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Graphite Rod, Carbon Rod, Graphite Electrode, Carbon Bar, Graphite Cylinder, Carbon Shaft, Graphite Stick, 7782-42-5

Graphite Rod, Carbon Rod, Graphite Electrode, Carbon Bar, Graphite Cylinder, Carbon Shaft, Graphite Stick, 7782-42-5

GRAPHITE ROD (GRAPHITE ELECTRODE / CARBON ROD)

PRODUCT IDENTIFICATION INFORMATION

Parameter Information
Product Name Graphite Rod
Synonyms (English) Graphite Rod, Graphite Electrode, Carbon Rod, Carbon Bar, Graphite Cylinder, Carbon Shaft, Graphite Stick
Synonyms (Turkish) Grafit Çubuk, Grafit Elektrot, Karbon Çubuk, Grafit Rod, Grafit Bar, Grafit Silindir, Karbon Şaft
CAS Number 7782-42-5
EC Number (EINECS) 231-955-3
Material High-purity graphite
Appearance Black, matte metallic

CHEMICAL STRUCTURE

    Graphite Rod (C)
    
    Hexagonal Layered Crystal Structure
    
         C   C   C   C
          \ / \ / \ /
           C   C   C
          / \ / \ / \
         C   C   C   C
    
    Hexagonal Layered Structure
    (Layers Connected by Weak van der Waals Bonds)
    Self-Lubricating Property
    High Electrical Conductivity

Molecular Formula: C (Elemental Carbon)
Crystal Structure: Hexagonal (Layered)
Classification: Non-metal; Carbon allotrope

SECTION 1: CHEMICAL IDENTITY AND DEFINITION

Parameter Information
Product Name Graphite Rod
Synonyms (English) Graphite Rod, Graphite Electrode, Carbon Rod, Carbon Bar, Graphite Cylinder, Carbon Shaft, Graphite Stick
Synonyms (Turkish) Grafit Çubuk, Grafit Elektrot, Karbon Çubuk, Grafit Rod, Grafit Bar, Grafit Silindir, Karbon Şaft
CAS Number 7782-42-5
EC Number (EINECS) 231-955-3
Material High-purity graphite (elemental carbon)
Crystal Structure Hexagonal (layered)
Classification Non-metal; carbon allotrope
Appearance Black, matte metallic
Odor Odorless
Color Black
Luster Matte to semi-metallic

SECTION 2: PHYSICAL AND CHEMICAL PROPERTIES

Property Value Test Method / Note
Appearance Black, matte metallic Visual
Density (20°C) ≥ 1.75 g/cm³ ASTM D854
Electrical Resistivity ≤ 15 µΩm ASTM C611
Flexural Strength ≥ 35 MPa ASTM C651
Compressive Strength ≥ 60 MPa ASTM C695
Ash Content ≤ 0.1% Gravimetric (800°C)
Coefficient of Thermal Expansion 2.0 - 3.0 × 10⁻⁶ /K ASTM E228
Open Porosity ≤ 15% ASTM C830
Thermal Conductivity 100-150 W/m·K -
Hardness (Shore) 50-70 HS -
Maximum Operating Temperature 3,000°C (inert atmosphere) -
Oxidation Onset ~500°C (in air) -
Coefficient of Friction Low (self-lubricating) -
Toxicity Low (dust may cause irritation) -

SECTION 3: GRAPHITE TYPES AND GRADES

Grade Production Method Grain Size Properties Applications
Isostatic Graphite Cold isostatic pressing Fine (<10 µm) High density, isotropic, high strength Nuclear, semiconductor, EDM
Extruded Graphite Extrusion Medium-coarse Anisotropic, economical Aluminum, continuous casting, glass
Molded Graphite Hot pressing Fine-medium Good mechanical properties Industrial applications, furnaces
Fine-Grained Graphite Special processing Very fine (<5 µm) Very high density, excellent surface EDM, precision applications

SECTION 4: CHEMICAL PROPERTIES AND REACTIVITY

Parameter Information
Chemical Character Elemental carbon; non-metal; inert; high temperature resistance; good electrical conductivity; self-lubricating
Stability Stable under normal conditions; Stable up to 3,000°C in inert atmosphere; Oxidation begins at ~500°C in air
Reactivity Reacts with oxygen at high temperature to form CO₂: C + O₂ → CO₂; Reacts with halogens; Reacts with strong oxidizing agents
Incompatible Materials Strong oxidizing agents, halogens, oxygen (at high temperature), some molten metals
Oxidation C + O₂ → CO₂ (~500°C in air)
Inert Atmosphere Stable up to 3,000°C
Acid Resistance Resistant to most acids
Alkali Resistance Resistant to most alkalis

