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Polyglycerol Polyricinoleate, Polyglycerol Esters of Condensed Castor Oil Fatty Acids, PGPR, E476, 29894-35-7

Polyglycerol Polyricinoleate, Polyglycerol Esters of Condensed Castor Oil Fatty Acids, PGPR, E476, 29894-35-7

POLYGLYCEROL POLYRICINOLEATE (E476 - PGPR)

PRODUCT IDENTIFICATION INFORMATION

Parameter Information
Product Name Polyglycerol Polyricinoleate
Chemical Name Polyglycerol esters of condensed castor oil fatty acids
Synonyms (Turkish) Poligliserol Polirisinoleat, PGPR, Poligliserol Polirisinoleat Esterleri
Synonyms (English) Polyglycerol Polyricinoleate, PGPR, Polyglycerol esters of polycondensed ricinoleic acid
E Number E476
CAS Number 29894-35-7
Molecular Formula Complex mixture of esters (C₁₈H₃₄O₃)n
Molecular Weight Variable (typically 1,000 – 2,000 g/mol)
Appearance Clear, yellowish to brownish viscous liquid
Odor Characteristic mild odor; No off-odors

CHEMICAL STRUCTURE

PGPR Structure (Simplified Representation):

                    O
                    ||
Ricinoleic Acid—O—CH₂—(CH—CH₂—O)—CH—CH₂—O—CO—Ricinoleic Acid
                    |
                 CH₂OH

Structure Description:

  • Polyglycerol (typically 2-10 glycerol units) esterified with polycondensed ricinoleic acid (from castor oil).

  • Complex mixture of esters formed by polyglycerol and polyricinoleic acid.

  • Contains hydrophilic polyglycerol groups and lipophilic polyricinoleic acid groups.

  • Non-ionic surfactant and emulsifier.

SECTION 1: CHEMICAL IDENTITY AND DESCRIPTION

Parameter Information
Product Name Polyglycerol Polyricinoleate
Chemical Name Polyglycerol esters of condensed castor oil fatty acids
Synonyms (Turkish) Poligliserol Polirisinoleat, PGPR, Poligliserol Polirisinoleat Esterleri
Synonyms (English) Polyglycerol Polyricinoleate, PGPR, Polyglycerol esters of polycondensed ricinoleic acid
E Number E476
CAS Number 29894-35-7
Molecular Formula Complex mixture of esters (C₁₈H₃₄O₃)n
Molecular Weight Variable (typically 1,000 – 2,000 g/mol)
Chemical Class Non-ionic emulsifier; Polyglycerol ester; Food additive
Source Synthetic (esterification of polyglycerol with condensed castor oil fatty acids)
Physical State (20°C) Liquid (viscous)
Odor Characteristic mild odor; No off-odors
Color Clear, yellowish to brownish
Taste Neutral; No unpleasant taste

SECTION 2: PHYSICAL AND CHEMICAL PROPERTIES

Property Value Test Method / Note
Appearance Clear, yellowish to brownish viscous liquid Visual
Odor Characteristic mild odor; No off-odors Olfactometric
Molecular Weight 1,000 – 2,000 g/mol (variable) Calculated / GPC
Density (20°C) ~0.94 – 0.98 g/cm³ ASTM D4052
Melting Point Liquid at room temperature; Solidifies at low temperatures
Viscosity (25°C) ~500 – 1,500 cP Brookfield
Boiling Point Decomposes before boiling
Flash Point > 200°C
Solubility in Water Insoluble in cold water; Dispersible General Method
Solubility in Ethanol Soluble General Method
Solubility in Acetone Soluble General Method
Solubility in Fats/Oils Soluble General Method
Solubility in Hot Water Dispersible (forms emulsion) General Method
Log P (Octanol/Water) Lipophilic (HLB ~ 1-3)
HLB Value ~1 – 3 (very low)
pH (1% Dispersion) ~4.0 – 6.0 pH Meter
Stability Good thermal stability; Stable at high temperatures
Emulsification Properties Excellent water-in-oil (W/O) emulsifier
Heavy Metals (as Pb) ≤ 10 ppm AAS / ICP
Arsenic (As) ≤ 2 ppm AAS / ICP
Lead (Pb) ≤ 2 ppm AAS / ICP
Acid Value ≤ 6.0 mg KOH/g Titrimetric
Saponification Value 170 – 185 mg KOH/g Titrimetric
Hydroxyl Value 50 – 70 mg KOH/g Titrimetric
Iodine Value 70 – 95 g I₂/100g Titrimetric
Loss on Drying ≤ 0.5% Gravimetric
Assay (PGPR) ≥ 99.0% HPLC / Gravimetric

