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Aluminum Silicon Ingot, Aluminum-Silicon Alloy, Al-Si Alloy, 7429-90-5

Aluminum Silicon Ingot, Aluminum-Silicon Alloy, Al-Si Alloy, 7429-90-5

ALUMINUM SILICON INGOT (Al-Si ALLOY / SILUMIN)

PRODUCT IDENTIFICATION INFORMATION

Parameter Information
Product Name Aluminum Silicon Ingot
Other Names Aluminum-Silicon Alloy, Al-Si Alloy, Silumin
English Name Aluminum Silicon Ingot, Aluminum-Silicon Alloy, Al-Si Alloy, Silumin
Composition Aluminum (Al) + Silicon (Si) + (optional other elements)
CAS Numbers 7429-90-5 (Aluminum), 7440-21-3 (Silicon)
Appearance Silvery-gray metallic ingot/block
Alloy Type Eutectic / Hypoeutectic / Hypereutectic

CHEMICAL STRUCTURE

    Aluminum Silicon Alloy (Al-Si)
    
    Eutectic Microstructure
    
    Aluminum Matrix (α-Al) with
    Silicon Phases (Si)
    
          Al           Al
            \         /
             Si --- Si
            /         \
          Al           Al
    
    Al-Si Eutectic Structure
    (Eutectic point at 577°C with 12.6% Si)

Key Components:

  • Aluminum (Al): Matrix metal (lightweight, corrosion-resistant)

  • Silicon (Si): Alloying element (improves castability, provides strength)

  • Eutectic Point: 12.6% Si, 577°C

SECTION 1: CHEMICAL IDENTITY AND DEFINITION

Parameter Information
Product Name Aluminum Silicon Ingot
Other Names (English) Aluminum-Silicon Alloy, Al-Si Alloy, Silumin, Al-Si Ingot
Other Names (Turkish) Alüminyum-Silisyum Alaşımı, Al-Si Alaşımı, Silumin
Alloy Type Eutectic / Hypoeutectic / Hypereutectic Al-Si alloy
CAS Numbers 7429-90-5 (Aluminum); 7440-21-3 (Silicon)
Appearance Silvery-gray metallic ingot/block
Odor Odorless
Color Silvery-gray
Magnetic Properties Non-magnetic

SECTION 2: PHYSICAL AND CHEMICAL PROPERTIES

Property Value Test Method / Note
Appearance Silvery-gray metallic ingot/block Visual
Density (20°C) 2.65 - 2.70 g/cm³ ASTM D792
Melting Point 577 - 660°C (depending on Si content) DSC
Eutectic Point 577°C (12.6% Si) -
Thermal Conductivity 150 - 180 W/m·K -
Electrical Conductivity Moderate ASTM E1004
Coefficient of Thermal Expansion 21 - 23 × 10⁻⁶ /°C -
Hardness (Brinell) 60 - 120 HB (depending on Si content) ASTM E10
Tensile Strength 150 - 350 MPa (depending on Si content) ASTM E8
Elongation 1 - 10% (depending on Si content) ASTM E8
Corrosion Resistance Good (aluminum matrix) -
Boiling Point ~2,470°C -
Magnetic Properties Non-magnetic -

SECTION 3: ALLOY TYPES AND CLASSIFICATION

Classification by Silicon Content

Alloy Type Si Content (%) Properties Typical Applications
Hypoeutectic 5 - 12% Good castability, moderate strength Automotive parts, general casting
Eutectic 12 - 13% Excellent castability, good strength Complex castings, engine blocks
Hypereutectic 13 - 25% High strength, wear resistance Pistons, wear parts

Standard Al-Si Alloy Grades

Grade Si (%) Cu (%) Mg (%) Fe (%) Other Application
EN AC-42000 (AlSi7Mg) 6.5-7.5 ≤0.05 0.25-0.45 ≤0.15 - General casting, automotive
EN AC-43000 (AlSi10Mg) 9.0-11.0 ≤0.05 0.25-0.45 ≤0.15 - Engine blocks, pumps
EN AC-44200 (AlSi12) 11.0-13.0 ≤0.05 ≤0.05 ≤0.15 - Complex castings
EN AC-45000 (AlSi6Cu4) 5.0-7.0 3.0-5.0 ≤0.05 ≤0.15 - High-strength castings
EN AC-48000 (AlSi17Cu4Mg) 16.0-18.0 3.0-5.0 0.45-0.65 ≤0.15 - Pistons, wear parts

SECTION 4: CHEMICAL COMPOSITION (TYPICAL VALUES)

Hypoeutectic Al-Si Alloy (AlSi7Mg - EN AC-42000)