SECTION 5: PRODUCTION METHODS

Method 1: Isostatic Pressing (High Performance)

  • Process: Petroleum coke + Pitch binder → Mixing → Cold isostatic pressing → Baking (1,000°C) → Graphitization (2,500-3,000°C) → Machining → Graphite rod

  • Properties: Fine grain, isotropic, high density, high strength

  • Applications: Nuclear, semiconductor, EDM, precision applications

Method 2: Extrusion (Industrial Standard)

  • Process: Petroleum coke + Pitch binder → Mixing → Extrusion → Baking (1,000°C) → Graphitization (2,500-3,000°C) → Machining → Graphite rod

  • Properties: Medium-coarse grain, anisotropic, economical

  • Applications: Aluminum, continuous casting, glass

Method 3: Molding (Hot Pressing)

  • Process: Petroleum coke + Pitch binder → Mixing → Hot pressing → Baking (1,000°C) → Graphitization (2,500-3,000°C) → Machining → Graphite rod

  • Properties: Fine-medium grain, good mechanical properties

  • Applications: Industrial furnaces, general applications

SECTION 6: FUNCTIONAL PROPERTIES AND MECHANISM OF ACTION

Property Description
Electrical Conductivity High electrical conductivity (≤15 µΩm); Used as electrode and conductor; Electrochemical applications; Arc furnaces
Thermal Stability Stable up to 3,000°C in inert atmosphere; High-temperature furnace components; Molten metal applications
Self-Lubrication Low coefficient of friction; Used as dry lubricant; Bushings, bearings, sliding surfaces
Chemical Inertness Resistant to most chemicals; Resistant to acids and alkalis; Used in corrosive environments
Thermal Shock Resistance Low thermal expansion; High thermal conductivity; Resistant to rapid temperature changes
Neutron Absorption Low neutron capture cross-section; Nuclear reactor moderator; Nuclear applications
Machinability Easily machined; Can be produced to precision dimensions; Custom shapes

SECTION 7: MAIN APPLICATION AREAS

Industry / Application Function Typical Use
Electrical & Electrochemical Electrode / conductor Electrolysis cells; Arc furnaces; Battery electrodes; Carbon brushes; Electroplating
High-Temperature Applications Heat-resistant components Molten metal stirring; Furnace components; Crucibles; Heating elements
Machinery & Mechanical Bushing / bearing Self-lubricating bearings; Sliding surfaces; Piston rings; Mechanical seals
Nuclear Industry Moderator Nuclear reactor moderator; Neutron shielding; Nuclear control rods
Semiconductor & Electronics Heater / crucible Semiconductor production; Crystal pulling; LED production; Photovoltaics
Metallurgy Casting aid Continuous casting; Aluminum casting; Casting molds
EDM (Electrical Discharge Machining) Electrode Tool and die making; Precision machining; EDM electrodes
Glass & Refractory Component Glass melting; Refractory furnaces; Heating elements

SECTION 8: QUALITY SPECIFICATIONS (ISOSTATIC GRAPHITE)

Parameter Specification Test Method
Appearance Black, matte metallic Visual
Density (20°C) ≥ 1.75 g/cm³ ASTM D854
Electrical Resistivity ≤ 15 µΩm ASTM C611
Flexural Strength ≥ 35 MPa ASTM C651
Compressive Strength ≥ 60 MPa ASTM C695
Ash Content ≤ 0.1% Gravimetric (800°C)
Coefficient of Thermal Expansion 2.0 - 3.0 × 10⁻⁶ /K ASTM E228
Open Porosity ≤ 15% ASTM C830
Grain Size ≤ 10 µm (isostatic) ASTM E112
Maximum Temperature 3,000°C (inert atmosphere) -
Oxidation Onset ~500°C (in air) -
Diameter Tolerance ±0.1 - ±0.5 mm Micrometer
Length Tolerance ±1.0 - ±5.0 mm Measurement

SECTION 9: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity Low toxicity (elemental carbon)
Acute Inhalation Toxicity Dust inhalation may cause mechanical irritation
Skin Irritation Non-irritant
Eye Irritation Non-irritant (mechanical irritation)
Chronic Toxicity Graphite dust may cause pneumoconiosis (graphitosis) with prolonged inhalation
Carcinogenicity Not classified as carcinogenic
Mutagenicity Not classified as mutagenic
Target Organs Respiratory system (dust irritation)
Occupational Exposure Limit (8h TWA) 10 mg/m³ (total dust); 5 mg/m³ (respirable)
Special Toxicity Note Elemental graphite is non-toxic; Graphite dust may cause graphitosis (benign pneumoconiosis) with prolonged inhalation; Avoid inhalation of dust during processing

SECTION 10: GHS CLASSIFICATION AND LABELING

GHS Classification (Compliant with CLP and UN GHS):

Hazard Class Category H-Statement
Generally not classified as hazardous - -
STOT - SE (Single Exposure) Category 3 H335 (optional)

Note: Graphite is generally considered non-hazardous. However, fine dust may cause mechanical irritation.

