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Lead Anode, Lead Electrode, Lead Block, Lead Plate, Pure Lead, 7439-92-1

Lead Anode, Lead Electrode, Lead Block, Lead Plate, Pure Lead, 7439-92-1

LEAD ANODE (PURE LEAD)

PRODUCT IDENTIFICATION INFORMATION

Parameter Information
Product Name Lead Anode
Chemical Symbol Pb
Synonyms (English) Lead Anode, Lead Electrode, Lead Block, Lead Plate, Pure Lead
Synonyms (Turkish) Kurşun Anot, Kurşun Elektrot, Kurşun Blok, Kurşun Levha, Saf Kurşun
CAS Number 7439-92-1
EC Number (EINECS) 231-100-4
Atomic Number 82
Atomic Weight 207.20 g/mol
Appearance Bluish-gray metallic block/plate

CHEMICAL STRUCTURE

    Lead Anode (Pb)
    
    Metallic Lattice Structure
    
         Pb  Pb  Pb  Pb
           \  |  /  |
            Pb Pb Pb Pb
           /  |  \  |
         Pb  Pb  Pb  Pb
    
    Face-Centered Cubic (FCC) Crystal Structure
    Anode in Electrochemical Cell (Oxidation Occurs)

Molecular Formula: Pb (Elemental)
Crystal Structure: Face-Centered Cubic (FCC)
Electron Configuration: [Xe] 4f¹⁴ 5d¹⁰ 6s² 6p²
Oxidation States: +2, +4 (primary)
Synonyms: Lead Anode, Lead Electrode, Lead Block, Lead Plate, Pure Lead

SECTION 1: CHEMICAL IDENTITY AND DEFINITION

Parameter Information
Product Name Lead Anode
Chemical Symbol Pb
Synonyms (English) Lead Anode, Lead Electrode, Lead Block, Lead Plate, Pure Lead
Synonyms (Turkish) Kurşun Anot, Kurşun Elektrot, Kurşun Blok, Kurşun Levha, Saf Kurşun
CAS Number 7439-92-1
EC Number (EINECS) 231-100-4
Atomic Number 82
Atomic Weight 207.20 g/mol
Chemical Class Post-transition metal; heavy metal; elemental metal
Crystal Structure Face-Centered Cubic (FCC)
Electron Configuration [Xe] 4f¹⁴ 5d¹⁰ 6s² 6p²
Oxidation States +2, +4 (primary)
Magnetic Properties Non-magnetic
Appearance Bluish-gray metallic block/plate
Odor Odorless
Color Bluish-gray
Luster Metallic luster, dulls upon oxidation

SECTION 2: PHYSICAL AND CHEMICAL PROPERTIES

Property Value Test Method / Note
Appearance Bluish-gray metallic block/plate Visual
Atomic Weight 207.20 g/mol Calculated
Density (20°C) 11.34 g/cm³ ASTM D792
Melting Point 327.5°C DSC
Boiling Point 1,749°C -
Electrical Conductivity 4.8 × 10⁶ S/m (moderate) ASTM E1004
Thermal Conductivity 35.3 W/m·K -
Specific Heat (25°C) 0.129 J/g·K -
Electrical Resistivity 2.08 × 10⁻⁷ Ω·m -
Hardness (Brinell) ~5 HB (very soft) ASTM E10
Tensile Strength ~10-15 MPa (low) ASTM E8
Elongation ~30-50% (high ductility) ASTM E8
Magnetic Properties Non-magnetic -
Oxidation States +2, +4 -
Corrosion Resistance Excellent (forms protective layer) -
Standard Electrode Potential -0.126 V (Pb²⁺/Pb) -
Coefficient of Thermal Expansion 29.0 × 10⁻⁶ /°C -
Toxicity Highly toxic -