Element Weight % Function
Aluminum (Al) Balance (~90%) Matrix metal
Silicon (Si) 6.5 - 7.5 Improves castability, provides strength
Magnesium (Mg) 0.25 - 0.45 Increases strength through heat treatment
Iron (Fe) ≤ 0.15 Impurity (controlled)
Copper (Cu) ≤ 0.05 Impurity
Manganese (Mn) ≤ 0.05 Impurity
Zinc (Zn) ≤ 0.05 Impurity
Titanium (Ti) ≤ 0.05 Grain refiner

Eutectic Al-Si Alloy (AlSi12 - EN AC-44200)

Element Weight % Function
Aluminum (Al) Balance (~88%) Matrix metal
Silicon (Si) 11.0 - 13.0 Eutectic formation, excellent castability
Iron (Fe) ≤ 0.15 Impurity (controlled)
Copper (Cu) ≤ 0.05 Impurity
Magnesium (Mg) ≤ 0.05 Impurity

Hypereutectic Al-Si Alloy (AlSi17Cu4Mg - EN AC-48000)

Element Weight % Function
Aluminum (Al) Balance (~78%) Matrix metal
Silicon (Si) 16.0 - 18.0 High strength, wear resistance
Copper (Cu) 3.0 - 5.0 Increases strength
Magnesium (Mg) 0.45 - 0.65 Increases strength through heat treatment
Iron (Fe) ≤ 0.15 Impurity (controlled)

SECTION 5: PRODUCTION METHODS

Method 1: Melt Alloying (Most Common Method)

  • Process: Pure aluminum + Silicon → Melting → Alloying → Casting → Ingot

  • Description: Pure aluminum and silicon (or silicon-containing master alloys) are melted; Homogeneous mixing is achieved; Cast into molds to obtain ingots; Most common industrial production method

Method 2: Master Alloy Use

  • Process: Al-Si master alloy → Dilution with pure aluminum → Alloy → Casting

  • Description: High-silicon master alloy (20-50% Si) is diluted with pure aluminum; Desired silicon content is achieved; Provides more homogeneous distribution

Method 3: Recycling (Scrap Melting)

  • Process: Al-Si scrap → Sorting → Melting → Refining → Alloy → Casting

  • Description: Al-Si alloy scraps are collected, sorted, and melted; Purified by refining; Composition adjusted; Sustainable production

Method 4: Powder Metallurgy

  • Process: Al powder + Si powder → Mixing → Pressing → Sintering → Alloy

  • Description: Aluminum and silicon powders are mixed, pressed, and sintered; Used for specialized applications

SECTION 6: FUNCTIONAL PROPERTIES AND MECHANISM OF ACTION

Property Description
Excellent Castability Silicon increases alloy fluidity; Enables casting of complex shapes; Eutectic point (577°C) provides low melting temperature; Allows production of fine details
High Strength-to-Weight Ratio Silicon strengthens aluminum matrix; Lightweight metal (2.65-2.70 g/cm³) with high strength; Ideal for automotive and aerospace applications
Good Corrosion Resistance Aluminum matrix forms protective oxide layer; Silicon does not negatively affect corrosion resistance; Good performance in most environments
Thermal Expansion Control Silicon reduces thermal expansion of aluminum; Provides thermal stability; Suitable for pistons and engine parts
Wear Resistance Hypereutectic alloys provide wear resistance through silicon particles; Ideal for pistons, cylinder liners, and wear parts
Good Machinability Depends on silicon content; Hypoeutectic alloys are easier to machine; Hypereutectic alloys are harder
Lightweight Low density (2.65-2.70 g/cm³); Provides weight savings; Improves fuel efficiency

SECTION 7: MAIN APPLICATION AREAS

Industry / Application Function Typical Use Preferred Alloy
Automotive Industry Structural components Engine blocks; Cylinder heads; Pistons; Wheels; Transmission housings AlSi7Mg, AlSi10Mg, AlSi17Cu4Mg
Aerospace Industry Structural components Aircraft parts; Fuselage components; Engine mounts AlSi7Mg
Construction Industry Structural components Facade panels; Window profiles; Structural elements AlSi12
Electronics Industry Thermal management Heat sinks; Electronic enclosures; LED coolers AlSi10Mg, AlSi12
Casting Industry Casting material Pressure die casting; Permanent mold casting; Sand casting; Investment casting AlSi12, AlSi7Mg
Marine Corrosion-resistant Boat parts; Marine equipment AlSi7Mg
Sports Equipment Lightweight structures Bicycle parts; Sports equipment AlSi10Mg

SECTION 8: QUALITY SPECIFICATIONS (EN AC-42000 / AlSi7Mg)