SECTION 3: PGPR (E476) vs OTHER EMULSIFIERS

Property PGPR (E476) Lecithin (E322) Mono- and Diglycerides (E471) Polyglycerol Esters (E475)
CAS Number 29894-35-7 8002-43-5 Various 67784-82-1
Type Non-ionic Amphoteric Non-ionic Non-ionic
HLB Value ~1 – 3 ~4 – 8 ~2 – 4 ~5 – 12
Emulsion Type Water-in-oil (W/O) Oil-in-water (O/W) W/O and O/W O/W and W/O
Viscosity High viscosity liquid Liquid/Paste Solid/Paste Liquid/Paste
Heat Stability Excellent Moderate Good Good
Primary Use Chocolate, low-fat spreads Chocolate, bakery, margarine Bakery, dairy, margarine Bakery, dairy, cosmetics
Cost Medium Low-Medium Low Medium-High
Vegetarian/Vegan Yes (from castor oil) Yes (from soy/egg) Yes (from plant/animal) Yes (from plant)
Allergenicity Low Soy allergy concern Low Low

SECTION 4: MECHANISM OF ACTION

Property Description
Emulsification Mechanism Reduces interfacial tension between water and oil phases; Stabilizes water-in-oil (W/O) emulsions; Prevents coalescence and separation.
Viscosity Modification Imparts high viscosity to the continuous phase; Provides structural stability; Affects flow properties.
Fat Crystal Modification Interacts with fat crystals; Prevents fat bloom; Controls crystallization behavior.
Yield Value Reduction Reduces yield value and plastic viscosity; Enables better flow; Facilitates molding and pumping.
Surface Activity Highly lipophilic (very low HLB); Adsorbs at oil-water interfaces; Forms stable interfacial films.
Bubble Elimination Eliminates small bubbles and voids; Prevents hollow hole formation; Facilitates easy demolding; Improves product structure.

SECTION 5: PRODUCTION PROCESS

Method 1: Esterification of Polyglycerol with Polyricinoleic Acid

Reaction: Polyglycerol + Condensed Castor Oil Fatty Acids → PGPR + Water

Description: Castor oil is hydrolyzed to obtain ricinoleic acid; Ricinoleic acid is polymerized (condensed) to form polyricinoleic acid; Glycerol is polymerized to form polyglycerol; Polyglycerol and polyricinoleic acid are esterified under vacuum at high temperature; Product is purified by distillation and filtration.

Method 2: Direct Esterification of Polyglycerol with Castor Oil Fatty Acids

Process: Castor Oil → Hydrolysis → Ricinoleic Acid → Polymerization → Polyricinoleic Acid → Esterification → PGPR

Description: Direct esterification process using pre-prepared polyglycerol and polyricinoleic acid; Optimized reaction conditions for specific product properties.