SECTION 3: CHEMICAL PROPERTIES AND REACTIVITY

Parameter Information
Chemical Character Post-transition metal; very soft; highly ductile; excellent corrosion resistance; non-magnetic; toxic
Stability Stable under normal conditions; Forms protective oxide/carbonate layer on surface; Resistant to corrosion
Reactivity (As Anode) Acts as anode in electrochemical cells; Oxidation occurs at surface: Pb → Pb²⁺ + 2e⁻; Provides lead ions for electroplating; Resistant to sulfuric acid
Incompatible Materials Strong oxidizing agents, strong acids (nitric acid), strong bases, halogens, nitrates
Corrosion Resistance Excellent; Forms protective oxide/carbonate layer; Resistant to sulfuric acid (used in lead-acid batteries)
Acid Reaction (Anodic) Pb + 2HNO₃ → Pb(NO₃)₂ + H₂ (with nitric acid); Pb + H₂SO₄ → PbSO₄ + H₂ (forms protective layer)
Alkali Reaction Reacts with strong bases to form plumbites
Oxidation (Anodic) Pb → Pb²⁺ + 2e⁻ (anodic dissolution); Provides lead ions for electroplating
Alloy Formation Easily forms alloys with tin (solder), antimony (hard lead), calcium (battery grids)
Toxicity Highly toxic; Bioaccumulates in body; Affects nervous system, kidneys, and blood

SECTION 4: COMPARISON OF LEAD AND RELATED METALS

Property Lead (Pb) Tin (Sn) Zinc (Zn) Copper (Cu)
CAS Number 7439-92-1 7440-31-5 7440-66-6 7440-50-8
Symbol Pb Sn Zn Cu
Atomic Number 82 50 30 29
Density (g/cm³) 11.34 7.28 7.14 8.96
Melting Point (°C) 327.5 231.9 419.5 1,085
Hardness Very soft Very soft Moderate Hard
Toxicity Highly toxic Low toxicity Low toxicity Low toxicity
Primary Use Batteries, shielding Solder, plating Galvanizing Wiring, plumbing

SECTION 5: PRODUCTION METHODS

Method 1: Smelting and Refining (Most Common Method)

  • Process: Lead ore (Galena - PbS) → Roasting → Smelting → Refining → Pure Lead

  • Description: Lead ore is roasted to remove sulfur; Smelted with coke to produce crude lead; Refined by electrolysis or thermal refining; Most common industrial production method

Method 2: Electrolytic Refining

  • Process: Crude lead → Electrolysis → Pure lead

  • Reaction: Pb²⁺ + 2e⁻ → Pb (deposition at cathode)

  • Description: Crude lead is used as anode; Pure lead is deposited on cathode through electrolysis; Produces high-purity lead (99.99%+)

Method 3: Casting and Forming

  • Process: Pure lead → Melting → Casting → Forming → Lead anode

  • Description: Pure lead is melted and cast into anode shapes (blocks, plates); Custom shapes available

Method 4: Thermal Refining (Fire Refining)

  • Process: Crude lead → Heating → Fluxing → Slag removal → Pure lead

  • Description: Crude lead is heated and treated with fluxes to remove impurities; Produces commercial-grade lead

SECTION 6: FUNCTIONAL PROPERTIES AND MECHANISM OF ACTION

Property Description
Anodic Dissolution Acts as anode in electrochemical cells; Oxidation occurs: Pb → Pb²⁺ + 2e⁻; Provides lead ions for electroplating and battery applications
Electroplating Anode Used as soluble anode in lead electroplating; Supplies lead ions to the plating bath; Maintains bath concentration; Ensures uniform coating thickness
Battery Electrode Used in lead-acid batteries; Acts as anode during discharge; Rechargeable; High surge current capability; Reliable and low cost
Radiation Shielding Used for protection against X-rays and gamma radiation; High density (11.34 g/cm³) provides excellent radiation attenuation
Cathodic Protection Used as anode in cathodic protection systems; Protects pipelines, ship hulls, and marine structures
Chemical Resistance Excellent resistance to sulfuric acid; Used in chemical processing equipment; Protective layer formation
Corrosion Protection Forms protective oxide/carbonate layer; Resistant to corrosion in most environments

SECTION 7: MAIN APPLICATION AREAS

Industry / Application Function Typical Use
Electroplating Anode Lead plating baths; Supplies lead ions for deposition; Corrosion protection; Industrial coatings
Battery Industry Electrode Lead-acid batteries (automotive, industrial, UPS); Starter batteries; Deep-cycle batteries
Radiation Shielding Shield Medical X-ray rooms; Nuclear facilities; Radiography; Radiation protection equipment
Cathodic Protection Anode Pipeline protection; Ship hulls; Marine structures; Underground tanks
Chemical Industry Corrosion resistance Chemical processing equipment; Sulfuric acid handling; Protective linings
Cable Industry Sheathing Electrical cable protection; Underground cables; Submarine cables
Alloy Production Alloy component Solder (tin-lead); Hard lead (antimony-lead); Battery grids (calcium-lead)