Signal Word: No signal word required (non-hazardous) or WARNING (optional)

Hazard Pictograms: GHS07 (optional)

Hazard Statements (H-Codes) - if classified:

Code Statement
H335 May cause respiratory irritation

NFPA 704 Hazard Classification:

Health Flammability Reactivity Special
0 0 0 -
(Minimal health hazard) (Will not burn) (Stable) (None)

SECTION 11: PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P264 Wash hands thoroughly after handling
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P312 Call a POISON CENTER/doctor if you feel unwell
P362+P364 Take off contaminated clothing and wash it before reuse
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P501 Dispose of contents/container in accordance with local/regional/national/international regulations

SECTION 12: FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Move to fresh air immediately. Rest in a position comfortable for breathing. If symptoms persist, get medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If skin irritation occurs, get medical advice/attention.
Eye Contact Rinse immediately with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses if present. Continue rinsing. If eye irritation persists, get medical advice/attention.
Ingestion Rinse mouth with water. Do NOT induce vomiting. Drink plenty of water. Get medical attention if symptoms occur.

SECTION 13: FIREFIGHTING MEASURES

Parameter Information
Fire Hazard Non-combustible (bulk). Powder form may be combustible. Burns at high temperatures forming CO₂.
Hazards During Fire Thermal decomposition produces CO₂ and CO; Oxidation releases heat
Suitable Extinguishers Dry chemical powder, CO₂, sand, graphite powder
Unsuitable Extinguishers Water (may spread powder)
Special Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing
Special Precautions Prevent dust from entering sewers and waterways

SECTION 14: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Store in a cool, dry, well-ventilated area; Keep away from moisture and incompatible substances
Container Requirements Original packaging, dry containers; Protect from dust
Materials to Protect From Strong oxidizing agents, halogens, moisture
Shelf Life Unlimited (under proper storage conditions)
Stability Note Stable under normal conditions; Oxidation in air is slow; Protect from moisture
Special Storage Requirements Store separately from oxidizing agents; Keep in dry area

SECTION 15: PACKAGING OPTIONS

Packaging Type Quantity Material
Carton Box 10-50 pieces Carton box (foam-lined)
Wooden Crate 50-200 pieces Wooden crate (lined)
Plastic Bag 100-500 pieces PE bag (dust-proof)
Custom Packaging As per request As per customer requirement

SECTION 16: TRANSPORT INFORMATION

Parameter Information
UN Number Not regulated (non-hazardous)
Hazard Class Not applicable
Packing Group Not applicable
ADR/RID Not regulated
IMDG Code Not regulated
IATA (Air) Not regulated
Marine Pollutant No
Transport Temperature Ambient temperature; Protect from moisture

SECTION 17: REGULATORY STATUS

Region / Authority Status
European Union REACH registered; Not classified as hazardous
USA (TSCA) Listed
USA (EPA) Not regulated as hazardous substance
Turkey Industrial raw material; Subject to KKDIK regulation
IARC Group 3 (Not classifiable as to carcinogenicity to humans)
NTP Not listed
OSHA Regulated as nuisance dust
California (Prop 65) Not listed
EU Restrictions Not restricted under REACH Annex XVII
RoHS Compliant

SECTION 18: OTHER NAMES AND SYNONYMS

Type Name
Turkish Names Grafit Çubuk, Grafit Elektrot, Karbon Çubuk, Grafit Rod, Grafit Bar, Grafit Silindir, Karbon Şaft
English Names Graphite Rod, Graphite Electrode, Carbon Rod, Carbon Bar, Graphite Cylinder, Carbon Shaft, Graphite Stick
Chemical Names Graphite; Elemental Carbon; Carbon
CAS Number 7782-42-5
EC Number 231-955-3
Molecular Formula C