SECTION 6: FUNCTIONAL PROPERTIES

Property Description
Chocolate Viscosity Reducer Enables production of high-quality chocolate with reduced cocoa butter content; Reduces yield value and plastic viscosity; Allows production of thinner chocolate with less fat.
Emulsifier (W/O) Stabilizes water-in-oil emulsions; Used in low-fat spreads and sauces; Prevents phase separation.
Flow Improver Facilitates easy discharge and molding; Improves pumping properties; Enhances processing efficiency.
Bubble/Void Eliminator Eliminates formation of small bubbles and hollow holes; Results in smooth, dense product structure.
Fat Bloom Prevention Interacts with fat crystals; Prevents surface fat crystallization; Maintains glossy appearance.
Thermal Stability Excellent thermal stability; Maintains function at high temperatures; Suitable for hot processing.
Synergistic Action Works effectively with lecithin; Enhanced performance in chocolate systems; Better results in combination.

SECTION 7: MAIN APPLICATION AREAS

Industry / Application Function Typical Use
Chocolate & Confectionery Viscosity reducer, emulsifier Chocolate, compound coatings, pralines, filling creams; Dosage: 0.1 – 1.0% of total weight
Low-Fat Spreads Emulsifier, stabilizer Low-fat spreads (<41% fat), table spreads; Dosage: 0.2 – 1.0%
Sauces & Dressings Emulsifier Water-in-oil emulsions, creamy sauces; Dosage: 0.1 – 0.5%
Ice Cream Mixes Stabilizer, emulsifier Ice cream, frozen desserts; Dosage: 0.1 – 0.3%
Confectionery Stabilizer Chewing gum, soft candy, marzipan; Dosage: 0.1 – 0.5%
Cocoa-Based Products Viscosity modifier, emulsifier Cocoa-based confectionery, chocolate spreads, cocoa drinks; Dosage: 0.1 – 1.0%
Pharmaceutical Emulsifier, stabilizer Ointments, creams, oral formulations; Dosage: 0.1 – 0.5%
Cosmetics Emulsifier, skin conditioner Creams, lotions, makeup, skincare; Dosage: 0.1 – 0.5%
Oil-Water Emulsions Stabilizer Various food emulsions, technical emulsions; Dosage: 0.1 – 1.0%

SECTION 8: SAMPLE FORMULATIONS

Chocolate Viscosity Reduction (100 kg Chocolate):

Component Amount
PGPR (E476) 0.1 – 1.0 kg
Lecithin (E322) 0.3 – 0.5 kg
Sugar As required
Cocoa Butter As required
Cocoa Mass As required

Instructions: Add PGPR during the conching process; For best results, use in combination with lecithin; Add at 45-50°C; Mix thoroughly for optimal dispersion.

Low-Fat Spread (100 kg):

Component Amount
PGPR (E476) 0.2 – 1.0 kg
Oil Phase 20 – 40 kg
Water Phase 60 – 80 kg
Other Emulsifiers As required
Flavorings As required
Preservatives As required

Instructions: Dissolve PGPR in the oil phase; Mix oil and water phases with high shear; Homogenize; Cool with stirring.

SECTION 9: QUALITY SPECIFICATIONS

Parameter Food Grade (E476) Pharmaceutical Grade Cosmetic Grade Test Method
Appearance Clear, yellowish to brownish liquid Clear, yellowish liquid Clear, yellowish liquid Visual
Assay (PGPR) ≥ 99.0% ≥ 99.5% ≥ 99.0% HPLC / Gravimetric
Acid Value ≤ 6.0 mg KOH/g ≤ 5.0 mg KOH/g ≤ 6.0 mg KOH/g Titrimetric
Saponification Value 170 – 185 mg KOH/g 172 – 183 mg KOH/g 170 – 185 mg KOH/g Titrimetric
Hydroxyl Value 50 – 70 mg KOH/g 50 – 70 mg KOH/g 50 – 70 mg KOH/g Titrimetric
Iodine Value 70 – 95 g I₂/100g 72 – 90 g I₂/100g 70 – 95 g I₂/100g Titrimetric
Loss on Drying ≤ 0.5% ≤ 0.5% ≤ 0.5% Gravimetric
Heavy Metals (as Pb) ≤ 10 ppm ≤ 5 ppm ≤ 10 ppm AAS / ICP
Arsenic (As) ≤ 2 ppm ≤ 1 ppm ≤ 2 ppm AAS / ICP
Lead (Pb) ≤ 2 ppm ≤ 1 ppm ≤ 2 ppm AAS / ICP
Peroxide Value ≤ 5.0 meq/kg ≤ 3.0 meq/kg ≤ 5.0 meq/kg Titrimetric
Viscosity (25°C) 500 – 1,500 cP Customer requirement Customer requirement Brookfield
Density (20°C) 0.94 – 0.98 g/cm³ 0.95 – 0.97 g/cm³ 0.94 – 0.98 g/cm³ ASTM D4052

