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Indian Standard Natural Rubber, Technically Specified Rubber, TSR, ISNR, ISNR 10, ISNR 20, 9006-04-6

Indian Standard Natural Rubber, Technically Specified Rubber, TSR, ISNR, ISNR 10, ISNR 20, 9006-04-6

INDIAN STANDARD NATURAL RUBBER (ISNR)

Indian Standard Natural Rubber / ISNR / ISNR 10 / ISNR 20 / Technically Specified Rubber / TSR
CAS Number: 9006-04-6
EINECS: 232-674-7

1. PRODUCT IDENTIFICATION AND CHEMICAL IDENTITY

Parameter Description
Product Name Indian Standard Natural Rubber (ISNR)
Other Names ISNR, Technically Specified Rubber (TSR), Natural Rubber (NR), Indian Rubber
CAS Number 9006-04-6
EINECS 232-674-7
Chemical Formula (C₅H₈)ₙ
Molecular Weight Variable (depends on degree of polymerization)
Chemical Class Natural rubber (polyisoprene)
Appearance Pressed bales, light to dark brown depending on grade
Odor Characteristic rubber odor
Density 0.92 - 0.94 g/cm³
Glass Transition Temperature (Tg) ~ -70°C
Standard IS 4588 (Indian Standard for Technically Specified Rubber)

Indian Standard Natural Rubber (ISNR) is a technically specified natural rubber (TSR) produced in India according to Indian Standard IS 4588, which is aligned with international standards (ISO 2000:2014). India is one of the world's largest producers of natural rubber, and ISNR grades are widely used in domestic and international markets. ISNR grades are classified based on technical specifications including dirt content, ash content, nitrogen content, volatile matter, plasticity, and Plasticity Retention Index (PRI). The grading system follows the TSR (Technically Specified Rubber) convention. The main ISNR grades are ISNR 10 (medium quality) and ISNR 20 (economic quality). ISNR grades are comparable to STR 10/20, SMR 10/20, SVR 10/20, and SIR 10/20 grades from other producing countries.

2. ISNR GRADES AND CLASSIFICATION

Grade Quality Level Dirt Content (max) Ash Content (max) Nitrogen Content (max) Volatile Matter (max) Mooney Viscosity Primary Applications
ISNR 10 Medium Quality 0.05% 0.75% 0.60% 0.80% 65 ± 5 Automotive tires, industrial rubber products, high-performance applications
ISNR 20 Economic Quality 0.20% 1.00% 0.60% 0.80% 60 ± 5 General-purpose tires, low-cost rubber products, economic applications

Grade Definitions:

  • ISNR 10 (Medium Quality): Medium quality grade with low dirt content (0.05%) and low ash content (0.75%). Used in automotive tires, industrial rubber products, high-performance applications, and applications requiring a balance of quality and cost. Mooney viscosity is 65 ± 5.

  • ISNR 20 (Economic Quality): Economic quality grade with higher dirt (0.20%) and ash (1.00%) content. Most cost-effective grade. Used in general-purpose tires, low-cost rubber products, and applications where cost is the primary consideration. Mooney viscosity is 60 ± 5.

3. TECHNICAL SPECIFICATIONS (IS 4588 / ISO 2000:2014)

Detailed Quality Parameters by Grade:

Parameter Unit ISNR 10 ISNR 20
Dirt Content (max) % wt 0.05 0.20
Ash Content (max) % wt 0.75 1.00
Nitrogen Content (max) % wt 0.60 0.60
Volatile Matter (max) % wt 0.80 0.80
Mooney Viscosity (ML 1+4 at 100°C) MU 65 ± 5 60 ± 5
Color - Light brown Darker brown
Packaging - Pressed bales, 33.33 kg Pressed bales, 33.33 kg

Explanation of Key Parameters:

  1. Dirt Content: Impurities such as sand, bark, and foreign matter. Lower is better for premium applications. ISNR 10 has lower dirt content (0.05%) compared to ISNR 20 (0.20%).

