Cam Katkı maddesi Cam özelliklerini iyileştirir

6.2. Laboratuvar ve Reaktif Kullanımı

Uygulama Fonksiyon Detaylar
Analitik Reaktif Standart çözelti Nadir toprak çözeltilerinin hazırlanması
Sentez Öncüsü Başlangıç maddesi Diğer lantan bileşiklerinin sentezi
Araştırma Laboratuvar kimyasalı Kimyasal araştırma ve geliştirme
Standart Hazırlama Referans malzeme Kalibrasyon ve analiz

6.3. Katalizör Sistemleri

Uygulama Fonksiyon Detaylar
Katalizör Öncüsü Aktif faz Organik sentez reaksiyonları
Taşıyıcı Malzeme Destek Katalizör taşıyıcı olarak
Petrokimya Rafineri katalizörleri Hidrokarbon dönüşümü
Çevre Katalizi DeNOx sistemleri Emisyon kontrolü

6.4. Seramik Endüstrisi

Uygulama Fonksiyon Detaylar
Dielektrik Katkı Elektriksel özellikler Seramik kondansatörler
Yüksek Sıcaklık Seramikleri Isıl kararlılık Termal dayanım artışı
Elektronik Seramikler Katkı maddesi Elektriksel özellikleri iyileştirir
Pigment Öncüsü Renk katkısı Seramik pigmentler için öncü

6.5. Elektrokaplama

Uygulama Fonksiyon Detaylar
İyonik Kaplama Kaplama çözeltisi Metal yüzeylerde iyonik kaplama
Yüzey Modifikasyonu Yüzey işleme Özel kaplama uygulamaları
Lantan Kaplamaları Koruyucu kaplama Korozyon direnci

6.6. Diğer Uygulamalar

Uygulama Fonksiyon Detaylar
Fosfat Bağlayıcı Farmasötik araştırma Fosfat bağlama çalışmaları
Nanomalzeme Öncüsü Sentez öncüsü Lantan içeren nanomalzemeler
Yakıt Hücreleri Elektrolit katkısı Katı oksit yakıt hücreleri
Lazer Malzemeleri Katkı maddesi Lazer kristalleri

7. PRODUCTION PROCESS

7.1. Ore Sources

Lanthanum nitrate is derived from lanthanum-containing ores:

Ore Type Lanthanum Content Main Locations
Monazite 10-30% of REE content Australia, Brazil, India, China
Bastnäsite 20-30% of REE content China, USA (Mountain Pass), Vietnam
Xenotime 5-10% of REE content China, Malaysia, Australia

7.2. Production Process Flow

Lanthanum Oxide (La₂O₃) or Lanthanum Carbonate
         ↓
Dissolution in Nitric Acid (HNO₃)
         ↓
La(NO₃)₃ Solution Formation
         ↓
Filtration → Purification
         ↓
Evaporation → Crystallization
         ↓
La(NO₃)₃·6H₂O Crystals
         ↓
Drying → Classification → Packaging

7.3. Process Stages

Stage Description
1. Raw Material Lanthanum oxide (La₂O₃) or lanthanum carbonate is used as starting material
2. Acid Dissolution Lanthanum oxide is dissolved in nitric acid (HNO₃)
3. Solution Formation La(NO₃)₃ solution is formed
4. Filtration Solution is filtered to remove impurities
5. Evaporation Water is evaporated to concentrate the solution
6. Crystallization La(NO₃)₃·6H₂O crystals are formed
7. Drying Crystals are dried under controlled conditions
8. Packaging Packaged in moisture-proof containers due to hygroscopic nature

8. ALTERNATIVE MATERIALS COMPARISON

Application Area Alternative Materials Notes
Glass Additive Lanthanum Oxide, Cerium Nitrate Different optical and UV properties
Laboratory Solutions Lanthanum Chloride, Lanthanum Acetate Different solubility and ionic properties
Electroplating Neodymium Nitrate, Praseodymium Nitrate Similar ionic behavior
Catalyst Precursor Lanthanum Acetate, Lanthanum Chloride Different decomposition characteristics

9. SAFETY AND TOXICOLOGY

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 2,000 mg/kg (low toxicity)
Dermal Toxicity Low
Skin Irritation Mild irritant
Eye Irritation Mild to severe irritant
Inhalation Dust may cause respiratory irritation
Carcinogenicity Not classified as a carcinogen
Mutagenicity Not mutagenic
Chronic Effects May cause liver effects at high doses
Oxidizing Properties Not a strong oxidizer, but supports combustion
Environmental Hazards Low to moderate toxicity to aquatic life

10. GHS CLASSIFICATION

Hazard Class Category H-Statement
Skin Irritation Category 2 H315: Causes skin irritation
Eye Irritation Category 2 H319: Causes serious eye irritation
Specific Target Organ Toxicity Category 3 H335: May cause respiratory irritation
Oxidizing Solid Category 3 H272: May intensify fire; oxidizer

Signal Word: WARNING

Hazard Pictograms: GHS03 (Flame over circle), GHS07 (Exclamation Mark)

11. PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking
P220 Keep/Store away from clothing/.../combustible materials
P261 Avoid breathing dust
P264 Wash hands thoroughly after handling
P271 Use only in well-ventilated areas
P280 Wear protective gloves/eye protection/face protection
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present
P337+P313 If eye irritation persists: Get medical advice/attention
P501 Dispose of contents/container in accordance with local regulations

12. FIRST AID MEASURES

Route of Exposure Action to Be Taken
Inhalation Move to fresh air. If symptoms persist, seek medical attention
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes. Remove contact lenses. If irritation persists, seek medical attention
Ingestion Rinse mouth. Drink plenty of water. Do not induce vomiting. Seek medical attention

13. STORAGE AND SHELF LIFE

Parameter Condition
Storage Conditions Store in a cool, dry, well-ventilated area
Container Requirements Moisture-proof, tightly sealed containers
Moisture Protection Store with desiccant (silica gel)
Temperature Room temperature (15-25°C)
Shelf Life 24 months under proper conditions
Stability Note Hygroscopic; may become damp or deliquesce if exposed to moisture

14. PACKAGING OPTIONS

Packaging Type Quantity Material
PE Bag 1 kg, 5 kg, 10 kg Polyethylene, moisture-proof
Glass Bottle 100 g, 500 g Amber glass with desiccant
Plastic Drum 25 kg, 50 kg HDPE drum, moisture-proof
Fiber Drum 25 kg, 50 kg PE-lined, moisture-proof

15. TRANSPORT INFORMATION

Parameter Information
UN Number Not applicable (not dangerous goods)
Hazard Class Not applicable
Packing Group Not applicable
ADR/RID Not regulated
IMDG Not regulated
IATA Not regulated

16. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Registered
Turkey (KKDIK) Compliance required
TSCA (USA) Registered
EINECS 233-238-0
HS Code 2846.90

17. OTHER NAMES AND SYNONYMS

  • Lanthanum(III) Nitrate

  • Lanthanum Nitrate Hexahydrate

  • La(NO₃)₃·6H₂O

  • Rare Earth Nitrate

  • Optical Grade Lanthanum Nitrate

  • Lanthanum Trinitrate

  • Nitric Acid, Lanthanum Salt

18. QUICK REFERENCE TABLE

Property Value
CAS Number 10277-43-7
EC Number 233-238-0
Chemical Formula La(NO₃)₃·6H₂O
Molecular Weight 433.01 g/mol
Appearance White, crystalline, hygroscopic solid
Density ~2.5 g/cm³
Water Solubility Completely soluble (>1000 g/L)
pH (1% solution) ~3-4 (slightly acidic)
Purity ≥ 99.9% (high purity grade)
Hygroscopicity High
HS Code 2846.90
GHS Signal Word WARNING
UN Number Not applicable

19. CRITICAL NOTICES AND BEST PRACTICES

CRITICAL NOTICES:

  1. Hygroscopic Property: Lanthanum nitrate hexahydrate is highly hygroscopic and readily absorbs moisture from the air. May become damp or deliquesce if exposed to moisture. Must be stored in moisture-proof containers.

  2. Thermal Decomposition: Decomposes at temperatures above 150°C, releasing toxic nitrogen oxides (NOₓ). Should not be heated above this temperature.

  3. Oxidizing Properties: May intensify fire and act as an oxidizer. Should be kept away from combustible materials.

  4. Skin and Eye Irritation: Causes skin and eye irritation. Use appropriate personal protective equipment.

  5. Inhalation Hazard: Dust may cause respiratory irritation. Use in well-ventilated areas or with dust control measures.

  6. Acid Sensitivity: Reacts with acids to release nitric acid fumes.

  7. Solution Stability: Aqueous solutions are stable but may hydrolyze over time.

BEST PRACTICE RECOMMENDATIONS:

Storage:

  • Store in a cool, dry, well-ventilated area

  • Use moisture-proof, tightly sealed containers

  • Store with desiccant (silica gel)

  • Keep away from combustible materials

  • Store at room temperature (15-25°C)

Handling:

  • Use in well-ventilated areas

  • Use dust mask, protective goggles, and gloves

  • Avoid dust formation

  • Wash hands after handling

  • Immediately reseal container after use

Waste Management:

  • Dispose in accordance with local regulations

  • Do not discharge into water bodies

  • Consider rare earth recovery for large quantities

Fire Prevention:

  • Keep away from heat, sparks, and open flames

  • Use appropriate fire extinguishing media (water, CO₂, dry chemical)

LEGAL DISCLAIMER

This Technical Data Sheet (TDS) is for informational purposes only and is prepared based on available technical data. The user is solely responsible for determining the suitability of the product for their specific application and for complying with all local, national, and international regulations. For complete safety, storage, handling, transport, waste, and regulatory compliance information, the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier must be consulted. This document does not substitute professional advice. Lanthanum nitrate is a hygroscopic material; appropriate precautions must be taken during handling.

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