SECTION 10: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity (LD50, Rat) > 5,000 mg/kg (low toxicity)
Acute Dermal Toxicity Low toxicity; No significant irritation
Skin Irritation Non-irritating
Eye Irritation Mildly irritating
Chronic Toxicity Low toxicity; No significant effects
Carcinogenicity Not classified as carcinogenic
Mutagenicity Not mutagenic
Reproductive Toxicity No reproductive toxicity at normal levels
Allergenicity Low allergenicity; No known allergenicity
Acceptable Daily Intake (ADI) 25 mg/kg body weight (EFSA and JECFA)
Special Toxicity Note Generally recognized as safe (GRAS); Approved for food use; High thermal stability reduces degradation products; Used safely in many food products; No known specific toxicity concerns; Metabolized to normal dietary components.

SECTION 11: GHS CLASSIFICATION AND LABELING

GHS Classification (in accordance with CLP and UN GHS):

Hazard Class Category H-Statement
Not classified as hazardous according to CLP criteria

Signal Word: None (Not classified as hazardous)

Hazard Pictograms: None

Hazard Statements (H-Codes):
Not classified as hazardous under GHS. In some jurisdictions, may be classified with:

Code Statement (if applicable)
H315 May cause skin irritation (mild)
H319 May cause eye irritation (mild)

NFPA 704 Hazard Classification:

Health Flammability Reactivity Special
0 1 0 -
(Minimal health hazard) (Combustible) (Stable) (None)

SECTION 12: PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P264 Wash hands thoroughly after handling
P280 Wear protective gloves/protective clothing/eye protection/face protection
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and continue rinsing
P332+P313 If skin irritation occurs: Get medical advice/attention
P337+P313 If eye irritation persists: Get medical advice/attention
P362+P364 Take off contaminated clothing and wash it before reuse
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P501 Dispose of contents/container in accordance with local/regional/national/international regulations

SECTION 13: FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air. If respiratory irritation develops, seek medical attention (unlikely due to low volatility).
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If irritation persists, get medical attention.
Eye Contact Rinse immediately with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses if present. If irritation persists, seek medical attention.
Ingestion Rinse mouth. Drink plenty of water. Seek medical attention if large quantities are ingested or if feeling unwell.

SECTION 14: FIREFIGHTING MEASURES

Parameter Information
Fire Hazard Combustible organic material. May burn with thick smoke.
Hazards Arising from Fire Thermal decomposition produces carbon monoxide, carbon dioxide, and irritating fumes.
Suitable Extinguishing Media Water spray, CO₂, dry chemical powder, foam.
Unsuitable Extinguishing Media Water jet (may spread burning liquid)
Special Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing.
Special Precautions Prevent material from entering sewers and waterways. Use protective equipment.

SECTION 15: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Store in a cool, dry, well-ventilated area; PROTECT FROM LIGHT and HEAT; Keep away from direct sunlight and high temperatures.
Container Requirements Tightly closed containers (HDPE, PET, stainless steel, coated drums).
Materials to Protect From Light, heat, strong oxidizing agents, moisture
Shelf Life 24 – 36 months (in unopened original packaging, under proper storage conditions).
Stability Note Stable under recommended storage conditions; May thicken or become cloudy at low temperatures (reversible); Good thermal stability; Resists oxidation.
Special Storage Requirements Store in a dark, cool, dry place; Avoid exposure to air and light; Opened containers must be resealed immediately; Keep away from sources of ignition.

