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Lead Nitrate, Lead Dinitrate, Plumbous Nitrate, 10099-74-8

Lead Nitrate, Lead Dinitrate, Plumbous Nitrate, 10099-74-8

LEAD NITRATE – LEAD NITRATE

1. CHEMICAL IDENTITY AND DEFINITION

Parameter Information
Chemical Name (IUPAC) Lead(II) Nitrate
Other Names Lead Dinitrate, Plumbous Nitrate
Chemical Formula Pb(NO₃)₂
Molecular Weight 331.2 g/mol
CAS Number 10099-74-8
EC Number (EINECS) 233-245-9
Appearance White crystalline solid
Odor Odorless
Physical State (20°C) Solid (crystalline)
Chemical Class Inorganic salt (nitrate)

2. WHAT IS LEAD NITRATE?

Lead Nitrate (Pb(NO₃)₂) is a white crystalline, water-soluble inorganic compound. It is one of the most commonly used lead compounds and is a powerful oxidizing agent. Due to its oxidizing properties, it is used in various industries including chemicals, explosives production, paints, and metal processing. It is highly toxic and environmentally hazardous.

3. PHYSICAL PROPERTIES

Property Value
Appearance White crystalline solid
Chemical Formula Pb(NO₃)₂
Molecular Weight 331.2 g/mol
Density 4.53 g/cm³
Melting Point 470 °C (decomposes)
Boiling Point Decomposes
Solubility in Water (20°C) ~56 g/100 mL (freely soluble)
Solubility in Ethanol Sparingly soluble
pH (5% solution) ~3.0 – 4.0 (acidic)
Color White
Odor Odorless
Crystal Structure Cubic

4. CHEMICAL PROPERTIES

Property Information
Chemical Formula Pb(NO₃)₂
Molecular Weight 331.2 g/mol
CAS Number 10099-74-8
EC Number 233-245-9
Lead Content ~62.6%
Nitrate Content ~37.4%
Oxidizing Properties Strong oxidizing agent
Thermal Decomposition Pb(NO₃)₂ → PbO + NO₂ + O₂ (at 470°C)
Stability Stable under normal conditions
Hygroscopicity Low

5. THERMAL DECOMPOSITION

Temperature Reaction Products
470 °C Pb(NO₃)₂ → PbO + 2NO₂ + ½O₂ Lead oxide, nitrogen dioxide, oxygen
> 470 °C Further decomposition PbO, NO₂, O₂

Warning: Heating releases toxic nitrogen dioxide (NO₂) gas.

6. APPLICATIONS

6.1. Chemical Industry

Application Description
Lead Compound Production Raw material for synthesis of other lead salts
Lead Oxide Production Thermal decomposition to produce lead oxide (PbO)
Lead Acetate Production Lead acetate synthesis
Lead Chromate Production Pigment production

6.2. Explosives Production

Application Description
Fireworks Bright white light and silver effects
Special Explosives Oxidizer in explosive formulations
Flare Devices Signal flares
Pyrotechnics Pyrotechnic displays

6.3. Paints and Pigment Production

Application Description
Lead-Based Paints Lead chromate (yellow) and lead carbonate (white) pigments
Ceramic Glazes Ceramic coatings
Glass Industry Optical glass formulations

6.4. Gold and Silver Processing

Application Description
Cyanidation Process Gold and silver purification
Precious Metal Recovery Separation of precious metals from ores

6.5. Research and Education

Application Description
Chemical Analysis Reagent in laboratory analyses
Educational Experiments Demonstration experiments in chemistry education
Analytical Chemistry Qualitative and quantitative analyses

6.6. Other Applications

Application Description
Textile Industry Mordant (dye fixing agent)
Photographic Chemicals Some photographic formulations
Dye Fixing Mordant for textile dyes

7. SOLUBILITY TABLE

Solvent Temperature Solubility (g/100 mL)
Water 20°C ~56.0
Water 100°C ~127.0
Ethanol 20°C Sparingly soluble
Nitric Acid 20°C Soluble
Acetone 20°C Sparingly soluble

8. PROPERTIES OF LEAD NITRATE

Property Value / Information
Oxidizer Class Class 5.1 (Oxidizing)
Refractive Index 1.78
Crystal System Cubic
Dielectric Constant ~8.5
Magnetic Properties Diamagnetic

9. SAFETY AND HEALTH INFORMATION

Parameter Value
Oral LD50 (Rat) ~450 – 500 mg/kg
Dermal LD50 (Rabbit) > 2,000 mg/kg
Lead Toxicity Neurotoxin, blood and kidney damage
Carcinogenicity Suspected (IARC Group 2A)
Mutagenicity Positive
Reproductive Toxicity Positive
Acute Toxicity High
Chronic Toxicity Very high (lead accumulation)

9.1. GHS CLASSIFICATION

Hazard Category Category Description
Acute Toxicity Category 3 H301 (Toxic if swallowed)
Acute Toxicity Category 3 H332 (Harmful if inhaled)
Carcinogenicity Category 1B H350 (May cause cancer)
Reproductive Toxicity Category 1A H360 (May damage fertility)
Specific Target Organ Toxicity Category 1 H372 (Organ damage)
Aquatic Toxicity Category 1 H400 (Very toxic to aquatic life)
Oxidizing Category 2 H272 (May intensify fire)

9.2. GHS HAZARD STATEMENTS (H-Codes)

Code Statement
H272 May intensify fire; oxidizer
H301 Toxic if swallowed
H332 Harmful if inhaled
H350 May cause cancer
H360 May damage fertility or the unborn child
H372 Causes damage to organs through prolonged exposure
H400 Very toxic to aquatic life
H410 Very toxic to aquatic life with long-lasting effects

