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Sorbitan Monolaurate, Sorbitan Laurate, Span 20, SML, E432, 1338-39-2

Sorbitan Monolaurate, Sorbitan Laurate, Span 20, SML, E432, 1338-39-2

E432 – Span 20 (Sorbitan monolaurate) 

Key Properties

  • Chemical Name: Sorbitan monolaurate

  • Fatty Acid: Lauric acid (C12)

  • Appearance: Yellowish liquid

  • HLB Value: ~8.6 (relatively high, more hydrophilic)

  • Solubility: Soluble in oils, partially soluble in water

Applications

  • Food Industry: Emulsifier in margarine, coffee creamers, milk powder, and oil–water blends.

  • Pharmaceuticals: Carrier in emulsions, stabilizer in formulations.

  • Cosmetics: Used in creams, lotions, and hair care products, especially in oil-in-water (O/W) emulsions.

Functional Role

  • Span 20 has one of the highest HLB values among the Span series, making it suitable for oil-in-water emulsions.

  • Often combined with Tween (Polysorbate) series to achieve balanced emulsification.

  • Improves product texture, stability, and shelf life.

Span Series Comparison Table:

Product Chemical Name Fatty Acid E Number HLB Value Appearance Typical Applications
Span 20 Sorbitan monolaurate Lauric acid (C12) E432 ~8.6 Yellowish liquid Food emulsifier, pharmaceutical carrier, cosmetic creams
Span 40 Sorbitan monopalmitate Palmitic acid (C16) E494 ~6.7 Yellowish wax-like solid Margarine, milk powder, pharmaceutical emulsions
Span 60 Sorbitan monostearate Stearic acid (C18) E491 ~4.7 White/cream solid Chocolate, margarine, tablet binder, cosmetics
Span 80 Sorbitan monooleate Oleic acid (C18:1, unsaturated) E493 ~4.3 Dark yellow liquid Water-in-oil emulsions, veterinary drugs, cosmetics
Span 85 Sorbitan trioleate Three oleic acid chains E476 ~1.8 Dark yellow liquid Very low HLB, stabilizer in oil-based systems

Technical Notes

  • HLB Values: Spans generally have low HLB values, making them suitable for oil-based emulsions.

  • Combination with Tweens: They are often combined with Polysorbates (Tween series) to balance emulsification in food, pharma, and cosmetics.

  • Applications:

    • Food: margarine, chocolate, milk powder, coffee creamer

    • Pharma: tablet binder, emulsifier in suspensions

    • Cosmetics: creams, lotions, makeup formulations

Images

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