SECTION 16: PACKAGING OPTIONS

Packaging Type Quantity Material
Plastic Canister 5 L, 10 L, 20 L HDPE / PET (chemical-resistant)
Plastic Drum 25 kg, 50 kg, 100 kg HDPE / Polypropylene (sealed)
Steel Drum 50 kg, 100 kg, 200 kg Stainless steel or lined steel drum
Composite Container 25 kg, 50 kg PE-lined composite drum
IBC Container 500 L, 1000 L HDPE or stainless steel IBC
Flexitank 15,000 – 20,000 kg Multi-layer flexitank for bulk transport

SECTION 17: TRANSPORT INFORMATION

Parameter Information
UN Number Not regulated (non-hazardous)
Hazard Class Not applicable
Packing Group Not applicable
ADR/RID Not regulated
IMDG Code Not regulated (non-hazardous)
IATA (Air) Not regulated (non-hazardous)
Marine Pollutant No
Transport Temperature Ambient temperature; Protect from moisture and extreme temperatures.

SECTION 18: REGULATORY STATUS

Region / Authority Status
European Union Food additive E476 approved by EFSA; ADI: 25 mg/kg; Approved for specific food categories.
USA (TSCA) Listed (TSCA Inventory)
USA (FDA) GRAS (Generally Recognized as Safe); Food additive; 21 CFR 172.854
Turkey Food additive E476; Ministry of Agriculture approval required; Approved for use.
JECFA Approved; ADI: 25 mg/kg body weight; Specifications included.
IARC Not classified (non-carcinogenic)
NTP Not listed
OSHA Not regulated as hazardous
California (Prop 65) Not listed
Halal Yes (with certification, from halal sources)
Kosher Yes (with certification)
Vegan Yes (from castor oil, no animal ingredients)

SECTION 19: OTHER NAMES AND SYNONYMS

Type Name
Turkish Names Poligliserol Polirisinoleat, PGPR, Poligliserol Polirisinoleat Esterleri, Poligliserolün (Yoğunlaştırılmış Kastor Yağı Asitleri) Esterleri
English Names Polyglycerol Polyricinoleate, PGPR, Polyglycerol esters of polycondensed ricinoleic acid, Polyglycerol esters of condensed castor oil fatty acids
E Number E476
CAS Number 29894-35-7
HS Code 3404.20
Synonyms Polyglycerol polyricinoleate ester, Polyglycerol ricinoleate, PGPR 90, Polymuls

SECTION 20: SUMMARY TABLE

Parameter Value
Product Polyglycerol Polyricinoleate (PGPR - E476)
CAS Number 29894-35-7
E Number E476
Molecular Formula Complex mixture of esters (C₁₈H₃₄O₃)n
Molecular Weight Variable (1,000 – 2,000 g/mol)
Appearance Clear, yellowish to brownish viscous liquid
Primary Function Emulsifier, viscosity reducer, stabilizer
Main Application Areas Chocolate & confectionery, low-fat spreads, sauces, ice cream, pharmaceuticals, cosmetics
Shelf Life 24 – 36 months
GHS Signal Word None (Not classified as hazardous)
UN Number Not regulated
Special Properties Water-in-oil (W/O) emulsifier; Very low HLB (~1-3); Reduces chocolate viscosity; Excellent thermal stability; Synergistic with lecithin; ADI: 25 mg/kg; Vegan and halal certified.

SECTION 21: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • Not classified as hazardous under normal conditions of use.

  • Emulsifier primarily used for water-in-oil (W/O) emulsions.

  • Very effective in chocolate: Reduces yield value and viscosity; Enables reduced cocoa butter content.

  • Synergistic with lecithin: Works best when used together.

  • Thermally stable: Suitable for hot processing; Good heat resistance.

  • Insoluble in cold water: Dispersion requires proper mixing techniques.

