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Potassium Carbonate, Dipotassium Carbonate, Pearl Ash, Potash, Tartar Salt, E501, E501i, 584-08-7

Potassium Carbonate, Dipotassium Carbonate, Pearl Ash, Potash, Tartar Salt, E501, E501i, 584-08-7

POTASSIUM CARBONATE (E501)
PRODUCT IDENTIFICATION INFORMATION

Parameter Information
Product Name Potassium Carbonate
Chemical Name Potassium Carbonate
Synonyms (Turkish) Potasyum Karbonat, Potas, Karbonik Asit Potasyum Tuzu, Tartar Tuzu, İnci Külü
Synonyms (English) Potassium Carbonate, Carbonic Acid Potassium Salt, Salt of Tartar, Pearl Ash, Potash, Dipotassium Carbonate
E Number E501, E501i
CAS Number 584-08-7
Molecular Formula K₂CO₃
Molecular Weight 138.21 g/mol
Appearance White, crystalline powder or granules
Odor Odorless

CHEMICAL STRUCTURE

Potassium Carbonate

K⁺ — O⁻ — C(=O) — O⁻ — K⁺

Molecular Formula: K₂CO₃
SMILES: [K+].[K+].[O-]C([O-])=O
InChI: InChI=1S/CH2O3.2K/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2
InChIKey: BWHMMNNQKKPAPP-UHFFFAOYSA-L
Structure: Inorganic salt of carbonic acid; Dipotassium salt; Highly alkaline; Strong electrolyte.

SECTION 1: CHEMICAL IDENTITY AND DESCRIPTION

Parameter Information
Product Name Potassium Carbonate
Chemical Name Potassium Carbonate
Synonyms (Turkish) Potasyum Karbonat, Potas, Karbonik Asit Potasyum Tuzu, Tartar Tuzu, İnci Külü
Synonyms (English) Potassium Carbonate, Carbonic Acid Potassium Salt, Salt of Tartar, Pearl Ash, Potash, Dipotassium Carbonate
E Number E501, E501i
CAS Number 584-08-7
EC Number (EINECS) 209-529-3
Molecular Formula K₂CO₃
Molecular Weight 138.21 g/mol
Chemical Class Inorganic salt; Alkali metal carbonate; Strong base
Physical State (20°C) Solid (crystalline powder or granules)
Odor Odorless
Color White
Taste Alkaline, salty (do not ingest)

SECTION 2: PHYSICAL AND CHEMICAL PROPERTIES

Property Value Test Method / Note
Appearance White, crystalline powder or granules Visual
Odor Odorless Olfactometric
Molecular Weight 138.21 g/mol Calculated
Density (20°C) 2.43 g/cm³ ASTM D4052
Melting Point 891°C DSC
Boiling Point Decomposes before boiling
pH (1% Solution, 20°C) ~11.6 (highly alkaline) pH Meter
Solubility in Water (20°C) 111 g / 100 g water General Method
Solubility in Water (Hot) Higher (temperature dependent) General Method
Solubility in Ethanol Insoluble General Method
Hygroscopicity High (deliquescent)
Decomposition Decomposes to K₂O and CO₂ at high temperatures
Heat of Solution Endothermic (cools water)
Bulk Density 0.8 – 1.2 g/cm³ (grade dependent)
Refractive Index 1.531
Surface Tension (10% Solution) ~72 mN/m
K₂O Content ~68%
Chloride (Cl) ≤ 0.005% Titrimetric
Sulfate (SO₄) ≤ 0.005% Turbidimetric
Iron (Fe) ≤ 0.001% AAS / ICP
Heavy Metals (as Pb) ≤ 10 ppm AAS / ICP

