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Cocamidopropyl Betaine, CAPB​​​​​​, CAB-35, CAB-45, 61789-40-0

Cocamidopropyl Betaine, CAPB​​​​​​, CAB-35, CAB-45, 61789-40-0

COCAMIDOPROPYL BETAINE (CAPB)

1. PRODUCT DEFINITION AND CHEMICAL IDENTITY

Parameter Description
Chemical Name (IUPAC) 1-Propanaminium, 3-amino-N-(carboxymethyl)-N,N-dimethyl-, N-coco acyl derivatives, inner salt
Common Name Cocamidopropyl Betaine (CAPB)
Common Abbreviations CAPB, CAB
CAS Number 61789-40-0
EC Number 263-058-8
Molecular Formula C₁₉H₃₈N₂O₃ (representative)
Molecular Weight 342.52 g/mol
Chemical Class Amphoteric Surfactant
HS Code / Tariff Code 3402.11.00
Appearance Clear, colourless to pale yellow liquid

Note: Cocamidopropyl Betaine is a high-foaming, mild amphoteric surfactant derived from coconut oil. It exhibits both anionic and cationic properties, making it effective over a wide pH range. Due to its exceptional mildness, excellent foam boosting, and viscosity-building properties, it is a primary ingredient in baby shampoos, shower gels, facial cleansers, and other sensitive skin personal care products.

2. PHYSICAL AND CHEMICAL PROPERTIES (Typical for 30-35% Active Grade)

Property Value / Description
Appearance (25 °C) Clear, colourless to pale yellow, free-flowing liquid
Odour Neutral, odourless or faint characteristic odour
Density (25 °C) ~1.05 – 1.057 g/cm³
Boiling point ~100 °C (as an aqueous solution)
Freezing point ~ -10 °C
pH (10% solution) 4.0 – 7.0 (grade dependent)
Solubility in water Completely miscible in all proportions
Cloud point (1% in water) -3 °C
Flash point (1% in water) >94 °C

3. TYPICAL TECHNICAL SPECIFICATIONS (by Common Grade)

Parameter CAB-35 (CAPB-35) CAB-45 (CAPB-45)
Active Matter Content (%) 28.0 – 32.0 38.0 – 42.0
Solid Content (%) 33.0 – 37.0 43.0 – 47.0
pH (1% solution) 4.0 – 7.0 5.0 – 7.0
Sodium Chloride (NaCl, %) ≤ 6.0 ≤ 7.0
Free Amine (%) ≤ 0.5 ≤ 0.5
Colour (Hazen) ≤ 100 ≤ 100
Density (g/mL, 25 °C) ~1.05 ~1.05
Cloud Point (1% aq.) -3 °C -3 °C
Freezing Point -10 °C -10 °C

4. FUNCTIONAL PROPERTIES AND MODE OF ACTION

  • Mild, High-Foaming Primary or Secondary Surfactant: As an amphoteric surfactant, it is exceptionally mild and generates a rich, dense, and creamy foam. It is a key ingredient for "tear-free" baby shampoos and products for sensitive skin.

  • Foam Booster and Stabilizer: In combination with anionic surfactants (like SLES or LABSA), it significantly enhances both the quantity and the stability of the foam. It adds a creamy, luxurious texture that is difficult to achieve with anionic surfactants alone.

  • Viscosity Builder: When used with anionic surfactants in the presence of salt (NaCl), CAPB dramatically increases the viscosity of the formulation, helping to create the desired gel-like consistency for shampoos and body washes. It also helps to mitigate the viscosity reduction caused by high fragrance or oil loads.

  • Skin and Hair Conditioner: It leaves the skin feeling soft and smooth and helps to reduce the static charge on hair, improving wet and dry combability.

  • Broad pH Stability: It maintains its surfactant properties effectively in both mildly acidic and alkaline formulations.

5. ANTIMICROBIAL EFFICACY

CAPB has been shown to exhibit antimicrobial activity against the following common microorganisms:

Microorganism Effect
Staphylococcus aureus Effective
Streptococcus pyogenes Effective
Bacillus subtilis Effective
Candida albicans Effective
Pityrosporum ovale Effective

6. ALTERNATIVE NAMES AND SYNONYMS

Category Names
Common Names Cocamidopropyl Betaine, CAPB, Coco Amido Betaine (CAB), Coconut Oil Amidopropyl Betaine
Trade Names Tego Betain, Dehyton PK, Empigen BB, Mackam CB-35, Mirataine BET-C 30
Chemical Synonyms N-(Coco alkyl) amidopropyl betaine, Cocoamidopropyldimethylglycine

7. SECTORAL APPLICATIONS, SUITABILITY, AND EXAMPLE FORMULATIONS

Sector / Product Function Typical Usage Rate
Personal Care & Cosmetics Baby shampoos, shower gels, facial cleansers, hand soaps, makeup removers 2 – 15%
Household Cleaning Dishwashing liquids, laundry detergents, hard surface cleaners 2 – 10%
Industrial & Institutional Metalworking fluids, agrochemical adjuvants, textile processing auxiliaries 1 – 5%

Example Formulations (as provided):

  • Economical Antibacterial Hand Soap: CAPB-35 (3.0%), SLES-70 (3.5%), CDEA-85 (1.0%), PCMX (0.2%), and q.s. water, salt, and citric acid to pH 7-8.

  • Degreasing Dishwashing Liquid: LABSA-96 (7.0%), SLES-70 (8.0%), CAPB-35 (3.0%), Caustic Soda (1.0%), and q.s. water, salt, and citric acid.

  • Concentrated Laundry Detergent: SLES-70 (14.0%), CAPB-35 (10.0%), LABSA-96 (3.0%), OP-10 (4.0%), AEO-9 (4.0%), and q.s. water, salt, and citric acid.

8. ADVANTAGES AND DISADVANTAGES

Advantages Disadvantages
Extremely mild, low irritation potential; ideal for sensitive skin and baby products Can reduce foam volume in very soft water if used in excess without optimizing the anionic ratio
Excellent foam booster; creates rich, creamy, and stable lather The high concentration product (CAPB-45) is viscous and may require gentle warming for easy handling
Effective viscosity builder, especially with salt in anionic surfactant systems  
Broad compatibility with anionic, cationic, and nonionic surfactants  
Biodegradable and environmentally friendly  

9. SAFETY, STORAGE, AND REGULATORY INFORMATION

  • GHS Classification: Not classified as a hazardous substance or mixture. It is a non-irritant at use concentrations.

  • Safety Profile: Extremely mild. The Cosmetic Ingredient Review (CIR) panel has confirmed its safety for use in cosmetic and personal care products. It is not a significant eye irritant, making it suitable for "tear-free" formulations.

  • Storage:

    • Store in a cool (5–30 °C), dry, and well-ventilated area in tightly sealed containers.

    • Use polyethylene (PE), polypropylene (PP), or HDPE containers. Avoid non-stainless steel tanks.

  • Freezing: The product may be affected by freeze-thaw cycles. If it freezes, it should be gently warmed and stirred to return to a homogeneous liquid; its performance will not be affected.

  • Shelf Life: 12–24 months under proper storage conditions.

10. QUICK REFERENCE TABLE

Property Value / Description
Common Name CAPB (Cocamidopropyl Betaine)
CAS 61789-40-0
Class Amphoteric Surfactant
Appearance Clear, colourless to pale yellow liquid
Active Matter (CAB-35) ~30%
Active Matter (CAB-45) ~40%
Main Functions Foam booster, viscosity builder, mild cleanser
Key Benefit Ultra-mild, high-foaming, and compatible with all surfactants

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