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Dimethylpyrazole Phosphate, 3,4-Dimethylpyrazole Phosphate, Pyrazole-based Nitrification Inhibitor, DMPP, 202842-98-6

Dimethylpyrazole Phosphate, 3,4-Dimethylpyrazole Phosphate, Pyrazole-based Nitrification Inhibitor, DMPP, 202842-98-6

🌱 DMPP in Agriculture: Technical Overview

🧪 What is DMPP?

  • Full Name: 3,4-Dimethylpyrazole phosphate

  • CAS Number: 202842-98-6

  • Function: A nitrification inhibitor used in fertilizers to slow the conversion of ammonium (NH₄⁺) to nitrate (NO₃⁻), thereby reducing nitrogen loss and improving nutrient efficiency.

✅ Benefits of DMPP

Benefit Description
Reduces Nitrogen Loss Minimizes leaching and volatilization by stabilizing ammonium nitrogen.
Improves Crop Yield Enhances root development and nitrogen uptake, leading to 10–20% higher yields.
Environmental Protection Reduces nitrate contamination in groundwater.
Efficient Fertilizer Use Extends nitrogen availability for 6–10 weeks.
Better Plant Health Promotes deeper green foliage and balanced growth.

⚠️ Risks and Precautions

Risk Description
Microbial Disruption May suppress soil microbial activity involved in nitrification.
Surface Application Failure Ineffective if not incorporated into soil or followed by irrigation.
Overdosage Excessive use may hinder plant development or soil balance.
Temperature Sensitivity Volatility increases above 30 °C; optimal effect at neutral pH.
Limited Duration Effectiveness fades after 6–10 weeks; not suitable for long-term nitrogen control.

🧑‍🌾 Application Guidelines

📌 Timing

  • Before Sowing: Mixed with base fertilizer during soil preparation.

  • At Sowing: Applied simultaneously via drill or broadcast.

  • After Sowing: Can be applied with top dressing, ideally before rainfall or irrigation.

📌 Method

  • Granular Form: Pre-mixed in NPK fertilizers (e.g., NovaTec, Inotec).

  • Liquid Form: Added to fertigation systems or sprayed directly.

📌 Dosage Examples

Product DMPP Content Application Rate Crop Type
NovaTec Classic ~0.8% 25–40 kg/ha Cereals, corn, sunflower
Inotec 15-15-15 ~1.0% 20–30 kg/ha Vegetables, vineyards
Nova Complex Optima ~0.5% 30–50 kg/ha Greenhouse, seedlings

🏭 Production Process

Step Description
Raw Materials 3,4-Dimethylpyrazole + Phosphorylating agent
Reaction Condensation and phosphorylation under controlled temperature (50–80 °C)
Purification Crystallization, filtration, solvent extraction
Drying & Packaging Final product in powder or liquid form, packed in PE bags, drums, or IBCs

Major Producers: BASF (Germany), COMPO Expert, Chinese manufacturers (e.g., NBINNO, Hebei)

🔄 Alternatives to DMPP

Compound CAS No Duration Notes
DCD (Dicyandiamide) 461-58-5 4–6 weeks Cost-effective, widely used
NPPT (Nitrapyrin) 1929-82-4 6–8 weeks Effective in corn and wheat
DMPSA 202842-98-6 8–12 weeks Environmentally friendly
NBPT 94317-64-3 1–2 weeks Urea stabilizer, not a nitrification inhibitor

🧾 Synonyms and Identifiers for DMPP

Type Name / Code
IUPAC Name 3,4-Dimethyl-1H-pyrazole phosphate
Common Name DMPP
Chemical Class Pyrazole-based nitrification inhibitor
CAS Number 202842-98-6
EC Number 606-013-00-4
REACH Registration Often listed under “nitrification inhibitors” or “soil additives”
Trade Names NovaTec® (COMPO Expert), Inotec® (Univera), Optima® (ICL)
Fertilizer Labeling Sometimes listed as “stabilized nitrogen” or “N-stabilizer”

 

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