SECTION 3: POTASSIUM COMPOUNDS COMPARISON

Property Potassium Carbonate (K₂CO₃) Potassium Bicarbonate (KHCO₃) Potassium Hydroxide (KOH) Potassium Chloride (KCl)
CAS Number 584-08-7 298-14-6 1310-58-3 7447-40-7
Formula K₂CO₃ KHCO₃ KOH KCl
Molecular Weight 138.21 100.12 56.11 74.55
pH (1% Solution) ~11.6 ~8.2 ~13.5 ~7.0
Solubility (g/100g water) 111 33 112 34
Alkalinity Strong Weak Very Strong Neutral
Primary Use Glass, detergents, baking Buffering, fire extinguishers Soap, batteries Fertilizer, salt substitute

SECTION 4: CHEMICAL PROPERTIES AND REACTIVITY

Parameter Information
Chemical Character Inorganic salt; Alkaline; Highly hygroscopic; Strong base; Excellent CO₂ absorber
Stability Stable under normal conditions; Hygroscopic (absorbs moisture from air); Decomposes at high temperatures
Reactivity Reacts with acids to form potassium salts and CO₂; Absorbs CO₂ to form potassium bicarbonate; Reacts with acidic oxides; Forms double salts with many metals
Incompatible Materials Strong acids (violent reaction, CO₂ release), strong oxidizing agents, acidic oxides, moisture/humidity (deliquescence)
Polymerization Does not polymerize
Decomposition Products (Heating) Potassium oxide (K₂O), carbon dioxide (CO₂)
Acid Reaction K₂CO₃ + 2HCl → 2KCl + H₂O + CO₂↑
CO₂ Absorption K₂CO₃ + CO₂ + H₂O → 2KHCO₃
Hydrolysis K₂CO₃ + H₂O → K⁺ + HCO₃⁻ + OH⁻ (alkaline solution)
Neutralization Reacts with acids to form salts, water, and CO₂
Deliquescence Absorbs moisture from air and may form a liquid solution
Complexation Forms complexes with metal ions in solution

SECTION 5: PRODUCTION METHODS

Method 1: Electrolysis of Potassium Chloride (KCl)

Process: KCl + H₂O → KOH + Cl₂ + H₂; KOH + CO₂ → K₂CO₃

Description: Potassium chloride solution is electrolyzed to produce potassium hydroxide (KOH) and chlorine gas; KOH is reacted with carbon dioxide to form potassium carbonate. Most common industrial method.

Method 2: Leblanc Process (Ash Method)

Process: Plant ash (K₂CO₃) → Purification → Crystallization

Description: Plant ash (from burning wood/plants) is leached with water; The potassium carbonate is crystallized and purified; Traditional method; Less common today.

Method 3: Carbonation of Potassium Hydroxide

Reaction: 2KOH + CO₂ → K₂CO₃ + H₂O

Description: Pure potassium hydroxide is reacted with carbon dioxide gas; Yields high-purity potassium carbonate.

Method 4: Thermal Decomposition of Potassium Bicarbonate

Reaction: 2KHCO₃ → K₂CO₃ + H₂O + CO₂↑

Description: Potassium bicarbonate is heated to decompose; Produces potassium carbonate, water, and carbon dioxide; High-purity product.

SECTION 6: FUNCTIONAL PROPERTIES AND MECHANISM OF ACTION

Property Description
Alkalizing Agent Provides strong alkaline pH (11.6 in 1% solution); Neutralizes acids; Used in cocoa processing, wine making, and pH adjustment
CO₂ Absorber Absorbs carbon dioxide to form potassium bicarbonate; Used in gas purification, air scrubbing, and CO₂ removal; Effective in high-temperature applications
Potassium Source Provides essential potassium ions; Used in fertilizers, animal feed, and nutritional supplements; Essential for plant growth
Buffering Agent Maintains pH in solutions; Used in laboratory and industrial applications; Prevents pH fluctuations
Water Softener Precipitates calcium and magnesium ions; Removes hardness from water; Used in detergents and cleaning formulations
Drying Agent Highly hygroscopic; Absorbs moisture effectively; Used to dry fruits and other products; Dehydration agent
Glass Former Lowers melting point of silica; Improves glass properties; Used in television glass, optical glass, and specialty glass
Flux Lowers melting point in ceramics and glass; Improves workability; Used in pottery and glazes
Soil Amendment Increases potassium content in soil; Improves plant health and yield; Used in fertilizers (K₂O content ~68%)
Acid Neutralizer Neutralizes acids in various processes; Used in chemical synthesis; pH control