Parameter Specification Test Method
Appearance Silvery-gray metallic ingot Visual
Aluminum (Al) Balance (~90%) AAS / ICP
Silicon (Si) 6.5 - 7.5% AAS / ICP
Magnesium (Mg) 0.25 - 0.45% AAS / ICP
Iron (Fe) ≤ 0.15% AAS / ICP
Copper (Cu) ≤ 0.05% AAS / ICP
Manganese (Mn) ≤ 0.05% AAS / ICP
Zinc (Zn) ≤ 0.05% AAS / ICP
Titanium (Ti) ≤ 0.05% AAS / ICP
Lead (Pb) ≤ 0.01% AAS / ICP
Tin (Sn) ≤ 0.01% AAS / ICP
Ingot Weight 5-25 kg (standard) Weighing
Dimensions As per customer requirement Measurement

SECTION 9: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity Low toxicity (metallic form)
Acute Inhalation Toxicity Dust inhalation may cause irritation
Skin Irritation Metallic form is non-irritant
Eye Irritation Metallic form is non-irritant
Chronic Toxicity Aluminum dust may cause lung effects with prolonged inhalation; Silicon dust poses silicosis risk
Carcinogenicity Aluminum and silicon are not classified as carcinogenic
Target Organs Respiratory system (dust irritation)
Special Toxicity Note Metallic alloy is non-toxic; Processing dust may cause respiratory irritation; Prolonged silicon dust inhalation poses silicosis risk; Use appropriate dust control measures

SECTION 10: GHS CLASSIFICATION AND LABELING

GHS Classification (Compliant with CLP and UN GHS):

Hazard Class Category H-Statement
Generally not classified as hazardous - -
STOT - SE (Single Exposure) Category 3 H335 (optional)

Note: Al-Si alloy is generally considered non-hazardous. However, processing dust may cause mechanical irritation.

Signal Word: No signal word required (non-hazardous) or WARNING (optional)

Hazard Pictograms: GHS07 (optional)

Hazard Statements (H-Codes) - if classified:

Code Statement
H335 May cause respiratory irritation

NFPA 704 Hazard Classification:

Health Flammability Reactivity Special
0 0 0 -
(Minimal health hazard) (Will not burn) (Stable) (None)

SECTION 11: PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P264 Wash hands thoroughly after handling
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P312 Call a POISON CENTER/doctor if you feel unwell
P362+P364 Take off contaminated clothing and wash it before reuse
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P501 Dispose of contents/container in accordance with local/regional/national/international regulations

SECTION 12: FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Move to fresh air immediately. Rest in a position comfortable for breathing. If symptoms persist, get medical attention.
Skin Contact Wash with plenty of soap and water. Remove contaminated clothing. If skin irritation occurs, get medical advice/attention.
Eye Contact Rinse immediately with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses if present. Continue rinsing. If eye irritation persists, get medical advice/attention.
Ingestion Rinse mouth with water. Do NOT induce vomiting. Drink plenty of water. Get medical attention if symptoms occur.

SECTION 13: FIREFIGHTING MEASURES

Parameter Information
Fire Hazard Non-combustible. Powder form may be combustible. Melts at high temperatures.
Hazards During Fire Thermal decomposition produces no toxic fumes; Molten metal may react with water
Suitable Extinguishers Use appropriate extinguishing media for surrounding fire. Dry chemical powder, CO₂, sand
Unsuitable Extinguishers Water (violent reaction with molten metal)
Special Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing
Special Precautions Prevent dust from entering sewers and waterways; Do not apply water to molten metal

SECTION 14: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Store in a cool, dry, well-ventilated area; Keep away from moisture and incompatible substances
Container Requirements Original packaging, dry containers; Protect from corrosion
Materials to Protect From Strong acids, strong bases, oxidizing agents, moisture
Shelf Life Unlimited (under proper storage conditions)
Stability Note Stable under normal conditions; Forms protective oxide layer on surface; Protect from moisture
Special Storage Requirements Store separately from acids and bases; Keep in dry area

SECTION 15: PACKAGING OPTIONS

Packaging Type Quantity Material
Wooden Crate 50-200 kg Wooden crate (lined)
Steel Crate 50-200 kg Steel crate
Steel Drum 100-500 kg Corrosion-resistant lined steel
Pallet 500-1000 kg Steel pallet
Bulk Custom quantities Container

SECTION 16: TRANSPORT INFORMATION

Parameter Information
UN Number Not regulated (non-hazardous)
Hazard Class Not applicable
Packing Group Not applicable
ADR/RID Not regulated
IMDG Code Not regulated
IATA (Air) Not regulated
Marine Pollutant No
Transport Temperature Ambient temperature; Protect from moisture

SECTION 17: REGULATORY STATUS

Region / Authority Status
European Union REACH registered; Not classified as hazardous
USA (TSCA) Listed
Turkey Industrial raw material; Subject to KKDIK regulation
IARC Aluminum and silicon Group 3 (Not classifiable)
NTP Not listed
OSHA Not regulated as toxic or carcinogenic substance
California (Prop 65) Not listed
EU Restrictions Not restricted under REACH Annex XVII
RoHS Compliant