  2. Ash Content: Inorganic residue after combustion. Indicates mineral contamination. ISNR 10 has lower ash content (0.75%) compared to ISNR 20 (1.00%).

  3. Nitrogen Content: Protein content indicator. Both grades have a maximum of 0.60%.

  4. Volatile Matter: Moisture and volatiles. High levels can cause porosity in finished products. Both grades have a maximum of 0.80%.

  5. Mooney Viscosity: Resistance to flow. ISNR 10 has higher viscosity (65 ± 5) indicating higher molecular weight and better mechanical properties. ISNR 20 has lower viscosity (60 ± 5).

4. COMPARISON OF ISNR GRADES

Property ISNR 10 ISNR 20
Quality Level Medium Economic
Dirt Content Low (0.05%) Higher (0.20%)
Ash Content Low (0.75%) Higher (1.00%)
Mooney Viscosity 65 ± 5 60 ± 5
Color Light brown Darker brown
Price Moderate Lowest
Primary Applications Automotive tires, industrial products General-purpose tires, low-cost products

5. COMPARISON WITH OTHER NATURAL RUBBER GRADES

Grade Origin Characteristics Equivalence
ISNR 10 India Medium quality Comparable to STR 10 / SMR 10 / SVR 10 / SIR 10
ISNR 20 India Economic quality Comparable to STR 20 / SMR 20 / SVR 20 / SIR 20
STR 10 Thailand Medium quality Comparable to ISNR 10
SMR 10 Malaysia Medium quality Comparable to ISNR 10
SVR 10 Vietnam Medium quality Comparable to ISNR 10
SIR 10 Indonesia Medium quality Comparable to ISNR 10
STR 20 Thailand Standard quality Comparable to ISNR 20

TSR Naming Convention: The letters indicate country of origin (ISNR = India, STR = Thailand, SMR = Malaysia, SVR = Vietnam, SIR = Indonesia), and the number indicates the grade.

6. PHYSICAL AND CHEMICAL PROPERTIES

Property Value
Appearance Pressed bales, light to dark brown
Odor Characteristic rubber odor
Density 0.92 - 0.94 g/cm³
Glass Transition Temperature ~ -70°C
Mooney Viscosity (ML 1+4 at 100°C) 60-70 MU (grade dependent)
Color Light brown (ISNR 10) to darker brown (ISNR 20)
Service Temperature Range -50°C to +100°C

7. APPLICATIONS AND INDUSTRIAL USES

7.1. Tire Industry (Largest Application)

Application Recommended Grade
Automotive Tires - Passenger ISNR 10
Automotive Tires - Truck and Bus ISNR 10
General-Purpose Tires ISNR 20
OTR (Mining/Construction) Tires ISNR 20
Retreading ISNR 10

7.2. Industrial Rubber Products

Application Recommended Grade
Automotive Seals and Gaskets ISNR 10
Hoses and Tubing ISNR 10, ISNR 20
Conveyor Belts ISNR 10
V-Belts and Drive Belts ISNR 10
Anti-Vibration Mounts ISNR 10
Rubber Rollers ISNR 10

7.3. Footwear and Consumer Goods

Application Recommended Grade
Shoe Soles ISNR 10
Industrial Footwear ISNR 10, ISNR 20
Rubber Mats ISNR 20
Rubber Bands ISNR 10
Toys ISNR 10, ISNR 20

7.4. Specialty Applications

Application Recommended Grade
Light-colored Rubber Products ISNR 10
Adhesive Tapes ISNR 10

8. PACKAGING AND SHIPPING

Packaging Option Details
Bale Weight 33.33 kg
Bale Dimensions Standard block rubber dimensions
Pallet Configuration 36 bales/pallet = 1.26 MT
Pallet Type Wooden pallet, shrink-wrapped
Container Capacity (20-ft) 16 pallets = 20.16 MT
Container Type Standard 20-ft container