SECTION 7: MAIN APPLICATION AREAS

Industry / Application Function Typical Use
Glass Manufacturing Flux, potassium source Television glass, optical glass, cathode ray tubes; Lowers melting temperature; Improves transparency
Food Industry (E501) Acidity regulator, leavening agent Cocoa processing (alkalization); Wine making; Baking (leavening agent); pH adjustment; Cheese production
Fruit Dehydration Drying accelerator Grape, pear, apple, apricot drying; Speeds up dehydration; Improves color and appearance
Detergents & Cleaning Builder, water softener Phosphate-free detergents; Water softening; Cleaning formulations; Dishwashing products
Agriculture Fertilizer (potassium source) Potassium-rich fertilizers (K₂O content ~68%); Soil amendment; Plant nutrition
Chemical Synthesis Reagent, catalyst Potassium source for chemical reactions; Buffer solutions; Laboratory reagent; CO₂ absorption
Flue Gas Treatment CO₂ absorbent Carbon dioxide removal from flue gases; Air purification; Acid gas scrubbing
Pharmaceutical Electrolyte supplement Potassium supplements; Electrolyte formulations; Tablet production; Oral rehydration salts
Soap & Cosmetics Softening agent Liquid soaps; Shampoos; Skin care products; pH adjustment
Water Treatment Softening, pH adjustment Water softening; pH control; Corrosion inhibition
Metallurgy Flux, deoxidizer Metal treatment; Welding fluxes; Deoxidizing agent
Fertilizers Potassium source NK (Nitrogen-Potassium) fertilizers; Micronutrient carrier; Potassium deficiency correction

SECTION 8: QUALITY SPECIFICATIONS

Parameter Food Grade (E501) Pharmaceutical Grade Technical Grade Test Method
Appearance White powder/granules White powder/granules White powder/granules Visual
Assay (K₂CO₃) ≥ 99.0% ≥ 99.5% ≥ 98.0% Titrimetric
K₂O Content ≥ 68.0% ≥ 68.5% ≥ 67.5% Titrimetric
pH (1% Solution) 11.0 – 12.0 11.0 – 12.0 11.0 – 12.0 pH Meter
Loss on Drying (105°C) ≤ 1.0% ≤ 0.5% ≤ 1.0% Gravimetric
Chloride (Cl) ≤ 0.005% ≤ 0.002% ≤ 0.01% Titrimetric
Sulfate (SO₄) ≤ 0.005% ≤ 0.002% ≤ 0.01% Turbidimetric
Iron (Fe) ≤ 0.001% ≤ 0.0005% ≤ 0.005% AAS / ICP
Heavy Metals (as Pb) ≤ 10 ppm ≤ 5 ppm ≤ 20 ppm AAS / ICP
Arsenic (As) ≤ 2 ppm ≤ 1 ppm ≤ 5 ppm AAS / ICP
Lead (Pb) ≤ 2 ppm ≤ 1 ppm ≤ 5 ppm AAS / ICP
Insoluble Matter ≤ 0.02% ≤ 0.01% ≤ 0.05% Gravimetric
Particle Size Customer requirement Customer requirement Customer requirement Sieve / Laser

SECTION 9: TOXICOLOGICAL PROFILE

Parameter Value
Acute Oral Toxicity (LD50, Rat) ~ 1,870 mg/kg (moderate toxicity)
Acute Dermal Toxicity May cause skin irritation
Acute Inhalation Toxicity Respiratory tract irritation (dust)
Skin Irritation Irritating; Corrosive in high concentrations
Eye Irritation Causes serious eye irritation
Respiratory Irritation May cause respiratory irritation
Chronic Toxicity High doses may cause gastrointestinal irritation; Electrolyte imbalance
Carcinogenicity Not classified as carcinogenic
Mutagenicity Not mutagenic
Reproductive Toxicity No reproductive toxicity
Target Organs Eyes, skin, respiratory system, gastrointestinal system
Occupational Exposure Limit (8h TWA) Not established (general dust limit applies)
Special Toxicity Note Alkaline – causes irritation; Corrosive in high concentrations; Overdose may cause electrolyte imbalance (hyperkalemia); Food additive E501 approved; GRAS status for food use