SECTION 8: QUALITY SPECIFICATIONS (PURE LEAD ANODE)

Parameter Specification Test Method
Appearance Bluish-gray metallic block/plate Visual
Purity (Pb) ≥ 99.0% - 99.99% AAS / ICP
Antimony (Sb) ≤ 0.001% - 0.5% AAS / ICP
Tin (Sn) ≤ 0.001% - 0.05% AAS / ICP
Arsenic (As) ≤ 0.001% - 0.02% AAS / ICP
Bismuth (Bi) ≤ 0.001% - 0.02% AAS / ICP
Copper (Cu) ≤ 0.001% - 0.01% AAS / ICP
Zinc (Zn) ≤ 0.001% - 0.01% AAS / ICP
Iron (Fe) ≤ 0.001% - 0.01% AAS / ICP
Silver (Ag) ≤ 0.001% - 0.01% AAS / ICP
Nickel (Ni) ≤ 0.001% - 0.01% AAS / ICP
Shape Block, Plate, Sheet, Rod Measurement
Dimensions As per customer requirement Measurement
Weight per Piece Custom (5-50 kg) Weighing

SECTION 9: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity High toxicity
Acute Inhalation Toxicity Toxic; Dust/fume inhalation causes lead poisoning
Skin Irritation Metallic form may cause irritation
Eye Irritation Metallic form may cause irritation
Chronic Toxicity Highly toxic; Accumulates in body; Affects nervous system, kidneys, blood, and reproductive system
Carcinogenicity IARC Group 2A (Probably carcinogenic to humans); NTP: Known human carcinogen
Mutagenicity Suspected of causing genetic defects (H341)
Reproductive Toxicity May damage fertility or the unborn child (H360Df)
Target Organs Nervous system, kidneys, blood, bones, reproductive system
Occupational Exposure Limit (8h TWA) 0.05 mg/m³ (OSHA PEL); 0.05 mg/m³ (ACGIH TLV)
Special Toxicity Note LEAD IS HIGHLY TOXIC. Chronic exposure causes lead poisoning (plumbism). Symptoms: abdominal pain, headache, fatigue, memory loss, anemia, kidney damage, neurological damage. Children are especially sensitive. Bioaccumulates in bones and teeth.

SECTION 10: GHS CLASSIFICATION AND LABELING

GHS Classification (Compliant with CLP and UN GHS):

Hazard Class Category H-Statement
Reproductive Toxicity Category 1A H360Df
Carcinogenicity Category 2 H351
Acute Toxicity (Oral) Category 4 H302
Acute Toxicity (Inhalation) Category 4 H332
STOT - RE (Repeated Exposure) Category 1 H372
Aquatic Toxicity Category 2 H411

Signal Word: DANGER

Hazard Pictograms: GHS08 (Health Hazard), GHS07 (Exclamation Mark), GHS09 (Environment)

Hazard Statements (H-Codes):

Code Statement
H302 Harmful if swallowed
H332 Harmful if inhaled
H351 Suspected of causing cancer
H360Df May damage the unborn child and fertility
H372 Causes damage to organs through prolonged or repeated exposure
H411 Toxic to aquatic life with long lasting effects

NFPA 704 Hazard Classification:

Health Flammability Reactivity Special
3 0 0 -
(Severe health hazard) (Will not burn) (Stable) (None)

SECTION 11: PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P260 Do not breathe dust/fume/gas/mist/vapors/spray
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P264 Wash hands thoroughly after handling
P270 Do not eat, drink or smoke when using this product
P271 Use only outdoors or in a well-ventilated area
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection/respiratory protection
P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P308+P313 IF exposed or concerned: Get medical advice/attention
P330 Rinse mouth
P362+P364 Take off contaminated clothing and wash it before reuse
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P405 Store locked up
P501 Dispose of contents/container in accordance with local/regional/national/international regulations

SECTION 12: FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Move to fresh air immediately. Rest in a position comfortable for breathing. If breathing is difficult, give oxygen. If symptoms occur, call a POISON CENTER/doctor immediately.
Skin Contact Remove contaminated clothing immediately. Rinse skin with plenty of water for at least 15-20 minutes. Wash with soap and water. If skin irritation occurs, get medical advice/attention.
Eye Contact Rinse immediately with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses if present. Continue rinsing. Get immediate medical attention.
Ingestion Rinse mouth with water. Do NOT induce vomiting. Drink plenty of water. Immediately call a POISON CENTER/doctor. Never give anything by mouth to an unconscious person.

