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Cocamidopropyl Betaine, CAPB​​​​​​, CAB-35, CAB-45, 61789-40-0

Cocamidopropyl Betaine, CAPB​​​​​​, CAB-35, CAB-45, 61789-40-0

Cocamidopropyl Betaine (CAPB)

1. Product Identity

Property Details
Product Name Cocamidopropyl Betaine
Abbreviations CAPB, CAB
CAS Number 61789-40-0
EC Number 263-058-8
Molecular Formula C₁₉H₃₈N₂O₃
Molecular Weight 342.52 g/mol
Chemical Type Amphoteric Surfactant
HS Code 3402.11.00 – Other organic surface-active agents

2. Synonyms and Other Names

Common Names

  • Cocamidopropyl Betaine

  • CAPB

  • CAB (Coco Amido Betaine)

  • Coconut oil amidopropyl betaine

Trade Names

  • Tego® Betain

  • Dehyton® PK

  • Empigen® BB

  • Mackam® CB-35

  • Mirataine® BET-C 30

Chemical Names

  • 1-Propanaminium, 3-amino-N-(carboxymethyl)-N,N-dimethyl-, N-coco acyl derivatives, inner salt

  • N-(Coco alkyl) amidopropyl betaine

  • Cocoamidopropyldimethylglycine

3. Product Description

Cocamidopropyl Betaine (CAPB) is an amphoteric surfactant derived from coconut oil. It exhibits both anionic and cationic properties, making it effective over a wide pH range. It is widely used in personal care products, especially in baby shampoos, shower gels, facial cleansers, and sensitive skin products.

Key Features:

  • High compatibility with other surfactants

  • Viscosity enhancing effect

  • Rich and stable foam formation

  • Low irritation potential (suitable for sensitive skin)

  • Antimicrobial activity

4. Physical and Chemical Properties

Property Value
Appearance (25°C) Colorless to pale yellow, clear liquid
Odor Neutral, odorless or faint characteristic odor
Density (25°C) Approx. 1.05 - 1.057 g/cm³
Boiling Point ~100 °C (with water)
Melting/Freezing Point -10 °C
pH (10% solution) 4.0 – 7.0 (depending on grade)
Solubility Completely soluble in water
Cloud Point (1% in water) -3 °C
Flash Point (1% in water) >94 °C

5. Technical Specifications (By Grade)

CAPB is typically classified by its active matter content. The two most common grades are CAB-35 and CAB-45.

Parameter CAB-35 CAB-45
Classification Amphoteric surfactant Amphoteric surfactant
Appearance (25°C) Colorless – pale yellow liquid Colorless – pale yellow liquid
Density (g/ml, 25°C) 1.05 1.05
Color (Hazen) ≤100 ≤100
Active Matter Content (%) 28.0 – 32.0 38.0 – 42.0
Solid Content (%) 33.0 – 37.0 43.0 – 47.0
pH (1% solution) 4.0 – 7.0 5.0 – 7.0
Sodium Chloride (NaCl) (%) ≤6.0 ≤7.0
Free Amine (%) ≤0.5 ≤0.5
Cloud Point (1% in water) -3 °C -3 °C
Freezing Point -10 °C -10 °C
Flash Point >94 °C >94 °C

6. Antimicrobial Activity

Cocamidopropyl Betaine exhibits antimicrobial activity against the following common microorganisms:

Microorganism Activity
Staphylococcus aureus Effective
Streptococcus pyogenes Effective
Bacillus subtilis Effective
Candida albicans Effective
Pityrosporum ovale Effective

7. Applications and Uses

CAPB is a versatile surfactant with a wide range of applications.