SECTION 10: GHS CLASSIFICATION AND LABELING

GHS Classification (in accordance with CLP and UN GHS):

Hazard Class Category H-Statement
Skin Irritation Category 2 H315
Eye Irritation Category 2 H319
Specific Target Organ Toxicity (Single Exposure) Category 3 H335

Signal Word: WARNING

Hazard Pictograms: GHS07 (Exclamation Mark)

Hazard Statements (H-Codes):

Code Statement
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation

NFPA 704 Hazard Classification:

Health Flammability Reactivity Special
2 0 1 -
(Moderate health hazard) (Will not burn) (Moderate reactivity – CO₂ with acids) (None)

SECTION 11: PRECAUTIONARY STATEMENTS (P-CODES)

Code Statement
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P264 Wash hands thoroughly after handling
P271 Use only outdoors or in a well-ventilated area
P280 Wear protective gloves/protective clothing/eye protection/face protection
P302+P352 IF ON SKIN: Wash with plenty of soap and water
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and continue rinsing
P312 Call a POISON CENTER/doctor if you feel unwell
P332+P313 If skin irritation occurs: Get medical advice/attention
P337+P313 If eye irritation persists: Get medical advice/attention
P362+P364 Take off contaminated clothing and wash it before reuse
P403+P233 Store in a well-ventilated place. Keep container tightly closed
P501 Dispose of contents/container in accordance with local/regional/national/international regulations

SECTION 12: FIRST AID MEASURES

Exposure Route Action to Take
Inhalation Remove to fresh air immediately. If respiratory irritation develops (dust inhalation), seek medical attention.
Skin Contact Remove contaminated clothing. Wash with plenty of soap and water. If irritation persists, get medical attention.
Eye Contact Rinse immediately with plenty of water for at least 15 minutes. Keep eyelids open. Remove contact lenses if present. If irritation persists, seek medical attention.
Ingestion Rinse mouth. Do NOT induce vomiting. Drink plenty of water. Seek medical attention if large quantities are ingested.

SECTION 13: FIREFIGHTING MEASURES

Parameter Information
Fire Hazard Non-combustible. Does not burn.
Hazards Arising from Fire Thermal decomposition produces potassium oxide fumes and carbon dioxide.
Suitable Extinguishing Media Use extinguishing media suitable for surrounding fire. Water spray, CO₂, dry chemical powder, foam.
Unsuitable Extinguishing Media None
Special Protective Equipment Self-contained breathing apparatus (SCBA), full protective clothing.
Special Precautions Prevent dust from entering sewers and waterways.

SECTION 14: STORAGE AND SHELF LIFE

Parameter Information
Storage Conditions Store in a cool, dry, well-ventilated area; PROTECT FROM MOISTURE and high humidity; Keep away from acids and direct sunlight.
Container Requirements Tightly closed, moisture-proof containers (HDPE, lined steel drums, plastic bags with PE liner).
Materials to Protect From Moisture, high humidity, strong acids, acid gases (CO₂ absorption)
Shelf Life 24 – 36 months (in unopened original packaging, under proper storage conditions).
Stability Note Very hygroscopic (deliquescent) – absorbs moisture and CO₂ from air; Keep container tightly closed after opening; Protect from excessive humidity.
Special Storage Requirements Store in a dry, well-ventilated warehouse; Avoid exposure to rain, sun, and moisture; Opened containers must be resealed immediately; Store separately from acids.