9.3. GHS PRECAUTIONARY STATEMENTS (P-Codes)

Code Statement
P210 Keep away from heat/sparks/open flames
P220 Keep away from combustible materials
P260 Do not breathe dust/fumes
P280 Wear protective gloves/clothing/eye protection
P301+P310 IF SWALLOWED: Call a POISON CENTER/doctor
P304+P340 IF INHALED: Remove to fresh air
P308+P313 IF exposed or concerned: Get medical advice
P405 Store locked up

10. FIRST AID MEASURES

Route of Exposure Action
Inhalation Remove to fresh air. If breathing stopped, give artificial respiration. Get immediate medical attention.
Skin Contact Remove contaminated clothing. Wash with plenty of soap and water. Get medical attention.
Eye Contact Rinse thoroughly with water for at least 20 minutes. Get immediate medical attention.
Ingestion Do NOT induce vomiting. Rinse mouth. Get immediate medical attention.

11. CHRONIC HEALTH EFFECTS

Effect Description
Neurotoxicity Nervous system damage (lead encephalopathy)
Hematological Effects Anemia, hemolysis, impaired hemoglobin synthesis
Kidney Damage Nephrotoxicity, kidney failure
Reproductive Effects Infertility, miscarriage, birth defects
Carcinogenicity Lung, kidney, and stomach cancer risk
Lead Accumulation Accumulates in bones, teeth, and soft tissues

12. ENVIRONMENTAL EFFECTS

Parameter Information
Aquatic Toxicity Extremely toxic
Fish Toxicity (LC50) 0.1 – 1 mg/L
Bioaccumulation High (accumulates in food chain)
Persistence Not biodegradable
Environmental Risk Very high
Soil Contamination Long-term persistence

13. STORAGE AND HANDLING

Parameter Information
Storage Conditions Cool, dry, well-ventilated area
Container Requirements Tightly closed, dedicated lead container
Protect From Heat, sparks, flame, combustible materials, organic substances
Shelf Life 12-24 months (with proper storage)
Temperature 15-25°C
Warning Oxidizer; avoid contact with combustible materials

14. WASTE MANAGEMENT

Parameter Information
Waste Code Hazardous waste (06 01 04)
Disposal Licensed disposal facilities
Recycling Lead recycling is possible
Wastewater Lead-containing wastewater must be treated

15. TRANSPORT INFORMATION

Parameter Information
UN Number 1469
Hazard Class 5.1 (Oxidizer) + 6.1 (Toxic)
Packing Group II
ADR/RID 5.1 + 6.1
IMDG Code 5.1 + 6.1
IATA (Air) 5.1 + 6.1
Marine Pollutant Yes

16. PACKAGING OPTIONS

Packaging Type Quantity Material
Plastic Bucket 5-25 kg HDPE
Plastic Drum 25-50 kg HDPE
Plastic Bag 1-5 kg PE
Fiber Drum 25-50 kg Fiberboard

17. REGULATORY STATUS

Region / Authority Status
European Union (REACH) Substance of Very High Concern (SVHC)
USA (EPA) Toxic Substance
USA (OSHA) Lead regulation
RoHS Restricted substance
Turkey Hazardous substance

18. OTHER NAMES AND SYNONYMS

Type Name
Turkish Names Kurşun Nitrat, Kurşun Dinitrat
English Names Lead Nitrate, Lead Dinitrate, Plumbous Nitrate
Chemical Names Lead(II) Nitrate
CAS Number 10099-74-8
EC Number 233-245-9

19. SUMMARY AND CRITICAL WARNINGS

Product Summary

Parameter Value
Product Lead Nitrate
CAS Number 10099-74-8
Formula Pb(NO₃)₂
Molecular Weight 331.2 g/mol
Appearance White crystalline solid
Density 4.53 g/cm³
Water Solubility ~56 g/100 mL
Primary Applications Chemicals, explosives, paints, metal processing

CRITICAL WARNINGS

1. HIGH TOXICITY: Lead nitrate is highly toxic. Lead accumulates in the body and causes neurological, hematological, and kidney damage. Exposure can be fatal.

2. OXIDIZER: A strong oxidizing agent. Contact with combustible materials poses fire and explosion risk. Keep away from heat, sparks, and flames.

3. CARCINOGEN: May cause cancer (IARC Group 2A). Prolonged exposure increases risk of lung, kidney, and stomach cancer.

4. THERMAL DECOMPOSITION: Decomposes at 470°C releasing toxic nitrogen dioxide (NO₂) gas. Proper ventilation is essential for heating operations.

5. REPRODUCTIVE TOXICITY: May damage fertility or the unborn child. Can cause infertility, miscarriage, and birth defects.

6. ENVIRONMENT: Extremely toxic to aquatic life. Bioaccumulates and accumulates in the food chain. Avoid release to the environment.

7. PPE: Full protective equipment (gloves, goggles, apron, respirator) is required when handling.

8. STORAGE: Store in a cool, dry, well-ventilated area. Keep away from combustible materials and organic substances.

9. WASTE: Lead-containing waste must be sent to licensed disposal facilities. Release into the environment causes serious ecological damage.

10. TRANSPORT: UN 1469, Class 5.1 (Oxidizer) + 6.1 (Toxic). Packing Group II.

**11. REGULATORY STATUS: Restricted in many countries. Subject to RoHS and other regulations.

**12. ALTERNATIVES: Lead-free alternatives should be preferred whenever possible.

IMPORTANT DISCLAIMER: This Technical Data Sheet (TDS) is for informational purposes only and is prepared based on available technical data. The user is responsible for determining the suitability of the product for their specific application and for complying with all local, national, and international regulations. For complete safety, storage, use, handling, disposal, and regulatory compliance information, refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier. This document is not a substitute for professional or medical advice.

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