SECTION 18: OTHER NAMES AND SYNONYMS

Type Name
Turkish Names Alüminyum Silisyum Külçe, Alüminyum-Silisyum Alaşımı, Al-Si Alaşımı, Silumin
English Names Aluminum Silicon Ingot, Aluminum-Silicon Alloy, Al-Si Alloy, Silumin
Trade Names Silumin, Al-Si, Alpax, Silafont
Chemical Names Aluminum-Silicon Alloy; Al-Si
CAS Numbers 7429-90-5 (Al); 7440-21-3 (Si)

SECTION 19: SUMMARY TABLE

Parameter Value
Product Aluminum Silicon Ingot (Al-Si Alloy / Silumin)
Alloy Type Hypoeutectic / Eutectic / Hypereutectic
Si Content 5% - 25% (depending on grade)
Density 2.65 - 2.70 g/cm³
Melting Point 577 - 660°C
Eutectic Point 577°C (12.6% Si)
Appearance Silvery-gray metallic ingot
Primary Function Casting, structural components
Main Applications Automotive, aerospace, construction, electronics, casting
Shelf Life Unlimited
GHS Signal Word No signal word required (non-hazardous)
UN Number Not regulated
Magnetic Properties Non-magnetic
Special Feature Excellent castability; High strength-to-weight ratio; Good corrosion resistance

SECTION 20: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • Non-hazardous material but processing dust may cause respiratory irritation.

  • Non-combustible. Does not burn. Stable at high temperatures.

  • Powder form may be combustible. Avoid dust generation.

  • Molten metal contact with water may cause violent reaction (explosion risk). Do not use water for firefighting.

  • Excellent castability enables production of complex shapes.

  • Alloy selection is critical for application success. Wrong alloy type will negatively affect performance.

  • Incompatibilities: Keep away from strong acids, strong bases, and oxidizing agents.

  • Hygiene Requirement: Wash hands thoroughly after handling.

BEST PRACTICE RECOMMENDATIONS:

  • Automotive Industry: Use AlSi7Mg or AlSi10Mg for engine blocks and cylinder heads; Use hypereutectic AlSi17Cu4Mg for pistons; Provides high strength and lightweight properties.

  • Casting Applications: Use eutectic AlSi12 for complex shapes; Suitable for pressure die casting, permanent mold casting, and sand casting; Excellent fluidity.

  • Aerospace: Use AlSi7Mg for structural components; High strength-to-weight ratio; Corrosion resistance.

  • Electronics: Use AlSi10Mg or AlSi12 for heat sinks; High thermal conductivity; Lightweight.

  • Handling: Use in well-ventilated areas; Avoid dust generation; Wear protective gloves and safety goggles (if dust).

  • Personal Protective Equipment: Safety goggles, protective clothing, protective gloves (nitrile, neoprene), NIOSH-approved dust mask (if dust).

  • Hygiene: Wash hands thoroughly after handling; Do not eat, drink, or smoke when using.

  • Storage: Store in cool, dry, well-ventilated area; Protect from moisture; Keep away from acids and bases.

  • Spill Response: Avoid dust generation; Vacuum or sweep; Place in closed containers; Do not allow to enter drains or waterways.

  • Disposal: Dispose of in accordance with local, regional, and national regulations; Al-Si is recyclable; Recycle where possible.

ALLOY SELECTION GUIDE:

Application Recommended Alloy Description
General casting, automotive AlSi7Mg (EN AC-42000) Good strength, heat treatable
Complex castings AlSi12 (EN AC-44200) Excellent castability, eutectic composition
High strength AlSi6Cu4 (EN AC-45000) Copper-strengthened
Pistons, wear parts AlSi17Cu4Mg (EN AC-48000) Hypereutectic, high wear resistance
Heat sinks, electronics AlSi10Mg, AlSi12 High thermal conductivity
Marine applications AlSi7Mg Good corrosion resistance

SPECIAL NOTE ON MOLTEN METAL SAFETY:

Important considerations for Al-Si alloy melting and casting operations:

  • Water Contact: Molten Al-Si alloy contacting water causes violent steam explosion

  • Precaution: All equipment and molds must be dry

  • Fire Extinguishing: DO NOT USE WATER; Use dry chemical powder or sand

  • Heating: Controlled heating; Avoid overheating

LEGAL DISCLAIMER:

The information provided in this document is based on our current knowledge and experience and is presented in good faith. However, as all conditions of use are beyond our control, this document does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing suitability for their own applications. For complete safety, storage, handling, transportation, waste, and regulatory compliance information, please refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.

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