SECTION 19: SUMMARY TABLE

Parameter Value
Product Graphite Rod (Graphite Electrode / Carbon Rod)
CAS Number 7782-42-5
Material High-purity graphite
Density ≥ 1.75 g/cm³
Electrical Resistivity ≤ 15 µΩm
Flexural Strength ≥ 35 MPa
Compressive Strength ≥ 60 MPa
Ash Content ≤ 0.1%
Maximum Temperature 3,000°C (inert atmosphere)
Primary Function Electrode, conductor, bearing, refractory
Main Applications Electrical, high-temperature, machinery, nuclear, semiconductor, EDM
Shelf Life Unlimited
GHS Signal Word No signal word required (non-hazardous)
UN Number Not regulated
Toxicity Low toxicity
Special Feature High temperature resistance; Self-lubricating; Good electrical conductivity; Chemical inertness

SECTION 20: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • Non-hazardous material but fine dust may cause respiratory tract irritation. Use appropriate dust control measures.

  • Non-combustible (bulk). Powder form may be combustible.

  • High temperature resistance: Stable up to 3,000°C in inert atmosphere. Oxidation begins at ~500°C in air.

  • Good electrical conductivity: Suitable for electrode and conductor applications.

  • Self-lubricating: Low coefficient of friction; can be used as dry lubricant.

  • Chemical inertness: Resistant to most chemicals; avoid strong oxidizing agents.

  • Incompatibilities: Keep away from strong oxidizing agents, halogens, and oxygen at high temperature.

  • Graphitosis: Prolonged inhalation of graphite dust may cause benign pneumoconiosis (graphitosis).

  • Hygiene Requirement: Wash hands thoroughly after handling.

BEST PRACTICE RECOMMENDATIONS:

  • Electrical & Electrochemical Applications: Use as electrode in electrolysis cells; Arc furnaces; Battery electrodes; Carbon brushes; Electroplating anodes/cathodes; Provides high conductivity and chemical inertness.

  • High-Temperature Applications: Use for molten metal stirring; Furnace components; Crucibles; Heating elements; Can be used up to 3,000°C in inert atmosphere.

  • Machinery & Mechanical Applications: Use in self-lubricating bearings; Sliding surfaces; Piston rings; Mechanical seals; Low friction and wear resistance.

  • Nuclear Applications: Use as nuclear reactor moderator; Neutron shielding; Low neutron capture cross-section.

  • Semiconductor & Electronics: Use in semiconductor production; Crystal pulling; LED production; Photovoltaics; Requires high purity.

  • EDM (Electrical Discharge Machining): Use in tool and die making; Precision machining; EDM electrodes; Requires fine grain and high density.

  • Handling: Use in well-ventilated areas; Avoid dust generation; Wear protective gloves, safety goggles, and appropriate respiratory protection (if dust).

  • Personal Protective Equipment: Safety goggles, protective clothing, protective gloves (nitrile, neoprene), NIOSH-approved dust mask (if dust).

  • Hygiene: Wash hands thoroughly after handling; Do not eat, drink, or smoke when using.

  • Storage: Store in cool, dry, well-ventilated area; Protect from moisture; Keep away from oxidizing agents and halogens.

  • Spill Response: Avoid dust generation; Vacuum or sweep; Place in closed containers; Do not allow to enter drains or waterways.

  • Disposal: Dispose of in accordance with local, regional, and national regulations; Graphite is recyclable; Recycle where possible.

GRAPHITE GRADE SELECTION GUIDE:

Application Recommended Grade Description
Nuclear, semiconductor, EDM Isostatic Graphite Fine grain, high density, isotropic
Aluminum, continuous casting Extruded Graphite Economical, anisotropic
Industrial furnaces Molded Graphite Good mechanical properties
Precision EDM applications Fine-Grained Graphite Very fine grain, excellent surface

SPECIAL NOTE ON OXIDATION RESISTANCE:

Graphite oxidation resistance depends on temperature:

  • In Air: Oxidation begins at ~500°C

  • Inert Atmosphere (Argon, Nitrogen): Stable up to 3,000°C

  • Vacuum: Stable up to ~2,000°C

  • Oxidation Reaction: C + O₂ → CO₂

  • Precaution: Use inert atmosphere for high-temperature applications

LEGAL DISCLAIMER:

The information provided in this document is based on our current knowledge and experience and is presented in good faith. However, as all conditions of use are beyond our control, this document does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing suitability for their own applications. For complete safety, storage, handling, transportation, waste, and regulatory compliance information, please refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.

NOTE: CARBON RODS CAN BE MANUFACTURED AND SHIPPED IN CUSTOM SIZES.

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