9. STORAGE AND HANDLING

Parameter Information
Storage Conditions Cool, dry, well-ventilated area; away from direct sunlight
Recommended Temperature Below 30°C
Humidity Avoid high humidity to prevent mold growth
Shelf Life 12-24 months under proper storage conditions
Handling Avoid contamination with oils, solvents, and dirt
Protection Keep bales covered and protected from moisture and dust
Stacking Maximum 4-5 pallets high for stable storage

10. SAFETY AND HEALTH INFORMATION

Parameter Information
Toxicity Non-toxic
Skin Irritation Non-irritant
Eye Irritation Mild irritant (dust)
Inhalation May cause respiratory irritation (dust)
Flammability Combustible (can burn)
Fire Extinguishing Media Water spray, foam, CO₂, dry chemical powder
Special Hazards Burning produces toxic fumes (CO, CO₂, SO₂)

11. FIRST AID MEASURES

Exposure Route Action
Inhalation Move person to fresh air. If irritation persists, seek medical attention.
Skin Contact Wash with soap and water. Remove contaminated clothing.
Eye Contact Rinse with plenty of water for at least 15 minutes. Seek medical attention if irritation persists.
Ingestion Rinse mouth. Do NOT induce vomiting. Seek medical attention if large amounts are swallowed.

12. REGULATORY INFORMATION

Region Status
EU REACH registered
Turkey (KKDİK) Mandatory compliance; requires registration
USA (TSCA) Listed
Canada (DSL) Listed
Australia (AICS) Listed
Japan (ENCS) Listed
Korea (KECL) Listed
China (IECSC) Listed

Regulatory Status:

Status Information
HS Code 40012200 (Technically Specified Natural Rubber)
CAS Number 9006-04-6
EINECS 232-674-7
IARC Classification Not classified
WGK Germany 1 (slight hazard to water)
Indian Standard IS 4588

13. OTHER NAMES AND DATABASE IDENTIFIERS

Category Names / Identifiers
Product Names Indian Standard Natural Rubber, ISNR, Indian Rubber, Natural Rubber
Grade Names ISNR 10, ISNR 20
Common Names TSR (Technically Specified Rubber), NR
Country Equivalents ISNR (India), STR (Thailand), SMR (Malaysia), SVR (Vietnam), SIR (Indonesia)

Database Identifiers:

Database Identifier
CAS 9006-04-6
EINECS 232-674-7
HS Code 40012200

14. HS CODE AND CUSTOMS INFORMATION

Grade Material HS Code
ISNR 10 4001.2210 / 4001.2220
ISNR 20 4001.2210 / 4001.2220

15. QUALITY CONTROL PARAMETERS

Parameter Test Method Significance
Dirt Content Sieve Analysis Purity level; impacts surface finish and processing
Ash Content Ignition Inorganic contamination
Nitrogen Content Kjeldahl Method Protein content; affects aging
Volatile Matter Oven Drying Moisture content; affects processability
Mooney Viscosity Mooney Viscometer Processing consistency
Color Visual Inspection Quality indicator

16. SELECTION GUIDE FOR ISNR GRADES

Application Recommended Grade
Automotive tires, high-performance products ISNR 10
General-purpose tires, low-cost products ISNR 20
Industrial rubber products ISNR 10
Light-colored rubber products ISNR 10
Footwear and consumer goods ISNR 10, ISNR 20

17. INDUSTRY SUITABILITY TABLE

Industry Applications Recommended Grade Suitability
Tire Industry Automotive tires ISNR 10 High
Tire Industry General-purpose tires ISNR 20 High
Industrial Products Seals, hoses, conveyor belts ISNR 10 High
Footwear Shoe soles ISNR 10, ISNR 20 High
Specialty Light-colored products ISNR 10 High
Consumer Mats, toys, rubber bands ISNR 10, ISNR 20 High

18. PRODUCTION PROCESS

ISNR is produced from natural rubber latex through a standardized process:

  1. Latex Collection: Latex is tapped from Hevea brasiliensis trees in India (primarily Kerala, Tamil Nadu, and Karnataka).

