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Sorbitan Monostearate, Sorbitan Fatty Acid Ester, Monostearate Ester of Sorbitan, E491, 1338-41-6

Sorbitan Monostearate, Sorbitan Fatty Acid Ester, Monostearate Ester of Sorbitan, E491, 1338-41-6

E491, also known as Sorbitan Monostearate, is a food additive used as an emulsifier. Here's a detailed overview:

Properties:

  • Appearance: Waxy solid, white to light yellow in color.

  • Solubility: Insoluble in water but mixes well with oils.

Applications:

  • Food Industry:

    • Stabilizes emulsions in products like margarine, ice cream, and salad dressings.

    • Improves texture and shelf life in baked goods and confectioneries.

    • Enhances the rehydration of instant dry yeast.

  • Other Uses:

    • Used in cosmetics, pharmaceuticals, and industrial applications for its emulsifying and stabilizing properties.

Safety:

E491 is generally recognized as safe (GRAS) when used within recommended limits.

Other Names:

  • Sorbitan Monostearate

  • Sorbitan Fatty Acid Ester

  • Monostearate Ester of Sorbitan

  • The CAS (Chemical Abstracts Service) number for E491, also known as Sorbitan Monostearate, is 1338-41-6

 

Span Series Comparison Table

Product Chemical Name Fatty Acid E Number HLB Value Appearance Typical Applications
Span 20 Sorbitan monolaurate Lauric acid (C12) E432 ~8.6 Yellowish liquid Food emulsifier, pharmaceutical carrier, cosmetic creams
Span 40 Sorbitan monopalmitate Palmitic acid (C16) E494 ~6.7 Yellowish wax-like solid Margarine, milk powder, pharmaceutical emulsions
Span 60 Sorbitan monostearate Stearic acid (C18) E491 ~4.7 White/cream solid Chocolate, margarine, tablet binder, cosmetics
Span 80 Sorbitan monooleate Oleic acid (C18:1, unsaturated) E493 ~4.3 Dark yellow liquid Water-in-oil emulsions, veterinary drugs, cosmetics
Span 85 Sorbitan trioleate Three oleic acid chains E476 ~1.8 Dark yellow liquid Very low HLB, stabilizer in oil-based systems

Technical Notes

  • HLB Values: Spans generally have low HLB values, making them suitable for oil-based emulsions.

  • Combination with Tweens: They are often combined with Polysorbates (Tween series) to balance emulsification in food, pharma, and cosmetics.

  • Applications:

    • Food: margarine, chocolate, milk powder, coffee creamer

    • Pharma: tablet binder, emulsifier in suspensions

    • Cosmetics: creams, lotions, makeup formulations

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