  • May become cloudy or thicken at low temperatures (reversible upon warming).

  • No known allergenicity; Suitable for most dietary requirements.

  • ADI: 25 mg/kg body weight – safe at recommended usage levels.

BEST PRACTICE RECOMMENDATIONS:

  • Chocolate & Confectionery: Add during conching process; Recommended dosage: 0.1-1.0% of total weight; Use with lecithin (typically 3:1 to 5:1 lecithin:PGPR ratio); Add at 45-50°C; Mix thoroughly for optimal dispersion; Results in thinner chocolate with better flow properties.

  • Low-Fat Spreads: Use as primary emulsifier; Dosage: 0.2-1.0%; Dissolve in oil phase; Important for low-fat formulations (<41% fat); Provides stable water-in-oil emulsion.

  • Sauces & Dressings: Use as W/O emulsifier; Dosage: 0.1-0.5%; Dissolve in oil phase; Combine with other emulsifiers if needed.

  • Ice Cream: Use as stabilizer/emulsifier; Dosage: 0.1-0.3%; Improves texture and body; Reduces ice crystal formation.

  • Pharmaceuticals: Use as emulsifier in ointments and creams; Dosage: 0.1-0.5%; Dissolve in oil phase; Non-irritating.

  • Cosmetics: Use as emulsifier and skin conditioner; Dosage: 0.1-0.5%; Dissolve in oil phase; Stable formulations; Non-comedogenic.

  • Handling: Use appropriate pumping equipment; Room temperature handling; Avoid low temperatures during processing; Use proper mixing systems for dispersion.

  • Personal Protective Equipment: Chemical-resistant gloves, safety goggles, protective clothing (minimal risk).

  • Hygiene: Wash hands after handling; Maintain good industrial hygiene.

  • Storage: Store in tightly closed containers; Store in cool, dry, well-ventilated area; Protect from light and heat; Avoid exposure to air and moisture; Opened containers must be resealed immediately; Shelf life: 24-36 months under proper conditions.

  • Spill Management: Absorb with inert material (sand, vermiculite); Contain and collect; Avoid entry into drains or waterways.

  • Disposal: Dispose of in accordance with local, regional, and national regulations; Non-hazardous waste; Can be incinerated or recycled.

DETECTION METHODS:

Method Description Advantages Disadvantages
HPLC Most common for food and pharmaceutical products High sensitivity, reliable High cost, requires expertise
GC-FID Fatty acid profile analysis Detects component fatty acids Complex sample preparation
TLC Fingerprinting method Rapid screening, low cost Semi-quantitative
FTIR Functional group identification Fast, non-destructive Requires reference spectra
Acid/Saponification Values Chemical characterization Simple, standard method Not specific to PGPR

PGPR (E476) vs ALTERNATIVES COMPARISON:

Product Chemical Name / E Code Application Strength Weakness Status
PGPR (E476) Polyglycerol Polyricinoleate Chocolate, low-fat spreads, sauces Excellent W/O emulsifier, reduces chocolate viscosity High viscosity, limited use Widely approved
Lecithin (E322) Phosphatidylcholine Chocolate, bakery, margarine Natural, widely available Soy allergy, moderate performance Widely approved
Mono- & Diglycerides (E471) Glycerol fatty acid esters Bakery, dairy, margarine Versatile, low cost Low emulsifying power Widely approved
Polyglycerol Esters (E475) Polyglycerol fatty acid esters Bakery, dairy, cosmetics High HLB variety, good emulsifier Higher cost Widely approved
Sorbitan Esters (E491-495) Sorbitan esters Bakery, chocolate Good W/O emulsifier Digestion concerns Approved, restricted

LEGAL DISCLAIMER:
The information provided in this document is based on our current knowledge and experience and is presented in good faith. However, as all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing the suitability for their own applications and for complying with all local, regional, and national regulations. For complete safety, storage, use, handling, waste, and regulatory compliance information, please refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.

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