  2. Coagulation: Latex is coagulated using formic acid or acetic acid.

  3. Milling: Coagulum is milled to remove water and impurities.

  4. Drying: Rubber is dried in hot air ovens.

  5. Baling: Dried rubber is compressed into bales (33.33 kg).

  6. Grading: Bales are graded based on technical specifications (IS 4588).

19. ADVANTAGES AND LIMITATIONS OF ISNR

Advantages Limitations
Technically specified (consistent quality) Poor ozone resistance
Standardized specifications ensure consistency Poor oil and fuel resistance
Wide range of grades for different applications Susceptible to oxidation at high temperatures
Good mechanical properties Requires proper storage to prevent mold growth
Competitive pricing (especially ISNR 20) Lower grades have darker color
Widely accepted in domestic and international markets  

20. SUMMARY AND CRITICAL WARNINGS

SUMMARY:

Indian Standard Natural Rubber (ISNR) is a technically specified natural rubber produced in India according to Indian Standard IS 4588, aligned with ISO 2000:2014. The main grades are ISNR 10 (medium quality, dirt content 0.05%, Mooney viscosity 65 ± 5) and ISNR 20 (economic quality, dirt content 0.20%, Mooney viscosity 60 ± 5). ISNR 10 is used in automotive tires, industrial rubber products, and high-performance applications. ISNR 20 is used in general-purpose tires, low-cost rubber products, and economic applications. India is one of the world's largest producers of natural rubber. ISNR grades are comparable to STR, SMR, SVR, and SIR grades from other producing countries. Packaging: 33.33 kg bales, 36 bales/pallet (1.26 MT), 16 pallets/20-ft container (20.16 MT). Certified by ISO 9001:2015 and the Indian Rubber Board. HS Code: 40012200.

Key Properties:

Property Value
Appearance Pressed bales, light to dark brown
CAS Number 9006-04-6
Density 0.92 - 0.94 g/cm³
Primary Grades ISNR 10, ISNR 20
Primary Use Tires, industrial products, footwear

Major Application Areas:

Industry Applications
Tire Industry Automotive, general-purpose tires
Industrial Products Seals, hoses, conveyor belts
Footwear Shoe soles
Specialty Light-colored products
Consumer Mats, toys, rubber bands

Key Safety Points:

  • NON-TOXIC: Generally safe for handling

  • COMBUSTIBLE: Can burn; keep away from ignition sources

  • STORAGE: Store in cool, dry, well-ventilated area; avoid direct sunlight and high humidity

  • PPE RECOMMENDED: Dust mask, safety goggles, protective gloves (for handling)

  • PROTECT: Keep away from oils, solvents, and contaminants

CRITICAL WARNINGS:

  • ISNR grades are classified by technical specifications (IS 4588) rather than visual inspection, ensuring consistent quality.

  • ISNR 10 offers a balance of quality and price with low dirt (0.05%) and moderate Mooney viscosity (65 ± 5).

  • ISNR 20 provides cost advantage with higher dirt (0.20%) and lower Mooney viscosity (60 ± 5).

  • India is one of the world's largest producers of natural rubber, and ISNR grades are widely used in domestic and international markets.

  • ISNR grades are comparable to STR 10/20, SMR 10/20, SVR 10/20, and SIR 10/20 from other producing countries.

  • Store away from direct sunlight and heat sources to prevent degradation and maintain quality.

  • Contamination with oils or solvents can significantly affect rubber performance.

  • ISNR is certified by ISO 9001:2015 and the Indian Rubber Board, ensuring quality and consistency.

Important Disclaimer: This Technical Data Sheet (TDS) is for informational purposes only. The information provided is based on available data and is believed to be accurate. However, the user is solely responsible for determining the suitability of the product for their specific application and for complying with all applicable regulations and safety requirements. For complete safety, handling, storage, and regulatory compliance information, always refer to the official Safety Data Sheet (SDS/MSDS) provided by the manufacturer/supplier.


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