7.1. Personal Care and Cosmetic Products

Product Type Function
Baby Shampoos Gentle cleansing for sensitive skin, tear-free formulation
Shower Gels and Foam Baths Rich foam, soft skin feel
Facial Cleansers Gentle cleansing, low irritation risk
Sensitive Skin Products Preferred in dermatological formulations
Hair Care Products Foaming and conditioning in shampoos and conditioners
Makeup Removers Gentle but effective cleansing

7.2. Detergents and Cleaning Products

Product Type Function
Liquid Hand Soaps Foam booster, viscosity regulator
Dishwashing Detergents Grease removal, foam stabilizer
Laundry Detergents Co-surfactant, anti-redeposition agent
Industrial Cleaners Antimicrobial effect, cleaning power enhancer
Household Cleaners Foaming and cleaning in surface cleaners

7.3. Other Industrial Applications

  • Metalworking fluids

  • Agricultural chemicals

  • Textile processing aids

8. Formulation Examples

8.1. Economical Antibacterial Hand Soap Formulation

Ingredient % Amount Function
SLES 70% 3.5 Primary surfactant
CAB 35% 3.0 Secondary surfactant, foam booster
CDEA 85% 1.0 Secondary surfactant, foam stabilizer
PCMX 0.2 Antiseptic
EDTA-2Na 0.1 Chelating agent
Fragrance, dye, etc. q.s. Additives
Deionized water q.s. Carrier
Salt (NaCl) q.s. Viscosity modifier
Citric acid q.s. pH adjuster (7–8)

8.2. Grease-Cutting Dishwashing Detergent Formulation

Ingredient % Amount Function
Caustic soda 1.0 Neutralizer
LABSA 96% 7.0 Primary surfactant
SLES 70% 8.0 Primary surfactant
CAB 35% 3.0 Secondary surfactant, foam stabilizer
EDTA-2Na 0.5 Chelating agent
Fragrance, dye, etc. q.s. Additives
Deionized water q.s. Carrier
Salt (NaCl) q.s. Viscosity modifier
Citric acid q.s. pH adjuster (7–8)

8.3. Concentrated Laundry Detergent Formulation

Ingredient % Amount Function
Caustic soda 0.4 Neutralizer
LABSA 96% 3.0 Primary surfactant
SLES 70% 14.0 Primary surfactant
CAB 35% 10.0 Secondary surfactant, foam booster
OP-10 4.0 Secondary surfactant
AEO-9 4.0 Secondary surfactant
EDTA-2Na 0.2 Chelating agent
Fragrance, dye, etc. q.s. Additives
Deionized water q.s. Carrier
Salt (NaCl) q.s. Viscosity modifier
Citric acid q.s. pH adjuster (7–8)

9. Safety and Storage

Parameter Details
Skin Tolerance Low irritation potential, safe for sensitive skin
Eye Irritation Minimal, safely used in baby shampoos
Transport Classification Not subject to ADR classification (non-hazardous)
Storage Temperature 5–30 °C, cool and dry place
Packaging Material PE, PP, or HDPE containers preferred (avoid non-stainless metal tanks)
Shelf Life 12–24 months under proper conditions
Freezing May be affected by freeze-thaw cycles; if frozen, warm and mix to homogenize

10. Advantages and Summary

Cocamidopropyl Betaine (CAPB, CAS: 61789-40-0) is an amphoteric surfactant derived from coconut oil. It is a pale yellow liquid, completely soluble in water, and effective over a wide pH range.

Key Advantages:

Advantage Description
✅ Gentle Cleansing Low irritation potential, safe for baby and sensitive skin products
✅ Foam Booster Produces rich, stable, and creamy foam
✅ Viscosity Modifier Acts as a thickening agent in formulations
✅ Compatibility Excellent compatibility with anionic, cationic, and nonionic surfactants
✅ Antimicrobial Effective against various bacteria and fungi
✅ Biodegradable Environmentally friendly, suitable for green chemistry

Main Application Areas:

  • Personal Care: Baby shampoos, shower gels, facial cleansers, sensitive skin products

  • Household Cleaning: Hand soaps, dishwashing detergents, laundry detergents

  • Industrial: Metalworking, agricultural chemicals, textiles

Grade Selection:

  • CAB-35 (30% active): Ideal for general-purpose personal care and household cleaning products

  • CAB-45 (40% active): Suitable for concentrated formulations and high-performance applications

CAPB is an indispensable component of modern detergent and cosmetic formulations. With its gentle nature, excellent foaming properties, and high compatibility with other ingredients, it finds wide application in both consumer products and industrial uses.

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