SECTION 15: PACKAGING OPTIONS

Packaging Type Quantity Material
Multi-layer Paper Bag 10 kg, 20 kg, 25 kg PE-lined kraft paper bag (moisture-proof)
Plastic Bag 5 kg, 10 kg, 25 kg PE bag (inner-lined, sealed, moisture-proof)
Fiber Drum 20 kg, 25 kg PE-lined fiberboard drum
Plastic Drum 25 kg, 50 kg HDPE / Polypropylene (moisture-proof)
FIBC / Big Bag 500 kg, 1000 kg PE-lined, moisture-resistant PP woven bag

SECTION 16: TRANSPORT INFORMATION

Parameter Information
UN Number Not regulated (non-hazardous)
Hazard Class Not applicable
Packing Group Not applicable
ADR/RID Not regulated
IMDG Code Not regulated (non-hazardous)
IATA (Air) Not regulated (non-hazardous)
Marine Pollutant No
Transport Temperature Ambient temperature; Protect from moisture.

SECTION 17: REGULATORY STATUS

Region / Authority Status
European Union Food additive E501/E501i approved by EFSA; Not classified as hazardous
USA (TSCA) Listed (TSCA Inventory)
USA (FDA) GRAS (Generally Recognized as Safe) – 21 CFR 184.1002; Food additive E501
Turkey Food additive E501; Subject to KKDIK regulation; Fertilizer regulations apply
IARC Not classified (non-toxic, non-carcinogenic)
NTP Not listed
OSHA Not regulated as toxic or carcinogenic substance
California (Prop 65) Not listed
Halal Yes
Kosher Yes
Vegan Yes

SECTION 18: OTHER NAMES AND SYNONYMS

Type Name
Turkish Names Potasyum Karbonat, Potas, Karbonik Asit Potasyum Tuzu, Tartar Tuzu, İnci Külü
English Names Potassium Carbonate, Carbonic Acid Potassium Salt, Salt of Tartar, Pearl Ash, Potash, Dipotassium Carbonate
Chemical Names Dipotassium carbonate; Carbonic acid, dipotassium salt; Potassium salt of carbonic acid
CAS Number 584-08-7
E Number E501, E501i
Molecular Formula K₂CO₃
HS Code 2836.40
Synonyms Potassium salt of carbonic acid, Pearl ash, Salt of tartar, Potash, Carbonate of potash

SECTION 19: SUMMARY TABLE

Parameter Value
Product Potassium Carbonate (E501)
CAS Number 584-08-7
Molecular Formula K₂CO₃
Molecular Weight 138.21 g/mol
Appearance White crystalline powder/granules
Density 2.43 g/cm³
Melting Point 891°C
Solubility in Water 111 g/100 g water (high)
pH (1% Solution) ~11.6
Primary Function Alkalizing agent, potassium source, CO₂ absorber, flux
Main Application Areas Glass manufacturing, food (E501), detergents, fertilizers, chemical synthesis, flue gas treatment, pharmaceuticals
Shelf Life 24 – 36 months
GHS Signal Word WARNING
UN Number Not regulated
Special Properties Hygroscopic; Deliquescent; Strong base; CO₂ absorber; FDA GRAS; E501 approved

SECTION 20: CRITICAL WARNINGS AND BEST PRACTICES

CRITICAL WARNINGS:

  • Causes skin irritation (H315) and serious eye irritation (H319). Wear protective equipment.

  • May cause respiratory irritation (H335). Avoid inhalation of dust. Use in well-ventilated areas.

  • Highly alkaline – pH ~11.6 (1% solution). Handle with care.

  • Hygroscopic / Deliquescent – absorbs moisture and CO₂ from air. Store in tightly closed, moisture-proof containers.

  • Not flammable. Stable under normal conditions.

  • Reacts with acids – releases CO₂; Store separately from acids.

  • Absorbs CO₂ – forms potassium bicarbonate; Keep container tightly closed.

  • Moderate toxicity – LD50 ~1,870 mg/kg (rat). Avoid ingestion.

  • Food additive E501 – approved for food use; GRAS status.

  • Not suitable for individuals with hyperkalemia – contains potassium.