SECTION 13: FIREFIGHTING MEASURES

Parameter Information
Fire Hazard Non-combustible. High temperatures release toxic lead oxide fumes.
Hazards During Fire Thermal decomposition produces toxic lead oxide fumes
Suitable Extinguishers Use appropriate extinguishing media for surrounding fire. Dry chemical powder, CO₂, sand
Unsuitable Extinguishers Water (with powder form)
Special Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing
Special Precautions Prevent dust from entering sewers and waterways; Do not inhale fumes

SECTION 14: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Store in a cool, dry, well-ventilated area; Keep away from moisture and incompatible substances; Store separately from food and feed
Container Requirements Original packaging, dry containers; Protect from corrosion
Materials to Protect From Strong oxidizing agents, strong acids, strong bases, halogens
Shelf Life Unlimited (under proper storage conditions)
Stability Note Stable under normal conditions; Forms protective oxide/carbonate layer on surface; Protect from moisture
Special Storage Requirements Store separately from food and feed; Store locked up; Regular monitoring for lead contamination

SECTION 15: PACKAGING OPTIONS

Packaging Type Quantity Material
Wooden Crate 50-200 kg Wooden crate (lined)
Steel Crate 50-200 kg Steel crate
Steel Drum 100-500 kg Corrosion-resistant lined steel
Pallet 500-1000 kg Steel pallet
Bulk Custom quantities Container

SECTION 16: TRANSPORT INFORMATION

Parameter Information
UN Number UN 3077 (Environmentally hazardous substance, solid, n.o.s.)
Hazard Class 9 (Miscellaneous Dangerous Goods)
Packing Group III
ADR/RID UN 3077, Environmentally hazardous substance, solid, n.o.s., 9, PG III
IMDG Code UN 3077, Environmentally hazardous substance, solid, n.o.s., 9, PG III, Marine Pollutant: Yes
IATA (Air) UN 3077, Environmentally hazardous substance, solid, n.o.s., 9, PG III
Marine Pollutant Yes
Transport Temperature Ambient temperature; Protect from moisture

SECTION 17: REGULATORY STATUS

Region / Authority Status
European Union REACH registered; Classified as reproductive toxicant and carcinogen
USA (TSCA) Listed
USA (EPA) Regulated as hazardous substance; Lead and Lead Compounds
Turkey Industrial raw material; Subject to KKDIK regulation; Classified as toxic
IARC Group 2A (Probably carcinogenic to humans)
NTP Known human carcinogen
OSHA Regulated (highly toxic substance)
California (Prop 65) Listed as carcinogen and reproductive toxicant
EU Restrictions Restricted under REACH Annex XVII
RoHS Restricted in electronic equipment

SECTION 18: OTHER NAMES AND SYNONYMS

Type Name
Turkish Names Kurşun Anot, Kurşun Elektrot, Kurşun Blok, Kurşun Levha, Saf Kurşun
English Names Lead Anode, Lead Electrode, Lead Block, Lead Plate, Pure Lead
Chemical Names Lead; Elemental Lead; Lead Metal
CAS Number 7439-92-1
EC Number 231-100-4
Atomic Number 82
Atomic Symbol Pb

SECTION 19: SUMMARY TABLE

Parameter Value
Product Lead Anode (Pure Lead)
CAS Number 7439-92-1
Atomic Number 82
Atomic Weight 207.20 g/mol
Appearance Bluish-gray metallic block/plate
Density 11.34 g/cm³
Melting Point 327.5°C
Boiling Point 1,749°C
Hardness Very soft (~5 HB)
Electrical Conductivity 4.8 × 10⁶ S/m
Magnetic Properties Non-magnetic
Primary Function Anode, battery electrode, shielding
Main Applications Electroplating (lead plating), lead-acid batteries, radiation shielding, cathodic protection
Shelf Life Unlimited
GHS Signal Word DANGER
UN Number UN 3077
Toxicity Highly toxic; IARC Group 2A; NTP Known carcinogen
Special Feature High density; Excellent corrosion resistance; Soft and ductile; Toxic

SECTION 20: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • HIGHLY TOXIC. Lead is a toxic metal that accumulates in the body. Causes serious health effects.