BEST PRACTICE RECOMMENDATIONS:

Glass Manufacturing: Use as flux and potassium source; Lowers melting temperature of silica; Improves transparency; Used in television glass, optical glass, cathode ray tubes; Dosage varies by glass formulation; Replaces sodium carbonate for specialty glass.

Food Industry (E501): Use as acidity regulator and leavening agent; Cocoa processing (alkalization) – neutralizes acidity; Wine making – pH adjustment; Baking – leavening agent; Cheese production – pH control; Dosage depends on application; Follow food-grade specifications.

Fruit Dehydration: Use as drying accelerator; Grapes, pears, apples, apricots; Speeds up dehydration; Improves color and appearance; Apply as dilute solution (1-5%) before drying; Traditional for raisins and dried fruit.

Detergents & Cleaning: Use as builder and water softener; Phosphate-free detergents; Precipitates calcium and magnesium; Improves cleaning efficiency; Dosage 5-20% of formulation.

Agriculture: Use as potassium fertilizer; K₂O content ~68%; Provides essential potassium for plant growth; Improves crop yield and quality; Soil application; Foliar spray possible; Use as NK (Nitrogen-Potassium) fertilizer component.

Flue Gas Treatment: Use as CO₂ absorbent; Removes CO₂ from flue gases; ~98% CO₂ capture efficiency; Air purification; Acid gas scrubbing; Higher efficiency than amine-based systems; Used in combined cycle power plants.

Chemical Synthesis: Use as laboratory reagent; Potassium source for chemical reactions; Buffer solutions; CO₂ absorption; pH adjustment; Drying agent; Precipitating agent.

Handling: Use in well-ventilated areas; Avoid dust formation; Use dust masks (N95/FFP2) when handling powder; Use gloves and safety goggles.

Personal Protective Equipment: Dust mask (N95/FFP2 or higher), safety goggles, chemical-resistant gloves (nitrile, neoprene), protective clothing.

Hygiene: Wash hands thoroughly after handling; Do not eat, drink, or smoke while using.

Storage: Store in tightly closed, moisture-proof containers; Store in a cool, dry, well-ventilated area; Protect from moisture, acids, and CO₂; Opened containers must be resealed immediately; Shelf life: 24-36 months under proper conditions.

Spill Management: Sweep or vacuum (HEPA) and place in suitable sealed container; Avoid dust formation; Neutralize with dilute acid (if safe); Do not allow entry into drains or waterways.

Disposal: Dispose of in accordance with local, regional, and national regulations; Non-hazardous waste; Neutralize before disposal if required.

FOOD ADDITIVE E501 - SPECIAL NOTE:

Potassium carbonate (E501) is an approved food additive:

  • Approved Uses: Acidity regulator, leavening agent, stabilizer, thickener.

  • Food Products: Cocoa and chocolate products (alkalization), baked goods, wine, cheese, jams, confectionery, fruit processing.

  • Safety: EFSA approved; FDA GRAS; WHO JECFA approved (ADI: Not specified).

  • Maximum Usage: Good Manufacturing Practice (GMP) – no specific limit.

  • Labels: May be labeled as "Potassium carbonate" or "E501".

COMPARISON: POTASSIUM CARBONATE vs SODIUM CARBONATE:

Property Potassium Carbonate (K₂CO₃) Sodium Carbonate (Na₂CO₃)
Molecular Weight 138.21 105.99
Solubility (g/100g water) 111 21.5
pH (1% Solution) ~11.6 ~11.4
Hygroscopicity Very high (deliquescent) Moderate
K₂O / Na₂O Content 68% (K₂O) 58% (Na₂O)
Primary Use Specialty glass, food, fertilizers Glass, detergents, paper
Cost Higher Lower

LEGAL DISCLAIMER:
The information provided in this document is based on our current knowledge and experience and is presented in good faith. However, as all conditions of use are beyond our control, it does not constitute a binding specification or warranty. This Technical Data Sheet is for informational purposes only. Users are responsible for testing the suitability for their own applications. For complete safety, storage, use, handling, waste, and regulatory compliance information, please refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.

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