  • Suspected of causing cancer (H351). IARC Group 2A; NTP Known human carcinogen.

  • May damage fertility or the unborn child (H360Df). Reproductive toxicant.

  • Causes damage to organs through prolonged or repeated exposure (H372). Affects nervous system, kidneys, blood.

  • Harmful if swallowed or inhaled (H302/H332). Avoid ingestion and inhalation.

  • Toxic to aquatic life with long lasting effects (H411). Prevent environmental release.

  • Non-combustible but decomposes at high temperatures releasing toxic lead oxide fumes.

  • Forms protective oxide layer but avoid contact with acids.

  • Incompatibilities: Keep away from strong oxidizing agents, strong acids, and strong bases.

  • Hygiene Requirement: Contaminated clothing should not be allowed out of the workplace. Separate work clothing required.

  • Children and pregnant women are especially sensitive to lead exposure.

BEST PRACTICE RECOMMENDATIONS:

  • Electroplating (Lead Anode): Use as soluble anode in lead plating baths; Provides lead ions for deposition; Maintains bath concentration; Ensures uniform coating thickness; Use appropriate current density; Monitor anode consumption.

  • Battery Production: Use as electrode in lead-acid battery manufacturing; Automotive and industrial batteries; Maintain strict purity specifications; Lead is essential for battery grids and active materials.

  • Radiation Shielding: Use for protection against X-rays and gamma radiation; Medical and nuclear applications; High density (11.34 g/cm³) provides effective shielding; Handle with care; Follow radiation safety protocols.

  • Cathodic Protection: Use as anode in cathodic protection systems; Protects pipelines, ship hulls, and marine structures; Provides electrochemical corrosion protection.

  • Handling: Use ONLY in well-ventilated areas or under fume hoods; Avoid dust generation; Wear appropriate respiratory protection; Do not eat, drink, or smoke in work areas.

  • Personal Protective Equipment: Wear impermeable gloves (nitrile, neoprene), chemical safety goggles, full-face shield, protective clothing, and NIOSH-approved lead fume/dust respirator.

  • Hygiene: Wash hands thoroughly after handling; Do not eat, drink, or smoke when using; Do not take contaminated working clothes home; Shower at the end of the work shift; Regular blood lead monitoring for workers.

  • Storage: Store in tightly closed, properly labeled containers in dry conditions; Store separately from food and feed; Store locked up; Regular monitoring for lead contamination.

  • Spill Response: Avoid raising dust; Wear full PPE; Vacuum or wet-sweep; Place in properly labeled closed containers; Do not allow to enter drains or waterways.

  • Disposal: Dispose of in accordance with local, regional, and national regulations; Lead is regulated as hazardous waste; Do not discharge into sewers or water sources.

SPECIAL NOTE ON LEAD TOXICITY (PLUMBISM):

Lead poisoning (plumbism) is a serious health concern:

  • Symptoms: Abdominal pain, headache, fatigue, memory loss, anemia, kidney damage, neurological damage

  • Children: Developmental delays, learning difficulties, behavioral problems

  • Pregnant Women: Miscarriage, premature birth, developmental problems in fetus

  • Bioaccumulation: Accumulates in bones and teeth (half-life 20-30 years)

  • Blood Lead Level (BLL): OSHA requires medical removal at BLL ≥ 50 µg/dL; CDC recommends intervention at BLL ≥ 5 µg/dL

  • Prevention: Regular blood lead monitoring; Proper PPE; Hygiene practices; Engineering controls; Substitution where possible

SPECIAL NOTE ON LEAD-ACID BATTERIES:

Lead is essential for lead-acid battery technology:

  • Anode: Lead (Pb) → Lead sulfate (PbSO₄) during discharge

  • Cathode: Lead dioxide (PbO₂) → Lead sulfate (PbSO₄) during discharge

  • Electrolyte: Sulfuric acid (H₂SO₄)

  • Applications: Automotive starter batteries; Industrial batteries; UPS batteries; Renewable energy storage

  • Recycling: Lead-acid batteries are highly recyclable (>99% recycling rate)

LEGAL DISCLAIMER:

The information provided in this document is based on our current knowledge and experience and is presented in good faith. However, as all conditions of use are beyond our control, this document does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing suitability for their own applications. For complete safety, storage, handling, transportation, waste, and regulatory compliance information, please refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.

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